ES2575730T3 - Complejo de recirculación para aumentar el rendimiento de una pila de combustible con captura de CO2 - Google Patents

Complejo de recirculación para aumentar el rendimiento de una pila de combustible con captura de CO2 Download PDF

Info

Publication number
ES2575730T3
ES2575730T3 ES12722564.7T ES12722564T ES2575730T3 ES 2575730 T3 ES2575730 T3 ES 2575730T3 ES 12722564 T ES12722564 T ES 12722564T ES 2575730 T3 ES2575730 T3 ES 2575730T3
Authority
ES
Spain
Prior art keywords
fuel cell
anode
waste heat
heat recovery
recovery cycle
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
ES12722564.7T
Other languages
English (en)
Inventor
Matthew Alexander Lehar
Andrew Maxwell Peter
Matthew Joseph Alinger
Andrew Philip Shapiro
Laura Michele Hudy
Bruce Philip Biederman
Vitali Victor Lissianski
Roger Allen Shisler
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
General Electric Co
Original Assignee
General Electric Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by General Electric Co filed Critical General Electric Co
Application granted granted Critical
Publication of ES2575730T3 publication Critical patent/ES2575730T3/es
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/06Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0662Treatment of gaseous reactants or gaseous residues, e.g. cleaning
    • H01M8/0668Removal of carbon monoxide or carbon dioxide
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04007Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids related to heat exchange
    • H01M8/04059Evaporative processes for the cooling of a fuel cell
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04082Arrangements for control of reactant parameters, e.g. pressure or concentration
    • H01M8/04089Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants
    • H01M8/04097Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants with recycling of the reactants
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04082Arrangements for control of reactant parameters, e.g. pressure or concentration
    • H01M8/04089Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants
    • H01M8/04111Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants using a compressor turbine assembly
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/12Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
    • H01M2008/1293Fuel cells with solid oxide electrolytes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Energy (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Fuel Cell (AREA)
  • Engine Equipment That Uses Special Cycles (AREA)

Abstract

Un complejo de recirculación de pilas de combustible (10; 20) que comprende: una pila de combustible que comprende un ánodo (11) configurado para generar un gas de salida caliente, comprendiendo el ánodo una entrada y una salida; un ciclo de recuperación del calor de desecho configurado para generar energía a partir del enfriamiento del ánodo caliente (11); un compresor (14) configurado para comprimir el gas de salida generado a través del ciclo de recuperación del calor de desecho; un expansor (15) configurado para expandir y enfriar el gas de salida comprimido; un sistema intercambiador de calor (16) configurado para recibir al menos una porción del gas expandido y para preenfriar el gas de salida comprimido del ciclo de recuperación del calor de desecho antes de su enfriamiento a través del expansor (15), y configurado adicionalmente para eliminar mediante cambio de fase el agua (H2O) y el dióxido de carbono (CO2) del gas de salida que pasa a través del ciclo de recuperación del calor de desecho, y configurado adicionalmente para generar una corriente de combustible que es devuelta a la entrada del ánodo (11) de la pila de combustible con una mayor concentración molar de monóxido de carbono (CO) y de combustible de hidrógeno (H2) de la que había inicialmente presente en el gas de salida del ánodo (11) de la pila de combustible antes de entrar en el ciclo de recuperación del calor de desecho.

Description

imagen1
imagen2
imagen3
imagen4
imagen5

Claims (1)

  1. imagen1
    imagen2
ES12722564.7T 2011-03-31 2012-03-29 Complejo de recirculación para aumentar el rendimiento de una pila de combustible con captura de CO2 Active ES2575730T3 (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201113076664 2011-03-31
US13/076,664 US8778545B2 (en) 2011-03-31 2011-03-31 Recirculation complex for increasing yield from fuel cell with CO2 capture
PCT/US2012/031133 WO2012135447A1 (en) 2011-03-31 2012-03-29 Recirculation complex for increasing yield from fuel cell with co2 capture

Publications (1)

Publication Number Publication Date
ES2575730T3 true ES2575730T3 (es) 2016-06-30

Family

ID=46147011

Family Applications (1)

Application Number Title Priority Date Filing Date
ES12722564.7T Active ES2575730T3 (es) 2011-03-31 2012-03-29 Complejo de recirculación para aumentar el rendimiento de una pila de combustible con captura de CO2

Country Status (10)

