ES2668071T3 - Composición química para la producción de partículas de vidrio esféricas huecas con alta resistencia compresiva - Google Patents
Composición química para la producción de partículas de vidrio esféricas huecas con alta resistencia compresiva Download PDFInfo
- Publication number
- ES2668071T3 ES2668071T3 ES15201520.2T ES15201520T ES2668071T3 ES 2668071 T3 ES2668071 T3 ES 2668071T3 ES 15201520 T ES15201520 T ES 15201520T ES 2668071 T3 ES2668071 T3 ES 2668071T3
- Authority
- ES
- Spain
- Prior art keywords
- hollow spherical
- spherical glass
- weight
- metal
- glass particle
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000002245 particle Substances 0.000 title claims abstract description 79
- 239000011521 glass Substances 0.000 title claims abstract description 74
- 239000000203 mixture Substances 0.000 title claims description 13
- 238000004519 manufacturing process Methods 0.000 title description 8
- 239000000126 substance Substances 0.000 title description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 11
- 235000012239 silicon dioxide Nutrition 0.000 claims abstract description 11
- 229910044991 metal oxide Inorganic materials 0.000 claims abstract description 8
- 150000004706 metal oxides Chemical class 0.000 claims abstract description 8
- 229910000272 alkali metal oxide Inorganic materials 0.000 claims abstract description 7
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical group [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910052681 coesite Inorganic materials 0.000 claims abstract description 6
- 229910052906 cristobalite Inorganic materials 0.000 claims abstract description 6
- 229910052682 stishovite Inorganic materials 0.000 claims abstract description 6
- 229910052905 tridymite Inorganic materials 0.000 claims abstract description 6
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical group [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910052796 boron Inorganic materials 0.000 claims abstract description 4
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims abstract description 4
- 150000001340 alkali metals Chemical group 0.000 claims abstract description 3
- 150000001342 alkaline earth metals Chemical group 0.000 claims abstract 2
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 12
- 239000000945 filler Substances 0.000 claims description 12
- 239000006260 foam Substances 0.000 claims description 11
- 239000011159 matrix material Substances 0.000 claims description 10
- 238000002844 melting Methods 0.000 claims description 10
- 230000008018 melting Effects 0.000 claims description 10
- 229910052751 metal Inorganic materials 0.000 claims description 8
- 239000002184 metal Substances 0.000 claims description 8
- 229910052782 aluminium Inorganic materials 0.000 claims description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 5
- 229910000838 Al alloy Inorganic materials 0.000 claims description 3
- 229910000287 alkaline earth metal oxide Inorganic materials 0.000 claims description 3
- 101100055113 Caenorhabditis elegans aho-3 gene Proteins 0.000 claims description 2
- 229910001092 metal group alloy Inorganic materials 0.000 claims 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract description 3
- 229910052593 corundum Inorganic materials 0.000 abstract 1
- 229910001845 yogo sapphire Inorganic materials 0.000 abstract 1
- 239000004005 microsphere Substances 0.000 description 10
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 description 7
- 229910001948 sodium oxide Inorganic materials 0.000 description 7
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 6
- 239000008187 granular material Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 4
- 229910001950 potassium oxide Inorganic materials 0.000 description 4
- 239000004115 Sodium Silicate Substances 0.000 description 3
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 3
