ES2181079T3 - Productos de reaccion de isocianatos con compuestos hidroxilados para acabados textiles. - Google Patents

Productos de reaccion de isocianatos con compuestos hidroxilados para acabados textiles.

Info

Publication number
ES2181079T3
ES2181079T3 ES98104641T ES98104641T ES2181079T3 ES 2181079 T3 ES2181079 T3 ES 2181079T3 ES 98104641 T ES98104641 T ES 98104641T ES 98104641 T ES98104641 T ES 98104641T ES 2181079 T3 ES2181079 T3 ES 2181079T3
Authority
ES
Spain
Prior art keywords
groups
isocianate
reaction products
hydroxylated compounds
alcoholic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES98104641T
Other languages
English (en)
Inventor
Franz Dr Dirschl
Franz Mosch
Theodor Angele
Wilhelm Artner
Edeltraud Schidek
Erich Rossler
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Huntsman Textile Effects Germany GmbH
Original Assignee
Ciba Spezialitaetenchemie Pfersee GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=7826388&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ES2181079(T3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Ciba Spezialitaetenchemie Pfersee GmbH filed Critical Ciba Spezialitaetenchemie Pfersee GmbH
Application granted granted Critical
Publication of ES2181079T3 publication Critical patent/ES2181079T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08Processes
    • C08G18/0804Manufacture of polymers containing ionic or ionogenic groups
    • C08G18/0809Manufacture of polymers containing ionic or ionogenic groups containing cationic or cationogenic groups
    • C08G18/0814Manufacture of polymers containing ionic or ionogenic groups containing cationic or cationogenic groups containing ammonium groups or groups forming them
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08Processes
    • C08G18/0838Manufacture of polymers in the presence of non-reactive compounds
    • C08G18/0842Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents
    • C08G18/0861Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents in the presence of a dispersing phase for the polymers or a phase dispersed in the polymers
    • C08G18/0866Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents in the presence of a dispersing phase for the polymers or a phase dispersed in the polymers the dispersing or dispersed phase being an aqueous medium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08Processes
    • C08G18/10Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/2805Compounds having only one group containing active hydrogen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30Low-molecular-weight compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30Low-molecular-weight compounds
    • C08G18/32Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3271Hydroxyamines
    • C08G18/3275Hydroxyamines containing two hydroxy groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72Polyisocyanates or polyisothiocyanates
    • C08G18/80Masked polyisocyanates
    • C08G18/8003Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen
    • C08G18/8006Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/32
    • C08G18/8009Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/32 with compounds of C08G18/3203
    • C08G18/8035Masked aromatic polyisocyanates not provided for in one single of the groups C08G18/8019 and C08G18/8029
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D06M15/277Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof containing fluorine
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/564Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/564Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
    • D06M15/568Reaction products of isocyanates with polyethers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/564Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
    • D06M15/576Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them containing fluorine

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Textile Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Dispersion Chemistry (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)

Abstract

LA INVENCION TRATA DE PRODUCTOS QUE SE FORMAN POR REACCION DE DIISOCIANATOS CON ALCOHOLES BIVALENTES O SUPERIORES Y/O CON UNO O VARIOS MONOETERES Y/O DIETERES DE TALES ALCOHOLES Y, A CONTINUACION, REACCION CON AMINAS ORGANICAS CON DOS O TRES GRUPOS HIDROXILOS ALCOHOLICOS Y BLOQUEO SUBSIGUIENTE DE GRUPOS ISOCIANATOS LIBRES. ESTOS PRODUCTOS SON APTOS PARA EL ACABADO DE MATERIALES DE FIBRA, EN ESPECIAL EN FORMA DE DISPERSIONES ACUOSAS COMO DILUYENTE PARA SU EMPLEO EN COMBINACION CON POLIMEROS QUE CONTIENEN GRUPOS PERFLUORALQUILOS QUE SIRVEN PARA EL ACABADO DE MATERIALES DE FIBRA CON UN TRATAMIENTO ANTIMANCHAS Y QUE NO DEJA PASAR ACEITE NI AGUA.
ES98104641T 1997-04-14 1998-03-14 Productos de reaccion de isocianatos con compuestos hidroxilados para acabados textiles. Expired - Lifetime ES2181079T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19715416A DE19715416A1 (de) 1997-04-14 1997-04-14 Umsetzungsprodukte von Isocyanaten mit Hydroxyverbindungen für die Textilveredelung

Publications (1)

Publication Number Publication Date
ES2181079T3 true ES2181079T3 (es) 2003-02-16

Family

ID=7826388

Family Applications (1)

Application Number Title Priority Date Filing Date
ES98104641T Expired - Lifetime ES2181079T3 (es) 1997-04-14 1998-03-14 Productos de reaccion de isocianatos con compuestos hidroxilados para acabados textiles.

