ES2185751T3 - Prepolimeros terminados en isocianato de viscosidad estable y polioxialquileno polieter polioles con estabilidad de almacenamiento mejorada. - Google Patents
Prepolimeros terminados en isocianato de viscosidad estable y polioxialquileno polieter polioles con estabilidad de almacenamiento mejorada.Info
- Publication number
- ES2185751T3 ES2185751T3 ES96305838T ES96305838T ES2185751T3 ES 2185751 T3 ES2185751 T3 ES 2185751T3 ES 96305838 T ES96305838 T ES 96305838T ES 96305838 T ES96305838 T ES 96305838T ES 2185751 T3 ES2185751 T3 ES 2185751T3
- Authority
- ES
- Spain
- Prior art keywords
- prepolimeros
- polyoles
- polyoxialquylene
- isocianate
- finished
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920005862 polyol Polymers 0.000 abstract 2
- 150000003077 polyols Chemical class 0.000 abstract 2
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 238000009792 diffusion process Methods 0.000 abstract 1
- 230000008030 elimination Effects 0.000 abstract 1
- 238000003379 elimination reaction Methods 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
- C08G65/2645—Metals or compounds thereof, e.g. salts
- C08G65/2663—Metal cyanide catalysts, i.e. DMC's
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4866—Polyethers having a low unsaturation value
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Toxicology (AREA)
- Polyurethanes Or Polyureas (AREA)
- Polyethers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
LOS POLIOLES DE POLIOXIALQUILENO, QUE CONTIENEN COMPLEJOS DOBLES DE CIANURO METALICO, O RESIDUOS DE LOS MISMOS, TAL Y COMO SON PRODUCIDOS DURANTE LA PREPARACION DE POLIOLES DE POLIOXIALQUENO, MEDIANTE LA OXIALQUILACION DE UN INICIADOR FUNCIONAL HIDRICO ADECUADO, CATALIZADA POR EL COMPLEJO DOBLE DE CIANURO METALICO, SON ESTABLES SIN ELIMINACION DEL CATALIZADOR. LOS PREPOLIMEROS ACABADOS EN ISOCIANATO, PREPARADOS A PARTIR DE DICHOS POLIOLES, TIENEN, SORPRENDENTEMENTE, VISCOSIDAD ESTABLE RESPECTO A PREPOLIMEROS SIMILARES PREPARADOS A PARTIR DE POLIOLES QUE NO CONTIENEN COMPLEJOS DOBLES DE CIANURO METALICO, O RESIDUOS DE LOS MISMOS.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US513264 | 1995-08-10 | ||
| US08/513,264 US5811829A (en) | 1995-08-10 | 1995-08-10 | Viscosity stable isocyanate-terminated prepolymers and polyoxyalkylene polyether polyols having improved storage stability |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| ES2185751T3 true ES2185751T3 (es) | 2003-05-01 |
| ES2185751T5 ES2185751T5 (es) | 2010-10-27 |
Family
ID=24042522
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES96305838T Expired - Lifetime ES2185751T5 (es) | 1995-08-10 | 1996-08-08 | Prepolimeros terminados en isocianato de viscosidad estable y polioxialquileno polieter polioles con estabilidad de almacenamiento mejorada. |
Country Status (19)
| Country | Link |
|---|---|
| US (3) | US5811829A (es) |
| EP (1) | EP0759450B2 (es) |
| JP (2) | JP4041549B2 (es) |
| KR (1) | KR100422795B1 (es) |
| CN (3) | CN1092678C (es) |
| AR (1) | AR003223A1 (es) |
| AT (1) | ATE226602T1 (es) |
| AU (1) | AU702431B2 (es) |
| BR (1) | BR9603364A (es) |
| CA (1) | CA2182910C (es) |
| DE (1) | DE69624424T8 (es) |
| DK (1) | DK0759450T4 (es) |
