ES2344139T3 - Proceso para la descontaminacion y la descomposicion de los pcb. - Google Patents
Proceso para la descontaminacion y la descomposicion de los pcb. Download PDFInfo
- Publication number
- ES2344139T3 ES2344139T3 ES01945374T ES01945374T ES2344139T3 ES 2344139 T3 ES2344139 T3 ES 2344139T3 ES 01945374 T ES01945374 T ES 01945374T ES 01945374 T ES01945374 T ES 01945374T ES 2344139 T3 ES2344139 T3 ES 2344139T3
- Authority
- ES
- Spain
- Prior art keywords
- pcbs
- decomposition
- enclosure
- materials
- pcb
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 150000003071 polychlorinated biphenyls Chemical group 0.000 title claims abstract description 62
- 238000000034 method Methods 0.000 title claims abstract description 38
- 238000000354 decomposition reaction Methods 0.000 title claims abstract description 33
- 238000005202 decontamination Methods 0.000 title claims abstract description 25
- 230000003588 decontaminative effect Effects 0.000 title claims abstract description 23
- 239000000463 material Substances 0.000 claims abstract description 66
- 238000010438 heat treatment Methods 0.000 claims abstract description 33
- 239000003344 environmental pollutant Substances 0.000 claims abstract description 32
- 231100000719 pollutant Toxicity 0.000 claims abstract description 32
- 239000000356 contaminant Substances 0.000 claims abstract description 23
- 238000004821 distillation Methods 0.000 claims abstract description 19
- 239000011261 inert gas Substances 0.000 claims abstract description 14
- 239000000693 micelle Substances 0.000 claims abstract description 14
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000001301 oxygen Substances 0.000 claims abstract description 11
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 11
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910052753 mercury Inorganic materials 0.000 claims abstract description 10
- 238000009833 condensation Methods 0.000 claims abstract description 7
- 230000005494 condensation Effects 0.000 claims abstract description 7
- 239000000047 product Substances 0.000 claims description 12
- 238000006386 neutralization reaction Methods 0.000 claims description 10
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 9
- 239000000460 chlorine Substances 0.000 claims description 9
- 229910052801 chlorine Inorganic materials 0.000 claims description 9
- 238000002485 combustion reaction Methods 0.000 claims description 5
- 230000006698 induction Effects 0.000 claims description 5
- 238000005979 thermal decomposition reaction Methods 0.000 claims description 5
- 239000006227 byproduct Substances 0.000 claims description 4
- 230000005611 electricity Effects 0.000 claims description 4
- 238000011068 loading method Methods 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 2
- 239000004020 conductor Substances 0.000 claims description 2
- 238000007669 thermal treatment Methods 0.000 claims 1
- 239000007788 liquid Substances 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 5
- 238000000605 extraction Methods 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- YLQBMQCUIZJEEH-UHFFFAOYSA-N Furan Chemical compound C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 230000003472 neutralizing effect Effects 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000009434 installation Methods 0.000 description 3
- 239000002023 wood Substances 0.000 description 3
- KVGZZAHHUNAVKZ-UHFFFAOYSA-N 1,4-Dioxin Chemical compound O1C=COC=C1 KVGZZAHHUNAVKZ-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 159000000007 calcium salts Chemical class 0.000 description 2
- 239000003990 capacitor Substances 0.000 description 2
- 239000012809 cooling fluid Substances 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 150000002013 dioxins Chemical class 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 150000002240 furans Chemical class 0.000 description 2
- 238000005984 hydrogenation reaction Methods 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000003595 mist Substances 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000003507 refrigerant Substances 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 230000004580 weight loss Effects 0.000 description 2
- 238000004804 winding Methods 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 239000012080 ambient air Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 231100000357 carcinogen Toxicity 0.000 description 1
- 239000003183 carcinogenic agent Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000006298 dechlorination reaction Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005674 electromagnetic induction Effects 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000011081 inoculation Methods 0.000 description 1
- 238000009533 lab test Methods 0.000 description 1
- 230000000696 methanogenic effect Effects 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 238000009666 routine test Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000002604 ultrasonography Methods 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D3/00—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances
- A62D3/40—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances by heating to effect chemical change, e.g. pyrolysis
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G7/00—Distillation of hydrocarbon oils
- C10G7/006—Distillation of hydrocarbon oils of waste oils other than lubricating oils, e.g. PCB's containing oils
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D2101/00—Harmful chemical substances made harmless, or less harmful, by effecting chemical change
- A62D2101/20—Organic substances
- A62D2101/22—Organic substances containing halogen
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D2203/00—Aspects of processes for making harmful chemical substances harmless, or less harmful, by effecting chemical change in the substances
- A62D2203/04—Combined processes involving two or more non-distinct steps covered by groups A62D3/10 - A62D3/40
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D2203/00—Aspects of processes for making harmful chemical substances harmless, or less harmful, by effecting chemical change in the substances
- A62D2203/10—Apparatus specially adapted for treating harmful chemical agents; Details thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Business, Economics & Management (AREA)
- Emergency Management (AREA)
- Processing Of Solid Wastes (AREA)
- Fire-Extinguishing Compositions (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/FR2001/001766 WO2002098514A1 (fr) | 2001-06-07 | 2001-06-07 | Procede pour la decontamination et la decomposition des pcb |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2344139T3 true ES2344139T3 (es) | 2010-08-19 |
Family
ID=8859822
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES01945374T Expired - Lifetime ES2344139T3 (es) | 2001-06-07 | 2001-06-07 | Proceso para la descontaminacion y la descomposicion de los pcb. |
Country Status (6)
| Country | Link |
|---|---|
| EP (1) | EP1432477B1 (de) |
| AT (1) | ATE459394T1 (de) |
| DE (1) | DE60141484D1 (de) |
| ES (1) | ES2344139T3 (de) |
| HU (1) | HU228885B1 (de) |
| WO (1) | WO2002098514A1 (de) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2825641B1 (fr) * | 2001-06-07 | 2006-03-03 | Aprochim | Procede pour la decontamination de materiaux souilles par les pcb et la decomposition de la molecule de pcb |
| FR2961722B1 (fr) | 2010-06-29 | 2013-02-22 | Aprochim | Procede et dispositif pour la decontamination de materiaux pollues |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3426059A1 (de) * | 1984-07-14 | 1986-01-16 | Hugo Petersen Gesellschaft für verfahrenstechnischen Anlagenbau mbH & Co KG, 6200 Wiesbaden | Verfahren zur abscheidung und beseitigung von organischen schadstoffen, insbesondere von polychlorierten dibenzodioxinen (pcdd) aus rauchgasen |
| GB2167061B (en) * | 1984-11-12 | 1987-10-07 | Micanite And Insulators Compan | Polychlorobiphenyl decontamination |
| US4982039A (en) * | 1987-09-03 | 1991-01-01 | University Of Southern California | Conversion of halogenated toxic substances |
| FR2653044B1 (fr) * | 1989-10-12 | 1992-03-27 | Pec Engineering | Procede et dispositifs de decontamination de produits solides. |
| DE4005002A1 (de) * | 1990-02-19 | 1991-08-22 | Gsu Systemtechnik Gmbh | Verfahren zur gezielten zerlegung und verwertung von mit hochtoxischen substanzen verunreinigtem metallschrott |
| US5103578A (en) * | 1991-03-26 | 1992-04-14 | Amoco Corporation | Method and apparatus for removing volatile organic compounds from soils |
| FR2686347B1 (fr) * | 1992-01-22 | 1994-10-07 | Lorraine Carbone | Procede de pyrolyse d'effluents fluides et dispositif correspondant. |
| US5253597A (en) * | 1992-06-18 | 1993-10-19 | Chemical Waste Management, Inc. | Process for separating organic contaminants from contaminated soils and sludges |
| DE19581565T1 (de) * | 1994-03-15 | 1997-05-07 | Eskom | Behandlung von unerwünschten organischen Halogenverbindungen |
| JPH08758A (ja) * | 1994-06-17 | 1996-01-09 | Toshiba Corp | 有害塩素化合物の光分解装置 |
| DE19904903A1 (de) * | 1998-08-07 | 2000-02-10 | Ald Vacuum Techn Gmbh | Verfahren und Vorrichtung zum Entsorgen von elektrischen Grossgeräten |
| FR2800628B3 (fr) * | 1999-11-09 | 2002-04-12 | Yves Rene Pierre Guibert | Procede de traitement d'effluents gazeux et des fumees |
| FR2801800B1 (fr) * | 1999-12-07 | 2003-09-26 | Yves Guibert | Procede de decontamination de materiaux souilles par les pcb(polychlorobiphenyles) et decomposition de la molecule pcb sans production de dioxines ou furanes |
-
2001
- 2001-06-07 AT AT01945374T patent/ATE459394T1/de active
- 2001-06-07 ES ES01945374T patent/ES2344139T3/es not_active Expired - Lifetime
- 2001-06-07 HU HU0401688A patent/HU228885B1/hu not_active IP Right Cessation
- 2001-06-07 DE DE60141484T patent/DE60141484D1/de not_active Expired - Lifetime
- 2001-06-07 WO PCT/FR2001/001766 patent/WO2002098514A1/fr not_active Ceased
- 2001-06-07 EP EP01945374A patent/EP1432477B1/de not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| EP1432477A1 (de) | 2004-06-30 |
| ATE459394T1 (de) | 2010-03-15 |
| DE60141484D1 (de) | 2010-04-15 |
| HUP0401688A2 (hu) | 2005-08-29 |
| HU228885B1 (en) | 2013-06-28 |
| EP1432477B1 (de) | 2010-03-03 |
| WO2002098514A1 (fr) | 2002-12-12 |
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