ES2678086T3 - Compuestos de diona cíclicos (alquil-fenil)-sustituidos activos como herbicidas y derivados de los mismos - Google Patents

Compuestos de diona cíclicos (alquil-fenil)-sustituidos activos como herbicidas y derivados de los mismos Download PDF

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ES2678086T3
ES2678086T3 ES14730476T ES14730476T ES2678086T3 ES 2678086 T3 ES2678086 T3 ES 2678086T3 ES 14730476 T ES14730476 T ES 14730476T ES 14730476 T ES14730476 T ES 14730476T ES 2678086 T3 ES2678086 T3 ES 2678086T3
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alkyl
ring
fluoroalkyl
alkoxy
cycloalkyl
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Janice Black
James Nicholas Scutt
Louisa WHALLEY
Nigel James WILLETS
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Syngenta Ltd
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  • Organic Chemistry (AREA)
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  • Life Sciences & Earth Sciences (AREA)
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  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)
  • Thiazole And Isothizaole Compounds (AREA)
  • Epoxy Compounds (AREA)
  • Pyrane Compounds (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)

Abstract

Un compuesto de fórmula (I) **Fórmula** en donde: X es metilo o cloro; R1 es flúor o bromo; R2 es etinilo, alcoxiC1-C3-, haloalcoxiC1-C3- o alcoxiC1-C3-alcoxiC1-C3-; y Q es un grupo de fórmula Q2: **Fórmula** en donde en Q2: 33 y R36, independientemente entre sí, son hidrógeno, alquiloC1-C5, alqueniloC2-C4, alquiniloC2-C4, fluoroalquiloC1- C2, alcoxiC1-C3alquiloC1-C3, alquilC1-C3tioalquiloC1-C3, alquilC1-C3sulfinilalquiloC1-C3, alquilC1-C3sulfonilalquiloC1-C3, cicloalquiloC3-C4, o un heterociclilo monocíclico de 4, 5 o 6 miembros insustituido que tiene un heteroátomo del anillo que se selecciona independientemente de oxígeno, azufre y nitrógeno, estando dicho heterociclilo unido a un átomo de carbono del anillo dentro del heterociclilo; siempre que no más de uno de R33 y R36 sea alquenilo, alquinilo, alcoxialquilo, alquiltioalquilo, alquilsulfinilalquilo, alquilsulfonilalquilo, cicloalquilo o heterociclilo; y 34 y R35 tomados juntos son -(CH2)n34- o -(CH2)n35-C(R37a)(R37b)-(CH2)n36-; n donde R37a es alquiloC1-C2; 37b es hidrógeno o alquiloC1-C2; 34 es 1, 2 o 3; y 35 y n36 son independientemente 0, 1 o 2 siempre que n35 + n36 sea 0, 1 o 2; e Y es O, , S(O), S(O)2, N(alquilC1-C2), N(alcoxiC1-C2), C(O), CR38R39 o -CR310R311CR312R313-; y R38 y R39 son, independientemente entre sí: hidrógeno, alquiloC1-C6, alqueniloC2-C4, alquiniloC2-C4, fluoroalquiloC1-C2, alcoxiC1-C3alquiloC1-C3, alquilC1-C3tioalquiloC1-C3, alquilC1-C3sulfinilalquiloC1-C3 o alquilC1-C3sulfonilalquiloC1- C3; cicloalquiloC3-C6 o cicloalquiloC3-C6 sustituido por uno o dos sustituyentes que independientemente son alquiloC1-C3 o fluoroalquiloC1-C2, y en donde un resto CH2 