ES2640523T3 - Procedimiento para pasivar superficies metálicas con copolímeros que exhiben grupos ácido fosfórico y/o ácido fosfónico - Google Patents
Procedimiento para pasivar superficies metálicas con copolímeros que exhiben grupos ácido fosfórico y/o ácido fosfónico Download PDFInfo
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- ES2640523T3 ES2640523T3 ES07787669.6T ES07787669T ES2640523T3 ES 2640523 T3 ES2640523 T3 ES 2640523T3 ES 07787669 T ES07787669 T ES 07787669T ES 2640523 T3 ES2640523 T3 ES 2640523T3
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Classifications
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
- C23C22/08—Orthophosphates
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/12—Wash primers
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
- C23C22/08—Orthophosphates
- C23C22/12—Orthophosphates containing zinc cations
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
- C23C22/08—Orthophosphates
- C23C22/12—Orthophosphates containing zinc cations
- C23C22/13—Orthophosphates containing zinc cations containing also nitrate or nitrite anions
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
- C23C22/08—Orthophosphates
- C23C22/12—Orthophosphates containing zinc cations
- C23C22/17—Orthophosphates containing zinc cations containing also organic acids
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
- C23C22/08—Orthophosphates
- C23C22/20—Orthophosphates containing aluminium cations
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
- C23C22/08—Orthophosphates
- C23C22/22—Orthophosphates containing alkaline earth metal cations
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/34—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides
- C23C22/36—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides containing also phosphates
Landscapes
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Metallurgy (AREA)
- Mechanical Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Paints Or Removers (AREA)
- Chemical Treatment Of Metals (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP06117802 | 2006-07-25 | ||
| EP06117802 | 2006-07-25 | ||
| PCT/EP2007/057406 WO2008012248A1 (de) | 2006-07-25 | 2007-07-18 | Verfahren zum passivieren von metallischen oberflächen mit phosphorsäure- und/oder phosphonsäuregruppen aufweisenden copolymeren |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2640523T3 true ES2640523T3 (es) | 2017-11-03 |
Family
ID=38512307
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES07787669.6T Active ES2640523T3 (es) | 2006-07-25 | 2007-07-18 | Procedimiento para pasivar superficies metálicas con copolímeros que exhiben grupos ácido fosfórico y/o ácido fosfónico |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US8568522B2 (https=) |
| EP (1) | EP2049708B1 (https=) |
| JP (1) | JP5377305B2 (https=) |
| KR (1) | KR101376468B1 (https=) |
| CN (1) | CN101495676B (https=) |
| BR (1) | BRPI0714839A2 (https=) |
| CA (1) | CA2657124A1 (https=) |
| ES (1) | ES2640523T3 (https=) |
| MX (1) | MX2009000338A (https=) |
| WO (1) | WO2008012248A1 (https=) |
Families Citing this family (34)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102046843A (zh) * | 2008-05-27 | 2011-05-04 | 油研工业股份有限公司 | 表面剂及具有由表面剂形成的外涂层的部件 |
| CN102892506A (zh) | 2009-12-17 | 2013-01-23 | 巴斯夫欧洲公司 | 含有纳米级铁-铂族金属颗粒的金属氧化物载体材料 |
| US20130171521A1 (en) * | 2010-09-16 | 2013-07-04 | Zeon Corporation | Positive electrode for secondary cell |
| KR20130116251A (ko) | 2010-10-05 | 2013-10-23 | 바스프 에스이 | 염기성 조성물을 사용한 금속 표면의 부동화 방법 |
| KR101820186B1 (ko) | 2010-10-05 | 2018-02-28 | 바스프 에스이 | 계면활성제를 포함하는 수성 조성물을 사용하는 금속 표면의 부동태화 방법 |
| JP2013540202A (ja) | 2010-10-05 | 2013-10-31 | ビーエーエスエフ ソシエタス・ヨーロピア | 金属表面を不動態化する方法 |
| US9034473B2 (en) | 2010-10-05 | 2015-05-19 | Basf Se | Method for passivating a metallic surface with a basic composition |