| ES (1) | ES2185751T5 (es) |
| HU (1) | HU218734B (es) |
| ID (1) | ID16161A (es) |
| RO (1) | RO120262B1 (es) |
| SG (1) | SG55224A1 (es) |
| TW (1) | TW440573B (es) |
| ZA (1) | ZA966792B (es) |
Families Citing this family (50)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5811829A (en) * | 1995-08-10 | 1998-09-22 | Arco Chemical Technology, L.P. | Viscosity stable isocyanate-terminated prepolymers and polyoxyalkylene polyether polyols having improved storage stability |
| DE19730467A1 (de) * | 1997-07-16 | 1999-01-21 | Bayer Ag | Neue Zink/Metall-Hexacyanocobaltat-Katalysatoren für die Herstellung von Polyetherpolyolen |
| US6008263A (en) * | 1998-04-03 | 1999-12-28 | Lyondell Chemical Worldwide, Inc. | Molded and slab polyurethane foam prepared from double metal cyanide complex-catalyzed polyoxyalkylene polyols and polyols suitable for the preparation thereof |
| US6066683A (en) * | 1998-04-03 | 2000-05-23 | Lyondell Chemical Worldwide, Inc. | Molded and slab polyurethane foam prepared from double metal cyanide complex-catalyzed polyoxyalkylene polyols and polyols suitable for the preparation thereof |
| CN1174022C (zh) * | 1998-07-10 | 2004-11-03 | 旭硝子株式会社 | 环氧烷开环聚合用催化剂及其制造方法和用途 |
| US6063309A (en) * | 1998-07-13 | 2000-05-16 | Arco Chemical Technology L.P. | Dispersion polyols for hypersoft polyurethane foam |
| US6432543B2 (en) * | 1998-07-29 | 2002-08-13 | Basf Corporation | Decorative components having an elastomeric outer surface and methods of making such components |
| US6303731B1 (en) | 1999-01-20 | 2001-10-16 | H.B. Fuller Licensing & Financing Inc. | Moisture curable polyurethane compositions |
| DE19913260C2 (de) | 1999-03-24 | 2001-07-05 | Bayer Ag | Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen |
| JP4320846B2 (ja) * | 1999-06-10 | 2009-08-26 | 旭硝子株式会社 | 光硬化性組成物 |
| US6287080B1 (en) * | 1999-11-15 | 2001-09-11 | General Electric Company | Elastomeric formulation used in the construction of lightweight aircraft engine fan blades |
| WO2001083107A2 (en) | 2000-04-28 | 2001-11-08 | Synuthane International, Inc. | Double metal cyanide catalysts containing polyglycol ether complexing agents |
| DE10137628A1 (de) * | 2001-08-03 | 2003-02-27 | Basf Ag | Verfahren zur Herstellung von Polyurethan-Weichschaumstoffen |
| EP1288244A1 (en) | 2001-08-31 | 2003-03-05 | Asahi Glass Company, Limited | Double metal cyanide complex catalyst for ring opening polymerization of alkylene oxide and its production process |
| DE10142747A1 (de) * | 2001-08-31 | 2003-03-20 | Bayer Ag | Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen |
| DE10240186A1 (de) * | 2002-08-28 | 2004-03-11 | Basf Ag | Verfahren zur Herstellung von emissionsarmen Polyurethan-Weichschaumstoffen |
| EP1589071B1 (en) | 2003-01-28 | 2012-11-14 | Asahi Glass Company, Limited | Polyether polyol composition and use thereof |
| DE10324998A1 (de) * | 2003-06-03 | 2004-12-23 | Basf Ag | Herstellung von Polyetheralkoholen unter Verwendung der DMC-Katalyse |
| US20050014637A1 (en) * | 2003-06-04 | 2005-01-20 | Duijghuisen Henricus Petrus Bernardus | Polyether polyol composition |
| DE10351530A1 (de) * | 2003-11-03 | 2005-06-16 | Basf Ag | Verfahren zur Herstellung von Isocyanatgruppen enthaltenden Prepolymeren |
