ES2531399T3 - Recuperación de ácido carboxílico de una mezcla de carboxilato de magnesio - Google Patents
Recuperación de ácido carboxílico de una mezcla de carboxilato de magnesio Download PDFInfo
- Publication number
- ES2531399T3 ES2531399T3 ES12169359T ES12169359T ES2531399T3 ES 2531399 T3 ES2531399 T3 ES 2531399T3 ES 12169359 T ES12169359 T ES 12169359T ES 12169359 T ES12169359 T ES 12169359T ES 2531399 T3 ES2531399 T3 ES 2531399T3
- Authority
- ES
- Spain
- Prior art keywords
- magnesium
- carboxylic acid
- mixture
- forming
- recovery
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000203 mixture Substances 0.000 title abstract 4
- 150000001735 carboxylic acids Chemical class 0.000 title abstract 3
- 229910052749 magnesium Inorganic materials 0.000 title abstract 2
- 239000011777 magnesium Substances 0.000 title abstract 2
- -1 magnesium carboxylate Chemical class 0.000 title abstract 2
- 238000011084 recovery Methods 0.000 title 1
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 abstract 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 3
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 abstract 2
- 150000002500 ions Chemical class 0.000 abstract 2
- 229910001629 magnesium chloride Inorganic materials 0.000 abstract 2
- 229910001425 magnesium ion Inorganic materials 0.000 abstract 2
- 239000000395 magnesium oxide Substances 0.000 abstract 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 abstract 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 abstract 2
- 230000002378 acidificating effect Effects 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/02—Preparation of carboxylic acids or their salts, halides or anhydrides from salts of carboxylic acids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J39/00—Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
- B01J39/04—Processes using organic exchangers
- B01J39/05—Processes using organic exchangers in the strongly acidic form
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J49/00—Regeneration or reactivation of ion-exchangers; Apparatus therefor
- B01J49/50—Regeneration or reactivation of ion-exchangers; Apparatus therefor characterised by the regeneration reagents
- B01J49/53—Regeneration or reactivation of ion-exchangers; Apparatus therefor characterised by the regeneration reagents for cationic exchangers
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B7/00—Halogens; Halogen acids
- C01B7/01—Chlorine; Hydrogen chloride
- C01B7/03—Preparation from chlorides
- C01B7/035—Preparation of hydrogen chloride from chlorides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F5/00—Compounds of magnesium
- C01F5/02—Magnesia
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F5/00—Compounds of magnesium
- C01F5/02—Magnesia
- C01F5/06—Magnesia by thermal decomposition of magnesium compounds
- C01F5/10—Magnesia by thermal decomposition of magnesium compounds by thermal decomposition of magnesium chloride with water vapour
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F5/00—Compounds of magnesium
- C01F5/14—Magnesium hydroxide
- C01F5/16—Magnesium hydroxide by treating magnesia, e.g. calcined dolomite, with water or solutions of salts not containing magnesium
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F5/00—Compounds of magnesium
- C01F5/26—Magnesium halides
- C01F5/30—Chlorides
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P7/00—Preparation of oxygen-containing organic compounds
- C12P7/40—Preparation of oxygen-containing organic compounds containing a carboxyl group including Peroxycarboxylic acids
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Zoology (AREA)
- Wood Science & Technology (AREA)
- Microbiology (AREA)
- General Chemical & Material Sciences (AREA)
- Biotechnology (AREA)
- Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- Bioinformatics & Cheminformatics (AREA)
- General Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- Genetics & Genomics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Removal Of Specific Substances (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
Abstract
Método para recuperar ácido carboxílico de una mezcla acuosa que contiene carboxilato de magnesio, que incluye las fases de - poner la mezcla acuosa en contacto con un intercambiador iónico ácido, formando así una mezcla de ácido carboxílico y un intercambiador iónico cargado con iones de magnesio; y - poner el intercambiador iónico cargado con iones de magnesio en contacto con una solución de ácido clorhídrico, formando así una solución de cloruro de magnesio; y - descomponer térmicamente la solución de cloruro de magnesio a una temperatura de al menos 300 °C, formando así óxido de magnesio (MgO) y cloruro de hidrógeno (HCl).