- 229910052911 sodium silicate Inorganic materials 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 239000004111 Potassium silicate Substances 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 2
- 229910000323 aluminium silicate Inorganic materials 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 2
- 239000004327 boric acid Substances 0.000 description 2
- 150000001639 boron compounds Chemical class 0.000 description 2
- 239000000292 calcium oxide Substances 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000010433 feldspar Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- FUJCRWPEOMXPAD-UHFFFAOYSA-N lithium oxide Chemical compound [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 229910000027 potassium carbonate Inorganic materials 0.000 description 2
- 229910052913 potassium silicate Inorganic materials 0.000 description 2
- 235000019353 potassium silicate Nutrition 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 231100000167 toxic agent Toxicity 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000010457 zeolite Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000012669 compression test Methods 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- XUCJHNOBJLKZNU-UHFFFAOYSA-M dilithium;hydroxide Chemical compound [Li+].[Li+].[OH-] XUCJHNOBJLKZNU-UHFFFAOYSA-M 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000012774 insulation material Substances 0.000 description 1
- 229910001947 lithium oxide Inorganic materials 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- -1 metacaolin Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 239000006262 metallic foam Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical compound [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000012798 spherical particle Substances 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B19/00—Other methods of shaping glass
- C03B19/08—Other methods of shaping glass by foaming
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C11/00—Multi-cellular glass ; Porous or hollow glass or glass particles
- C03C11/002—Hollow glass particles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D25/00—Special casting characterised by the nature of the product
- B22D25/005—Casting metal foams
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B19/00—Other methods of shaping glass
- C03B19/10—Forming beads
- C03B19/107—Forming hollow beads
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B19/00—Other methods of shaping glass
- C03B19/10—Forming beads
- C03B19/108—Forming porous, sintered or foamed beads
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/083—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/083—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound
- C03C3/085—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound containing an oxide of a divalent metal
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/10—Production of cement, e.g. improving or optimising the production methods; Cement grinding
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Glass Compositions (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP15201520.2A EP3184494B1 (en) | 2015-12-21 | 2015-12-21 | Chemical composition for production of hollow spherical glass particles with high compressive strength |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2668071T3 true ES2668071T3 (es) | 2018-05-16 |
Family
ID=55083292
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES15201520.2T Active ES2668071T3 (es) | 2015-12-21 | 2015-12-21 | Composición química para la producción de partículas de vidrio esféricas huecas con alta resistencia compresiva |
| ES16826026T Active ES2804777T3 (es) | 2015-12-21 | 2016-12-20 | Composición química para la producción de partículas de vidrio esféricas huecas con elevada resistencia a la compresión |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES16826026T Active ES2804777T3 (es) | 2015-12-21 | 2016-12-20 | Composición química para la producción de partículas de vidrio esféricas huecas con elevada resistencia a la compresión |