| DE102004013408A1 (de) | 2004-03-18 | 2005-10-06 | Basf Ag | Polyetheralkohole und Verfahren zur Herstellung von Polyetheralkoholen zur Polyurethansynthese |
| DE102004015983A1 (de) * | 2004-04-01 | 2005-10-20 | Bayer Materialscience Ag | Verfahren zur Herstellung von Polyetherallophanaten unter Verwendung von Zink-Verbindungen als Katalysatoren |
| DE102004015985A1 (de) * | 2004-04-01 | 2005-10-20 | Bayer Materialscience Ag | Verfärbungsstabile Polyetherallophanate |
| DE102005047560A1 (de) * | 2005-10-04 | 2007-04-05 | Bayer Materialscience Ag | Zusammensetzung zur Herstellung von Polyharnstoffbeschichtungen |
| US20070175621A1 (en) * | 2006-01-31 | 2007-08-02 | Cooligy, Inc. | Re-workable metallic TIM for efficient heat exchange |
| US7569653B2 (en) | 2006-02-01 | 2009-08-04 | Momentive Performance Materials Inc. | Sealant composition having reduced permeability to gas |
| US8580361B2 (en) * | 2006-02-01 | 2013-11-12 | Momentive Performance Materials Inc. | Insulated glass unit with sealant composition having reduced permeability to gas |
| US20070178256A1 (en) * | 2006-02-01 | 2007-08-02 | Landon Shayne J | Insulated glass unit with sealant composition having reduced permeability to gas |
| US7541076B2 (en) * | 2006-02-01 | 2009-06-02 | Momentive Performance Materials Inc. | Insulated glass unit with sealant composition having reduced permeability to gas |
| US20070179236A1 (en) * | 2006-02-01 | 2007-08-02 | Landon Shayne J | Sealant composition having reduced permeability to gas |
| DE102007057146A1 (de) * | 2007-11-28 | 2009-06-04 | Evonik Goldschmidt Gmbh | Verfahren zur Herstellung von Polyetheralkoholen mit DMC-Katalysatoren unter Verwendung von speziellen Additiven mit aromatischer Hydroxy-Funktionalisierung |
| JP4507263B2 (ja) * | 2008-01-16 | 2010-07-21 | 信越化学工業株式会社 | 含フッ素硬化性組成物 |
| CN102574977B (zh) | 2009-09-30 | 2013-12-11 | 旭硝子株式会社 | 异氰酸酯基末端预聚物的制造方法以及由此获得的预聚物及聚氨酯树脂 |
| US9200160B2 (en) * | 2010-03-29 | 2015-12-01 | Momentive Performance Materials Inc. | Silylated polyurethane/polyorganosiloxane blend and sealant composition and fumed silica composition containing same |
| US8598248B2 (en) | 2010-07-16 | 2013-12-03 | Bayer Materialscience Llc | Flexible polyurethane foams made from alkoxylated natural oil |
| JP5648797B2 (ja) * | 2010-11-22 | 2015-01-07 | 旭硝子株式会社 | ポリエーテルヒドロキシ化合物の製造方法 |
| WO2013070227A1 (en) | 2011-11-10 | 2013-05-16 | Momentive Performance Materials Inc. | Moisture curable composition of a polymer having silyl groups |
| EP2776162B1 (en) | 2011-11-10 | 2017-01-04 | Momentive Performance Materials Inc. | Moisture curable organopolysiloxane composition |
| EP2791265A4 (en) | 2011-12-15 | 2016-01-13 | Momentive Performance Mat Inc | HUMIDITY-CURABLE POLYORGANOSILOXANE COMPOSITIONS |
| WO2013090127A1 (en) | 2011-12-15 | 2013-06-20 | Momentive Performance Materials, Inc. | Moisture curable organopolysiloxane compositions |
| KR20140116885A (ko) | 2011-12-29 | 2014-10-06 | 모멘티브 퍼포먼스 머티리얼즈 인크. | 수분 경화성 오가노폴리실록산 조성물 |
| EP3378905A1 (en) | 2013-02-15 | 2018-09-26 | Momentive Performance Materials Inc. | Antifouling system comprising silicone hydrogel |
| TW201434882A (zh) | 2013-03-13 | 2014-09-16 | Momentive Performance Mat Inc | 可濕氣固化之有機聚矽氧烷組成物 |