Country Status (16)

Country Link
US (1) US6080830A (es)
EP (1) EP0872503B1 (es)
JP (1) JP4280325B2 (es)
KR (1) KR100514532B1 (es)
CN (1) CN1098870C (es)
AT (1) ATE223452T1 (es)
AU (1) AU724928B2 (es)
BR (1) BR9801016A (es)
DE (2) DE19715416A1 (es)
ES (1) ES2181079T3 (es)
ID (1) ID20149A (es)
IL (1) IL123582A (es)
PT (1) PT872503E (es)
TR (1) TR199800574A3 (es)
TW (1) TW472096B (es)
ZA (1) ZA982989B (es)

Families Citing this family (33)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1342829A3 (en) * 1997-09-18 2003-10-01 Minnesota Mining And Manufacturing Company Fluorochemical composition comprising a blocked isocyanate extender and method of treatment of a fibrous substrate therewith
WO1999014422A1 (en) * 1997-09-18 1999-03-25 Minnesota Mining And Manufacturing Company Fluorochemical composition comprising a blocked isocyanate extender and method of treatment of a fibrous substrate therewith
DE19852621A1 (de) * 1998-11-14 2000-05-18 Hansa Textilchemie Gmbh Permanentes Mittel zum Ausrüsten von Fasern oder aus Faser bestehenden Produkten
ATE293135T1 (de) 1998-12-22 2005-04-15 Ciba Sc Pfersee Gmbh Wässrige dispersionen für die textilveredlung
US6673889B1 (en) * 1999-06-28 2004-01-06 Omnova Solutions Inc. Radiation curable coating containing polyfuorooxetane
EP1088867A1 (de) 1999-09-30 2001-04-04 Ciba Spezialitätenchemie Pfersee GmbH Zusammensetzungen für die öl- und wasserabweisende Ausrüstung von Fasermaterialien
US6290867B1 (en) * 1999-12-08 2001-09-18 National Starch And Chemical Investment Holding Corporation Treatment composition which provides anti-wrinkling properties to textiles
AU2001281835A1 (en) * 2000-06-13 2001-12-24 Basf Aktiengesellschaft Use of polymers containing urethane and/or urea groups for the modification of surfaces
WO2002095123A1 (en) * 2001-05-23 2002-11-28 Ciba Specialty Chemicals Holdig Inc. Process for printing textile fabrics
EP1264863A1 (de) * 2001-06-08 2002-12-11 Ciba Spezialitätenchemie Pfersee GmbH Zusammensetzungen mit Polysiloxanen und weiteren Polymeren
GB0115240D0 (en) * 2001-06-22 2001-08-15 Ciba Sc Holding Ag Process for printing textile fabrics
DE10139126A1 (de) 2001-08-09 2003-02-20 Ciba Sc Pfersee Gmbh Zusammensetzungen aus Polysiloxanen, Fluorpolymeren und Extendern
DE10211549B9 (de) 2002-03-15 2004-11-25 Rudolf Gmbh & Co. Kg Chemische Fabrik Zubereitungen auf Basis von Wasser und/oder organischen Lösemitteln und deren Anwendung als Appretur auf Flächengebilden
AU2003234544B2 (en) * 2002-05-24 2008-04-03 3M Innovative Properties Company Fluorochemical composition for treatment of a fibrous substrate
US7094829B2 (en) * 2002-05-24 2006-08-22 3M Innovative Properties Company Fluorochemical composition comprising a fluorinated polymer and treatment of a fibrous substrate therewith
US7425279B2 (en) * 2002-05-24 2008-09-16 3M Innovative Properties Company Fluorochemical composition for treatment of a fibrous substrate
CA2487068A1 (en) * 2002-05-24 2003-12-04 3M Innovative Properties Company Fluorochemical composition comprising perfluoropolyether and an extender for the treatment of fibrous substrates
ITVA20020064A1 (it) * 2002-12-02 2004-06-03 Lamberti Spa Dispersioni acquose stabili di poliisocianati bloccati non ionici.
US20040137818A1 (en) * 2003-01-10 2004-07-15 Kimbrell William C. Wash-durable, liquid repellent, and stain releasing cotton fabric substrates
US7407899B2 (en) * 2003-01-10 2008-08-05 Milliken & Company Textile substrates having layered finish structure for improving liquid repellency and stain release
US20040138083A1 (en) * 2003-01-10 2004-07-15 Kimbrell Wiliam C. Substrates having reversibly adaptable surface energy properties and method for making the same
US7485588B2 (en) * 2003-01-10 2009-02-03 Yunzhang Wang Method for making textile substrates having layered finish structure for improving liquid repellency and stain release
US7468333B2 (en) * 2003-01-10 2008-12-23 Milliken & Company Wash-durable, liquid repellent, and stain releasing polyester fabric substrates
DE10325094B4 (de) * 2003-06-03 2006-02-16 Rudolf Gmbh & Co. Kg Chemische Fabrik Zubereitungen für die öl- und wasserabweisende Ausrüstung von Flächengebilden und deren Anwendung
EP1496073A1 (de) * 2003-07-08 2005-01-12 Ciba Spezialitätenchemie Pfersee GmbH Extender für die Behandlung von Fasermaterialien
EP1672006A1 (de) * 2004-12-14 2006-06-21 Ciba Spezialitätenchemie Pfersee GmbH Wässrige Dispersionen von Harnstoffgruppen enthaltenden Polyorganosiloxanen
US7820563B2 (en) * 2006-10-23 2010-10-26 Hawaii Nanosciences, Llc Compositions and methods for imparting oil repellency and/or water repellency
US8828098B2 (en) * 2006-12-18 2014-09-09 3M Innovative Properties Company Extenders for fluorochemical treatment of fibrous substrates
EP2302130A1 (de) 2009-09-26 2011-03-30 Huntsman Textile Effects (Germany) GmbH Zusammensetzung für die Öl- und/oder Wasserabweisende Ausrüstung von Fasermaterialien
TWI425026B (zh) 2011-09-19 2014-02-01 Everlight Chem Ind Corp 聚氨酯衍生物及其組成物及包括該衍生物的染料添加劑
CN102658057B (zh) * 2012-04-16 2014-09-10 王志军 一种新型聚氨酯分散剂及其制备方法
CN111101216B (zh) * 2019-12-16 2022-06-14 浙江工商大学 聚丙烯腈基-羟基脲螯合纤维及其合成方法和应用
CN112724365B (zh) * 2020-11-30 2022-10-14 温州大学 阻燃型超支化聚合物皮革复鞣剂

