ES2311505T3 - Procedimiento para la eliminacion del residuo generado por la hidrogenacion catalitica de los polimeros hidrogenadas. - Google Patents
Procedimiento para la eliminacion del residuo generado por la hidrogenacion catalitica de los polimeros hidrogenadas. Download PDFInfo
- Publication number
- ES2311505T3 ES2311505T3 ES01903746T ES01903746T ES2311505T3 ES 2311505 T3 ES2311505 T3 ES 2311505T3 ES 01903746 T ES01903746 T ES 01903746T ES 01903746 T ES01903746 T ES 01903746T ES 2311505 T3 ES2311505 T3 ES 2311505T3
- Authority
- ES
- Spain
- Prior art keywords
- polymer
- acid
- hydrogenation
- amount
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920000642 polymer Polymers 0.000 title claims abstract description 50
- 238000000034 method Methods 0.000 title claims abstract description 30
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical class [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims abstract description 8
- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract description 8
- 239000001257 hydrogen Substances 0.000 title claims abstract description 8
- 238000009903 catalytic hydrogenation reaction Methods 0.000 title claims description 9
- 239000002699 waste material Substances 0.000 title claims description 7
- 230000008030 elimination Effects 0.000 title description 5
- 238000003379 elimination reaction Methods 0.000 title description 5
- 239000002253 acid Substances 0.000 claims abstract description 27
- 238000005984 hydrogenation reaction Methods 0.000 claims abstract description 24
- 239000007864 aqueous solution Substances 0.000 claims abstract description 23
- 239000011414 polymer cement Substances 0.000 claims abstract description 20
- 239000003054 catalyst Substances 0.000 claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000007788 liquid Substances 0.000 claims abstract description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 19
- 239000000243 solution Substances 0.000 claims description 13
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 12
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 12
- 238000011282 treatment Methods 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 10
- 229910052759 nickel Inorganic materials 0.000 claims description 10
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 8
- 239000003963 antioxidant agent Substances 0.000 claims description 8
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 6
- 229910052757 nitrogen Inorganic materials 0.000 claims description 6
- 229910052760 oxygen Inorganic materials 0.000 claims description 6
- 239000001301 oxygen Substances 0.000 claims description 6
- 230000002378 acidificating effect Effects 0.000 claims description 5
- 239000011260 aqueous acid Substances 0.000 claims description 5
- 150000001993 dienes Chemical class 0.000 claims description 5
- 229910052751 metal Inorganic materials 0.000 claims description 5
- 239000002184 metal Substances 0.000 claims description 5
- 239000000178 monomer Substances 0.000 claims description 5
- 238000006116 polymerization reaction Methods 0.000 claims description 5
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 claims description 4
- -1 anionic diene Chemical class 0.000 claims description 4
- 230000003078 antioxidant effect Effects 0.000 claims description 4
- 239000007800 oxidant agent Substances 0.000 claims description 3
- 238000005406 washing Methods 0.000 claims description 3
- 235000019799 monosodium phosphate Nutrition 0.000 claims description 2
- 238000000926 separation method Methods 0.000 claims description 2
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 claims description 2
