ES2609994A1 - Procedure to recycle olive mill products, preparation thus obtained and uses given to it (Machine-translation by Google Translate, not legally binding) - Google Patents

Procedure to recycle olive mill products, preparation thus obtained and uses given to it (Machine-translation by Google Translate, not legally binding) Download PDF

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Publication number
ES2609994A1
ES2609994A1 ES201531513A ES201531513A ES2609994A1 ES 2609994 A1 ES2609994 A1 ES 2609994A1 ES 201531513 A ES201531513 A ES 201531513A ES 201531513 A ES201531513 A ES 201531513A ES 2609994 A1 ES2609994 A1 ES 2609994A1
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preparation
acid
olive
procedure
limestone
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ES2609994B2 (en
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Juan Luis Fernández De Mesa Coca
Mercedes FERNÁNDEZ DE MESA MOYANA
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/66Treatment of water, waste water, or sewage by neutralisation; pH adjustment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/32Nature of the water, waste water, sewage or sludge to be treated from the food or foodstuff industry, e.g. brewery waste waters
    • C02F2103/322Nature of the water, waste water, sewage or sludge to be treated from the food or foodstuff industry, e.g. brewery waste waters from vegetable oil production, e.g. olive oil production

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  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Cosmetics (AREA)

Abstract

Procedure to recycle olive mill products, preparation thus obtained and uses given to it. The present invention relates to a method for recycling mill products to the preparation thus obtained and to the uses given thereto. The object of the invention is to take advantage of the residues that are formed in the mills in the production of olive oil. The present invention recycles both the liquid effluents and part of the sludge formed in the mills and the leaves of the olive tree and limestone lands of the olive farms themselves, giving rise to a composition rich in active ingredients but free of hormones, parabens, heavy metals and harmful pesticides for people, animals and the environment. The composition of the present invention will have uses in agriculture, cosmetics, pharmacy and cleaning. (Machine-translation by Google Translate, not legally binding)

Description

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DESCRIPCIONDESCRIPTION

Procedimiento para reciclar productos de almazara, preparation asi obtenida y usos dados a la mismaProcedure to recycle oil mill products, preparation thus obtained and uses given to it

La presente invention se refiere a un procedimiento para reciclar productos de almazara a la preparacion asi obtenida y a los usos dados a la misma.The present invention relates to a process for recycling mill products to the preparation thus obtained and to the uses given thereto.

El objeto de la invencion es aprovechar los residuos que se forman en las almazaras en la production del aceite de oliva. La presente invencion recicla tanto los efluentes liquidos como parte de los lodos formados en las almazaras y las hojas del olivo y tierras calizas de las propias fincas de olivos, dando lugar a una composition rica en ingredientes activos pero libres de hormonas, parabenos, metales pesados y pesticidas nocivos para persona animales y el medio ambiente.The object of the invention is to take advantage of the residues that are formed in the oil mills in the production of olive oil. The present invention recycles both liquid effluents and part of the sludges formed in olive oil mills and leaves and limestone lands of the olive farms themselves, giving rise to a composition rich in active ingredients but free of hormones, parabens, heavy metals and pesticides harmful to animals and the environment.

La composicion de la presente invencion tendra usos en agricultura, cosmetica, farmacia y limpieza.The composition of the present invention will have uses in agriculture, cosmetics, pharmacy and cleaning.

Antecedentes de la invencionBackground of the invention

Se conocen diversas composiciones obtenidas a traves de procesos de elimination de residuos contaminantes, (especialmente el alperujo y los lodos de las balsas de evaporation), que se generan en la elaboration del aceite de oliva.Various compositions obtained through processes of elimination of contaminating residues are known (especially the alperujo and sludges from evaporation rafts), which are generated in the elaboration of olive oil.

La patente espanola con numero de publication ES2116923 titulada, “Procedimiento de obtencion de residuos reciclables derivados de la aceituna” describe un procedimiento de reciclaje del residuo del alpeichm. El procedimiento consiste en el secado de los fangos provenientes del residuo de alpeichm. Este residuo puede ser utilizado como abono en la agricultura. Es esta patente como se ha dicho el unico tratamiento que se realiza a los fangos previamente a ser utilizado como abono es el secado y por lo tanto no se elimina los contaminantes que pudiera presentar.The Spanish patent with publication number ES2116923 entitled, "Procedure for obtaining recyclable waste derived from olives" describes a procedure for recycling alpeichm residue. The procedure consists of drying the sludge from the alpeichm residue. This residue can be used as fertilizer in agriculture. It is this patent as it has been said the only treatment that is done to the sludge before being used as fertilizer is the drying and therefore the pollutants that could be presented are not eliminated.