| EP2994501A2 (en) | 2013-05-10 | 2016-03-16 | Momentive Performance Materials Inc. | Non-metal catalyzed room temperature moisture curable organopolysiloxane compositions |
| US9663621B2 (en) | 2013-08-23 | 2017-05-30 | Momentive Performance Materials Inc. | Moisture curable compositions |
| CN105793326B (zh) | 2013-11-26 | 2020-07-21 | 莫门蒂夫性能材料股份有限公司 | 具有金属-芳烃配合物的可湿固化的组合物 |
| WO2016137881A1 (en) | 2015-02-23 | 2016-09-01 | King Industries | Curable coating compositions of silane functional polymers |
| JP7443696B2 (ja) * | 2018-12-21 | 2024-03-06 | 東ソー株式会社 | 軟質ポリウレタンフォーム成型用ポリオール組成物 |
| CN117280004A (zh) | 2021-03-09 | 2023-12-22 | 迈图高新材料公司 | 基于硅的组合物及其应用 |
| WO2023229913A1 (en) | 2022-05-23 | 2023-11-30 | Momentive Performance Materials Inc. | Protective coating composition for metals and polymeric surfaces |
Family Cites Families (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3427256A (en) * | 1963-02-14 | 1969-02-11 | Gen Tire & Rubber Co | Double metal cyanide complex compounds |
| US3829505A (en) * | 1970-02-24 | 1974-08-13 | Gen Tire & Rubber Co | Polyethers and method for making the same |
| US3941849A (en) † | 1972-07-07 | 1976-03-02 | The General Tire & Rubber Company | Polyethers and method for making the same |
| US4156759A (en) * | 1978-01-16 | 1979-05-29 | Krause Milling Company | Polyurethane foams containing stabilized amylaceous materials |
| CA1155871A (en) * | 1980-10-16 | 1983-10-25 | Gencorp Inc. | Method for treating polypropylene ether and poly-1,2- butylene ether polyols |
| AU552988B2 (en) * | 1982-03-31 | 1986-06-26 | Shell Internationale Research Maatschappij B.V. | Polymerizing epoxides and catalyst suspensions for this |
| AU551979B2 (en) † | 1982-03-31 | 1986-05-15 | Shell Internationale Research Maatschappij B.V. | Epoxy polymerisation catalysts |
| US4721818A (en) * | 1987-03-20 | 1988-01-26 | Atlantic Richfield Company | Purification of polyols prepared using double metal cyanide complex catalysts |
| US5114619A (en) * | 1989-07-14 | 1992-05-19 | The Dow Chemical Company | Production of polyether polyols with reduced unsaturation |
| US4987271A (en) * | 1989-02-17 | 1991-01-22 | Asahi Glass Company, Ltd. | Method for purifying a polyoxyalkylene alcohol |
| US5010047A (en) † | 1989-02-27 | 1991-04-23 | Arco Chemical Technology, Inc. | Recovery of double metal cyanide complex catalyst from a polymer |
| US4985491A (en) † | 1989-10-05 | 1991-01-15 | Olin Corporation | Polyurethane sealants made using high molecular weight polyols prepared with double metal cyanide catalysts |
| JP2653236B2 (ja) * | 1990-10-05 | 1997-09-17 | 旭硝子株式会社 | ポリエーテル化合物の製造方法 |
| US5185420A (en) | 1990-11-02 | 1993-02-09 | Olin Corporation | Thermoplastic polyurethane elastomers and polyurea elastomers made using low unsaturation level polyols prepared with double metal cyanide catalysts |
| US5099075A (en) † | 1990-11-02 | 1992-03-24 | Olin Corporation | Process for removing double metal cyanide catalyst residues from a polyol |
| US5132387A (en) * | 1991-01-07 | 1992-07-21 | Elf Atochem North America, Inc. | Hindered amine light stabilizer hydrazides for stabilizing polyurethane, polyurea and polyurethane-polyurea polymers |