- 229910000162 sodium phosphate Inorganic materials 0.000 claims description 2
- 229920002554 vinyl polymer Polymers 0.000 claims description 2
- 229910017052 cobalt Inorganic materials 0.000 claims 1
- 239000010941 cobalt Substances 0.000 claims 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims 1
- 150000007522 mineralic acids Chemical class 0.000 claims 1
- 239000004568 cement Substances 0.000 description 14
- 239000008346 aqueous phase Substances 0.000 description 5
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 238000000605 extraction Methods 0.000 description 4
- 239000012634 fragment Substances 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 230000003197 catalytic effect Effects 0.000 description 3
- 238000006555 catalytic reaction Methods 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- OBETXYAYXDNJHR-UHFFFAOYSA-N 2-Ethylhexanoic acid Chemical compound CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 229930013930 alkaloid Natural products 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 229920001400 block copolymer Polymers 0.000 description 2
- 238000003889 chemical engineering Methods 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 238000009616 inductively coupled plasma Methods 0.000 description 2
- 239000010814 metallic waste Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 235000020030 perry Nutrition 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
- 101100283604 Caenorhabditis elegans pigk-1 gene Proteins 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 238000010306 acid treatment Methods 0.000 description 1
- 239000003929 acidic solution Substances 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 238000010539 anionic addition polymerization reaction Methods 0.000 description 1
- 238000010533 azeotropic distillation Methods 0.000 description 1
- FACXGONDLDSNOE-UHFFFAOYSA-N buta-1,3-diene;styrene Chemical compound C=CC=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 FACXGONDLDSNOE-UHFFFAOYSA-N 0.000 description 1
- SHZIWNPUGXLXDT-UHFFFAOYSA-N caproic acid ethyl ester Natural products CCCCCC(=O)OCC SHZIWNPUGXLXDT-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001868 cobalt Chemical class 0.000 description 1
- 150000004700 cobalt complex Chemical class 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000001095 inductively coupled plasma mass spectrometry Methods 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- WGOPGODQLGJZGL-UHFFFAOYSA-N lithium;butane Chemical compound [Li+].CC[CH-]C WGOPGODQLGJZGL-UHFFFAOYSA-N 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 239000012074 organic phase Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 230000002110 toxicologic effect Effects 0.000 description 1
- 231100000027 toxicology Toxicity 0.000 description 1
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C2/00—Treatment of rubber solutions
- C08C2/02—Purification
- C08C2/04—Removal of catalyst residues
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
- C08C19/02—Hydrogenation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F6/00—Post-polymerisation treatments
- C08F6/02—Neutralisation of the polymerisation mass, e.g. killing the catalyst also removal of catalyst residues
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/04—Reduction, e.g. hydrogenation
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP00301081 | 2000-02-11 | ||
| EP00301081 | 2000-02-11 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2311505T3 true ES2311505T3 (es) | 2009-02-16 |
Family
ID=8172699