La solicitud internacional WO2014155141 se refiere a un proceso de reciclado de aguas que provienen de la obtencion de aceite mediante la adicion de una sal y mediante un proceso de electrolisis. Tras un proceso complejo se obtiene un agua reciclada.The international application WO2014155141 refers to a process of water recycling that comes from the production of oil by the addition of a salt and by an electrolysis process. After a complex process, recycled water is obtained.

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De lo que se conoce en el estado de la tecnica, se deriva que el uso de preparaciones libres de residuos contaminantes obtenidas por procedimientos sencillos que provengan del reciclado de productos obtenidos en la obtencion de aceite puede ser de gran interes para la agricultura.From what is known in the state of the art, it follows that the use of preparations free of contaminating residues obtained by simple procedures that come from the recycling of products obtained in obtaining oil can be of great interest for agriculture.

Descripcion de la invencionDescription of the invention

Los inventores han desarrollado un procedimiento de reciclado y una preparation obtenida por dicho procedimiento que comprende productos reciclados procedentes de la elaboracion del aceite de oliva que presenta unas excelentes propiedades para la agricultura y unas propiedades regenerativas que lo hacen adecuado para ser utilizado en las areas de la cosmetica o la farmacia.The inventors have developed a recycling process and a preparation obtained by said procedure that includes recycled products from the production of olive oil that has excellent properties for agriculture and regenerative properties that make it suitable for use in the areas of Cosmetics or pharmacy.

La preparacion de la invencion ha resultado ser mas eficaz que otras preparaciones que comprende liquidos reciclados de almazara y ademas tiene la ventaja de su origen natural. La preparacion esta libre de hormonas, parabenos, metales pesados y pesticidas nocivos para personas, animales y el medio ambiente por su nulo o escaso porcentaje de dichos contaminantes. Se han realizado analisis de los productos y no se ha encontrado presencia de parabenos, ni de hormonas y la cantidad de metales pesados es menor de 0,01pmm y la posible presencia de pesticidas tambien es menor a 0,01 ppm.The preparation of the invention has proved to be more effective than other preparations comprising recycled mill liquids and also has the advantage of its natural origin. The preparation is free of hormones, parabens, heavy metals and pesticides harmful to people, animals and the environment due to their zero or low percentage of these pollutants. Products have been analyzed and no presence of parabens or hormones has been found and the amount of heavy metals is less than 0.01pmm and the possible presence of pesticides is also less than 0.01 ppm.

No hay nada descrito en el estado de la tecnica que sugiera que la preparacion de la invencion pueda presentar los efectos que muestra.There is nothing described in the state of the art that suggests that the preparation of the invention may present the effects it shows.

El procedimiento de obtencion de la preparacion arriba mencionada mezcla los liquidos y los fangos que provienen de las balsas de evaporation de las almazaras con las hojas de olivo y la tierra caliza, tras la mezcla hay una fase de basificacion y de nuevo una mezcla, con este tratamiento se facilita la homogenization de la preparacion y se favorece las reacciones de oxidation-reduction, finalmente se acidifica la preparacion.The procedure for obtaining the aforementioned preparation mixes the liquids and sludges that come from the evaporation rafts of the oil mills with the olive leaves and the limestone earth, after the mixing there is a basification phase and again a mixture, with This treatment facilitates the homogenization of the preparation and the oxidation-reduction reactions are favored, finally the preparation is acidified.

Por lo tanto, un primer aspecto de la invencion se refiere a un procedimiento para reciclar productos de almazara que comprende las etapas de:Therefore, a first aspect of the invention relates to a process for recycling mill products comprising the steps of:

a) mezclar liquidos y fangos procedentes de las balsas de evaporacion de las almazaras, con hojas de olivo de las almazaras trituradas con granulometria de 0,01cm y 0,5 cm, y tierras calizas en la proporcion: entre el 70% y el 90% en peso de liquidos,a) mix liquids and sludge from the evaporation rafts of the oil mills, with olive leaves from the crushed oil mills with granulometry of 0.01cm and 0.5cm, and limestone lands in the proportion: between 70% and 90 % by weight of liquids,

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entre el 1% y el 10% en peso de fangos, entre el 0,5% y el 15% de hojas de olivo, entre el 0,5% y el 5% de tierras calizas;between 1% and 10% by weight of sludge, between 0.5% and 15% of olive leaves, between 0.5% and 5% of limestone lands;

b) llenar con la mezcla de la etapa a) un deposito de basificado;b) fill with the mixture of stage a) a basification tank;

c) anadir una base hasta alcanzar un pH comprendido entre 11 y 13;c) add a base until reaching a pH between 11 and 13;

d) homogeneizar mediante recirculacion en el deposito de basificado;d) homogenize by recirculation in the basification tank;

e) anadir un acido hasta alcanzar un pH comprendido entre 4 a 9.e) add an acid until a pH between 4 to 9 is reached.