Country Link
US (1) US8778545B2 (es)
EP (1) EP2692007B1 (es)
JP (1) JP6063922B2 (es)
CN (1) CN103443982B (es)
DK (1) DK2692007T3 (es)
ES (1) ES2575730T3 (es)
PL (1) PL2692007T3 (es)
PT (1) PT2692007E (es)
RU (1) RU2589884C2 (es)
WO (1) WO2012135447A1 (es)

Families Citing this family (37)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9819038B2 (en) 2011-03-31 2017-11-14 General Electric Company Fuel cell reforming system with carbon dioxide removal
CA2902986C (en) 2013-03-15 2019-09-17 Paul J. Berlowitz Integrated operation of molten carbonate fuel cells
US9077008B2 (en) 2013-03-15 2015-07-07 Exxonmobil Research And Engineering Company Integrated power generation and chemical production using fuel cells
US9755258B2 (en) 2013-09-30 2017-09-05 Exxonmobil Research And Engineering Company Integrated power generation and chemical production using solid oxide fuel cells
US9556753B2 (en) 2013-09-30 2017-01-31 Exxonmobil Research And Engineering Company Power generation and CO2 capture with turbines in series
US9819042B2 (en) 2013-09-30 2017-11-14 Exxonmobil Research And Engineering Company Fuel cell integration within a heat recovery steam generator
CA2956439C (en) * 2015-10-08 2017-11-14 1304338 Alberta Ltd. Method of producing heavy oil using a fuel cell
CA2914070C (en) 2015-12-07 2023-08-01 1304338 Alberta Ltd. Upgrading oil using supercritical fluids
CA2920656C (en) 2016-02-11 2018-03-06 1304342 Alberta Ltd. Method of extracting coal bed methane using carbon dioxide
JP6698406B2 (ja) * 2016-03-31 2020-05-27 東京瓦斯株式会社 燃料電池システム
CA3021632C (en) * 2016-04-21 2020-12-29 Fuelcell Energy, Inc. Carbon dioxide removal from anode exhaust of a fuel cell by cooling/condensation
NO345296B1 (en) * 2016-07-14 2020-11-30 Zeg Power As Method and power plant comprising a Solid Oxide Fuel Cell (SOFC) for production of electrical energy and H2 gas
WO2018018036A1 (en) 2016-07-22 2018-01-25 Fluidic, Inc. Moisture and carbon dioxide management system in electrochemical cells
US10581106B2 (en) 2016-09-30 2020-03-03 Cummins Enterprise Llc Interconnect for an internally-manifolded solid oxide fuel cell stack; and related methods and power systems
WO2019070526A1 (en) 2017-10-02 2019-04-11 Battelle Energy Alliance, Llc METHODS AND SYSTEMS FOR ELECTROCHEMICAL REDUCTION OF CARBON DIOXIDE USING SWITCHABLE POLARITY MATERIALS
CN108005742B (zh) * 2017-11-29 2020-05-22 山东大学 可部分回收利用的固体氧化物燃料电池驱动冷热电联供系统
CA2997634A1 (en) 2018-03-07 2019-09-07 1304342 Alberta Ltd. Production of petrochemical feedstocks and products using a fuel cell
US11211621B2 (en) 2018-11-30 2021-12-28 Exxonmobil Research And Engineering Company Regeneration of molten carbonate fuel cells for deep CO2 capture
WO2020112806A1 (en) 2018-11-30 2020-06-04 Exxonmobil Research And Engineering Company Layered cathode for molten carbonate fuel cell
US11742508B2 (en) 2018-11-30 2023-08-29 ExxonMobil Technology and Engineering Company Reforming catalyst pattern for fuel cell operated with enhanced CO2 utilization
KR102662253B1 (ko) 2018-11-30 2024-04-29 퓨얼셀 에너지, 인크 Co2 이용률이 향상된 용융 탄산염 연료 전지의 증가된 압력 작동
WO2020112812A1 (en) 2018-11-30 2020-06-04 Exxonmobil Research And Engineering Company Operation of molten carbonate fuel cells with enhanced co 2 utilization
US11476486B2 (en) 2018-11-30 2022-10-18 ExxonMobil Technology and Engineering Company Fuel cell staging for molten carbonate fuel cells
RU2702136C1 (ru) * 2018-12-28 2019-10-04 Общество с ограниченной ответственностью "Научно-исследовательский центр "ТОПАЗ" (ООО "НИЦ "ТОПАЗ") Энергоустановка на основе твердооксидных топливных элементов с высоким коэффициентом полезного действия
CN111628190A (zh) * 2019-02-27 2020-09-04 国家能源投资集团有限责任公司 一种燃料电池系统
WO2021107933A1 (en) 2019-11-26 2021-06-03 Exxonmobil Research And Engineering Company Fuel cell module assembly and systems using same
KR20220107183A (ko) 2019-11-26 2022-08-02 엑손모빌 테크놀로지 앤드 엔지니어링 컴퍼니 높은 전해질 충전 수준을 갖는 용융 탄산염 연료 전지의 작동
JP6826683B1 (ja) * 2020-03-09 2021-02-03 東京瓦斯株式会社 燃料電池システム
CN111706431B (zh) * 2020-06-16 2021-08-24 山东晟卓信息技术有限公司 一种基于外部重整的sofc功冷联供系统
DE102020122082A1 (de) 2020-08-24 2022-02-24 Audi Aktiengesellschaft Festoxidbrennstoffzellenvorrichtung sowie Brennstoffzellenfahrzeug
US11978931B2 (en) 2021-02-11 2024-05-07 ExxonMobil Technology and Engineering Company Flow baffle for molten carbonate fuel cell
US11788474B2 (en) 2022-03-07 2023-10-17 General Electric Company Pericritical fluid systems for turbine engines
US12018594B2 (en) 2022-03-07 2024-06-25 General Electric Company Pericritical fluid systems for turbine engines
US11946378B2 (en) 2022-04-13 2024-04-02 General Electric Company Transient control of a thermal transport bus
CN114738062B (zh) * 2022-05-19 2024-04-26 西安热工研究院有限公司 耦合sofc和燃气轮机的铝燃料储能系统及工作方法
US11927142B2 (en) 2022-07-25 2024-03-12 General Electric Company Systems and methods for controlling fuel coke formation
CN115566237B (zh) * 2022-10-21 2023-09-08 大连海事大学 一种固体氧化物燃料电池与co2超-跨临界动力循环的联合发电系统