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DE2456469C2 (de) * 1974-11-29 1983-01-13 Bayer Ag, 5090 Leverkusen Verfahren zur Herstellung von in Wasser löslichen bzw. dispergierbaren blockierten Polyisocyanaten und ihre Verwendung als Beschichtungsmittel
US4531946A (en) * 1983-03-09 1985-07-30 Diamond Shamrock Chemicals Company Aftertreatment of dyed cellulosic materials
DE3319368A1 (de) * 1983-05-27 1984-11-29 Bayer Ag, 5090 Leverkusen Perfluoralkylgruppen-enthaltende polyurethane und verfahren zu ihrer herstellung
DE3435618A1 (de) * 1984-09-28 1986-04-10 Chemische Fabrik Pfersee Gmbh, 8900 Augsburg Verfahren zur erzielung wasch- und reinigungsbestaendiger textilausruestungen mit reaktiven (co)polymeren bzw. vorkondensaten
JPH0689323B2 (ja) * 1986-06-13 1994-11-09 第一工業製薬株式会社 制電加工剤
US4761337A (en) * 1986-09-26 1988-08-02 Basf Corporation Cationic electrodepositable resin compositions containing polyurethane resin dispersions
ZA873916B (en) * 1986-09-26 1988-02-24 Inmont Basf Cationic electrodepositable resin compositions containing polyurethane resin dispersions
DE4020115A1 (de) * 1990-06-23 1992-01-02 Basf Lacke & Farben Verfahren zum beschichten elektrisch leitfaehiger substrate, waessriger lack und blockierte nco-gruppen enthaltendes vernetzungsmittel
DE4134284A1 (de) * 1991-10-17 1993-04-22 Bayer Ag In wasser dispergierbare blockierte polyisocyanate, verfahren zu ihrer herstellung und ihre verwendung
US5508370A (en) * 1991-10-17 1996-04-16 Bayer Aktiengesellschaft Water-dispersible blocked isocyanates, method of manufacture, and use thereof

Also Published As

Publication number Publication date
PT872503E (pt) 2003-01-31
EP0872503B1 (de) 2002-09-04
DE19715416A1 (de) 1998-10-15
AU6078898A (en) 1998-10-15
TW472096B (en) 2002-01-11
KR19980081339A (ko) 1998-11-25
KR100514532B1 (ko) 2006-03-22
JPH10306137A (ja) 1998-11-17
JP4280325B2 (ja) 2009-06-17
IL123582A (en) 2001-08-08
TR199800574A2 (xx) 1999-06-21
ATE223452T1 (de) 2002-09-15
EP0872503A1 (de) 1998-10-21
ZA982989B (en) 1998-10-14
ID20149A (id) 1998-10-15
CN1196360A (zh) 1998-10-21
IL123582A0 (en) 1998-10-30
CN1098870C (zh) 2003-01-15
TR199800574A3 (tr) 1999-06-21
BR9801016A (pt) 1999-10-05
US6080830A (en) 2000-06-27
AU724928B2 (en) 2000-10-05
DE59805370D1 (de) 2002-10-10

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