ES2606920T3 - Materiales que proporcionan materiales compuestos dentales mejorados y materiales compuestos dentales fabricados a partir de éstos - Google Patents

Materiales que proporcionan materiales compuestos dentales mejorados y materiales compuestos dentales fabricados a partir de éstos Download PDF

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Publication number
ES2606920T3
ES2606920T3 ES07839685.0T ES07839685T ES2606920T3 ES 2606920 T3 ES2606920 T3 ES 2606920T3 ES 07839685 T ES07839685 T ES 07839685T ES 2606920 T3 ES2606920 T3 ES 2606920T3
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formula
dental composite
independently
materials
composite materials
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ES07839685.0T
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English (en)
Inventor
Douglas Robert Anton
Gary Delmar Jaycox
Yongqing Huang
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EIDP Inc
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EI Du Pont de Nemours and Co
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04—Polyurethanes
    • C08L75/14—Polyurethanes having carbon-to-carbon unsaturated bonds
    • C08L75/16—Polyurethanes having carbon-to-carbon unsaturated bonds having terminal carbon-to-carbon unsaturated bonds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K6/00—Preparations for dentistry
    • A61K6/20—Protective coatings for natural or artificial teeth, e.g. sealings, dye coatings or varnish
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K6/00—Preparations for dentistry
    • A61K6/30—Compositions for temporarily or permanently fixing teeth or palates, e.g. primers for dental adhesives
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K6/00—Preparations for dentistry
    • A61K6/80—Preparations for artificial teeth, for filling teeth or for capping teeth
    • A61K6/884—Preparations for artificial teeth, for filling teeth or for capping teeth comprising natural or synthetic resins
    • A61K6/891—Compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • A61K6/893—Polyurethanes
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P1/00—Drugs for disorders of the alimentary tract or the digestive system
    • A61P1/02—Stomatological preparations, e.g. drugs for caries, aphtae, periodontitis
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3203—Polyhydroxy compounds
    • C08G18/3212—Polyhydroxy compounds containing cycloaliphatic groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/67—Unsaturated compounds having active hydrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/67—Unsaturated compounds having active hydrogen
    • C08G18/671—Unsaturated compounds having only one group containing active hydrogen
    • C08G18/672—Esters of acrylic or alkyl acrylic acid having only one group containing active hydrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/75—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/75—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
    • C08G18/751—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring
    • C08G18/752—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group
    • C08G18/753—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group
    • C08G18/755—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group and at least one isocyanate or isothiocyanate group linked to a secondary carbon atom of the cycloaliphatic ring, e.g. isophorone diisocyanate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/75—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
    • C08G18/758—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing two or more cycloaliphatic rings

Landscapes

  • Health & Medical Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Oral & Maxillofacial Surgery (AREA)
  • Veterinary Medicine (AREA)
  • Animal Behavior & Ethology (AREA)
  • Public Health (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Epidemiology (AREA)
  • Plastic & Reconstructive Surgery (AREA)
  • Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
  • Pharmacology & Pharmacy (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dental Preparations (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Dental Tools And Instruments Or Auxiliary Dental Instruments (AREA)

Abstract

Material compuesto dental no curado que comprende (a) una composición que comprende al menos un compuesto de fórmula:**Fórmula** donde: n>= 0 a 5; R1 y R2 son cada uno independientemente H o metilo; R5 y R6 se seleccionan independientemente entre radicales orgánicos divalentes, comprendiendo cada uno 1-20 átomos de carbono cada uno; cada Q1 se selecciona independientemente y es un radical orgánico divalente que comprende 1-50 átomos de carbono; Z1 y Z2 se seleccionan independientemente y están representados por la fórmula**Fórmula** donde i>= 2-10; g y h son cada uno independientemente 0 o 1, con la condición de que al menos uno de g y h no son cero; y X e Y son cada uno independientemente H o un grupo alquilo C1-C4; R3 y R4 se seleccionan cada uno independientemente y están representados por la fórmula**Fórmula** donde X e Y son como se han definido anteriormente, p, q, y r son cada uno independientemente 0-50, con la condición de que al menos uno de q o r no deben ser cero si p no es cero, que s es 2 a 10, y que el número total de átomos de carbono en la cadena debe ser mayor que o igual a 9. (b) al menos 10% en peso de relleno radiopaco; y (c) un iniciador de polimerización.

Description

imagen1
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donde a y b son cada uno independientemente un número entero en el intervalo de 0 a 6 y a+b= 2-6.
UM-3: donde n=1-5; R1 y R2 son cada uno metilo; para grupos Z1 y Z2; g= 0, i= 0, h= 1 y X e Y son cada uno H o metilo; con la condición de que X e Y no son el mismo; para grupos R3 y R4, p= 0, q= 1-11, r= 0, s= 0; X e Y son cada uno H o metilo; con la condición de que X e Y no son el mismo; y R5 y R6 son cada uno
imagen10
y Q1 es
imagen11
La presente invención proporciona materiales compuestos dentales que comprenden una composición que comprende al menos un compuesto (met)acrilato de uretano de Fórmula I. Un conjunto de los compuestos (met)acrilato de uretano de Fórmula I son aquellos donde n= 0, es decir, compuestos de Fórmula II:
imagen12
15 donde R1, R2, R3, R4, R5, Z1 y Z2 son tal como se han descrito anteriormente. Ejemplos de compuestos de Fórmula II incluyen sin limitación:
10
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Claims (1)