Family Cites Families (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05205763A (ja) * 1992-01-23 1993-08-13 Toshiba Corp 燃料電池システム
JPH08255622A (ja) * 1995-03-17 1996-10-01 Toshiba Corp 燃料電池発電システム
US6301927B1 (en) * 1998-01-08 2001-10-16 Satish Reddy Autorefrigeration separation of carbon dioxide
JPH11214021A (ja) * 1998-01-27 1999-08-06 Ishikawajima Harima Heavy Ind Co Ltd 固体電解質型燃料電池発電設備
JPH11233129A (ja) 1998-02-17 1999-08-27 Mitsubishi Heavy Ind Ltd 固体電解質型燃料電池発電システム
JPH11312527A (ja) * 1998-04-28 1999-11-09 Nippon Steel Corp 製鉄副生ガスを利用した溶融炭酸塩型燃料電池発電−排ガス回収複合システム
NL1014585C2 (nl) * 2000-03-08 2001-09-21 Kema Nv Brandstofcel met een verbeterd rendement voor het opwekken van elektrische energie.
JP4979138B2 (ja) * 2001-01-31 2012-07-18 株式会社前川製作所 ドライアイス製造方法とその装置
US7118606B2 (en) 2001-03-21 2006-10-10 Ut-Battelle, Llc Fossil fuel combined cycle power system
US7285350B2 (en) 2002-09-27 2007-10-23 Questair Technologies Inc. Enhanced solid oxide fuel cell systems
NO320939B1 (no) * 2002-12-10 2006-02-13 Aker Kvaerner Engineering & Te Fremgangsmate for eksosgassbehandling i brenselcellesystem basert pa oksider i fast form
US6924053B2 (en) 2003-03-24 2005-08-02 Ion America Corporation Solid oxide regenerative fuel cell with selective anode tail gas circulation
WO2005050768A1 (en) 2003-11-19 2005-06-02 Questair Technologies Inc. High efficiency load-following solid oxide fuel cell systems
US7803473B2 (en) * 2004-06-30 2010-09-28 General Electric Company Integrated power plant and system and method incorporating the same
US7428816B2 (en) * 2004-07-16 2008-09-30 Honeywell International Inc. Working fluids for thermal energy conversion of waste heat from fuel cells using Rankine cycle systems
US7380749B2 (en) * 2005-04-21 2008-06-03 The Boeing Company Combined fuel cell aircraft auxiliary power unit and environmental control system
CA2569006C (en) 2006-11-20 2013-12-24 Jose Lourenco Method to condense and recover carbon dioxide from fuel cells
US7862938B2 (en) * 2007-02-05 2011-01-04 Fuelcell Energy, Inc. Integrated fuel cell and heat engine hybrid system for high efficiency power generation
JP5294291B2 (ja) 2007-05-15 2013-09-18 一般財団法人電力中央研究所 発電設備
JP2010071091A (ja) * 2008-09-16 2010-04-02 Fuji Electric Holdings Co Ltd 複合発電システム
JP5496494B2 (ja) * 2008-11-26 2014-05-21 中国電力株式会社 発電システム
RU2379796C1 (ru) * 2008-12-09 2010-01-20 Государственное образовательное учреждение высшего профессионального образования "Московский энергетический институт" (технический университет)" (ГОУВПО "МЭИ(ТУ)") Система твердооксидных топливных элементов
JP5416513B2 (ja) * 2009-09-09 2014-02-12 川崎重工業株式会社 水素製造方法及び水素製造装置

