ES2216011T3 - Detergentes que contienen un secuestrante de metales pesados y un sistema de blanqueante peroxiacido de liberacion retrasada. - Google Patents
Detergentes que contienen un secuestrante de metales pesados y un sistema de blanqueante peroxiacido de liberacion retrasada.Info
- Publication number
- ES2216011T3 ES2216011T3 ES95915004T ES95915004T ES2216011T3 ES 2216011 T3 ES2216011 T3 ES 2216011T3 ES 95915004 T ES95915004 T ES 95915004T ES 95915004 T ES95915004 T ES 95915004T ES 2216011 T3 ES2216011 T3 ES 2216011T3
- Authority
- ES
- Spain
- Prior art keywords
- peroxyacid
- bleach
- metal ion
- release
- heavy metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003599 detergent Substances 0.000 title claims abstract description 108
- 229910001385 heavy metal Inorganic materials 0.000 title claims abstract description 59
- 238000004061 bleaching Methods 0.000 title claims description 52
- 230000003111 delayed effect Effects 0.000 title description 17
- 239000000203 mixture Substances 0.000 claims abstract description 204
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 66
- 150000002500 ions Chemical class 0.000 claims abstract description 63
- 150000001875 compounds Chemical class 0.000 claims description 105
- 239000000243 solution Substances 0.000 claims description 86
- 239000007844 bleaching agent Substances 0.000 claims description 81
- -1 compound organic peroxyacid Chemical class 0.000 claims description 81
- 238000005406 washing Methods 0.000 claims description 70
- 239000002243 precursor Substances 0.000 claims description 67
- 125000000217 alkyl group Chemical group 0.000 claims description 63
- 239000003352 sequestering agent Substances 0.000 claims description 63
- 238000000034 method Methods 0.000 claims description 59
- 125000004432 carbon atom Chemical group C* 0.000 claims description 47
- 150000004967 organic peroxy acids Chemical class 0.000 claims description 41
- 239000002245 particle Substances 0.000 claims description 38
- 150000004965 peroxy acids Chemical class 0.000 claims description 37
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 36
- 238000000576 coating method Methods 0.000 claims description 36
- 239000003054 catalyst Substances 0.000 claims description 32
- 239000011248 coating agent Substances 0.000 claims description 32
- 125000003118 aryl group Chemical group 0.000 claims description 28
- 150000001412 amines Chemical class 0.000 claims description 22
- 239000003446 ligand Substances 0.000 claims description 21
- 229910052748 manganese Inorganic materials 0.000 claims description 18
- 239000000758 substrate Substances 0.000 claims description 17
- 238000010998 test method Methods 0.000 claims description 15
- YNJSNEKCXVFDKW-UHFFFAOYSA-N 3-(5-amino-1h-indol-3-yl)-2-azaniumylpropanoate Chemical compound C1=C(N)C=C2C(CC(N)C(O)=O)=CNC2=C1 YNJSNEKCXVFDKW-UHFFFAOYSA-N 0.000 claims description 13
- 229910052799 carbon Inorganic materials 0.000 claims description 13
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 12
- 229910052783 alkali metal Inorganic materials 0.000 claims description 12
- 125000002877 alkyl aryl group Chemical group 0.000 claims description 11
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 claims description 11
- 229910020366 ClO 4 Inorganic materials 0.000 claims description 9
- 239000000460 chlorine Substances 0.000 claims description 9
- WLDGDTPNAKWAIR-UHFFFAOYSA-N 1,4,7-trimethyl-1,4,7-triazonane Chemical compound CN1CCN(C)CCN(C)CC1 WLDGDTPNAKWAIR-UHFFFAOYSA-N 0.000 claims description 8
- 150000001340 alkali metals Chemical group 0.000 claims description 8
- 125000004429 atom Chemical group 0.000 claims description 8
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 7
- 125000003342 alkenyl group Chemical group 0.000 claims description 7
- 125000002091 cationic group Chemical group 0.000 claims description 7
- 229910052801 chlorine Inorganic materials 0.000 claims description 7
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 7
- 229910021645 metal ion Inorganic materials 0.000 claims description 7
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 7
- 125000003545 alkoxy group Chemical group 0.000 claims description 6
- 239000001257 hydrogen Substances 0.000 claims description 6
- 229910052739 hydrogen Inorganic materials 0.000 claims description 6