| US8986467B2 (en) | 2010-10-05 | 2015-03-24 | Basf Se | Method for passivating metallic surfaces with aqueous compositions comprising surfactants |
| ES2855180T3 (es) | 2011-04-14 | 2021-09-23 | Basf Se | Procedimiento de disolución y/o inhibición de la deposición de incrustación sobre la superficie de un sistema |
| KR101892623B1 (ko) | 2011-04-29 | 2018-08-30 | 삼성디스플레이 주식회사 | 중성표면을 형성하기 위한 랜덤 공중합체 및 그 제조 및 사용 방법들 |
| AU2012293631A1 (en) * | 2011-08-10 | 2014-02-27 | Basf Se | Method for passivating metal surfaces using carboxylate-containing copolymers |
| CN103183764B (zh) * | 2011-12-30 | 2016-02-03 | 财团法人工业技术研究院 | 超高吸水性聚合物及其形成方法 |
| US9109059B2 (en) | 2011-12-30 | 2015-08-18 | Industrial Technology Research Institute | Superabsorbent polymers |
| US9139715B2 (en) | 2012-09-14 | 2015-09-22 | Silberline Manufacturing Co., Inc. | Coating of metal pigments using phosphonic acid-based compounds |
| WO2014072249A1 (de) * | 2012-11-07 | 2014-05-15 | Basf Se | Mischungen für die beschichtung von metallischen oberflächen |
| EP2733179A1 (de) * | 2012-11-19 | 2014-05-21 | Basf Se | Mischungen für die beschichtung von metalloberflächen enthaltend organische korrosionsinhibitoren |
| KR101466006B1 (ko) * | 2013-07-25 | 2014-11-27 | 주식회사 위스코하이텍 | 금속 기재의 표면 처리방법 |
| WO2015098981A1 (ja) * | 2013-12-27 | 2015-07-02 | 国立大学法人九州大学 | 水素機器用の基材及びその製造方法 |
| KR101462620B1 (ko) * | 2014-01-28 | 2014-11-20 | 주식회사 위스코하이텍 | 금속기재의 제조방법 |
| KR101462621B1 (ko) * | 2014-01-28 | 2014-11-20 | 주식회사 위스코하이텍 | 금속기재 제조방법 |
| KR101462623B1 (ko) * | 2014-02-04 | 2014-11-20 | 주식회사 위스코하이텍 | 금속기재의 표면처리방법 |
| KR101452166B1 (ko) * | 2014-03-21 | 2014-10-22 | 주식회사 위스코하이텍 | 금속기재의 표면처리 방법 |
| KR101577132B1 (ko) * | 2014-03-25 | 2015-12-16 | 주식회사 위스코하이텍 | 금속기재의 표면처리방법 |
| JP2015183150A (ja) * | 2014-03-26 | 2015-10-22 | 貴和化学薬品株式会社 | 塑性加工用潤滑剤 |
| KR101528108B1 (ko) * | 2014-09-04 | 2015-06-11 | 주식회사 위스코하이텍 | 금속기재의 제조방법 |
| FR3027309B1 (fr) * | 2014-10-17 | 2018-08-10 | Rhodia Operations | Polymeres polyfonctionnels a base d'unites phosphonates et d'unites amines |
| EP3239354B1 (en) | 2014-12-26 | 2021-11-17 | Nippon Steel Corporation | Electrical steel sheet |
| EP3461878B1 (fr) * | 2015-05-04 | 2024-11-06 | Specialty Operations France | Utilisation des copolymères porteurs de groupes phosphorés pour la protection des métaux et la lubrification |
| WO2019053023A1 (en) * | 2017-09-14 | 2019-03-21 | Chemetall Gmbh | Method for pretreating aluminum materials, particularly aluminum wheels |
| KR102569350B1 (ko) | 2018-01-09 | 2023-08-23 | 삼성디스플레이 주식회사 | 표시장치 및 이의 제조방법 |
| EP3847297B1 (en) * | 2018-09-07 | 2023-11-08 | Chemetall GmbH | Method for treating surfaces of aluminum containing substrates |
| JP7476173B2 (ja) * | 2018-09-07 | 2024-04-30 | ケメタル ゲゼルシャフト ミット ベシュレンクテル ハフツング | アルミニウム含有基材の表面を処理する方法 |
| EP4506429A3 (en) * | 2020-06-10 | 2025-05-14 | Novelis Inc. | Pretreatment compositions bonded to metal substrates and methods of making the same |
| NL2033562B1 (en) * | 2022-11-18 | 2024-05-31 | Ad Int B V | Aqueous metal treatment coating composition and coating method using the composition |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6040054A (en) | 1996-02-01 | 2000-03-21 | Toyo Boseki Kabushiki Kaisha | Chromium-free, metal surface-treating composition and surface-treated metal sheet |
| DE19621184A1 (de) * | 1996-05-28 | 1997-12-04 | Henkel Kgaa | Zinkphosphatierung mit integrierter Nachpassivierung |
| US6802913B1 (en) * | 1997-10-14 | 2004-10-12 | Henkel Kommanditgesellschaft Aut Aktien | Composition and process for multi-purpose treatment of metal surfaces |
| GB2347678B (en) | 1999-03-12 | 2003-06-25 | Albright & Wilson Uk Ltd | Treating metal surfaces |
| DE19914896A1 (de) | 1999-04-01 | 2000-10-05 | Basf Coatings Ag | Thermisch und/oder mit aktinischer Strahlung härtbarer wäßriger Beschichtungsstoff und seine Verwendung |
