ES2206647T3 - Procedimiento para la obtencion de ceras de poliolefina oxidadas. - Google Patents
Procedimiento para la obtencion de ceras de poliolefina oxidadas.Info
- Publication number
- ES2206647T3 ES2206647T3 ES97122648T ES97122648T ES2206647T3 ES 2206647 T3 ES2206647 T3 ES 2206647T3 ES 97122648 T ES97122648 T ES 97122648T ES 97122648 T ES97122648 T ES 97122648T ES 2206647 T3 ES2206647 T3 ES 2206647T3
- Authority
- ES
- Spain
- Prior art keywords
- polyolefin waxes
- oxidized polyolefin
- waxes
- oxidized
- tubular reactor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000001993 wax Substances 0.000 title claims abstract description 62
- 238000000034 method Methods 0.000 title claims abstract description 25
- 229920000098 polyolefin Polymers 0.000 title claims description 39
- 239000007789 gas Substances 0.000 claims abstract description 13
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 8
- 238000006243 chemical reaction Methods 0.000 claims abstract description 8
- 239000001301 oxygen Substances 0.000 claims abstract description 8
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 8
- 238000007254 oxidation reaction Methods 0.000 claims description 20
- 229920001577 copolymer Polymers 0.000 claims description 16
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 12
- 239000005977 Ethylene Substances 0.000 claims description 12
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 9
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 7
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims description 6
- AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 claims description 6
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 claims description 6
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 claims description 6
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 claims description 6
- 238000000576 coating method Methods 0.000 claims description 5
- 229910052799 carbon Inorganic materials 0.000 claims description 4
- 238000006555 catalytic reaction Methods 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 239000011248 coating agent Substances 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 3
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 claims description 3
- 230000001590 oxidative effect Effects 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 2
- 239000002689 soil Substances 0.000 claims description 2
- 239000003054 catalyst Substances 0.000 abstract 1
- 230000007717 exclusion Effects 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 230000008569 process Effects 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 description 18
- 239000000047 product Substances 0.000 description 7
- PBKONEOXTCPAFI-UHFFFAOYSA-N 1,2,4-trichlorobenzene Chemical compound ClC1=CC=C(Cl)C(Cl)=C1 PBKONEOXTCPAFI-UHFFFAOYSA-N 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- -1 polyethylene Polymers 0.000 description 3
- ZGEGCLOFRBLKSE-UHFFFAOYSA-N 1-Heptene Chemical compound CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 229920005606 polypropylene copolymer Polymers 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 238000001644 13C nuclear magnetic resonance spectroscopy Methods 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 235000020971 citrus fruits Nutrition 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 230000005593 dissociations Effects 0.000 description 1
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 229940071125 manganese acetate Drugs 0.000 description 1
- UOGMEBQRZBEZQT-UHFFFAOYSA-L manganese(2+);diacetate Chemical compound [Mn+2].CC([O-])=O.CC([O-])=O UOGMEBQRZBEZQT-UHFFFAOYSA-L 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000004611 spectroscopical analysis Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/06—Oxidation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2810/00—Chemical modification of a polymer
- C08F2810/10—Chemical modification of a polymer including a reactive processing step which leads, inter alia, to morphological and/or rheological modifications, e.g. visbreaking
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19700892A DE19700892A1 (de) | 1997-01-14 | 1997-01-14 | Verfahren zur Herstellung oxidierter Polyolefinwachse |
| DE19700892 | 1997-01-14 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2206647T3 true ES2206647T3 (es) | 2004-05-16 |
Family
ID=7817271
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES97122648T Expired - Lifetime ES2206647T3 (es) | 1997-01-14 | 1997-12-22 | Procedimiento para la obtencion de ceras de poliolefina oxidadas. |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US6169148B1 (https=) |
| EP (1) | EP0853089B1 (https=) |
| JP (1) | JP4799716B2 (https=) |
| DE (2) | DE19700892A1 (https=) |
| ES (1) | ES2206647T3 (https=) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2001098377A2 (de) * | 2000-06-20 | 2001-12-27 | Basf Aktiengesellschaft | Oxidierte polyolefinwachse |