Con dicho procedimiento se obtiene una preparation que ademas de aprovechar los liquidos y los fangos provenientes de las almazaras tras el procedimiento de reciclado, tambien tiene hojas de olivo que aportan todos sus nutrientes y tierras calizas que ayudan a estabilizar el pH de la preparacion y que tambien se someten al mismo procedimiento de reciclaje.With this procedure a preparation is obtained that in addition to taking advantage of the liquids and sludge from the mills after the recycling process, it also has olive leaves that provide all its nutrients and limestone soils that help stabilize the pH of the preparation and that They also undergo the same recycling procedure.

Por lo tanto, de acuerdo con un segundo aspecto de la invention esta se refiere a una preparacion obtenida por el procedimiento arriba descrito.Therefore, according to a second aspect of the invention this refers to a preparation obtained by the process described above.

La preparacion obtenida por el procedimiento de la invencion se utiliza como fertilizante ya que presenta un alto poder fertilizante, fitofortificante y bioestimulante. Puede utilizarse en multiples cultivos y para jardineria y plantas de interior, con las ventajas anadidas de ser rico en nutrientes tanto por las aguas recicladas como por la adiccion de las hojas. La preparacion de la invencion es un potenciador de la asimilacion de nutrientes, preparado a base de vegetales exclusivamente, con presencia de tierras calizas, con componentes vegetales procedentes del olivar con alto poder antioxidante, rico en tocoferoles y polifenoles del que se ha eliminado los excesos de materia organica mediante el procedimiento de la invencion.The preparation obtained by the process of the invention is used as a fertilizer since it has a high fertilizing, phyto-fortifying and biostimulant power. It can be used in multiple crops and for gardening and indoor plants, with the added advantages of being rich in nutrients both by recycled waters and by the addition of leaves. The preparation of the invention is a nutrient assimilation enhancer, prepared exclusively from vegetables, with presence of limestone, with vegetable components from the olive grove with high antioxidant power, rich in tocopherols and polyphenols from which excesses have been eliminated of organic matter through the process of the invention.

El uso agricola puede ser como agua de riego fertilizante y util en tratamientos fitosanitarios como bioestimulante o si lleva mas presencia de hojas, tierras calizas y fangos puede ser un fertilizante semisolido o solido para jardineria y plantas de interior.The agricultural use can be as fertilizer irrigation water and useful in phytosanitary treatments such as biostimulant or if it has more presence of leaves, limestone and mud can be a semi-solid or solid fertilizer for gardening and indoor plants.

Por lo tanto un tercer aspecto de la invencion es el uso de la preparacion segun se define en las reivindicaciones como fertilizanteTherefore a third aspect of the invention is the use of the preparation as defined in the claims as fertilizer.

En el ambito de la agricultura es posible la administracion de la preparacion de la invencion sin ningun aditivo, excipiente o vehiculo. Tambien puede ser aplicado en combination con otros fertilizantes. Puede ser utilizado en amplios tipos de cultivos en invernaderos, frutalesIn the field of agriculture the administration of the preparation of the invention is possible without any additive, excipient or vehicle. It can also be applied in combination with other fertilizers. It can be used in broad types of crops in greenhouses, fruit trees

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de hueso y pipita, vinedos, olivares.of bone and pipita, vineyards, olive groves.

Con los fertilizantes de la invention se consigue un aumento de production, se consigue un enraizado rapido y una polinizacion amplia aun en cultivos de flores poco atrayentes.With the fertilizers of the invention, an increase in production is achieved, rapid rooting and broad pollination are achieved even in low-attractive flower crops.

Otro aspecto de la invencion es una composition farmaceutica, veterinaria o cosmetica que comprende una cantidad efectiva de la preparation como se define mas arriba junto a uno o mas excipientes o veticulos farmaceuticos, veterinarios o cosmeticos respectivamente.Another aspect of the invention is a pharmaceutical, veterinary or cosmetic composition comprising an effective amount of the preparation as defined above together with one or more pharmaceutical, veterinary or cosmetic excipients or carriers respectively.

Por ultimo otro aspecto de la invencion es el uso de la preparacion de la invencion en limpieza.Finally, another aspect of the invention is the use of the preparation of the invention in cleaning.

Description detallada de la invencionDetailed description of the invention

Como se ha indicado el procedimiento para reciclar productos de almazara de la presente invencion comprende las etapas de:As indicated the procedure for recycling mill products of the present invention comprises the steps of:

a) mezclar liquidos y fangos procedentes de las balsas de evaporation de las almazaras, con hojas de olivo de las almazaras trituradas con granulometria de 0,01cm y 0,5 cm, y tierras calizas en la proporcion:a) Mix liquids and sludge from the evaporation rafts of the oil mills, with olive leaves from the crushed oil mills with granulometry of 0.01cm and 0.5cm, and limestone soils in proportion:

