ES2836679T3 - Procedimiento para separar partículas que contienen sales metálicas alcalinas de hidrocarburos líquidos - Google Patents
Procedimiento para separar partículas que contienen sales metálicas alcalinas de hidrocarburos líquidos Download PDFInfo
- Publication number
- ES2836679T3 ES2836679T3 ES17784812T ES17784812T ES2836679T3 ES 2836679 T3 ES2836679 T3 ES 2836679T3 ES 17784812 T ES17784812 T ES 17784812T ES 17784812 T ES17784812 T ES 17784812T ES 2836679 T3 ES2836679 T3 ES 2836679T3
- Authority
- ES
- Spain
- Prior art keywords
- alkali metal
- mixture
- sulfur
- liquid hydrocarbon
- optionally
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000007788 liquid Substances 0.000 title claims abstract 25
- 229930195733 hydrocarbon Natural products 0.000 title claims abstract 21
- 150000002430 hydrocarbons Chemical class 0.000 title claims abstract 19
- 238000000034 method Methods 0.000 title claims abstract 19
- 239000002245 particle Substances 0.000 title claims abstract 15
- 229910052783 alkali metal Inorganic materials 0.000 title claims 20
- -1 alkali metal salts Chemical class 0.000 title claims 6
- 239000000203 mixture Substances 0.000 claims abstract 30
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract 20
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract 14
- 229910052717 sulfur Inorganic materials 0.000 claims abstract 10
- 239000011593 sulfur Substances 0.000 claims abstract 10
- 229910052977 alkali metal sulfide Inorganic materials 0.000 claims abstract 8
- 239000007787 solid Substances 0.000 claims abstract 6
- 238000010438 heat treatment Methods 0.000 claims abstract 3
- 150000001340 alkali metals Chemical class 0.000 claims 14
- 239000002006 petroleum coke Substances 0.000 claims 10
- 239000000126 substance Substances 0.000 claims 8
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims 4
- 239000003795 chemical substances by application Substances 0.000 claims 4
- 239000000446 fuel Substances 0.000 claims 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims 3
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims 3
- 229910000037 hydrogen sulfide Inorganic materials 0.000 claims 3
- 239000002002 slurry Substances 0.000 claims 3
- 239000000725 suspension Substances 0.000 claims 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 2
- 229910021529 ammonia Inorganic materials 0.000 claims 2
- 238000001914 filtration Methods 0.000 claims 2
- 239000010763 heavy fuel oil Substances 0.000 claims 2
- 229910052739 hydrogen Inorganic materials 0.000 claims 2
- 239000001257 hydrogen Substances 0.000 claims 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical class CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims 2
- 229910052708 sodium Inorganic materials 0.000 claims 2
- 239000011734 sodium Substances 0.000 claims 2
- 229910052979 sodium sulfide Inorganic materials 0.000 claims 2
- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 claims 2
- 150000003464 sulfur compounds Chemical class 0.000 claims 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims 1
- 235000011054 acetic acid Nutrition 0.000 claims 1
- 239000000956 alloy Substances 0.000 claims 1
- 229910045601 alloy Inorganic materials 0.000 claims 1
- 239000010426 asphalt Substances 0.000 claims 1
- 238000005119 centrifugation Methods 0.000 claims 1
- 239000010779 crude oil Substances 0.000 claims 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims 1
- 238000001035 drying Methods 0.000 claims 1
- 235000019253 formic acid Nutrition 0.000 claims 1
- 229910003480 inorganic solid Inorganic materials 0.000 claims 1
- 239000000543 intermediate Substances 0.000 claims 1
- 229910052744 lithium Inorganic materials 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 150000002739 metals Chemical class 0.000 claims 1
- DUWWHGPELOTTOE-UHFFFAOYSA-N n-(5-chloro-2,4-dimethoxyphenyl)-3-oxobutanamide Chemical compound COC1=CC(OC)=C(NC(=O)CC(C)=O)C=C1Cl DUWWHGPELOTTOE-UHFFFAOYSA-N 0.000 claims 1
- 235000019260 propionic acid Nutrition 0.000 claims 1
- HYHCSLBZRBJJCH-UHFFFAOYSA-M sodium hydrosulfide Chemical compound [Na+].[SH-] HYHCSLBZRBJJCH-UHFFFAOYSA-M 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
- 239000008096 xylene Substances 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
- C10G29/02—Non-metals
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
- C10G29/04—Metals, or metals deposited on a carrier
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G53/00—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more refining processes
- C10G53/02—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more refining processes plural serial stages only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/20—Characteristics of the feedstock or the products
- C10G2300/201—Impurities
- C10G2300/202—Heteroatoms content, i.e. S, N, O, P
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/20—Characteristics of the feedstock or the products
- C10G2300/201—Impurities
- C10G2300/205—Metal content
