ES2183189T3 - Catalizadores de polisiloxano modificados y metodo para utilizarlos. - Google Patents

Catalizadores de polisiloxano modificados y metodo para utilizarlos.

Info

Publication number
ES2183189T3
ES2183189T3 ES97928676T ES97928676T ES2183189T3 ES 2183189 T3 ES2183189 T3 ES 2183189T3 ES 97928676 T ES97928676 T ES 97928676T ES 97928676 T ES97928676 T ES 97928676T ES 2183189 T3 ES2183189 T3 ES 2183189T3
Authority
ES
Spain
Prior art keywords
radical
joined
selected independently
catalysts
metalaciclo
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES97928676T
Other languages
English (en)
Inventor
Sandor Nagy
John A Tyrell
Leonard V Cribbs
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Equistar Chemicals LP
Original Assignee
Equistar Chemicals LP
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Equistar Chemicals LP filed Critical Equistar Chemicals LP
Application granted granted Critical
Publication of ES2183189T3 publication Critical patent/ES2183189T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/02—Carriers therefor
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61916—Component covered by group C08F4/60 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

LA INVENCION SE REFIERE A CATALIZADORES PPARA LA POLIMERIZACION DE OLEFINAS, QUE CONTIENEN UNIDADES DE FORMULA (I), DONDE: CADA R SE SELECCIONA INDEPENDIENTEMENTE A PARTIR DE UN GRUPO ALIFATICO O CICLOALIFATICO C 1 - C 10 ; O UN ARILO, PARALQUILO O ALCARILO C 6 - C 18 ; CADA R 2 SE SELECCIONA INDEPENDIENTEMENTE A PARTIR DE HIDRURO, RADICALES R Y Q, DONDE AL MENOS UN R 2 ES Q; Q PRESENTA LA FORMULA GENERAL: LM P L'' R X P-R-1 , DONDE L ES UN LIGANDO AUX ILIAR AROMATICO MONOANIONICO, UNIDO A M A TRAVES DE UN ENLACE PI Y UNIDO COVALENTEMENTE A SI; L'' ES UN LIGANDO AUXILIAR AROMATICO MONOANIONICO UNIDO A TRAVES DE UN ENLACE PI A M Y, OPCIONALMENTE, UNIDO A L A TRAVES DE UN GRUPO DE PUENTE COVALENTE; M ES UN METAL SELECCIONADO A PARTIR DE LOS GRUPOS 3-10 DE LA TABLA PERIODICA O LANTANIDOS; X SE SELECCIONA INDEPENDIENTEMENTE A PARTIR DE UN RADICAL HIDRURO, RADICAL HALURO, RADICAL HIDROCARBILO, RADICAL HALOCARBILO, SILAHIDROCARBILO, RADICAL ALCOXI, RADICAL ARILOXI, RADICAL ALQUILSULFONATO, RADICALARILSULFONATO O RADICAL (R) 2 N - O DOS GRUPOS X ESTAN UNIDOS CON M P PARA FORMAR UNA FRACCION METALACICLO, SILAMETALACICLO O PI - DIENO METALACICLO; P ES LA VALENCIA DE M; R ES 0 O 1; N ES UN ENTERO ENTRE APROX. 10 Y 500.
ES97928676T 1996-05-28 1997-05-28 Catalizadores de polisiloxano modificados y metodo para utilizarlos. Expired - Lifetime ES2183189T3 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/654,435 US5747404A (en) 1996-05-28 1996-05-28 Polysiloxane supported metallocene catalysts
US08/859,319 US6121183A (en) 1996-05-28 1997-05-20 Modified polysiloxane catalysts and a method of using the same

Publications (1)

Publication Number Publication Date
ES2183189T3 true ES2183189T3 (es) 2003-03-16

Family

ID=27096743

Family Applications (1)

Application Number Title Priority Date Filing Date
ES97928676T Expired - Lifetime ES2183189T3 (es) 1996-05-28 1997-05-28 Catalizadores de polisiloxano modificados y metodo para utilizarlos.