- 125000001424 substituent group Chemical group 0.000 claims description 6
- 229910052736 halogen Inorganic materials 0.000 claims description 5
- 150000002367 halogens Chemical class 0.000 claims description 5
- ROFVEXUMMXZLPA-UHFFFAOYSA-N Bipyridyl Chemical compound N1=CC=CC=C1C1=CC=CC=N1 ROFVEXUMMXZLPA-UHFFFAOYSA-N 0.000 claims description 4
- 150000001408 amides Chemical group 0.000 claims description 4
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 4
- 150000002978 peroxides Chemical class 0.000 claims description 4
- 125000000732 arylene group Chemical group 0.000 claims description 3
- 229910017053 inorganic salt Inorganic materials 0.000 claims description 3
- 150000003951 lactams Chemical class 0.000 claims description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 3
- ITWBWJFEJCHKSN-UHFFFAOYSA-N 1,4,7-triazonane Chemical compound C1CNCCNCCN1 ITWBWJFEJCHKSN-UHFFFAOYSA-N 0.000 claims description 2
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 claims description 2
- RGHNJXZEOKUKBD-SQOUGZDYSA-M D-gluconate Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O RGHNJXZEOKUKBD-SQOUGZDYSA-M 0.000 claims description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
- 125000004171 alkoxy aryl group Chemical group 0.000 claims description 2
- 125000003282 alkyl amino group Chemical group 0.000 claims description 2
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims description 2
- 230000006870 function Effects 0.000 claims description 2
- 229940050410 gluconate Drugs 0.000 claims description 2
- NGLYWWPBKJFWRP-UHFFFAOYSA-L iron(2+) N-pyridin-2-ylpyridin-2-amine diperchlorate Chemical compound [Fe+2].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O.C=1C=CC=NC=1NC1=CC=CC=N1.C=1C=CC=NC=1NC1=CC=CC=N1.C=1C=CC=NC=1NC1=CC=CC=N1 NGLYWWPBKJFWRP-UHFFFAOYSA-L 0.000 claims description 2
- 150000002540 isothiocyanates Chemical class 0.000 claims description 2
- 230000001934 delay Effects 0.000 claims 2
- YRNNKGFMTBWUGL-UHFFFAOYSA-L copper(ii) perchlorate Chemical compound [Cu+2].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O YRNNKGFMTBWUGL-UHFFFAOYSA-L 0.000 claims 1
- FRPJTGXMTIIFIT-UHFFFAOYSA-N tetraacetylethylenediamine Chemical compound CC(=O)C(N)(C(C)=O)C(N)(C(C)=O)C(C)=O FRPJTGXMTIIFIT-UHFFFAOYSA-N 0.000 claims 1
- 239000003112 inhibitor Substances 0.000 abstract description 6
- 230000002087 whitening effect Effects 0.000 abstract description 5
- 239000000654 additive Substances 0.000 abstract description 3
- 230000000996 additive effect Effects 0.000 abstract description 3
- 238000002203 pretreatment Methods 0.000 abstract description 2
- 239000002253 acid Substances 0.000 description 72
- 239000004094 surface-active agent Substances 0.000 description 56
- 150000003839 salts Chemical class 0.000 description 49
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 48
- 239000000463 material Substances 0.000 description 48
- 239000000047 product Substances 0.000 description 39
- 239000011572 manganese Substances 0.000 description 33
- 239000000344 soap Substances 0.000 description 31
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 27
- 229910052757 nitrogen Inorganic materials 0.000 description 26
- 102000004190 Enzymes Human genes 0.000 description 25
- 108090000790 Enzymes Proteins 0.000 description 25
- 229940088598 enzyme Drugs 0.000 description 25
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 24
- 239000011734 sodium Substances 0.000 description 24
- 239000000377 silicon dioxide Substances 0.000 description 23
- 229920001296 polysiloxane Polymers 0.000 description 21
- 229920000642 polymer Polymers 0.000 description 20
- 229910052708 sodium Inorganic materials 0.000 description 20
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 19
- 150000001204 N-oxides Chemical class 0.000 description 17
- 229920000768 polyamine Polymers 0.000 description 17
- 229920005646 polycarboxylate Polymers 0.000 description 17
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 16
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 16
- 229920001577 copolymer Polymers 0.000 description 16
- 239000003795 chemical substances by application Substances 0.000 description 15
- 239000004744 fabric Substances 0.000 description 15