entre el 70% y el 90% en peso de liquidos, entre el 1% y el 10% en peso de fangos, entre el 0,5% y el 15% de hojas de olivo, entre el 0,5% y el 5% de tierras calizas;between 70% and 90% by weight of liquids, between 1% and 10% by weight of sludge, between 0.5% and 15% of olive leaves, between 0.5% and 5 % of limestone lands;

b) llenar con la mezcla de la etapa a) un deposito de basificado;b) fill with the mixture of stage a) a basification tank;

c) anadir una base hasta alcanzar un pH comprendido entre 11 y 13;c) add a base until reaching a pH between 11 and 13;

d) homogeneizar mediante recirculation en el deposito de basificado;d) homogenize by recirculation in the basification tank;

e) anadir un acido hasta alcanzar un pH comprendido entre 4 a 9.e) add an acid until a pH between 4 to 9 is reached.

En una materialization particular la base de la etapa c) del procedimiento es hidroxido potasico.In a particular materialization the basis of step c) of the process is potassium hydroxide.

En una materializacion preferente la homogeneizacion de la etapa d) se realiza durante un tiempo comprendido entre 4 horas y 6 horas.In a preferred embodiment the homogenization of step d) is carried out for a time between 4 hours and 6 hours.

En una materializacion preferente el acido de la e) se selecciona entre acido mtrico, acido acetico, acido dtrico, acido borico, o sulfato ferroso heptahidratado o sus mezclas. MasIn a preferred embodiment, the acid in e) is selected from metric acid, acetic acid, dic acid, boric acid, or ferrous sulfate heptahydrate or mixtures thereof. More

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preferentemente se selecciona entre acido acetico o acido dtrico o una combination de ambos. En una materialization aun mas preferente el acido es acido borico o el sulfato ferroso heptahidratado.preferably it is selected from acetic acid or dric acid or a combination of both. In an even more preferred materialization the acid is boric acid or ferrous sulfate heptahydrate.

En una materializacion preferente el rango de los Kquidos y fangos presentado es entre el 80% y el 85% en peso, y las hojas de olivo se encuentran entre el 0,5% y el 2% en peso. En una materializacion preferente las tierras calizas se encuentran entre el 1% y el 3%.In a preferred materialization the range of the Kquidos and sludge presented is between 80% and 85% by weight, and the olive leaves are between 0.5% and 2% by weight. In a preferred materialization the limestone lands are between 1% and 3%.

En una materializacion preferente el pH de la etapa e) esta entre 4 y 8. Mas preferentemente entre 5 y 7.In a preferred embodiment the pH of step e) is between 4 and 8. More preferably between 5 and 7.

En una materializacion particular tras la etapa d) y antes de la etapa e) se traspasa el contenido del deposito de basificacion a un deposito de acidification.In a particular materialization after stage d) and before stage e) the content of the basification tank is transferred to an acidification tank.

En una materializacion preferente tras la etapa e) se deja reposar.In a preferred materialization after step e) it is allowed to stand.

Un segundo aspecto de la invention se refiere a la preparation obtenida por el procedimiento y las materializaciones del procedimiento de la invencion arriba descritas.A second aspect of the invention relates to the preparation obtained by the process and the materializations of the process of the invention described above.

Como se ha mencionado mas arriba la presente invencion se refiere a composiciones farmaceuticas, veterinarias o cosmeticas que comprenden una cantidad efectiva de la preparacion como se ha definido antes junto a uno o mas excipientes o veticulos farmaceuticos, veterinarios o cosmeticos respectivamente.As mentioned above, the present invention relates to pharmaceutical, veterinary or cosmetic compositions comprising an effective amount of the preparation as defined above together with one or more pharmaceutical, veterinary or cosmetic excipients or carriers respectively.

Para el proposito de la presente invencion el termino cantidad efectiva” significa una cantidad que es suficiente para obtener el efecto esperado, En el caso de las composiciones farmaceuticas y veterinarios en la cantidad efectiva es "la cantidad terapeuticamente efectiva” y se refiere a la cantidad del compuesto que cuando es administrado es suficiente para prevenir el desarrollo o aliviar, uno o mas de los smtomas de la enfermedad que va a ser tratada.For the purpose of the present invention the term effective amount "means an amount that is sufficient to obtain the expected effect. In the case of pharmaceutical and veterinary compositions in the effective amount is" the therapeutically effective amount "and refers to the amount of the compound that when administered is sufficient to prevent the development or alleviate, one or more of the symptoms of the disease to be treated.

La expresion "excipiente o vehiculo farmaceuticamente o veterinariamente aceptable- se refiere a materiales veterinarios o farmaceuticos aceptables, composiciones o vehiculos utilizados en el ambito veterinario o farmaceutico. Deben ser adecuados para el uso en contacto con tejidos u organos humanos o animales sin que produzcan toxicidad, irritation u otros problemas o complicaciones con un razonable ratio beneficio/riesgo.The term "pharmaceutically or veterinarily acceptable excipient or vehicle - refers to acceptable veterinary or pharmaceutical materials, compositions or vehicles used in the veterinary or pharmaceutical field. They must be suitable for use in contact with human or animal tissues or organs without causing toxicity. , irritation or other problems or complications with a reasonable benefit / risk ratio.