  1. imagen1
    imagen2
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ES07839685.0T 2006-10-18 2007-10-18 Materiales que proporcionan materiales compuestos dentales mejorados y materiales compuestos dentales fabricados a partir de éstos Active ES2606920T3 (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US85252806P 2006-10-18 2006-10-18
US852528P 2006-10-18
PCT/US2007/022269 WO2008048674A2 (en) 2006-10-18 2007-10-18 Materials leading to improved dental composites and dental composites made therefrom

Publications (1)

Publication Number Publication Date
ES2606920T3 true ES2606920T3 (es) 2017-03-28

Family

ID=39161148

Family Applications (1)

Application Number Title Priority Date Filing Date
ES07839685.0T Active ES2606920T3 (es) 2006-10-18 2007-10-18 Materiales que proporcionan materiales compuestos dentales mejorados y materiales compuestos dentales fabricados a partir de éstos

Country Status (9)

Country Link
US (1) US8455566B2 (es)
EP (1) EP2078049B1 (es)
JP (1) JP2010506931A (es)
KR (1) KR101517628B1 (es)
CN (1) CN101675088B (es)
AU (1) AU2007313155B2 (es)
CA (1) CA2663033A1 (es)
ES (1) ES2606920T3 (es)
WO (1) WO2008048674A2 (es)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010116528A (ja) * 2007-12-21 2010-05-27 Sumitomo Chemical Co Ltd 光学フィルム及び該光学フィルムの製造方法
TW200938587A (en) * 2008-01-23 2009-09-16 Sumitomo Chemical Co Optical film and method for manufacturing the same
CN106242540A (zh) * 2016-07-25 2016-12-21 济南大学 一种金属冠牙用烤瓷粉
JP6941186B2 (ja) * 2017-11-28 2021-09-29 三井化学株式会社 （メタ）アクリレートおよびその用途
CN112074262B (zh) * 2018-05-04 2024-01-16 阿莱恩技术有限公司 用于基于高温光刻的光致聚合工艺的可固化组合物和由其制备交联聚合物的方法
EP3669853B1 (de) * 2018-12-21 2022-03-30 Ivoclar Vivadent AG Zusammensetzungen für die herstellung von bruchzähen dentalwerkstücken mittels stereolithographie
CN114349903B (zh) * 2021-12-20 2022-10-25 华南理工大学 一种不含双酚a结构的可流动性大块充填复合树脂及其制备与应用

Family Cites Families (16)

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GB1401805A (en) 1972-03-15 1975-07-30 Amalgamated Dental Co Ltd Dental filling materials
IE37702B1 (en) 1972-11-16 1977-09-28 Loctite Ltd Dental filling composition and process for use thereof
US4110184A (en) 1973-04-24 1978-08-29 Imperial Chemical Industries Limited Photocurable dental filling compositions
US3931678A (en) 1974-09-24 1976-01-13 Loctite (Ireland) Limited Dental filling method and composition formed thereby
DE2724260C2 (de) 1977-05-28 1985-06-05 Bayer Ag, 5090 Leverkusen Abformmaterialien für die Zahnheilkunde
US4400159A (en) 1980-06-24 1983-08-23 Scientific Pharmaceuticals, Inc. Adducts of 3-methacroyl-2-hydroxypropyl esters with diisocyanates
US5177120A (en) 1984-07-31 1993-01-05 Dentsply Research & Development Corp. Chain extended urethane diacrylate and dental impression formation
US4691045A (en) 1984-12-06 1987-09-01 Nippon Shokubai Kagaku Co., Ltd. Hydroxyl group-containing (meth)acrylate oligomer, prepolymer therefrom, and method for use thereof
DE3703130A1 (de) 1986-07-25 1988-01-28 Bayer Ag Urethangruppen enthaltende (meth)-acrylsaeurederivate
EP0807853B1 (en) * 1996-05-16 2003-10-08 Teijin Seiki Co., Ltd. Photocurable resin composition, method of producing photo-cured shaped object, vacuum casting mold, vacuum casting method and urethane acrylate
US6653375B2 (en) 1998-01-28 2003-11-25 Ivoclar Ag Urethane di(meth)acrylate derivatives of 1,3-bis(1-isocyanato-1-methylethyl)benzene
DE19803979C2 (de) * 1998-01-28 2001-06-28 Ivoclar Ag Schaan Zusammensetzungen enthaltend Urethandi(meth)acrylat-Derivate von 1,3-Bis (1-isocyanato-1-methylethyl)benzol
US6472454B1 (en) * 1999-10-22 2002-10-29 Kerr Corporation Endodontic dental compositions
US6353041B1 (en) * 1999-10-22 2002-03-05 Kerr Corporation Dental compositions
WO2001095862A1 (en) 2000-06-13 2001-12-20 Dentsply International Inc. Low shrinking polymerizable dental material
US8084514B2 (en) 2005-05-13 2011-12-27 E. I. Du Pont De Nemours And Company Materials leading to improved dental composites and dental composites made therefrom

Also Published As

Publication number Publication date
EP2078049B1 (en) 2016-09-28
WO2008048674A3 (en) 2008-06-19
WO2008048674A2 (en) 2008-04-24
AU2007313155A2 (en) 2009-09-24
AU2007313155B2 (en) 2012-11-01
JP2010506931A (ja) 2010-03-04
KR20090073225A (ko) 2009-07-02
EP2078049A2 (en) 2009-07-15
AU2007313155A1 (en) 2008-04-24
US20090105370A1 (en) 2009-04-23
CN101675088B (zh) 2013-07-10
US8455566B2 (en) 2013-06-04
CN101675088A (zh) 2010-03-17
KR101517628B1 (ko) 2015-05-04
CA2663033A1 (en) 2008-04-24

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