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES01903746T Expired - Lifetime ES2311505T3 (es) | 2000-02-11 | 2001-02-09 | Procedimiento para la eliminacion del residuo generado por la hidrogenacion catalitica de los polimeros hidrogenadas. |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US6800725B2 (enExample) |
| EP (1) | EP1263799B1 (enExample) |
| JP (1) | JP2003522258A (enExample) |
| CN (1) | CN1157418C (enExample) |
| AT (1) | ATE403681T1 (enExample) |
| AU (1) | AU2001231732A1 (enExample) |
| BR (1) | BR0108265A (enExample) |
| DE (1) | DE60135207D1 (enExample) |
| ES (1) | ES2311505T3 (enExample) |
| MX (1) | MXPA02007680A (enExample) |
| RU (1) | RU2254344C2 (enExample) |
| TW (1) | TW538061B (enExample) |
| WO (1) | WO2001058965A1 (enExample) |
| ZA (1) | ZA200206302B (enExample) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU2003247954A1 (en) * | 2002-07-10 | 2004-01-23 | Kraton Polymers Research B.V. | Improved wash process for hydrogenated polymers |
| KR100910255B1 (ko) | 2007-10-08 | 2009-07-31 | 금호석유화학 주식회사 | 수소화된 공역디엔계 중합체의 제조방법 |
| US9102766B2 (en) | 2009-06-03 | 2015-08-11 | Kuraray Co., Ltd. | Method for producing a hydrogenated block copolymer, hydrogenated block copolymer obtained by said production method and composition thereof |
| KR101730669B1 (ko) | 2009-06-03 | 2017-04-26 | 주식회사 쿠라레 | 수소 첨가 블록 공중합체의 제조 방법, 그 제조 방법에 의해 얻어진 수소 첨가 블록 공중합체 및 그 조성물 |
| CA3162668A1 (en) * | 2010-02-12 | 2011-08-18 | Gentelon, Inc. | Compositions and methods for treating depression |
| TWI586693B (zh) | 2013-07-23 | 2017-06-11 | 財團法人工業技術研究院 | 選擇性氫化共聚物的方法 |
| US10471405B2 (en) * | 2015-03-24 | 2019-11-12 | Sabic Global Technologies B.V. | Continuous gas fluidized bed polymerization process |
| CA3042699A1 (en) | 2016-11-03 | 2018-08-09 | Alexander Vuckovic, M.D., Llc | Compositions and methods for treating depression |
| CN109734828A (zh) * | 2018-12-25 | 2019-05-10 | 山东玉皇化工有限公司 | 一种脱除不饱和聚合物加氢后残余金属催化剂的方法 |
Family Cites Families (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB954992A (en) | 1960-11-24 | 1964-04-08 | Ici Ltd | New dyestuffs containing substituted pyrimidine or triazine radicals |
| BE615636A (enExample) | 1961-03-29 | 1900-01-01 | ||
| US3113986A (en) | 1962-01-08 | 1963-12-10 | Hercules Powder Co Ltd | Hydrogenation of unsaturated hydrocarbons |
| US3202647A (en) | 1962-11-19 | 1965-08-24 | Shell Oil Co | Elastomer recovery process |
| GB1151598A (en) | 1965-07-19 | 1969-05-07 | Bridgestone Tire Co Ltd | Hydrocarbon Polymers and process for producing them from Hydrocarbon Polymers containing Olefinic Unsaturations |
| US3531448A (en) * | 1968-11-06 | 1970-09-29 | Phillips Petroleum Co | Process for removal of hydrogenation catalyst from hyrogenated polymers |
| US3700748A (en) | 1970-05-22 | 1972-10-24 | Shell Oil Co | Selectively hydrogenated block copolymers |
| US3700633A (en) | 1971-05-05 | 1972-10-24 | Shell Oil Co | Selectively hydrogenated block copolymers |
| BE788698A (fr) * | 1971-09-14 | 1973-03-12 | Shell Int Research | Procede d'elimination de contaminants metalliques dans un polymere |
| US3801520A (en) | 1972-01-21 | 1974-04-02 | Phillips Petroleum Co | Carbon dioxide and water treatment of coupled lithium initiated polymer |
| US3987006A (en) | 1975-08-14 | 1976-10-19 | Phillips Petroleum Company | Carbon dioxide and excess water treatment of polymer stabilized with phosphite and glycine |
| US4028485A (en) * | 1976-01-29 | 1977-06-07 | Mobil Oil Corporation | Non-aqueous removal of soluble hydrogenation catalyst |
| US4396761A (en) * | 1981-08-21 | 1983-08-02 | Shell Oil Company | Method for removing hydrogenation catalyst residues from hydrogenated conjugated diene polymers |