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La expresion "excipiente o vedculo cosmeticamente aceptable” se refiere al excipiente o vedculo para el uso en contacto con la piel que no produzca toxicidad, incompatibilidad, inestabilidad, alergias u otros. Ejemplos de estos excipientes o vehiculos son: zumo de aloe vera, acido dtrico, acido borico, esencia de cipres, esencia de romero, esencia de eucalipto, esencia de tila, esencia de ortiga, esencia de hinojo, esencia de manzanilla, esencia de achicoria, esencia de abedul, esencia de raiz de bardena. Particularmente preferentes son el acido borico y el acido dtrico.The expression "excipient or cosmetically acceptable vehicle" refers to the excipient or vehicle for use in contact with the skin that does not produce toxicity, incompatibility, instability, allergies or others. Examples of these excipients or vehicles are: aloe vera juice, acid Doric, boric acid, cypress essence, rosemary essence, eucalyptus essence, linden essence, nettle essence, fennel essence, chamomile essence, chicory essence, birch essence, bardena root essence. Particularly preferred are boric acid and dric acid.

Las composiciones cosmeticas de la invencion pueden ser formuladas de varias formas que incluyen pero no se limitan a: soluciones, aerosoles, mascarillas faciales, cremas, lociones, champus, acondicionadores de pelo, o jabones de cara y cuerpo.The cosmetic compositions of the invention can be formulated in several ways that include but are not limited to: solutions, aerosols, face masks, creams, lotions, shampoos, hair conditioners, or face and body soaps.

Estas composiciones cosmeticas de la invencion pueden ser preparadas por los metodos bien conocidos en el estado de la tecnica. Los excipientes y/o vedculos apropiados y sus cantidades pueden ser determinados por el experto en la materia de acuerdo a la formulacion que desee preparar.These cosmetic compositions of the invention can be prepared by methods well known in the state of the art. Appropriate excipients and / or vegetables and their amounts can be determined by the person skilled in the art according to the formulation that he wishes to prepare.

Como se ha mencionado, la preparacion de la invencion puede utilizarse con un proposito cosmetico.As mentioned, the preparation of the invention can be used for a cosmetic purpose.

Por lo tanto la presente invencion se refiere a un uso cosmetico de la preparacion como un agente del cuidado de la piel o del pelo. El pelo puede mejorar en su estructura, brillo. De la misma manera previene la perdida de cabello. Los usos cosmeticos de la composicion cosmetica de la invencion pueden seleccionarse entre otros entre: regenerador capilar, control de cuticulas, callosidades y exfoliacion celular, limpieza facial, jabon de lavado de cabeza eliminado piojos y caspa, jabon de manos, limpieza severa de manos a operarios, jabon de ducha o bano, desodorante. Tambien elimina piojos y caspa del cabello. Se puede utilizar tambien como protector del contagio de piojos mediante la aplicacion de una vez por semana.Therefore the present invention relates to a cosmetic use of the preparation as a skin or hair care agent. The hair can improve in its structure, shine. In the same way it prevents hair loss. The cosmetic uses of the cosmetic composition of the invention can be selected among others: hair regenerator, cuticle control, calluses and cell exfoliation, facial cleansing, head and soap removal soap, lice and dandruff, hand soap, severe hand cleaning Operators, shower or bath soap, deodorant. It also removes lice and hair dandruff. It can also be used as a protector for the spread of lice by applying once a week.

La composicion cosmetica tiene un alto grado de eficacia por su poder emoliente y exfoliante ya que elimina celulas muertas, grietas y callosidades, hidrata las celulas cutaneas y mejora el aspecto aportando la elasticidad, frescura y brillo. Por lo tanto la preparacion de la invencion se usa en cremas hidratantes para uso corporal de manos y cutis.The cosmetic composition has a high degree of efficacy due to its emollient and exfoliating power since it eliminates dead cells, cracks and calluses, moisturizes the cutaneous cells and improves the appearance providing elasticity, freshness and shine. Therefore the preparation of the invention is used in moisturizers for body use of hands and skin.

Igualmente puede ser utilizado como jabon de ducha, bano, manos y limpieza severa deIt can also be used as shower soap, bath, hands and severe cleaning of

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manos a operarios ya que por los antioxidantes y regeneradores de tejidos presentes en la preparation se consigue una regeneration de la piel, el control del sudor y la elimination de sus olores.Operators' hands because the antioxidants and tissue regenerators present in the preparation achieve a regeneration of the skin, sweat control and the elimination of odors.

