ES2661518T3 - Adhesivo de fusión en caliente - Google Patents

Adhesivo de fusión en caliente Download PDF

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Publication number
ES2661518T3
ES2661518T3 ES09707743.2T ES09707743T ES2661518T3 ES 2661518 T3 ES2661518 T3 ES 2661518T3 ES 09707743 T ES09707743 T ES 09707743T ES 2661518 T3 ES2661518 T3 ES 2661518T3
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Prior art keywords
hot melt
melt adhesive
weight
total weight
polymer component
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Active
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ES09707743.2T
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English (en)
Inventor
Richard Ellis
Michaela Stolbova
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Henkel AG and Co KGaA
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Henkel AG and Co KGaA
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Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
    • C08L23/0853—Vinylacetate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J151/00—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
    • C09J151/06—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2314/00—Polymer mixtures characterised by way of preparation
    • C08L2314/06—Metallocene or single site catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • C08L2666/04—Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

Un adhesivo de fusión en caliente que comprende los siguientes componentes: (A) de 20 a 75 % en peso, con base al peso total del adhesivo de fusión en caliente, de un componente polimérico adhesivo base, en el que el componente polimérico adhesivo base comprende i) de 5 a 50 % en peso, con base al peso total del adhesivo de fusión en caliente, de un componente de poliolefina de metaloceno; y, ii) de 20 a 50 % en peso, con base al peso total del adhesivo de fusión en caliente, de un componente polimérico de α-olefina amorfo; (B) de 0.5 a 10 % en peso, con base al peso total del adhesivo de fusión en caliente, de una poliolefina maleada; y (C) de 20-60 % en peso, de un agente de pegajosidad de hidrocarburos hidrogenados, con base al peso total del adhesivo de fusión en caliente.

Description

imagen1
imagen2
imagen3
imagen4
imagen5
imagen6
imagen7
imagen8
imagen9
Ejemplo 6 de Referencia
Formulaciones adhesivas de fusión en caliente que tiene los ingredientes que se muestran en la Tabla 6 donde se
preparó y se comparó la resistencia al calor.
Tabla 6
Muestra 12
Muestra 13 Muestra 14 Muestra 15 Muestra 16
Sasolwax H1
5.0 5.0 5.0 5.0 5.0
Sasolwax 6805
15 15 15 15 15
Evernox 10
0.1 0.1 0.1 0.1 0.1
Escorez 5400
20 20 20 20 20
Kristalex F85
20 20 20 20 20
EVA 400-28
20 20 20 20 20
EVA 25-28
20 20 20 20 20
A-C 573
3
A-C 575
3
A-C 596
3
A-C 597
3
Resultados de tensión de escisión por calor promedio (X = 4)
46 55.5 59.5 55.0 58.8
Viscosidad (cP) @180°C
2950 2700 2910 2785 2870
Los resultados muestran que la adición en caliente de aditivo poliolefínico maleado (Muestras 13-16) incrementó la resistencia al calor de un adhesivo a base de EVA convencional.
10 Se pueden realizar muchas modificaciones y variaciones de esta invención sin apartarse de su espíritu y alcance, como será evidente para aquellos expertos en la técnica. Las realizaciones específicas descritas aquí se ofrecen solo a modo de ejemplo, y la invención debe limitarse únicamente por los términos de las reivindicaciones adjuntas.
11

Claims (1)

  1. imagen1
ES09707743.2T 2008-02-08 2009-02-09 Adhesivo de fusión en caliente Active ES2661518T3 (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US28424 1993-03-09
US12/028,424 US8076407B2 (en) 2008-02-08 2008-02-08 Hot melt adhesive
PCT/US2009/033513 WO2009100414A1 (en) 2008-02-08 2009-02-09 Hot melt adhesive

Publications (1)

Publication Number Publication Date
ES2661518T3 true ES2661518T3 (es) 2018-04-02

Family

ID=40578524

Family Applications (1)

Application Number Title Priority Date Filing Date
ES09707743.2T Active ES2661518T3 (es) 2008-02-08 2009-02-09 Adhesivo de fusión en caliente

Country Status (9)

Country Link
US (1) US8076407B2 (es)
EP (1) EP2242812B1 (es)
JP (1) JP5646348B2 (es)
KR (1) KR101544236B1 (es)
CN (1) CN101959985B (es)
BR (1) BRPI0908148A2 (es)
ES (1) ES2661518T3 (es)
RU (1) RU2488618C2 (es)
WO (1) WO2009100414A1 (es)

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US8076407B2 (en) 2011-12-13
JP5646348B2 (ja) 2014-12-24
CN101959985B (zh) 2016-05-11
CN101959985A (zh) 2011-01-26
RU2010137279A (ru) 2012-03-20
BRPI0908148A2 (pt) 2015-08-11
JP2011511866A (ja) 2011-04-14
US20090203847A1 (en) 2009-08-13
KR101544236B1 (ko) 2015-08-12
EP2242812A1 (en) 2010-10-27
RU2488618C2 (ru) 2013-07-27
WO2009100414A1 (en) 2009-08-13
EP2242812B1 (en) 2017-12-20
KR20100116655A (ko) 2010-11-01

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