| WO2001031083A1 (en) | 1999-10-22 | 2001-05-03 | Kawasaki Steel Corporation | Composition for metal surface treatment and surface treated metallic material |
| DE10010758A1 (de) * | 2000-03-04 | 2001-09-06 | Henkel Kgaa | Korrosionsschutzverfahren für Metalloberflächen |
| US6756459B2 (en) * | 2000-09-28 | 2004-06-29 | Rohm And Haas Company | Binder compositions for direct-to-metal coatings |
| DE10128894A1 (de) * | 2001-06-15 | 2002-12-19 | Basf Ag | Verfahren zur schmutzablösungsfördernden Behandlung von Oberflächen textiler und nicht-textiler Materialien |
| FR2837209B1 (fr) * | 2002-03-13 | 2004-06-18 | Rhodia Chimie Sa | Utilisation de copolymers a blocs portant des fonctions phosphates et/ou phosphonates comme promoteurs d'adhesion ou comme agents de protection contre la corrosion d'une surface metallique |
| CN1312214C (zh) * | 2003-02-24 | 2007-04-25 | 巴斯福股份公司 | 用于处理金属表面的含羧基聚合物 |
| BRPI0407625B1 (pt) * | 2003-02-24 | 2013-07-09 | composição para tratar superfícies metálicas, camada passivadora sobre uma superfície metálica, superfície, processo para formar uma camada passivadora sobre uma superfície metálica, uso de uma composição, sistema em uma superfície metálica, e, processo para formar um sistema de revestimento | |
| DE10310972A1 (de) * | 2003-03-13 | 2004-09-23 | Basf Ag | Stickstoffhaltige Polymere für die Metalloberflächenbehandlung |
| DE10349728A1 (de) * | 2003-10-23 | 2005-05-25 | Basf Ag | Im wesentlichen Chrom-freies Verfahren zum Passivieren von metallischen Oberflächen aus Zn, Zn-Legierungen, AI oder AI-Legierungen |
| DE102004041127A1 (de) * | 2004-08-24 | 2006-03-02 | Basf Ag | Verfahren zur Herstellung von carboxylatreichen Copolymeren aus monoethylenisch ungesättigten Mono- und Dicarbonsäuren sowie carboxylatreiche Copolymere mit niedrigem Neutralisationsgrad |
| DE102004041142A1 (de) * | 2004-08-24 | 2006-03-02 | Basf Ag | Verfahren zum Passivieren von metallischen Oberflächen unter Verwendung von Itaconsäure Homo- oder Copolymeren |
| DE102005027568A1 (de) * | 2005-06-14 | 2006-12-21 | Basf Ag | Verfahren zum Passivieren von metallischen Oberflächen mit Zubereitungen von säuregruppenhaltigen Polymeren und Wachsen |
| DE102005027567A1 (de) * | 2005-06-14 | 2006-12-21 | Basf Ag | Verfahren zum Passivieren von metallischen Oberflächen mit Säuregruppen aufweisenden Polymeren |
-
2007
- 2007-07-18 CN CN2007800287813A patent/CN101495676B/zh not_active Expired - Fee Related
- 2007-07-18 MX MX2009000338A patent/MX2009000338A/es unknown
- 2007-07-18 BR BRPI0714839-9A2A patent/BRPI0714839A2/pt not_active Application Discontinuation
- 2007-07-18 EP EP07787669.6A patent/EP2049708B1/de not_active Not-in-force
- 2007-07-18 JP JP2009521225A patent/JP5377305B2/ja not_active Expired - Fee Related
- 2007-07-18 CA CA002657124A patent/CA2657124A1/en not_active Abandoned
- 2007-07-18 WO PCT/EP2007/057406 patent/WO2008012248A1/de not_active Ceased
- 2007-07-18 KR KR1020097002712A patent/KR101376468B1/ko not_active Expired - Fee Related
- 2007-07-18 US US12/374,902 patent/US8568522B2/en not_active Expired - Fee Related
- 2007-07-18 ES ES07787669.6T patent/ES2640523T3/es active Active
Also Published As
| Publication number | Publication date |
|---|---|
| KR101376468B1 (ko) | 2014-03-27 |
| CA2657124A1 (en) | 2008-01-31 |
| KR20090036133A (ko) | 2009-04-13 |
| EP2049708A1 (de) | 2009-04-22 |
| EP2049708B1 (de) | 2017-06-21 |
| CN101495676A (zh) | 2009-07-29 |
| JP5377305B2 (ja) | 2013-12-25 |
| US20090324839A1 (en) | 2009-12-31 |
| BRPI0714839A2 (pt) | 2013-07-09 |
| US8568522B2 (en) | 2013-10-29 |
| JP2009544847A (ja) | 2009-12-17 |
| WO2008012248A1 (de) | 2008-01-31 |
| CN101495676B (zh) | 2011-07-20 |
| MX2009000338A (es) | 2009-01-28 |
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