| US4403074A (en) | 1982-01-13 | 1983-09-06 | Phillips Petroleum Company | Clear haze-free impact-resistant resinous polymers |
| US4471099A (en) * | 1983-03-07 | 1984-09-11 | Phillips Petroleum Company | Treatment of a hydrogenated polymer solution after hydrogenation catalyst removal to improve subsequent lithiation reaction |
| JPH01182308A (ja) * | 1988-01-14 | 1989-07-20 | Asahi Chem Ind Co Ltd | 重合体の取得法 |
| JP2884603B2 (ja) | 1989-07-17 | 1999-04-19 | 住友電気工業株式会社 | 半導体レーザ素子 |
| RU2043996C1 (ru) * | 1992-06-24 | 1995-09-20 | Воронежский филиал Государственного предприятия Научно-исследовательский институт синтетического каучука им.акад.С.В.Лебедева | Способ очистки полимера от остатков катализатора гидрирования, содержащего никелевый катализатор |
| JP3306520B2 (ja) | 1992-08-06 | 2002-07-24 | コニカ株式会社 | 画像形成装置 |
| JPH0764889A (ja) | 1993-08-31 | 1995-03-10 | Sanyo Electric Co Ltd | 通信端末装置 |
| CA2171045C (en) | 1995-03-06 | 2002-08-13 | Manabu Kusano | Microporous crumbs of hydrogenated block copolymers and process for producing the same |
| USH1956H1 (en) * | 1997-07-23 | 2001-04-03 | Shell Oil Company | Enhanced hydrogenation catalyst removal from block copolymers by reduction in polymer cement viscosity by increasing the vinyl content of the block copolymers |
| BR9803201A (pt) * | 1997-08-22 | 1999-12-21 | Shell Int Research | Extração de resíduos metálicos a partir de cimentos poliméricos. |
| US6207795B1 (en) | 1998-08-31 | 2001-03-27 | Shell Oil Company | Removal of hydrogenation catalyst from polymer solutions by treatment with ammonia and carbon dioxide |
| KR100411861B1 (ko) * | 2000-11-28 | 2003-12-18 | 금호석유화학 주식회사 | 유기티타늄 화합물로 선택적으로 수소화된 중합체로부터금속 촉매를 제거하는 방법 |
| JP4716602B2 (ja) * | 2001-05-30 | 2011-07-06 | 旭化成ケミカルズ株式会社 | 重合体の脱灰方法 |
-
2001
- 2001-02-09 JP JP2001558110A patent/JP2003522258A/ja active Pending
- 2001-02-09 AU AU2001231732A patent/AU2001231732A1/en not_active Abandoned
- 2001-02-09 BR BR0108265-5A patent/BR0108265A/pt not_active Application Discontinuation
- 2001-02-09 WO PCT/EP2001/001511 patent/WO2001058965A1/en not_active Ceased
- 2001-02-09 ES ES01903746T patent/ES2311505T3/es not_active Expired - Lifetime
- 2001-02-09 CN CNB018047564A patent/CN1157418C/zh not_active Expired - Fee Related
- 2001-02-09 RU RU2002124140/04A patent/RU2254344C2/ru not_active IP Right Cessation
- 2001-02-09 DE DE60135207T patent/DE60135207D1/de not_active Expired - Fee Related
- 2001-02-09 AT AT01903746T patent/ATE403681T1/de not_active IP Right Cessation
- 2001-02-09 US US10/203,142 patent/US6800725B2/en not_active Expired - Fee Related
- 2001-02-09 EP EP01903746A patent/EP1263799B1/en not_active Expired - Lifetime
- 2001-02-09 MX MXPA02007680A patent/MXPA02007680A/es not_active Application Discontinuation
- 2001-05-07 TW TW090110842A patent/TW538061B/zh not_active IP Right Cessation
-
2002
- 2002-08-07 ZA ZA200206302A patent/ZA200206302B/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| US6800725B2 (en) | 2004-10-05 |
| TW538061B (en) | 2003-06-21 |
| BR0108265A (pt) | 2003-03-05 |
| MXPA02007680A (es) | 2002-12-13 |
| CN1416436A (zh) | 2003-05-07 |
| RU2254344C2 (ru) | 2005-06-20 |
| CN1157418C (zh) | 2004-07-14 |
| AU2001231732A1 (en) | 2001-08-20 |
| EP1263799A1 (en) | 2002-12-11 |
| JP2003522258A (ja) | 2003-07-22 |
| EP1263799B1 (en) | 2008-08-06 |
| US20030139569A1 (en) | 2003-07-24 |
| RU2002124140A (ru) | 2004-01-10 |
| WO2001058965A1 (en) | 2001-08-16 |
| ATE403681T1 (de) | 2008-08-15 |
| DE60135207D1 (de) | 2008-09-18 |
| ZA200206302B (en) | 2003-07-29 |
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