- 150000007513 acids Chemical class 0.000 description 14
- 150000001768 cations Chemical class 0.000 description 14
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 14
- 239000002609 medium Substances 0.000 description 14
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 14
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 14
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 13
- 239000000975 dye Substances 0.000 description 13
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 12
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 12
- 239000002518 antifoaming agent Substances 0.000 description 12
- 235000014113 dietary fatty acids Nutrition 0.000 description 12
- 230000000694 effects Effects 0.000 description 12
- 239000000194 fatty acid Substances 0.000 description 12
- 229930195729 fatty acid Natural products 0.000 description 12
- 239000006260 foam Substances 0.000 description 12
- 238000012546 transfer Methods 0.000 description 12
- 239000011230 binding agent Substances 0.000 description 11
- 229910052751 metal Inorganic materials 0.000 description 11
- 239000002184 metal Substances 0.000 description 11
- BGRWYDHXPHLNKA-UHFFFAOYSA-N Tetraacetylethylenediamine Chemical compound CC(=O)N(C(C)=O)CCN(C(C)=O)C(C)=O BGRWYDHXPHLNKA-UHFFFAOYSA-N 0.000 description 10
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 10
- 239000002270 dispersing agent Substances 0.000 description 10
- 150000004665 fatty acids Chemical class 0.000 description 10
- PEDCQBHIVMGVHV-UHFFFAOYSA-N glycerol Substances OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 10
- 229910052700 potassium Inorganic materials 0.000 description 10
- 108090001060 Lipase Proteins 0.000 description 9
- 239000004367 Lipase Substances 0.000 description 9
- 102000004882 Lipase Human genes 0.000 description 9
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 9
- 239000003945 anionic surfactant Substances 0.000 description 9
- 238000007046 ethoxylation reaction Methods 0.000 description 9
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 9
- 235000019421 lipase Nutrition 0.000 description 9
- 239000011591 potassium Substances 0.000 description 9
- 125000002252 acyl group Chemical group 0.000 description 8
- 150000001298 alcohols Chemical class 0.000 description 8
- 125000002947 alkylene group Chemical group 0.000 description 8
- 229910000323 aluminium silicate Inorganic materials 0.000 description 8
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 8
- 230000003197 catalytic effect Effects 0.000 description 8
- 238000004453 electron probe microanalysis Methods 0.000 description 8
- UFZOPKFMKMAWLU-UHFFFAOYSA-N ethoxy(methyl)phosphinic acid Chemical compound CCOP(C)(O)=O UFZOPKFMKMAWLU-UHFFFAOYSA-N 0.000 description 8
- 125000000623 heterocyclic group Chemical group 0.000 description 8
- 125000001183 hydrocarbyl group Chemical group 0.000 description 8
- 230000002401 inhibitory effect Effects 0.000 description 8
- 239000007788 liquid Substances 0.000 description 8
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 8
- 229920000620 organic polymer Polymers 0.000 description 8
- 229920001223 polyethylene glycol Polymers 0.000 description 8
- 150000004760 silicates Chemical class 0.000 description 8
- 239000007787 solid Substances 0.000 description 8
- 238000012360 testing method Methods 0.000 description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 7
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 7
- 239000004115 Sodium Silicate Substances 0.000 description 7
- 244000269722 Thea sinensis Species 0.000 description 7
- 229960003237 betaine Drugs 0.000 description 7
- 239000011575 calcium Substances 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 7
- 239000013530 defoamer Substances 0.000 description 7
- 150000002191 fatty alcohols Chemical class 0.000 description 7
- 230000003287 optical effect Effects 0.000 description 7
- 239000003981 vehicle Substances 0.000 description 7
- 108010065511 Amylases Proteins 0.000 description 6
- 102000013142 Amylases Human genes 0.000 description 6
- 229920000742 Cotton Polymers 0.000 description 6
- 229910019142 PO4 Inorganic materials 0.000 description 6
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 6
- 238000005054 agglomeration Methods 0.000 description 6
- 230000002776 aggregation Effects 0.000 description 6