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP12169359.2A EP2666763B1 (en) | 2012-05-24 | 2012-05-24 | Carboxylic acid recovery from magnesium carboxylate mixture |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2531399T3 true ES2531399T3 (es) | 2015-03-13 |
Family
ID=46149285
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES12169359T Active ES2531399T3 (es) | 2012-05-24 | 2012-05-24 | Recuperación de ácido carboxílico de una mezcla de carboxilato de magnesio |
Country Status (9)
| Country | Link |
|---|---|
| US (2) | US9422217B2 (es) |
| EP (1) | EP2666763B1 (es) |
| JP (2) | JP6046242B2 (es) |
| CN (1) | CN104321298A (es) |
| BR (1) | BR112014028993B1 (es) |
| ES (1) | ES2531399T3 (es) |
| HU (1) | HUE024575T2 (es) |
| PL (1) | PL2666763T3 (es) |
| WO (1) | WO2013174911A1 (es) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10683520B2 (en) | 2011-12-23 | 2020-06-16 | Purac Biochem Bv | Polycarboxylic acid extraction |
| VN39714A1 (en) * | 2011-12-23 | 2014-10-27 | Purac Biochem Bv | Polycarboxylic acid extraction |
| WO2014189991A1 (en) * | 2013-05-22 | 2014-11-27 | Segetis, Inc. | Process to prepare levulinic acid |
| EP2821368A1 (en) * | 2013-07-03 | 2015-01-07 | PURAC Biochem BV | Method for processing magnesium chloride solutions |
| EP3174989B1 (en) | 2014-07-28 | 2024-03-06 | PURAC Biochem BV | Preparation of lactic acid and/or a lactate salt from lignocellulosic material by separate saccharification and fermentation steps |
| CA2979589C (en) * | 2015-03-17 | 2020-04-28 | Purac Biochem Bv | Method for manufacturing furan-2,5-dicarboxylic acid (fdca) from a salt solution |
| AU2017210245B2 (en) * | 2016-01-19 | 2019-10-17 | Purac Biochem Bv | Improved method for processing magnesium chloride solutions and method for manufacturing carboxylic acids |
| CN108947066A (zh) * | 2018-07-13 | 2018-12-07 | 宁波永顺精细化工有限公司 | 羧酸钡废水中羧酸及钡盐的回收方法 |
| CN113924282B (zh) * | 2019-06-12 | 2023-09-12 | 诺力昂化学品国际有限公司 | 用于从含水侧流中分离羧酸的方法 |
| ES2963382T3 (es) | 2019-06-12 | 2024-03-26 | Nouryon Chemicals Int Bv | Proceso para la producción de peróxidos de diacilo |
| US20220306490A1 (en) * | 2019-06-12 | 2022-09-29 | Nouryon Chemicals International B.V. | Method for isolating carboxylic acid from an aqueous side stream |
| WO2020249689A1 (en) | 2019-06-12 | 2020-12-17 | Nouryon Chemicals International B.V. | Process for the production of peroxyesters |
| ES2963357T3 (es) | 2019-06-12 | 2024-03-26 | Nouryon Chemicals Int Bv | Proceso para la producción de peróxidos de diacilo |
| ES2961184T3 (es) | 2019-06-12 | 2024-03-08 | Nouryon Chemicals Int Bv | Proceso para la producción de peróxidos de diacilo |
| CN110963984B (zh) * | 2019-11-28 | 2023-03-28 | 南京奥凯索生物技术有限公司 | 一种呋喃二甲酰-聚羟基酸酯增塑剂及其应用 |
| CN112521269B (zh) * | 2020-12-23 | 2023-12-22 | 郑州瑞普生物工程有限公司 | 一种琥珀酸镁的制备方法 |
| WO2022144867A1 (en) * | 2021-01-04 | 2022-07-07 | Harcros Chemicals, Inc. | Antimicrobial compounds based on glucoheptonic acids and their salts |
| CN114906812B (zh) * | 2022-06-01 | 2023-06-23 | 湖南吴赣药业有限公司 | 一种有机混酸分离纯化方法 |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3694153A (en) * | 1970-10-30 | 1972-09-26 | Audrey E Stern | Liquid-liquid extraction process for the purification of phosphoric acid |
| DE2748133C2 (de) * | 1977-10-27 | 1989-02-02 | Metallgesellschaft Ag, 6000 Frankfurt | Verfahren zur Herstellung von hochreinem Magnesiumoxid |
