ES2508172T3 - Ayudantes de procesado de pultrusión con partículas - Google Patents
Ayudantes de procesado de pultrusión con partículas Download PDFInfo
- Publication number
- ES2508172T3 ES2508172T3 ES11760925.5T ES11760925T ES2508172T3 ES 2508172 T3 ES2508172 T3 ES 2508172T3 ES 11760925 T ES11760925 T ES 11760925T ES 2508172 T3 ES2508172 T3 ES 2508172T3
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- Prior art keywords
- resin
- nanoparticles
- fibers
- fiber reinforced
- reinforced polymer
- Prior art date
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
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- B29C70/40—Shaping or impregnating by compression not applied
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- B29C70/52—Pultrusion, i.e. forming and compressing by continuously pulling through a die
- B29C70/521—Pultrusion, i.e. forming and compressing by continuously pulling through a die and impregnating the reinforcement before the die
-
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- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
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- C08J5/005—Reinforced macromolecular compounds with nanosized materials, e.g. nanoparticles, nanofibres, nanotubes, nanowires, nanorods or nanolayered materials
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
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- C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
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- C08J5/042—Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres with carbon fibres
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
- C08J5/06—Reinforcing macromolecular compounds with loose or coherent fibrous material using pretreated fibrous materials
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- C—CHEMISTRY; METALLURGY
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- C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
- C08J5/06—Reinforcing macromolecular compounds with loose or coherent fibrous material using pretreated fibrous materials
- C08J5/08—Reinforcing macromolecular compounds with loose or coherent fibrous material using pretreated fibrous materials glass fibres
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C08K3/36—Silica
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2509/00—Use of inorganic materials not provided for in groups B29K2503/00 - B29K2507/00, as filler
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2707/00—Use of elements other than metals for preformed parts, e.g. for inserts
- B29K2707/04—Carbon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2995/00—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
- B29K2995/0037—Other properties
- B29K2995/0078—Shear strength
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2363/00—Characterised by the use of epoxy resins; Derivatives of epoxy resins
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Nanotechnology (AREA)
- Composite Materials (AREA)
- Mechanical Engineering (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Reinforced Plastic Materials (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
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| US38390610P | 2010-09-17 | 2010-09-17 | |
| US383906P | 2010-09-17 | ||
| PCT/US2011/051277 WO2012037046A1 (en) | 2010-09-17 | 2011-09-13 | Nanoparticle pultrusion processing aide |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2508172T3 true ES2508172T3 (es) | 2014-10-16 |
Family
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Family Applications (1)
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|---|---|---|---|
| ES11760925.5T Active ES2508172T3 (es) | 2010-09-17 | 2011-09-13 | Ayudantes de procesado de pultrusión con partículas |
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| Country | Link |
|---|---|
| US (2) | US9162398B2 (enExample) |
| EP (1) | EP2616504B1 (enExample) |
| JP (1) | JP6039563B2 (enExample) |
| KR (1) | KR101874135B1 (enExample) |
| CN (1) | CN103108903B (enExample) |
| ES (1) | ES2508172T3 (enExample) |