Country Status (18)
| Country | Link |
|---|---|
| US (3) | US10414689B2 (OSRAM) |
| EP (3) | EP3184494B1 (OSRAM) |
| CN (1) | CN108463438B (OSRAM) |
| BR (1) | BR112018012695B1 (OSRAM) |
| CA (1) | CA3009476C (OSRAM) |
| CY (1) | CY1120156T1 (OSRAM) |
| DK (1) | DK3184494T3 (OSRAM) |
| ES (2) | ES2668071T3 (OSRAM) |
| HR (1) | HRP20180691T1 (OSRAM) |
| HU (1) | HUE038347T2 (OSRAM) |
| LT (1) | LT3184494T (OSRAM) |
| NO (1) | NO3184494T3 (OSRAM) |
| PL (2) | PL3184494T3 (OSRAM) |
| PT (2) | PT3184494T (OSRAM) |
| RS (1) | RS57226B1 (OSRAM) |
| RU (1) | RU2715578C2 (OSRAM) |
| SI (2) | SI3184494T1 (OSRAM) |
| WO (1) | WO2017108831A1 (OSRAM) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106977228B (zh) * | 2017-03-31 | 2021-09-03 | 美科特种材料股份有限公司 | 一种高强度强韧性的泡沫空心陶瓷材料 |
| JP7516344B2 (ja) * | 2018-07-26 | 2024-07-16 | オムヤ インターナショナル アクチェンゲゼルシャフト | 中空球状ガラス粒子 |
| EP3856996A4 (en) * | 2018-09-28 | 2022-06-29 | 3M Innovative Properties Company | Solar-reflective roofing granules with hollow glass spheres |
| MX2022009077A (es) * | 2020-01-24 | 2022-08-15 | Basf Se | Proceso de fabricacion de particulas de vidrio esfericas huecas. |
| CN111205515B (zh) * | 2020-03-13 | 2021-04-23 | 中国科学技术大学 | 一种轻质复合橡胶及其制备方法 |
| TW202330798A (zh) | 2021-11-01 | 2023-08-01 | 美商羅傑斯公司 | 經填充之聚矽氧發泡層、其製造組成物及製造方法、及包含該經填充之聚矽氧發泡層之製品 |
| DE102022213096A1 (de) * | 2022-12-05 | 2024-06-06 | Xella Technologie- Und Forschungsgesellschaft Mbh | Verfahren zur Herstellung eines aktivierten Materials, Verwendung des Materials in einer Trockenmörtelmischung, Trockenmörtelmischung mit dem Material, Verfahren zur Herstellung der Trockenmörtelmischung und deren Verwendung |
| CN118308076B (zh) * | 2024-04-11 | 2025-10-17 | 中钢集团马鞍山矿山研究总院股份有限公司 | 一种用于制备低密度钻井液的耐磨高强减轻剂 |
Family Cites Families (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL232500A (OSRAM) * | 1957-10-22 | |||
| US3365315A (en) * | 1963-08-23 | 1968-01-23 | Minnesota Mining & Mfg | Glass bubbles prepared by reheating solid glass partiles |
| US3458332A (en) * | 1966-03-25 | 1969-07-29 | Emerson & Cuming Inc | Microsphere glass agglomerates and method for making them |
| US3666506A (en) | 1969-04-01 | 1972-05-30 | Corning Glass Works | Batch for producing cellulated glassy bodies from rock |
| US3838998A (en) | 1971-01-07 | 1974-10-01 | R Carson | Process for forming hollow glass micro-spheres from admixed high and low temperature glass formers |
| US3888957A (en) * | 1972-02-03 | 1975-06-10 | Philadelphia Quartz Co | Method of making hollow spheres by spray drying |
| US4111713A (en) * | 1975-01-29 | 1978-09-05 | Minnesota Mining And Manufacturing Company | Hollow spheres |
| JPS53134807A (en) | 1977-04-28 | 1978-11-24 | Asahi Dow Ltd | Production of hollow particulae spherical glass bodies |
| US4303431A (en) * | 1979-07-20 | 1981-12-01 | Torobin Leonard B | Method and apparatus for producing hollow microspheres |
| US4448599A (en) * | 1982-03-22 | 1984-05-15 | Atlantic Richfield Company | Hollow spheres produced from natural zeolites |
| US4789501A (en) * | 1984-11-19 | 1988-12-06 | The Curators Of The University Of Missouri | Glass microspheres |
| US5064784A (en) * | 1989-04-18 | 1991-11-12 | Tokai Kogyo Co., Ltd. | Glass frit useful for the preparation of glass bubbles, and glass bubbles prepared by using it |
| WO1991016273A1 (en) * | 1990-04-25 | 1991-10-31 | United States Borax & Chemical Corporation | Calcia-aluminoborosilicate glass compositions |
| US5069702A (en) * | 1990-12-20 | 1991-12-03 | W. R. Grace & Co.-Conn. | Method of making small hollow glass spheres |
| AU695077B2 (en) * | 1993-09-08 | 1998-08-06 | Pq Holding, Inc. | Hollow borosilicate microspheres and method of making |
| JP3496050B2 (ja) * | 2000-04-13 | 2004-02-09 | 独立行政法人物質・材料研究機構 | フラーレン状窒化ホウ素の中空微粒子の製造法 |
| EP1156021A1 (en) * | 2000-05-19 | 2001-11-21 | Asahi Glass Co., Ltd. | Hollow aluminosilicate glass microspheres and process for their production |