- 125000002723 alicyclic group Chemical group 0.000 description 6
- 125000001931 aliphatic group Chemical group 0.000 description 6
- 125000000129 anionic group Chemical group 0.000 description 6
- 230000008901 benefit Effects 0.000 description 6
- 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 description 6
- 239000008280 blood Substances 0.000 description 6
- 210000004369 blood Anatomy 0.000 description 6
- 150000007942 carboxylates Chemical class 0.000 description 6
- 229910052681 coesite Inorganic materials 0.000 description 6
- 229910052906 cristobalite Inorganic materials 0.000 description 6
- 238000004851 dishwashing Methods 0.000 description 6
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- 239000002736 nonionic surfactant Substances 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 6
- 235000021317 phosphate Nutrition 0.000 description 6
- 239000000843 powder Substances 0.000 description 6
- 230000008569 process Effects 0.000 description 6
- 235000012239 silicon dioxide Nutrition 0.000 description 6
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 6
- 229910052911 sodium silicate Inorganic materials 0.000 description 6
- 241000894007 species Species 0.000 description 6
- 229910052682 stishovite Inorganic materials 0.000 description 6
- 229910052717 sulfur Inorganic materials 0.000 description 6
- 229910052905 tridymite Inorganic materials 0.000 description 6
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 5
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 5
- 239000005977 Ethylene Substances 0.000 description 5
- 235000019738 Limestone Nutrition 0.000 description 5
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 5
- WAEMQWOKJMHJLA-UHFFFAOYSA-N Manganese(2+) Chemical compound [Mn+2] WAEMQWOKJMHJLA-UHFFFAOYSA-N 0.000 description 5
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 5
- 108091005804 Peptidases Proteins 0.000 description 5
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 5
- 235000019418 amylase Nutrition 0.000 description 5
- 230000003254 anti-foaming effect Effects 0.000 description 5
- 150000001720 carbohydrates Chemical class 0.000 description 5
- 239000007859 condensation product Substances 0.000 description 5
- 229910052802 copper Inorganic materials 0.000 description 5
- 239000010949 copper Substances 0.000 description 5
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 5
- 125000000524 functional group Chemical group 0.000 description 5
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- 125000002768 hydroxyalkyl group Chemical group 0.000 description 5
- 238000011065 in-situ storage Methods 0.000 description 5
- 239000006028 limestone Substances 0.000 description 5
- 150000002696 manganese Chemical class 0.000 description 5
- 150000002739 metals Chemical class 0.000 description 5
- 229920002006 poly(N-vinylimidazole) polymer Polymers 0.000 description 5
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- 229940045872 sodium percarbonate Drugs 0.000 description 5
- 159000000000 sodium salts Chemical class 0.000 description 5
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- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 5
- OSSNTDFYBPYIEC-UHFFFAOYSA-N 1-ethenylimidazole Chemical compound C=CN1C=CN=C1 OSSNTDFYBPYIEC-UHFFFAOYSA-N 0.000 description 4
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- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 4
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- 125000002490 anilino group Chemical group [H]N(*)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 4
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- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 description 4
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- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 4
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- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 4
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- IBDSNZLUHYKHQP-UHFFFAOYSA-N sodium;3-oxidodioxaborirane;tetrahydrate Chemical compound O.O.O.O.[Na+].[O-]B1OO1 IBDSNZLUHYKHQP-UHFFFAOYSA-N 0.000 description 1
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