| PL (1) | PL2616504T3 (enExample) |
| WO (1) | WO2012037046A1 (enExample) |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| PL2616504T3 (pl) | 2010-09-17 | 2015-01-30 | 3M Innovative Properties Co | Wsparcie procesowe pultruzji nanocząstek |
| KR101800921B1 (ko) * | 2010-09-17 | 2017-11-23 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 섬유 강화되고 나노입자 로딩된 열경화성 중합체 복합 와이어 및 케이블, 및 방법 |
| DE102012205650A1 (de) | 2012-04-05 | 2013-10-10 | Siemens Aktiengesellschaft | Isolierstoff für rotierende Maschinen |
| US9828473B2 (en) | 2013-05-10 | 2017-11-28 | Zyvex Performance Materials, Inc. | Nanoparticulates and a linear polymer delivery system |
| US10759140B1 (en) | 2013-05-17 | 2020-09-01 | United States of America as Represented by the Admin of the National Aeronautics and Space Administration | Composite damage tolerance and through thickness conductivity by interleaving carbon fiber veil nanocomposites |
| EP3033379B1 (en) | 2013-08-13 | 2020-12-02 | 3M Innovative Properties Company | Nanocomposites containing silica nanoparticles and dispersant, composites, articles, and methods of making same |
| CN103497475B (zh) * | 2013-10-10 | 2016-08-17 | 成都思摩纳米技术有限公司 | 一种玻璃钢及其制备方法 |
| KR101653977B1 (ko) * | 2014-08-28 | 2016-09-09 | 윈엔윈(주) | 금형속대 교체형 화살대 제작장치 |
| US20160368821A1 (en) * | 2015-06-17 | 2016-12-22 | International Business Machines Corporation | Method of glass fabric production including resin adhesion for printed circuit board formation |
| WO2017120025A1 (en) * | 2016-01-04 | 2017-07-13 | Dow Global Technologies Llc | Fiber composites with reduced surface roughness and methods for making them |
| US9835239B2 (en) | 2016-01-21 | 2017-12-05 | General Electric Company | Composite gearbox housing |
| CN106009613A (zh) * | 2016-06-28 | 2016-10-12 | 大连华工创新科技股份有限公司 | 一种玻璃纤维板材或型材或管材及成型方法 |
| WO2018045383A1 (en) * | 2016-09-02 | 2018-03-08 | 3M Innovative Properties Company | Optical fiber splice element and optical network |
| KR102202383B1 (ko) * | 2018-08-10 | 2021-01-12 | (주)엘지하우시스 | 섬유 강화 복합재의 제조방법 |
| JP2020090645A (ja) * | 2018-12-07 | 2020-06-11 | 三菱重工業株式会社 | 引抜成形材料及び引抜成形材料の製造方法 |
| EP3733389A1 (de) * | 2019-04-29 | 2020-11-04 | Covestro Deutschland AG | Verfahren zur herstellung von faserverstärkten kunststoffen |
| PL3899313T3 (pl) * | 2019-07-01 | 2022-11-21 | Mitsubishi Steel Mfg. Co., Ltd. | Kompozytowa sprężyna zwojowa z warstwami z włókien węglowych i szklanych |
| US11485833B2 (en) | 2019-10-23 | 2022-11-01 | Hexcel Corporation | Thermoplastic toughened matrix resins containing nanoparticles |
| CN112590262A (zh) * | 2020-12-17 | 2021-04-02 | 郑州大学 | 制备纤维增强聚合物杆的拉挤成型系统 |
| US20250375941A1 (en) * | 2022-06-20 | 2025-12-11 | Sylvio Moretti FILHO | Fiberglass and graphene reinforced polymeric bar and method of production thereof |
| WO2024148043A2 (en) * | 2023-01-04 | 2024-07-11 | Colorado State University Research Foundation | Rapid manufacturing of composite structures using filament winding techniques |
Family Cites Families (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6183651A (ja) * | 1984-09-27 | 1986-04-28 | Nitto Electric Ind Co Ltd | 繊維強化光フアイバ−の製造方法 |
| JPH081804A (ja) * | 1994-06-17 | 1996-01-09 | Mitsui Toatsu Chem Inc | 繊維強化フェノール樹脂の引抜成形方法 |
| US5648407A (en) | 1995-05-16 | 1997-07-15 | Minnesota Mining And Manufacturing Company | Curable resin sols and fiber-reinforced composites derived therefrom |
| US5681513A (en) * | 1995-08-04 | 1997-10-28 | The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration | Method for fabricating composite structures using continuous press forming |
| WO1997028210A1 (en) * | 1996-02-02 | 1997-08-07 | Toray Industries, Inc. | Resin compositions for fiber-reinforced composite materials and processes for producing the same, prepregs, fiber-reinforced composite materials, and honeycomb structures |
| EP0825222B1 (en) | 1996-02-21 | 2005-06-01 | Toray Industries, Inc. | Yarn preprared and fiber-reinforced composite material prepeared therefrom |
| JPH09227693A (ja) * | 1996-02-21 | 1997-09-02 | Toray Ind Inc | エポキシ樹脂組成物、プリプレグ、複合材料およびコンクリート部材 |