La composition farmaceutica de la invention puede ser utilizada como cicatrizante antiinflamatorio, tratamiento de la psoriasis, acne, tratamiento y cicatrization de heridas incluyendo quemaduras, alivio de golpes, contusiones, esguinces, escoriaciones preferentemente hospitalarias, rozaduras.The pharmaceutical composition of the invention can be used as an anti-inflammatory healing, treatment of psoriasis, acne, treatment and wound healing including burns, relief of blows, bruises, sprains, preferably hospital scoriations, chafing.

Un ultimo aspecto de la invencion es el uso de la preparacion de la invencion en limpieza. Es especialmente indicada la preparacion en limpieza de automoviles en seco, interior y exterior incluidas llantas de aluminio eliminado olores e insectos, limpieza de vehiculos a motor de todo tipo a mano o a maquina, limpieza general de edificios eliminando suciedad, olores e insectos, limpieza de cristalerias y catavinos especialmente en concurso eliminando olores, limpieza de lugares de publica concurrencia donde se previene o elimina olores, hongos, insectos o acaros.A final aspect of the invention is the use of the preparation of the invention in cleaning. It is especially indicated the preparation in cleaning of cars in dry, interior and exterior including aluminum wheels eliminated odors and insects, cleaning of motor vehicles of all kinds by hand or machine, general cleaning of buildings eliminating dirt, odors and insects, cleaning of glassware and catavinos especially in competition eliminating odors, cleaning places of public concurrence where odors, fungi, insects or mites are prevented or eliminated.

Ejemplo 1Example 1

Se transportaron los liquidos desde las balsas de evaporation de las almazaras, mezclados con hojas de olivo trituradas con granulometria de 0,4 cm, y tierras calizas al 2% a un deposito de basificado.The liquids were transported from the evaporation rafts of the oil mills, mixed with crushed olive leaves with granulometry of 0.4 cm, and 2% limestone soils to a basified tank.

Los depositos de basificados estaban en una nave cerrada. Los depositos eran verticales, cilmdrico con base inclinada a 45°.Deposits of basified were in a closed ship. The deposits were vertical, cylindrical with base inclined at 45 °.

Los depositos citados dispoman de una salida en la zona mas inferior y que tambien se utilizo para el bombeo hacia la parte superior, la cual no es totalmente cerrada. Los depositos presentan una salida a unos 15 cm de altura, respecto del punto mas bajo del lateral, para cuando se finalice esta fase del proceso (basificado), con objeto de realizar el trasvase a los depositos de acidification que tendran similares caracteristicas a los de basificado.The aforementioned tanks have an outlet in the lower area and which was also used for pumping to the top, which is not completely closed. The deposits have an exit at about 15 cm high, with respect to the lowest point on the side, by the end of this phase of the process (basified), in order to transfer to the acidification tanks that will have similar characteristics to those of basified

Una vez se llenaron los depositos de basificacion, se anadio hidroxido potasico hasta alcanzar un pH de 8. Se homogeniza la mezcla. Se anadio de nuevo hidroxido sodico hasta que el pH llego a 12. Se recirculo durante 5 horas.Once the basification tanks were filled, potassium hydroxide was added until a pH of 8 was reached. The mixture was homogenized. Sodium hydroxide was added again until the pH reached 12. It was recirculated for 5 hours.

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Se traspaso el contenido del deposito de basificacion a un deposito de acidificacion.The content of the basification tank was transferred to an acidification tank.

Se anadio acido nrtrico al deposito de neutralization hasta que el pH fue inferior a 7.Nordic acid was added to the neutralization tank until the pH was below 7.

Ejemplo 2. Uso como fertilizanteExample 2. Use as fertilizer

El producto obtenido en el ejemplo 1 se utilizo para el riego de un cultivo como el olivar que presenta veceria (production alterna cada dos anos). Aplicando el producto en los olivos se consiguio la elimination de la veceria y aumento la produccion bianual un 60%.The product obtained in Example 1 was used to irrigate a crop such as the olive grove that has veceria (production alternates every two years). Applying the product in the olive trees achieved the elimination of the trice and increased bi-annual production by 60%.

Ejemplo 3. Uso como fertilizante semisolidoExample 3. Use as semi-solid fertilizer

El producto del ejemplo 1 se mezclo con arena para obtener un fertilizante mas solido. De esta manera sirvio de soporte en una maceta de limonero donde se ensayo su capacidad fertilizante, dando lugar a la floracion del mismo que nunca hatia florecido.The product of example 1 was mixed with sand to obtain a more solid fertilizer. In this way it served as a support in a pot of lemon tree where its fertilizing capacity was tested, giving rise to the flowering of the same that never bloomed hatia.

Este mismo ensayo se repitio en diversas macetas, 50, obteniendose siempre muy buenos resultados.This same test was repeated in different pots, 50, always obtaining very good results.