| DE10143685B4 (de) * | 2001-08-31 | 2008-07-24 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Strukturierte Siliciumcarbidpartikel, Verfahren zu ihrer Herstellung und Verwendung |
| JP4490816B2 (ja) * | 2002-08-23 | 2010-06-30 | ジェームズ ハーディー インターナショナル ファイナンス ベスローテン フェンノートシャップ | 合成中空小球体 |
| DE102004022629B9 (de) * | 2004-05-07 | 2008-09-04 | Schott Ag | Gefloatetes Lithium-Aluminosilikat-Flachglas mit hoher Temperaturbeständigkeit, das chemisch und thermisch vorspannbar ist und dessen Verwendung |
| US20060122049A1 (en) * | 2004-12-03 | 2006-06-08 | 3M Innovative Properties Company | Method of making glass microbubbles and raw product |
| CA2598708A1 (en) * | 2005-02-24 | 2006-08-31 | James Hardie International Finance B.V. | Alkali resistant glass compositions |
| US7730746B1 (en) * | 2005-07-14 | 2010-06-08 | Imaging Systems Technology | Apparatus to prepare discrete hollow microsphere droplets |
| US8609244B2 (en) * | 2005-12-08 | 2013-12-17 | James Hardie Technology Limited | Engineered low-density heterogeneous microparticles and methods and formulations for producing the microparticles |
| US7900474B2 (en) * | 2008-08-14 | 2011-03-08 | Beck Warren R | Hollow glass microspheres comprising selenium oxide and method of making thereof |
| US7846994B2 (en) * | 2008-12-23 | 2010-12-07 | Potters Industries, Inc. | Inorganic microspheres |
| US8815408B1 (en) | 2009-12-08 | 2014-08-26 | Imaging Systems Technology, Inc. | Metal syntactic foam |
| US8261577B2 (en) * | 2009-12-21 | 2012-09-11 | 3M Innovative Properties Company | Method for making hollow microspheres |
| KR101233744B1 (ko) * | 2011-01-27 | 2013-02-18 | 한국기계연구원 | 다공성 반응소결질화규소 제조 방법 및 그에 사용되는 가소결 규소혼합분말 과립 및 다공성 반응소결질화규소 제조 방법 |
| US9096034B2 (en) | 2011-04-12 | 2015-08-04 | Powdermet, Inc. | Syntactic metal matrix materials and methods |
| CA2885643C (en) | 2012-11-02 | 2020-09-29 | James Hardie Technology Limited | Synthetic microparticles |
| CN103395983B (zh) * | 2013-08-15 | 2016-03-09 | 蚌埠玻璃工业设计研究院 | 一种制备铝硅酸盐玻璃空心微球的方法 |
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2015
- 2015-12-21 NO NO15201520A patent/NO3184494T3/no unknown
- 2015-12-21 SI SI201530239T patent/SI3184494T1/en unknown
- 2015-12-21 LT LTEP15201520.2T patent/LT3184494T/lt unknown
- 2015-12-21 HU HUE15201520A patent/HUE038347T2/hu unknown
- 2015-12-21 DK DK15201520.2T patent/DK3184494T3/en active
- 2015-12-21 EP EP15201520.2A patent/EP3184494B1/en active Active
- 2015-12-21 PT PT152015202T patent/PT3184494T/pt unknown
- 2015-12-21 ES ES15201520.2T patent/ES2668071T3/es active Active
- 2015-12-21 PL PL15201520T patent/PL3184494T3/pl unknown
- 2015-12-21 RS RS20180513A patent/RS57226B1/sr unknown
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2016
- 2016-11-07 US US15/345,319 patent/US10414689B2/en active Active
- 2016-12-14 RU RU2016149096A patent/RU2715578C2/ru active
- 2016-12-20 SI SI201630824T patent/SI3393988T1/sl unknown
- 2016-12-20 PT PT168260263T patent/PT3393988T/pt unknown
- 2016-12-20 WO PCT/EP2016/081985 patent/WO2017108831A1/en not_active Ceased
- 2016-12-20 CA CA3009476A patent/CA3009476C/en active Active
- 2016-12-20 PL PL16826026T patent/PL3393988T3/pl unknown
- 2016-12-20 CN CN201680078737.2A patent/CN108463438B/zh active Active
- 2016-12-20 BR BR112018012695-0A patent/BR112018012695B1/pt active IP Right Grant
- 2016-12-20 EP EP20150082.4A patent/EP3670459B1/en active Active
- 2016-12-20 EP EP16826026.3A patent/EP3393988B1/en active Active
- 2016-12-20 ES ES16826026T patent/ES2804777T3/es active Active
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2018
- 2018-05-03 HR HRP20180691TT patent/HRP20180691T1/hr unknown
- 2018-05-03 CY CY20181100461T patent/CY1120156T1/el unknown
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2019
- 2019-07-10 US US16/508,043 patent/US20190337838A1/en not_active Abandoned
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2020
- 2020-07-08 US US16/923,780 patent/US20200331797A1/en not_active Abandoned
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