| US5235114A (en) † | 1991-04-29 | 1993-08-10 | Olin Corporation | Process for purifying and end-capping polyols made using double metal cyanide catalysts |
| US5216797A (en) † | 1991-07-17 | 1993-06-08 | R. Hall Manufacturing Inc. | Method and apparatus for debanding a bale |
| US5158922A (en) * | 1992-02-04 | 1992-10-27 | Arco Chemical Technology, L.P. | Process for preparing metal cyanide complex catalyst |
| TW276260B (es) * | 1992-07-15 | 1996-05-21 | Ciba Geigy Ag | |
| US5357038A (en) * | 1992-08-03 | 1994-10-18 | Olin Corporation | Process and composition for providing double metal cyanide catalyzed polyols having enhanced reactivity |
| US5248833A (en) * | 1992-09-22 | 1993-09-28 | Arco Chemical Technology, L.P. | Process for purifying polyols made with double metal cyanide catalysts |
| US5470813A (en) | 1993-11-23 | 1995-11-28 | Arco Chemical Technology, L.P. | Double metal cyanide complex catalysts |
| US5482908A (en) | 1994-09-08 | 1996-01-09 | Arco Chemical Technology, L.P. | Highly active double metal cyanide catalysts |
| US5824738A (en) * | 1994-10-07 | 1998-10-20 | Davidson Textron Inc. | Light stable aliphatic thermoplastic urethane elastomers and method of making same |
| US5811829A (en) * | 1995-08-10 | 1998-09-22 | Arco Chemical Technology, L.P. | Viscosity stable isocyanate-terminated prepolymers and polyoxyalkylene polyether polyols having improved storage stability |
-
1995
- 1995-08-10 US US08/513,264 patent/US5811829A/en not_active Expired - Lifetime
-
1996
- 1996-07-31 JP JP21694896A patent/JP4041549B2/ja not_active Expired - Lifetime
- 1996-08-05 TW TW085109436A patent/TW440573B/zh not_active IP Right Cessation
- 1996-08-08 ES ES96305838T patent/ES2185751T5/es not_active Expired - Lifetime
- 1996-08-08 ID IDP962268A patent/ID16161A/id unknown
- 1996-08-08 RO RO96-01622A patent/RO120262B1/ro unknown
- 1996-08-08 CA CA2182910A patent/CA2182910C/en not_active Expired - Lifetime
- 1996-08-08 DK DK96305838.3T patent/DK0759450T4/da active
- 1996-08-08 DE DE69624424T patent/DE69624424T8/de active Active
- 1996-08-08 EP EP96305838A patent/EP0759450B2/en not_active Expired - Lifetime
- 1996-08-08 AR ARP960103929A patent/AR003223A1/es unknown
- 1996-08-08 AT AT96305838T patent/ATE226602T1/de active
- 1996-08-09 AU AU62014/96A patent/AU702431B2/en not_active Expired
- 1996-08-09 HU HU9602195A patent/HU218734B/hu unknown
- 1996-08-09 KR KR1019960033138A patent/KR100422795B1/ko not_active Expired - Lifetime
- 1996-08-09 BR BR9603364A patent/BR9603364A/pt not_active IP Right Cessation
- 1996-08-10 SG SG1996010433A patent/SG55224A1/en unknown
- 1996-08-10 CN CN96113318A patent/CN1092678C/zh not_active Expired - Lifetime
- 1996-08-12 ZA ZA966792A patent/ZA966792B/xx unknown
-
1998
- 1998-06-01 US US09/088,275 patent/US5919888A/en not_active Expired - Lifetime
-
1999
- 1999-02-09 US US09/246,495 patent/US6036879A/en not_active Expired - Lifetime
-
2002
- 2002-03-15 CN CNB021073678A patent/CN1174013C/zh not_active Expired - Lifetime
- 2002-03-15 CN CNB02107366XA patent/CN1171922C/zh not_active Expired - Lifetime
-
2007
- 2007-08-17 JP JP2007212819A patent/JP5171156B2/ja not_active Expired - Lifetime
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