Also Published As

Publication number Publication date
RU2589884C2 (ru) 2016-07-10
EP2692007B1 (en) 2016-03-23
CN103443982A (zh) 2013-12-11
PL2692007T3 (pl) 2016-09-30
EP2692007A1 (en) 2014-02-05
RU2013143732A (ru) 2015-05-10
WO2012135447A1 (en) 2012-10-04
CN103443982B (zh) 2016-01-27
US8778545B2 (en) 2014-07-15
US20120251898A1 (en) 2012-10-04
PT2692007E (pt) 2016-06-23
DK2692007T3 (en) 2016-06-27
JP2014511012A (ja) 2014-05-01
JP6063922B2 (ja) 2017-01-18

Similar Documents

Publication Publication Date Title
ES2575730T3 (es) Complejo de recirculación para aumentar el rendimiento de una pila de combustible con captura de CO2
ES2508173T3 (es) Sistema y método para generación de energía con alta eficiencia utilizando un fluido de trabajo de nitrógeno gaseoso
ES2714675T3 (es) Integración de la adsorción por oscilación de presión con una central de energía eléctrica para la captura/utilización de CO2 y la producción de N2
CA2801492C (en) Stoichiometric combustion with exhaust gas recirculation and direct contact cooler
EA201400889A1 (ru) Реакция парциального окисления с быстрым охлаждением в закрытом цикле
ES2769047T3 (es) Procedimiento y planta para la captura de CO2
Stępczyńska-Drygas et al. Calculation of an advanced ultra-supercritical power unit with CO2 capture installation
JP2011080464A5 (es)
US20130025294A1 (en) System and method for carbon dioxide removal
MX2012014458A (es) Combustion estequiometrica de aire enriquecido con recirculacion de gas de escape.
EP2333255A3 (en) Fossil fuel combustion thermal power system including carbon dioxide separation and capture unit
AR081787A1 (es) Sistema integrado y metodo de separacion de co
RU2561755C2 (ru) Способ работы и устройство газотурбинной установки
CN203743849U (zh) 一种利用液化天然气冷能发电及co2捕集的装置
JP2004210597A (ja) 排熱利用水素・酸素システムおよび液体水素の製造方法
RU2013153197A (ru) Топливный элемент и гибридная система газопоршневого/дизельного двигателя
EP2431579A3 (en) Multipurpose thermal power plant system
Xie et al. Energy analyses and process integration of coal-fired power plant with CO2 capture using sodium-based dry sorbents
Ziółkowski et al. Thermodynamic analysis of the double Brayton cycle with the use of oxy combustion and capture of CO 2
CN102201586B (zh) 燃料电池系统
CN104157891A (zh) 回收co2的煤气化加压熔融碳酸盐燃料电池复合动力系统
JP2013530815A (ja) 燃焼流中のco2排出量を低減する方法、及びこれを利用した工業プラント
NZ592301A (en) Method and apparatus for using compressed air to increase the efficiency of a fuel driven turbine generator
ES2544612T3 (es) Sistema de gasificación integrada en ciclo combinado con refrigeración por absorción de vapor
NO20130881A1 (no) Forbedringer ved gassturbinanlegg med CO2 fangst