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Peptides Or Proteins (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201662404119P | 2016-10-04 | 2016-10-04 | |
| US15/446,299 US20170253816A1 (en) | 2016-03-03 | 2017-03-01 | Method for recovering alkali metal from hydrocarbon feedstocks treated with alkali metal |
| US201762513871P | 2017-06-01 | 2017-06-01 | |
| PCT/US2017/055213 WO2018067753A1 (en) | 2016-10-04 | 2017-10-04 | Process for separating particles containing alkali metal salts from liquid hydrocarbons |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2836679T3 true ES2836679T3 (es) | 2021-06-28 |
Family
ID=61831294
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES17784812T Active ES2836679T3 (es) | 2016-10-04 | 2017-10-04 | Procedimiento para separar partículas que contienen sales metálicas alcalinas de hidrocarburos líquidos |
Country Status (8)
| Country | Link |
|---|---|
| EP (1) | EP3523396B1 (de) |
| JP (1) | JP6817656B2 (de) |
| KR (1) | KR102211995B1 (de) |
| CN (1) | CN109890944B (de) |
| CA (1) | CA3039380C (de) |
| ES (1) | ES2836679T3 (de) |
| SG (1) | SG11201902990UA (de) |
| WO (1) | WO2018067753A1 (de) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP4153706A1 (de) * | 2020-05-19 | 2023-03-29 | Enlighten Innovations Inc. | Reinigungs- und umwandlungsverfahren für asphaltenhaltige einsatzstoffe |
| US20240018424A1 (en) * | 2020-05-19 | 2024-01-18 | Enlighten Innovations Inc. | Processes for improved performance of downstream oil conversion |
| EP4227384A4 (de) * | 2020-10-19 | 2024-04-10 | China Petroleum & Chemical Corporation | Verfahren und system zur herstellung von heizöl und verwendung davon sowie heizöl und verwendung davon |
| US20230089806A1 (en) * | 2021-09-17 | 2023-03-23 | Enlighten Innovations Inc. | Compositions and methods for making carbon fibers from asphaltenes |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1300816A (en) * | 1915-09-11 | 1919-04-15 | Standard Oil Co | Process of desulfurizing petroleum-oils. |
| US3791966A (en) * | 1972-05-24 | 1974-02-12 | Exxon Research Engineering Co | Alkali metal desulfurization process for petroleum oil stocks |
| US3849297A (en) * | 1972-06-08 | 1974-11-19 | Exxon Research Engineering Co | Process for removing metals from petroleum residua |
| US3904511A (en) * | 1973-10-05 | 1975-09-09 | Mobil Oil Corp | Process for eliminating unstable hydrogen from lubricating oil stock |
| US6210564B1 (en) * | 1996-06-04 | 2001-04-03 | Exxon Research And Engineering Company | Process for desulfurization of petroleum feeds utilizing sodium metal |
| WO2009070593A1 (en) * | 2007-11-27 | 2009-06-04 | Ceramatec, Inc. | Process for recovering alkali metals and sulfur from alkali metal sulfides and polysulfides |
| US9475998B2 (en) * | 2008-10-09 | 2016-10-25 | Ceramatec, Inc. | Process for recovering alkali metals and sulfur from alkali metal sulfides and polysulfides |
| US20160053185A1 (en) * | 2009-11-02 | 2016-02-25 | Field Upgrading Limited | Process to separate alkali metal salts from alkali metal reacted hydrocarbons |
| ES2656073T3 (es) | 2009-11-02 | 2018-02-23 | Field Upgrading Limited | Mejoramiento de materias primas de petróleo que usan metales alcalinos e hidrocarburos |
| US9688920B2 (en) * | 2009-11-02 | 2017-06-27 | Field Upgrading Limited | Process to separate alkali metal salts from alkali metal reacted hydrocarbons |
| DE102011013470A1 (de) * | 2010-07-26 | 2012-01-26 | L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude | Verfahren und Mittel zur Entfernung von Metallen aus hochsiedenden Kohlenwasserstofffraktionen |
| CA2863357C (en) * | 2012-02-03 | 2018-10-16 | Ceramatec, Inc. | Process for desulfurizing petroleum feedstocks |
| MX379295B (es) * | 2013-04-15 | 2025-03-11 | Field Upgrading Ltd | Proceso para separar sales de metales alcalinos de hidrocarburos de reaccion con metales alcalinos. |
-
2017
- 2017-10-04 CA CA3039380A patent/CA3039380C/en active Active
- 2017-10-04 SG SG11201902990UA patent/SG11201902990UA/en unknown
- 2017-10-04 ES ES17784812T patent/ES2836679T3/es active Active
- 2017-10-04 JP JP2019539740A patent/JP6817656B2/ja active Active
- 2017-10-04 EP EP17784812.4A patent/EP3523396B1/de active Active
- 2017-10-04 KR KR1020197012851A patent/KR102211995B1/ko active Active
- 2017-10-04 WO PCT/US2017/055213 patent/WO2018067753A1/en not_active Ceased
- 2017-10-04 CN CN201780067716.5A patent/CN109890944B/zh active Active
Also Published As
| Publication number | Publication date |
|---|---|
| JP6817656B2 (ja) | 2021-01-20 |
| EP3523396A1 (de) | 2019-08-14 |
| CA3039380A1 (en) | 2018-04-12 |
| WO2018067753A1 (en) | 2018-04-12 |
| KR102211995B1 (ko) | 2021-02-05 |
| EP3523396B1 (de) | 2020-11-25 |
| SG11201902990UA (en) | 2019-05-30 |
| CN109890944B (zh) | 2020-07-03 |
| JP2019536883A (ja) | 2019-12-19 |
| CN109890944A (zh) | 2019-06-14 |
| CA3039380C (en) | 2023-02-28 |
| KR20190058616A (ko) | 2019-05-29 |
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