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- DCQJDRNKCUQEMA-UHFFFAOYSA-N tetradecanediperoxoic acid Chemical compound OOC(=O)CCCCCCCCCCCCC(=O)OO DCQJDRNKCUQEMA-UHFFFAOYSA-N 0.000 description 1
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- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- DHCDFWKWKRSZHF-UHFFFAOYSA-L thiosulfate(2-) Chemical compound [O-]S([S-])(=O)=O DHCDFWKWKRSZHF-UHFFFAOYSA-L 0.000 description 1
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- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 1
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- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 125000004665 trialkylsilyl group Chemical group 0.000 description 1
- QQOWHRYOXYEMTL-UHFFFAOYSA-N triazin-4-amine Chemical class N=C1C=CN=NN1 QQOWHRYOXYEMTL-UHFFFAOYSA-N 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-O triethanolammonium Chemical compound OCC[NH+](CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-O 0.000 description 1
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical class [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
- C11D17/046—Insoluble free body dispenser
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0039—Coated compositions or coated components in the compositions, (micro)capsules
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/001—Softening compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/08—Silicates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/32—Amides; Substituted amides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/36—Organic compounds containing phosphorus
- C11D3/364—Organic compounds containing phosphorus containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3907—Organic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3932—Inorganic compounds or complexes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3942—Inorganic per-compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3945—Organic per-compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/12—Soft surfaces, e.g. textile
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB9407535 | 1994-04-13 | ||
| GB9407535A GB9407535D0 (en) | 1994-04-13 | 1994-04-13 | Detergent compositions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2216011T3 true ES2216011T3 (es) | 2004-10-16 |
Family
ID=10753619
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES95915004T Expired - Lifetime ES2216011T3 (es) | 1994-04-13 | 1995-04-03 | Detergentes que contienen un secuestrante de metales pesados y un sistema de blanqueante peroxiacido de liberacion retrasada. |
Country Status (13)
| Country | Link |
|---|---|
| EP (1) | EP0755429B1 (de) |
| JP (1) | JP4393582B2 (de) |
| CN (2) | CN1094514C (de) |
| AT (1) | ATE259412T1 (de) |
| AU (1) | AU2204895A (de) |
| BR (1) | BR9507379A (de) |
| CA (1) | CA2187438C (de) |
| DE (1) | DE69532559T2 (de) |
| ES (1) | ES2216011T3 (de) |
| GB (1) | GB9407535D0 (de) |
| MA (1) | MA23505A1 (de) |
| PE (1) | PE50595A1 (de) |
| WO (1) | WO1995028464A1 (de) |
Families Citing this family (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19609953A1 (de) * | 1996-03-14 | 1997-09-18 | Basf Ag | Feste Zusammensetzung aus heterocyclischen Verbindungen und/oder Oximestern und inerten porösen Trägermaterialien und ihre Verwendung als stabile Bleichaktivator-Komponente in Wasch-, Bleich- und Reinigungsmitteln |
| GB2311538A (en) * | 1996-03-29 | 1997-10-01 | Procter & Gamble | Detergent compositions |
| GB2311542A (en) * | 1996-03-29 | 1997-10-01 | Procter & Gamble | Percarbonate bleach composition |
| GB2311541A (en) * | 1996-03-29 | 1997-10-01 | Procter & Gamble | Oxygen-releasing bleach composition |
| GB2311535A (en) * | 1996-03-29 | 1997-10-01 | Procter & Gamble | Detergent compositions |
| GB2311536A (en) * | 1996-03-29 | 1997-10-01 | Procter & Gamble | Dishwashing and laundry detergents |
| DE19704634A1 (de) * | 1997-02-07 | 1998-08-27 | Henkel Kgaa | pH-gesteuerte Freisetzung von Waschmittelkomponenten |
| GB2329188A (en) * | 1997-09-11 | 1999-03-17 | Procter & Gamble | Detergent composition containing a stabilised percarboxylic bleaching system |
| JPH11217590A (ja) * | 1998-02-04 | 1999-08-10 | Kao Corp | 漂白洗浄剤組成物 |
| GB0004988D0 (en) | 2000-03-01 | 2000-04-19 | Unilever Plc | Composition and method for bleaching a substrate |
| JP5206166B2 (ja) * | 2008-07-03 | 2013-06-12 | コニカミノルタＩｊ株式会社 | インクジェットインク及び液晶配向膜の形成方法 |