| US8105690B2 (en) * | 1998-03-03 | 2012-01-31 | Ppg Industries Ohio, Inc | Fiber product coated with particles to adjust the friction of the coating and the interfilament bonding |
| AU3489800A (en) | 1999-02-12 | 2000-08-29 | Dow Chemical Company, The | Nanocomposite articles and process for making |
| JP2001181406A (ja) * | 1999-12-22 | 2001-07-03 | Kanazawa Inst Of Technology | 炭素繊維強化プラスチック、およびそれを用いた部材 |
| JP2003301364A (ja) | 2002-04-10 | 2003-10-24 | Shikibo Ltd | 短繊維交絡による一方向長繊維三次元構造体 |
| US7179522B2 (en) | 2002-04-23 | 2007-02-20 | Ctc Cable Corporation | Aluminum conductor composite core reinforced cable and method of manufacture |
| US6883370B2 (en) | 2002-06-28 | 2005-04-26 | Heetronix | Mass flow meter with chip-type sensors |
| GB0216170D0 (en) * | 2002-07-12 | 2002-08-21 | Hexcel Composites Ltd | Resin compositions |
| JP4201573B2 (ja) | 2002-10-29 | 2008-12-24 | 矢崎総業株式会社 | 電線被覆用樹脂組成物およびそれを用いた電線 |
| DE10334856B4 (de) | 2003-07-29 | 2007-06-06 | Deutsches Zentrum für Luft- und Raumfahrt e.V. | Verbundformteil und Verfahren zu seiner Herstellung |
| EP1678063A4 (en) | 2003-10-22 | 2008-10-08 | Ctc Cable Corp | ACCC-REINFORCED CABLE (ACCC-ALUMINUM CONDUCTOR COMPOSITE CORE) AND METHOD OF MANUFACTURING |
| US20050279527A1 (en) | 2004-06-17 | 2005-12-22 | Johnson Douglas E | Cable and method of making the same |
| US20050279526A1 (en) | 2004-06-17 | 2005-12-22 | Johnson Douglas E | Cable and method of making the same |
| US7093416B2 (en) | 2004-06-17 | 2006-08-22 | 3M Innovative Properties Company | Cable and method of making the same |
| EP1910443A2 (en) | 2005-07-15 | 2008-04-16 | Cyclics Corporation | Macrocyclic polyester oligomers as carriers and/or flow modifier additives for thermoplastics |
| FR2895398B1 (fr) | 2005-12-23 | 2008-03-28 | Saint Gobain Vetrotex | Fils de verre revetus d'un ensimage renfermant des nanoparticules. |
| US20080160286A1 (en) * | 2006-12-27 | 2008-07-03 | Jawed Asrar | Modified discontinuous glass fibers for use in the formation of thermoplastic fiber-reinforced composite articles |
| FR2918081B1 (fr) * | 2007-06-27 | 2009-09-18 | Cabinet Hecke Sa | Procede d'impregnation de fibres continues par une matrice polymerique composite renfermant un polymere thermoplastique |
| JP2009061701A (ja) * | 2007-09-06 | 2009-03-26 | Osaka Municipal Technical Research Institute | 引抜成形品の製造方法、および該製造方法により得られた成形品 |
| CN102037083B (zh) | 2008-03-28 | 2014-02-05 | 3M创新有限公司 | 用于粒子表面改性的方法 |
| DE102008038295B4 (de) * | 2008-08-18 | 2013-11-28 | Eads Deutschland Gmbh | Granulierung und Stabilisierung von Harzsystemen zur Verwendung bei der Herstellung von Faserverbundbauteilen |
| WO2010080459A1 (en) * | 2008-12-19 | 2010-07-15 | 3M Innovative Properties Company | Nanocalcite composites |
| EP2385974A4 (en) * | 2009-01-06 | 2012-12-05 | Dow Global Technologies Llc | METAL STABILIZERS FOR EPOXY RESINS AND DISPERSION METHOD |
| US8541485B2 (en) | 2009-05-26 | 2013-09-24 | 3M Innovative Properties Company | Process for making filled resins |
| KR101800921B1 (ko) * | 2010-09-17 | 2017-11-23 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 섬유 강화되고 나노입자 로딩된 열경화성 중합체 복합 와이어 및 케이블, 및 방법 |
| PL2616504T3 (pl) * | 2010-09-17 | 2015-01-30 | 3M Innovative Properties Co | Wsparcie procesowe pultruzji nanocząstek |
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2011
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- 2011-09-13 US US13/230,910 patent/US9162398B2/en not_active Expired - Fee Related
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Also Published As
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| JP6039563B2 (ja) | 2016-12-07 |
| US20160039153A1 (en) | 2016-02-11 |
| JP2013537124A (ja) | 2013-09-30 |
| US9682518B2 (en) | 2017-06-20 |
| CN103108903A (zh) | 2013-05-15 |
| US9162398B2 (en) | 2015-10-20 |
| EP2616504A1 (en) | 2013-07-24 |
| CN103108903B (zh) | 2017-02-15 |
| KR20130118868A (ko) | 2013-10-30 |
| WO2012037046A1 (en) | 2012-03-22 |
| US20120071586A1 (en) | 2012-03-22 |
| PL2616504T3 (pl) | 2015-01-30 |
| EP2616504B1 (en) | 2014-07-30 |
| KR101874135B1 (ko) | 2018-07-03 |
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