Ejemplo 4. Regenerador capilarExample 4. Hair regenerator

Con el producto del Ejemplo 1 se formulo un regenerador capilar anadiendo zumo de aloe vera, acido dtrico, acido borico, esencia de cipres, esencia de romero, esencia de eucalipto.With the product of Example 1 a hair regenerator was formulated by adding aloe vera juice, dric acid, boric acid, cypress essence, rosemary essence, eucalyptus essence.

Este regenerador capilar es respetuoso con el medio ambiente, pelo y cuero cabelludo, repelente de parasitos.This hair regenerator is respectful with the environment, hair and scalp, parasite repellent.

El regenerador actuo fortaleciendo el foliculo piloso, regenerando de forma continua su caida al atenuarla modificando el ciclo de caida y paulatinamente se aumento su numero y se empezo a aumentar su volumen y a disminuir las zonas despobladas de cabello y dando cuerpo al mismo, favoreciendo su crecimiento al controlar la segregacion sebacea y eliminar la caspa y partes danadas de los diferentes cabellos por lo que al disminuyo su caida, aumento su volumen, brillo, grosor, suavidad y numero.The regenerator acted by strengthening the hair follicle, continuously regenerating its fall by attenuating it by modifying the fall cycle and its number gradually increased and its volume began to increase and the depopulated areas of hair diminished and giving body to it, favoring its growth by controlling the sebaceous segregation and eliminating the dandruff and damaged parts of the different hairs so that by decreasing their fall, they increase their volume, brightness, thickness, softness and number.

Ejemplo 5. Uso para el control callosidades y escoriacionesExample 5. Use for the control of calluses and scoriations

Con el producto del Ejemplo 1 se formulo una crema que se aplico a un grupo de personas, 20, con objeto de probar la eliminacion de callosidades. En todos los casos las callosidadesWith the product of Example 1 a cream was formulated that was applied to a group of people, 20, in order to prove the elimination of calluses. In all cases the calluses

desaparecieron tras la aplicacion de la crema.They disappeared after the application of the cream.

A una persona con escoriaciones de una operation de cadera se le trato con la crema del presente ejemplo y quedo aliviada en la primera aplicacion y elimino las escoriaciones a los 5 cinco dias.A person with scoriations of a hip operation was treated with the cream of the present example and was relieved in the first application and eliminated the scoriations at 5 to 5 days.

Ejemplo 6. Composicion farmaceuticaExample 6. Pharmaceutical composition

Con el producto del Ejemplo 1 se formulo una composicion farmaceutica en forma de crema 10 para tratar la psoriasis.With the product of Example 1 a pharmaceutical composition in the form of cream 10 was formulated to treat psoriasis.

Se utilizo dicha composicion en 6 personas con psoriasis y los smtomas de las psoriasis desaparecieron.This composition was used in 6 people with psoriasis and the symptoms of psoriasis disappeared.

15 Ejemplo 7. Composicion de limpieza15 Example 7. Cleaning composition

Se formulo con el producto del Ejemplo 1 una composicion de limpieza que fue utilizada en la limpieza de automoviles.A cleaning composition that was used in car cleaning was formulated with the product of Example 1.

20 La limpieza del mismo fue muy eficaz. La bondad y diferencia de la eficacia esta motivada por la sustitucion del agua por el producto procedente de las almazaras siendo su20 Cleaning it was very effective. The goodness and difference in effectiveness is motivated by the substitution of water for the product from the oil mills being its

comportamiento no agresivo.non-aggressive behavior

Claims (9)