Country Status (11)

Country Link
US (2) US5747404A (es)
EP (1) EP0902793B1 (es)
JP (1) JP2001525860A (es)
KR (1) KR20000034778A (es)
CN (1) CN1151177C (es)
AU (1) AU3287897A (es)
BR (1) BR9709405A (es)
CA (1) CA2261822A1 (es)
DE (1) DE69714990T2 (es)
ES (1) ES2183189T3 (es)
WO (1) WO1997045459A1 (es)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030195109A1 (en) * 1996-10-31 2003-10-16 Jose Sancho Royo Catalytic systems for the polimerisation and copolimerisation of alpha-olefins
PT953581E (pt) * 1998-04-27 2004-07-30 Repsol Quimica Sa Sistemas cataliticos para a polimerizacao e a copolimerizacao de alfa-olefinas
DE69916358T2 (de) * 1998-04-29 2005-04-21 Repsol Quimica Sa Verfahren und Verwendung von heterogenen Katalysatorbestandteilen für die Olefinpolymerisation
US6194343B1 (en) * 1999-03-11 2001-02-27 University Of Waterloo Bridged “tethered” metallocenes
DE19915108A1 (de) 1999-04-01 2000-10-05 Bayer Ag Geträgerte Katalysatoren mit einer Donor-Akzeptor-Wechselwirkung
US6281155B1 (en) * 1999-11-19 2001-08-28 Equistar Chemicals, L.P. Supported olefin polymerization catalysts
US6541412B1 (en) 1999-12-10 2003-04-01 Univation Technologies, Llc Catalyst system method for preparing and using same in a polymerization process
US6255415B1 (en) 2000-02-29 2001-07-03 Equistar Chemicals, L.P. Ethylene polymerization process
US6403736B1 (en) 2000-06-14 2002-06-11 Equistar Chemicals, Lp Ethylene polymerization process
JP4576126B2 (ja) * 2002-04-12 2010-11-04 ダウ グローバル テクノロジーズ インコーポレイティド アザボロリル４族金属錯体、触媒及びオレフィン重合方法
KR100720079B1 (ko) * 2006-05-15 2007-05-18 주식회사 준건설 앵커플레이트 없이 드레인재를 지중에 매설하는 드레인재타설장치
KR101685232B1 (ko) * 2009-08-24 2016-12-09 가부시키가이샤 브리지스톤 폴리디엔 제조를 위한 방법 및 촉매 시스템
CN104130294A (zh) * 2014-07-18 2014-11-05 同济大学 半夹心型多取代氮硼杂茂钛系金属氯化物及其合成方法

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE372414C (de) * 1923-03-27 Siemens & Halske Akt Ges Besetztpruefeinrichtung fuer Fernsprechanlagen mit Vielfachfeld, insbesondere fuer Nebenstellenbetrieb
DE3840772A1 (de) * 1988-12-03 1990-06-07 Hoechst Ag Verfahren zur herstellung einer heterogenen metallocenkatalysatorkomponente
JPH0687923A (ja) * 1992-09-08 1994-03-29 Ube Ind Ltd オレフィン重合用固体触媒
FR2715661B1 (fr) * 1994-01-31 1996-04-05 Rhone Poulenc Chimie Nouveaux photoamorceurs organométalliques polymériques et les compositions polyorganosiloxanes qui les comprennent réticulables par voie cationique.
US5473020A (en) * 1994-06-30 1995-12-05 Phillips Petroleum Company Polymer bound ligands, polymer bound metallocenes, catalyst systems, preparation, and use
IT1272939B (it) * 1995-02-01 1997-07-01 Enichem Spa Catalizzatore metallocenico supportato per la (co)polimerizzazione delle olefine
JPH0977819A (ja) * 1995-09-11 1997-03-25 Daicel Chem Ind Ltd ポリオレフィン製造用触媒、およびポリオレフィンの製造方法

Also Published As

Publication number Publication date
CN1225643A (zh) 1999-08-11
US6121183A (en) 2000-09-19
DE69714990T2 (de) 2003-04-10
CN1151177C (zh) 2004-05-26
WO1997045459A1 (en) 1997-12-04
EP0902793B1 (en) 2002-08-28
EP0902793A1 (en) 1999-03-24
AU3287897A (en) 1998-01-05
JP2001525860A (ja) 2001-12-11
KR20000034778A (ko) 2000-06-26
US5747404A (en) 1998-05-05
BR9709405A (pt) 2000-05-09
DE69714990D1 (de) 2002-10-02
CA2261822A1 (en) 1997-12-04

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