| US20030073485A1 (en) * | 2001-10-15 | 2003-04-17 | Friedman Stacy A. | Method of playing wagering games |
| US7341619B2 (en) * | 2004-11-23 | 2008-03-11 | Chevron Phillips Chemical Company, Lp | Olefin waxes having improved hardness or viscosity |
| US7527686B2 (en) * | 2004-11-23 | 2009-05-05 | Chevron Phillips Chemical Company, Lp | Olefin waxes having improved hardness or viscosity |
| AU2006201172B2 (en) * | 2005-04-04 | 2010-11-25 | Rohm And Haas Company | Aqueous polymer dispersions |
| US7709571B2 (en) * | 2006-10-30 | 2010-05-04 | Honeywell International Inc | Multicomponent lubricant composition for processing rigid vinyl chloride polymers |
| WO2008114648A1 (ja) * | 2007-03-16 | 2008-09-25 | Idemitsu Kosan Co., Ltd. | 酸化変性α－オレフィン系重合体及びその製造方法 |
| US7875674B2 (en) * | 2008-05-01 | 2011-01-25 | Wacker Chemical Corporation | Building materials incorporated with hydrophobic silicone resin(s) |
| CN102164672A (zh) * | 2008-10-31 | 2011-08-24 | 切弗朗菲利浦化学公司 | 低聚催化剂系统和低聚烯烃的方法 |
| US9809497B2 (en) * | 2015-12-01 | 2017-11-07 | Wacker Chemical Corporation | Omniphobic grout additive |
| KR101901883B1 (ko) * | 2017-11-22 | 2018-09-27 | 주식회사 라이온켐텍 | 기능화된 폴리에틸렌 왁스의 제조방법 |
| CN110172109A (zh) * | 2019-06-18 | 2019-08-27 | 青岛科技大学 | 一种连续合成氧化聚乙烯蜡的方法 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL288516A (https=) * | 1962-02-06 | |||
| DE1570652A1 (de) * | 1964-03-09 | 1970-03-26 | Allied Chem | Verfahren zur Herstellung von oxydiertem Polyaethylen |
| DE2035706C3 (de) | 1970-07-18 | 1975-09-11 | Hoechst Ag, 6000 Frankfurt | Verfahren zur Herstellung von Oxidationsprodukten von Äthylenpolymeren |
| US3931024A (en) * | 1972-06-08 | 1976-01-06 | Exxon Research And Engineering Company | Nitrogen-containing dispersant from polyolefin |
| DE2758785A1 (de) * | 1977-12-29 | 1979-07-12 | Bayer Ag | Herstellung von hydroperoxidgruppen enthaltenden polymeren |
| GB8628339D0 (en) * | 1986-11-27 | 1986-12-31 | Bp Chemicals Additives | Chemical process |
| DE3720953A1 (de) | 1987-06-25 | 1989-01-05 | Basf Ag | Verfahren zur oxidation von polyethylen |
| DE69128579T2 (de) * | 1990-04-10 | 1998-05-28 | Mitsui Petrochemical Ind | Verfahren zum thermischen abbau von polymeren |
| IT1269916B (it) * | 1994-03-25 | 1997-04-16 | Enichem Spa | Procedimento migliorato per la sintesi di dimetilcarbonato |
-
1997
- 1997-01-14 DE DE19700892A patent/DE19700892A1/de not_active Withdrawn
- 1997-12-22 EP EP97122648A patent/EP0853089B1/de not_active Expired - Lifetime
- 1997-12-22 ES ES97122648T patent/ES2206647T3/es not_active Expired - Lifetime
- 1997-12-22 DE DE59710689T patent/DE59710689D1/de not_active Expired - Lifetime
-
1998
- 1998-01-08 US US09/004,340 patent/US6169148B1/en not_active Expired - Lifetime
- 1998-01-13 JP JP00440198A patent/JP4799716B2/ja not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| EP0853089B1 (de) | 2003-09-03 |
| DE19700892A1 (de) | 1998-07-16 |
| US6169148B1 (en) | 2001-01-02 |
| DE59710689D1 (de) | 2003-10-09 |
| JPH10279624A (ja) | 1998-10-20 |
| JP4799716B2 (ja) | 2011-10-26 |
| EP0853089A1 (de) | 1998-07-15 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| ES2206647T3 (es) | Procedimiento para la obtencion de ceras de poliolefina oxidadas. | |
| JP4233762B2 (ja) | エチレン系共重合体組成物およびその製造方法、この共重合体組成物を含有する樹脂組成物ならびにこれらの用途 | |
| JP3961030B2 (ja) | 良好な透明性および改良された耐衝撃性を有するポリプロピレン組成物 | |
| ES2209008T3 (es) | Procedimiento para la oxidacion de ceras polietilenicas. | |
| EP0373660B1 (en) | Propylene polymer compositions having good transparency and improved impact resistance | |
| US6114457A (en) | High melt strength polyethylene compositions | |
| ES2205795T5 (es) | (co)polimeros de polibuteno-1 y procedimiento para su preparacion. | |
| ES2272981T3 (es) | (co9 polimeros de 1-buteno y procedimiento para su preparacion. | |
| WO1994010216A1 (fr) | Copolymeres d'olefines et procede pour leur production | |
| WO1997004026A1 (en) | Ethylenic polymer composition | |
| KR100451259B1 (ko) | 분기형 폴리올레핀, 그 제조 방법 및 분기형폴리올레핀을 함유하는 열가소성 수지 조성물 | |
| WO2002002659A1 (en) | Butene copolymer, resin composition comprising the copolymer and moldings of the composition, and solid titanium catalyst for producing the copolymer and method for preparing the catalyst | |
| JP2001511212A (ja) | 高溶融強度ポリエチレン組成物 | |
| JPH0448804B2 (https=) | ||
| JPS61291603A (ja) | オレフイン重合用触媒 | |
| Marques et al. | Synthesis of acrylamide/olefin copolymers by a diimine nickel catalyst | |
| EP0302297A1 (en) | Butene-1 copolymer | |
| JP6955474B2 (ja) | 重合開始系および極めて反応性の高いオレフィン官能性ポリマーの製造方法 | |
| KR100635292B1 (ko) | 가열 멸균용 중공 용기 | |
| JP7071763B2 (ja) | 対称型ポリオレフィンブロック共重合体およびその製造方法 | |
| JP7232761B2 (ja) | エチレンおよびｃ３－ｃ１０アルファ－オレフィンの微細構造制御されたコポリマー | |
| US6825283B2 (en) | Oxidized polyolefin waxes | |
| WO1992016566A1 (fr) | Polyolefine modifiee en fin de chaine | |
| JPS6018316A (ja) | ゴムホ−ス製造用マンドレル | |
| JP3372074B2 (ja) | ポリエチレン組成物 |