del anillo de un cicloalquiloC4-C6 se reemplaza opcionalmente por un átomo de oxígeno o azufre o por un resto S(O), S(O)2, NH, N(alquiloC1-C3), N(fluoroalquiloC1- C2), N[C(O)alquiloC1-C3], N[C(O)fluoroalquiloC1-C2] o N(alcoxiC1-C2); cicloalquiloC3-C6 sustituido por un sustituyente que es alcoxiC1-C3 y opcionalmente sustituido adicionalmente por un sustituyente que es alquiloC1-C2; cicloalqueniloC5-C6 o cicloalqueniloC5-C6 sustituido por uno o dos alquiloC1-C3 sustituyentes; cicloalquilC3- C6alquiloC1-C2- o cicloalquilC3-C6alquiloC1-C2- sustituido por uno o dos sustituyentes del anillo que independientemente son alquiloC1-C3 o fluoroalquiloC1-C2, y en donde un resto CH2 del anillo de un cicloalquilC4- C6alquiloC1-C2- se reemplaza opcionalmente por un átomo de oxígeno o azufre o por un resto S(O), S(O)2, NH, N(alquilC1-C2), N(fluoroalquiloC1-C2), N[C(O)alquiloC1-C3], N[C(O)fluoroalquiloC1-C2] o N(alcoxiC1-C2); cicloalquilC3- C6alquiloC1-C2- sustituido por un sustituyente del anillo que es alcoxiC1-C3 y opcionalmente sustituido adicionalmente por un sustituyente del anillo que es alquiloC1-C2; o HetA o HetA-CH2-; en donde HetA es un heteroarilo, unido a un carbono del anillo, que está opcionalmente sustituido por 1, 2 o 3 sustituyentes del carbono del anillo que son independientemente alquiloC1-C3, fluoroalquiloC1-C2, alquilC1-C3-C(O)-, fluoroalquiloC1-C2-C(O)-, -C(O)-N(R6H)(R6J), SR6E, S(O)R6E, -S(O)2-R6E, -N(R6F)(R6G), hidroxi, alqueniloC2-C3, - C(R6BB)>=C(R6C1)(R6C2), alquiniloC2-C3, -C≡, alcoxiC1-C3, fluoroalcoxiC1-C2, ciclopropiloxi, CH2>=CH-CH2-O-, HC≡, halógeno, ciano o nitro; y/o, en el caso de un anillo heteroarilo de 5 miembros que contiene un átomo de nitrógeno del anillo que no participa en un enlace doble del anillo C>=N, el heteroarilo está opcionalmente sustituido en el átomo de nitrógeno del anillo que no participa en un enlace doble del anillo C>=N por un sustituyente alquiloC1-C3, fluoroalquiloC1-C2, alquilC1-C3-C(O)-, fluoroalquiloC1-C2-C(O)- o alquiloC1-C2-S(O)2-; siempre que no más de uno de R38 y R39 sea un cicloalquilo opcionalmente sustituido, un cicloalquilo opcionalmente 20 sustituido en donde un resto CH2 del anillo ha sido reemplazado por un átomo de oxígeno o azufre o por un resto S(O), S(O)2, NH, N(alquiloC1-C3), N(fluoroalquiloC1-C2), N[C(O)alquiloC1-C3], N[C(O)fluoroalquiloC1-C2] o N(alcoxiC1- C2); un cicloalquenilo opcionalmente sustituido, un cicloalquil-alquilo- opcionalmente sustituido, un cicloalquil-alquilo- opcionalmente sustituido en donde un resto CH2 del anillo ha sido reemplazado por un átomo de oxígeno o azufre o por un resto S(O), S(O)2, NH, N(alquiloC1-C2), N(fluoroalquiloC1-C2), N[C(O)alquiloC1-C3], N[C(O)fluoroalquiloC1-C2] 25 o N(alcoxiC1-C2), o HetA o HetA-CH2-;
ES14730476T 2013-05-30 2014-05-29 Compuestos de diona cíclicos (alquil-fenil)-sustituidos activos como herbicidas y derivados de los mismos Active ES2678086T3 (es)