55 1010 15fifteen 20twenty 2525 3030 3535 REIVINDICACIONES 1. Procedimiento para reciclar productos de almazara que comprende las etapas de:1. Procedure to recycle oil mill products comprising the stages of: a) mezclar Kquidos y fangos procedentes de las balsas de evaporacion de las almazaras, con hojas de olivo de las almazaras trituradas con granulometria de 0,01cm y 0,5 cm, y tierras calizas en la proporcion:a) Mix Kquidos and sludge from the evaporation rafts of the oil mills, with olive leaves of the crushed oil mills with granulometry of 0.01cm and 0.5cm, and limestone lands in the proportion: entre el 70% y el 90% en peso de Kquidos, entre el 1% y el 10% en peso de fangos, entre el 0,5% y el 15% de hojas de olivo, entre el 0,5% y el 5% de tierras calizas;between 70% and 90% by weight of Kquidos, between 1% and 10% by weight of sludge, between 0.5% and 15% of olive leaves, between 0.5% and 5 % of limestone lands; b) llenar con la mezcla de la etapa a) un deposito de basificado;b) fill with the mixture of stage a) a basification tank; c) anadir una base hasta alcanzar un pH comprendido entre 11 y 13;c) add a base until reaching a pH between 11 and 13; d) homogeneizar mediante recirculacion en el deposito de basificado;d) homogenize by recirculation in the basification tank; e) anadir un acido hasta alcanzar un pH comprendido entre 4 a 9.e) add an acid until a pH between 4 to 9 is reached. 2. El procedimiento segun la reivindicacion 1 donde la base es hidroxido potasico.2. The method according to claim 1 wherein the base is potassium hydroxide. 3. El procedimiento segun las reivindicacion 1 donde el acido se selecciona entre acido rntrico, acido acetico, acido dtrico, acido borico, o sulfato ferroso heptahidratado o sus mezclas.3. The method according to claim 1 wherein the acid is selected from nitric acid, acetic acid, dric acid, boric acid, or ferrous sulfate heptahydrate or mixtures thereof. 4. El procedimiento segun la reivindicacion 2 donde el acido se selecciona entre acido acetico o acido dtrico o una combinacion de ambos.4. The method according to claim 2 wherein the acid is selected from acetic acid or citric acid or a combination of both. 5. Preparacion obtenida mediante el procedimiento de las reivindicaciones 1-4.5. Preparation obtained by the procedure of claims 1-4. 6. Uso de la preparacion segun se define en la reivindicacion 5 como fertilizante.6. Use of the preparation as defined in claim 5 as fertilizer. 7. Una composicion farmaceutica, veterinaria o cosmetica que comprende una cantidad efectiva de la preparacion como se define en la reivindicacion 5 junto a uno o mas excipientes o vedculos farmaceuticos, veterinarios o cosmeticos respectivamente.7. A pharmaceutical, veterinary or cosmetic composition comprising an effective amount of the preparation as defined in claim 5 together with one or more pharmaceutical, veterinary or cosmetic excipients or vegetables respectively. 8. Uso de la composicion cosmetica segun se define en la reivindicacion 7 como agente para el cuidado de la piel, o como agente para el cuidado del pelo.8. Use of the cosmetic composition as defined in claim 7 as a skin care agent, or as a hair care agent. 9. Uso de la preparacion de la invencion segun la reivindicacion 5 en composiciones de9. Use of the preparation of the invention according to claim 5 in compositions of 55 1010 15fifteen 20twenty 2525 3030 3535
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2736118A1 (en) * 2018-06-21 2019-12-26 Univ Granada PROCEDURE FOR THE OBTAINING OF POLYOLS AND OTHER INTEREST COMPOUNDS FROM WASTE FROM LUNCHES (Machine-translation by Google Translate, not legally binding)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2005196A6 (en) * 1986-04-28 1989-03-01 Consiglio Nazionale Ricerche Purificn. of vegetable agricultural effluents
BE1016600A6 (en) * 2005-05-25 2007-02-06 Debillemont Paul Treatment of liquid effluents and/or sludge, useful to prepare a solid product, which is useful in agriculture, comprises electrolysis and biomethanation of the liquid effluents and/or the sludge
EP1810953A1 (en) * 2006-01-17 2007-07-25 Unieco Societa' Cooperativa A method and a plant for treating waste material from olive oil production
EP1849756A1 (en) * 2006-04-28 2007-10-31 Universidade de Tras-os-Montes e Alto Douro A process for the treatment and recovery of residues and effluents from olive oil production units through the utilisation and reprocessing of cork industry waste
WO2009101455A1 (en) * 2008-02-11 2009-08-20 Pantelis Xynogalas Physicochemical method of processing liquid and semisolid wastes of olive mills using ozone (o3)

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2005196A6 (en) * 1986-04-28 1989-03-01 Consiglio Nazionale Ricerche Purificn. of vegetable agricultural effluents
BE1016600A6 (en) * 2005-05-25 2007-02-06 Debillemont Paul Treatment of liquid effluents and/or sludge, useful to prepare a solid product, which is useful in agriculture, comprises electrolysis and biomethanation of the liquid effluents and/or the sludge
EP1810953A1 (en) * 2006-01-17 2007-07-25 Unieco Societa' Cooperativa A method and a plant for treating waste material from olive oil production
EP1849756A1 (en) * 2006-04-28 2007-10-31 Universidade de Tras-os-Montes e Alto Douro A process for the treatment and recovery of residues and effluents from olive oil production units through the utilisation and reprocessing of cork industry waste
WO2009101455A1 (en) * 2008-02-11 2009-08-20 Pantelis Xynogalas Physicochemical method of processing liquid and semisolid wastes of olive mills using ozone (o3)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2736118A1 (en) * 2018-06-21 2019-12-26 Univ Granada PROCEDURE FOR THE OBTAINING OF POLYOLS AND OTHER INTEREST COMPOUNDS FROM WASTE FROM LUNCHES (Machine-translation by Google Translate, not legally binding)
WO2019243655A1 (en) * 2018-06-21 2019-12-26 Universidad De Granada Method for producing polyols and other compounds of interest from oil mill waste

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