| US4661258A (en) * | 1982-09-13 | 1987-04-28 | The Dow Chemical Company | Traveling bed ion exchange contact apparatus and process employing same |
| JPS60217897A (ja) * | 1984-04-13 | 1985-10-31 | Taki Chem Co Ltd | 乳酸の分離精製方法 |
| DE4025195A1 (de) * | 1990-08-09 | 1992-02-13 | Metallgesellschaft Ag | Verfahren zum feinreinigen einer waessrigen alkalichloridloesung fuer die membranelektrolyse |
| US5279716A (en) * | 1992-09-21 | 1994-01-18 | General Motors Corporation | Method for producing magnesium metal from magnesium oxide |
| US5858119A (en) * | 1995-05-17 | 1999-01-12 | Mayne; Michael D. | Ion exchange resin cleaning method |
| IL119389A (en) * | 1996-10-09 | 2001-10-31 | Cargill Inc | Process for the recovery of lactic acid by liquid-liquid extraction using a cation exchanger |
| IL126264A0 (en) | 1998-09-17 | 1999-05-09 | Tami Inst For Research & Dev L | Process for preparing lactic acid |
| CN1283553C (zh) * | 2001-08-17 | 2006-11-08 | 白朝洪 | 一种生产氧化镁的方法 |
| AU2004264354A1 (en) | 2003-08-12 | 2005-02-24 | Amgen Inc. | Arylsulfonamidobenzylic compounds |
| EP1669459B1 (en) | 2003-09-30 | 2014-10-22 | Ajinomoto Co., Inc. | Method of purifying succinic acid from fermentation liquid |
| DE602005014478D1 (de) * | 2004-06-17 | 2009-06-25 | Purac Biochem Bv | Verfahren zur herstellung von milchsäure oder lactat aus einem magnesiumlactat enthaltenden medium |
| BRPI0708623B1 (pt) * | 2006-03-08 | 2016-11-29 | Purac Biochem Bv | método para preparar um complexo de amina orgânica/ácido lático |
| WO2009153886A1 (ja) | 2008-06-20 | 2009-12-23 | 旭化成ケミカルズ株式会社 | α-ヒドロキシ酸の製造方法 |
| EP2519491A4 (en) * | 2009-12-31 | 2014-10-08 | Groupe Novasep Sas | PURIFICATION OF BERNSTEINIC ACID FROM THE FERMENTATION OF SPROUTS WITH AMMONIUM UCCINATE |
| US20120259138A1 (en) * | 2011-04-05 | 2012-10-11 | BioAmber International S.à.r.I. | Methods and systems of producing dicarboxylic acids |
-
2012
- 2012-05-24 ES ES12169359T patent/ES2531399T3/es active Active
- 2012-05-24 HU HUE12169359A patent/HUE024575T2/hu unknown
- 2012-05-24 PL PL12169359T patent/PL2666763T3/pl unknown
- 2012-05-24 EP EP12169359.2A patent/EP2666763B1/en active Active
-
2013
- 2013-05-23 JP JP2015513178A patent/JP6046242B2/ja active Active
- 2013-05-23 CN CN201380026290.0A patent/CN104321298A/zh active Pending
- 2013-05-23 BR BR112014028993-0A patent/BR112014028993B1/pt active IP Right Grant
- 2013-05-23 WO PCT/EP2013/060594 patent/WO2013174911A1/en not_active Ceased
- 2013-05-23 US US14/402,441 patent/US9422217B2/en active Active
-
2016
- 2016-07-14 US US15/210,586 patent/US10040746B2/en active Active
- 2016-11-16 JP JP2016222907A patent/JP6368346B2/ja active Active
Also Published As
| Publication number | Publication date |
|---|---|
| BR112014028993A2 (pt) | 2020-12-22 |
| JP2017071621A (ja) | 2017-04-13 |
| EP2666763A1 (en) | 2013-11-27 |
| JP2015523968A (ja) | 2015-08-20 |
| JP6046242B2 (ja) | 2016-12-14 |
| US20150094491A1 (en) | 2015-04-02 |
| WO2013174911A1 (en) | 2013-11-28 |
| PL2666763T3 (pl) | 2015-06-30 |
| BR112014028993B1 (pt) | 2021-04-06 |
| US10040746B2 (en) | 2018-08-07 |
| US20160318837A1 (en) | 2016-11-03 |
| HUE024575T2 (hu) | 2016-02-29 |
| CN104321298A (zh) | 2015-01-28 |
| JP6368346B2 (ja) | 2018-08-01 |
| EP2666763B1 (en) | 2014-12-31 |
| US9422217B2 (en) | 2016-08-23 |
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