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GB201309679A GB201309679D0 (en) 2013-05-30 2013-05-30 Herbicidally active cyclic diones
GB201322855A GB201322855D0 (en) 2013-12-23 2013-12-23 Compounds
PCT/EP2014/061207 WO2014191535A1 (en) 2013-05-30 2014-05-29 Herbicidally active (alkynyl-phenyl)-substituted cyclic dione compounds and derivatives thereof

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ES14727003.7T Active ES2666119T3 (es) 2013-05-30 2014-05-29 Compuestos de diona cíclicos (alquil-fenil)-sustituidos activos como herbicidas y derivados de los mismos

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US (2) US10590143B2 (es)
EP (2) EP3004052B1 (es)
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Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
UA115160C2 (uk) * 2012-12-21 2017-09-25 Сінгента Лімітед Гербіцидно активні циклічні діонові сполуки або їхні похідні, заміщені фенілом із замісником, що містить алкініл
ES2678086T3 (es) * 2013-05-30 2018-08-08 Syngenta Limited Compuestos de diona cíclicos (alquil-fenil)-sustituidos activos como herbicidas y derivados de los mismos
GB201411418D0 (en) * 2014-06-26 2014-08-13 Syngenta Participations Ag Compounds
BR112017012917A2 (pt) * 2014-12-18 2018-03-13 Nissan Chemical Industries, Ltd. ?composto de cetona ou oxima ou sal do mesmo; produto químico agrícola e herbicida obtido do mesmo?
GB201621626D0 (en) * 2016-12-19 2017-02-01 Syngenta Participations Ag Improvements in or relating to organic compounds
CN106674264A (zh) * 2016-12-20 2017-05-17 苏州汉德创宏生化科技有限公司 (2,2,2‑三氟乙氧基)苯硼酸类化合物的合成方法
GB201802558D0 (en) 2018-02-16 2018-04-04 Syngenta Participations Ag Improvements in or relating to organic compounds
GB201803736D0 (en) * 2018-03-08 2018-04-25 Syngenta Participations Ag Improvements in or relating to organic compounds
GB201901878D0 (en) 2019-02-11 2019-04-03 Syngenta Crop Protection Ag Improvements in or relating to organic compounds
GB201901961D0 (en) 2019-02-13 2019-04-03 Syngenta Crop Protection Ag Improvements in or relating to organic compounds
GB201910168D0 (en) 2019-07-16 2019-08-28 Syngenta Crop Protection Ag Improvements in or relating to organic compounds
NZ784711A (en) 2019-07-30 2025-11-28 Taisho Pharmaceutical Co Ltd Urea compound for antagonizing lpa1 receptor
GB201910926D0 (en) 2019-07-31 2019-09-11 Syngenta Crop Protection Ag Improvements in or relating to organic compounds
GB201910940D0 (en) * 2019-07-31 2019-09-11 Syngenta Crop Protection Ag Improvements in or relating to oranic compounds
CN111960974A (zh) * 2020-08-28 2020-11-20 山东潍坊润丰化工股份有限公司 一种烯草酮中间体的合成方法
CN111960977A (zh) * 2020-08-28 2020-11-20 山东潍坊润丰化工股份有限公司 一种烯草酮中间体的绿色合成方法
WO2023203567A1 (en) * 2022-04-18 2023-10-26 Willowood Chemicals Limited Herbicidal composition comprising of cyclohexanedione, pyrimidinyl benzoate and diphenyl ether compound
CN116554487B (zh) * 2023-03-13 2025-05-13 江西中医药大学 一种苯脲类除草剂吸附用的MOFs材料及其制备和应用

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DK1209973T3 (da) * 1999-09-07 2004-06-21 Syngenta Participations Ag Herbicidt middel
DE10139465A1 (de) 2001-08-10 2003-02-20 Bayer Cropscience Ag Selektive Herbizide auf Basis von substituierten, cayclischen Ketoenolen und Safenern
GB0230155D0 (en) * 2002-12-24 2003-02-05 Syngenta Participations Ag Chemical compounds
DE102005059471A1 (de) * 2005-12-13 2007-07-12 Bayer Cropscience Ag Herbizide Zusammensetzungen mit verbesserter Wirkung
GB0704653D0 (en) 2007-03-09 2007-04-18 Syngenta Participations Ag Novel herbicides
GB0704652D0 (en) * 2007-03-09 2007-04-18 Syngenta Participations Ag Novel herbicides
GB0710223D0 (en) * 2007-05-29 2007-07-11 Syngenta Ltd Novel Herbicides
GB0715576D0 (en) 2007-08-09 2007-09-19 Syngenta Ltd Novel herbicides
GB0812310D0 (en) 2008-07-03 2008-08-13 Syngenta Ltd Novel herbicides
GB0819205D0 (en) * 2008-10-20 2008-11-26 Syngenta Ltd Novel herbicides
WO2010081689A2 (en) 2009-01-19 2010-07-22 Bayer Cropscience Ag Cyclic diones and their use as insecticides, acaricides and/or fungicides
GB0901835D0 (en) * 2009-02-04 2009-03-11 Syngenta Ltd Novel herbicides
GB201117019D0 (en) * 2011-10-04 2011-11-16 Syngenta Ltd Herbicidal compounds
EP2512237A2 (en) 2009-12-18 2012-10-24 Syngenta Participations AG 2 -aryl-3 -hydroxy-cyclopentenones as insecticides, acaricides, nematocides and molluscicides
CN103003239A (zh) * 2010-05-31 2013-03-27 先正达参股股份有限公司 基于螺杂环吡咯烷衍生物的杀虫剂
HRP20161297T1 (hr) 2011-11-30 2016-11-18 Syngenta Limited 2-(supstituirani-fenil)-ciklopentan-1,3-dion spojevi, i njihovi derivati
GB201120644D0 (en) 2011-11-30 2012-01-11 Syngenta Participations Ag Herbicidal uses of compounds
UA115160C2 (uk) * 2012-12-21 2017-09-25 Сінгента Лімітед Гербіцидно активні циклічні діонові сполуки або їхні похідні, заміщені фенілом із замісником, що містить алкініл
ES2678086T3 (es) * 2013-05-30 2018-08-08 Syngenta Limited Compuestos de diona cíclicos (alquil-fenil)-sustituidos activos como herbicidas y derivados de los mismos
GB201411418D0 (en) * 2014-06-26 2014-08-13 Syngenta Participations Ag Compounds

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