| GB0902959D0 (en) * | 2009-02-23 | 2009-04-08 | Reckitt Benckiser Nv | Composition |
| EP3050951A1 (de) * | 2015-02-02 | 2016-08-03 | The Procter and Gamble Company | Verfahren zum Geschirrspülen |
| EP3050952A1 (de) * | 2015-02-02 | 2016-08-03 | The Procter and Gamble Company | Verfahren zum Geschirrspülen |
| EP3050953B1 (de) | 2015-02-02 | 2018-12-26 | The Procter and Gamble Company | Reinigungsmittelzusammensetzung |
| US9783766B2 (en) | 2015-04-03 | 2017-10-10 | Ecolab Usa Inc. | Enhanced peroxygen stability using anionic surfactant in TAED-containing peroxygen solid |
| US10280386B2 (en) | 2015-04-03 | 2019-05-07 | Ecolab Usa Inc. | Enhanced peroxygen stability in multi-dispense TAED-containing peroxygen solid |
| EP3184601A1 (de) * | 2015-12-23 | 2017-06-28 | Agrana Beteiligungs- Aktiengesellschaft | Prozessfluid mit umweltverträglichem biostabilisator |
| AU2017322243B2 (en) | 2016-09-07 | 2020-05-21 | Ecolab Usa Inc. | Detergent compositions containing a stabilized enzyme by phosphonates |
| CN110997889B (zh) * | 2017-07-31 | 2022-04-12 | 陶氏环球技术有限责任公司 | 洗涤剂添加剂 |
| CN111010876B (zh) * | 2017-07-31 | 2022-01-11 | 陶氏环球技术有限责任公司 | 包封方法 |
| WO2019027631A1 (en) * | 2017-07-31 | 2019-02-07 | Dow Global Technologies Llc | DETERGENT ADDITIVE |
| US10870818B2 (en) | 2018-06-15 | 2020-12-22 | Ecolab Usa Inc. | Enhanced peroxygen stability using fatty acid in bleach activating agent containing peroxygen solid |
| EP3693450A1 (de) * | 2019-02-08 | 2020-08-12 | The Procter & Gamble Company | Verfahren zur behandlung von geweben mit automatischer vorbehandlung von wasser |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IE51848B1 (en) * | 1980-11-06 | 1987-04-15 | Procter & Gamble | Bleach activator compositions,preparation thereof and use in granular detergent compositions |
| US4378300A (en) * | 1981-12-10 | 1983-03-29 | Colgate-Palmolive Company | Peroxygen bleaching composition |
| ES523135A0 (es) * | 1982-06-10 | 1985-03-01 | Kao Corp | Un procedimiento para la preparacion de percarborato sodico recubierto con un borato. |
| US4421664A (en) * | 1982-06-18 | 1983-12-20 | Economics Laboratory, Inc. | Compatible enzyme and oxidant bleaches containing cleaning composition |
| JPS59194000A (ja) * | 1983-04-18 | 1984-11-02 | 花王株式会社 | 漂白洗浄剤組成物 |
| US5130044A (en) * | 1987-10-30 | 1992-07-14 | The Clorox Company | Delayed onset active oxygen bleach composition |
-
1994
- 1994-04-13 GB GB9407535A patent/GB9407535D0/en active Pending
-
1995
- 1995-04-03 CN CN95193547A patent/CN1094514C/zh not_active Expired - Fee Related
- 1995-04-03 AU AU22048/95A patent/AU2204895A/en not_active Abandoned
- 1995-04-03 AT AT95915004T patent/ATE259412T1/de not_active IP Right Cessation
- 1995-04-03 BR BR9507379A patent/BR9507379A/pt not_active IP Right Cessation
- 1995-04-03 EP EP95915004A patent/EP0755429B1/de not_active Expired - Lifetime
- 1995-04-03 ES ES95915004T patent/ES2216011T3/es not_active Expired - Lifetime
- 1995-04-03 JP JP52699095A patent/JP4393582B2/ja not_active Expired - Fee Related
- 1995-04-03 DE DE69532559T patent/DE69532559T2/de not_active Expired - Fee Related
- 1995-04-03 CA CA002187438A patent/CA2187438C/en not_active Expired - Fee Related
- 1995-04-03 WO PCT/US1995/004085 patent/WO1995028464A1/en active IP Right Grant
- 1995-04-12 MA MA23833A patent/MA23505A1/fr unknown
- 1995-04-12 PE PE1995266408A patent/PE50595A1/es not_active Application Discontinuation
-
2001
- 2001-11-24 CN CN01139470.6A patent/CN1206334C/zh not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN1206334C (zh) | 2005-06-15 |
| DE69532559T2 (de) | 2004-12-16 |
| CA2187438C (en) | 2000-10-31 |
| EP0755429A1 (de) | 1997-01-29 |
| PE50595A1 (es) | 1996-02-13 |
| CA2187438A1 (en) | 1995-10-26 |
| CN1373180A (zh) | 2002-10-09 |
| CN1150451A (zh) | 1997-05-21 |
| ATE259412T1 (de) | 2004-02-15 |
| MA23505A1 (fr) | 1995-12-31 |
| JPH09512049A (ja) | 1997-12-02 |
| EP0755429A4 (de) | 1998-07-29 |
| EP0755429B1 (de) | 2004-02-11 |
| AU2204895A (en) | 1995-11-10 |
| DE69532559D1 (de) | 2004-03-18 |
| GB9407535D0 (en) | 1994-06-08 |
| WO1995028464A1 (en) | 1995-10-26 |
| CN1094514C (zh) | 2002-11-20 |
| BR9507379A (pt) | 1997-09-16 |
| JP4393582B2 (ja) | 2010-01-06 |
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