ES2179356T3 - Procedimiento para la halogenacion de copolimeros de isomonoolefina/para alquilestireno. - Google Patents

Procedimiento para la halogenacion de copolimeros de isomonoolefina/para alquilestireno.

Info

Publication number
ES2179356T3
ES2179356T3 ES97933562T ES97933562T ES2179356T3 ES 2179356 T3 ES2179356 T3 ES 2179356T3 ES 97933562 T ES97933562 T ES 97933562T ES 97933562 T ES97933562 T ES 97933562T ES 2179356 T3 ES2179356 T3 ES 2179356T3
Authority
ES
Spain
Prior art keywords
halogenation
isomonoolefine
procedure
hydrogen
renting
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES97933562T
Other languages
English (en)
Inventor
David Yen-Lung Chung
Neil Frederick Newman
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
ExxonMobil Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ExxonMobil Chemical Patents Inc filed Critical ExxonMobil Chemical Patents Inc
Application granted granted Critical
Publication of ES2179356T3 publication Critical patent/ES2179356T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • C08F8/18Introducing halogen atoms or halogen-containing groups
    • C08F8/20Halogenation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • C08F8/18Introducing halogen atoms or halogen-containing groups
    • C08F8/20Halogenation
    • C08F8/22Halogenation by reaction with free halogens

Landscapes

  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

SE EXPONE UN PROCEDIMIENTO PARA HALOGENAR UN COPOLIMERO DE UNA ISOMONOOLEFINA C 4 - C 7 , POR EJEMPLO, ISOBUTILENO, Y UN PARA ALQUILESTIRENO, POR EJEMPLO, PARA - METILESTIRENO. EL AUMENTO DE LA EFICIENCIA DE LA HALOGENACION SE CONSIGUE DESARROLLANDOSE EN LA REACCION EN CONDICIONES DE HALOGENACION DE RADICALES LIBRES Y EN PRESENCIA DE UN AGENTE OXIDANTE, POR EJEMPLO, PEROXIDO DE HIDROGENO, QUE OXIDA EL HALOGENURO DE HIDROGENO GENERADO IN SITU EN EL LUGAR DE LA REACCION, CONVIRTIENDOLO EN HALOGENO LIBRE. EL AGENTE OXIDANTE NO SE AÑADE PREFERENTEMENTE AL MEDIO DE REACCION HASTA QUE SE HAYA COMPLETADO SUSTANCIALMENTE LA PRIMERA ETAPA DE LA HALOGENACION.
ES97933562T 1996-07-24 1997-07-18 Procedimiento para la halogenacion de copolimeros de isomonoolefina/para alquilestireno. Expired - Lifetime ES2179356T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US08/686,194 US5670582A (en) 1996-07-24 1996-07-24 Process for halogenation of isomonoolefin/para-alkylstyrene copolymers

Publications (1)

Publication Number Publication Date
ES2179356T3 true ES2179356T3 (es) 2003-01-16

Family

ID=24755320

Family Applications (1)

Application Number Title Priority Date Filing Date
ES97933562T Expired - Lifetime ES2179356T3 (es) 1996-07-24 1997-07-18 Procedimiento para la halogenacion de copolimeros de isomonoolefina/para alquilestireno.

Country Status (15)

Country Link
US (1) US5670582A (es)
EP (1) EP0914357B1 (es)
JP (1) JP4233607B2 (es)
KR (1) KR20000067959A (es)
CN (1) CN1225648A (es)
AT (1) AT406582B (es)
BR (1) BR9710883A (es)
CA (1) CA2257820C (es)
CZ (1) CZ21299A3 (es)
DE (1) DE69715424T2 (es)
EA (1) EA199900132A1 (es)
ES (1) ES2179356T3 (es)
HU (1) HUP9904350A3 (es)
PL (1) PL330991A1 (es)
WO (1) WO1998003563A1 (es)

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6100343A (en) * 1998-11-03 2000-08-08 Beholz Technology, L.L.C. Process for producing paintable polymeric articles
AU3198199A (en) * 1998-03-26 1999-10-18 Beholz Technology, L.L.C. Process for producing paintable polymeric articles
US6077913A (en) * 1998-03-26 2000-06-20 Beholz Technology, L.L.C. Process for producing paintable polymeric articles
CA2247675C (en) * 1998-09-17 2009-05-05 Pola Chemical Industries, Inc. Antifungal agents
US7901603B1 (en) 2004-06-21 2011-03-08 Lars Guenter Beholz Process for producing adhesive polymeric articles from expanded foam materials
HU230261B1 (hu) * 2007-11-27 2015-11-30 Egis Gyógyszergyár Nyilvánosan Működő Részvénytársaság Eljárás gyógyszeripari intermedierek előállítására
WO2011117280A1 (en) * 2010-03-24 2011-09-29 Lanxess International Sa Process for the production of water and solvent-free polymers
US20130203943A1 (en) * 2010-03-24 2013-08-08 Lanxess International Sa Process for the production of water and solvent-free halobutyl rubbers
US8524859B2 (en) 2010-04-30 2013-09-03 Exxonmobil Chemical Patents Inc. Method for elastomer finishing
US8242236B2 (en) * 2010-05-26 2012-08-14 Exxonmobil Chemical Patents Inc. Elastomeric nanocomposite manufacturing
US9079990B2 (en) 2010-06-01 2015-07-14 Exxonmobil Chemical Patents Inc. Methods of production of alkylstyrene/isoolefin polymers
CN102167844B (zh) * 2011-03-17 2012-12-12 北京化工大学 以氢溴酸为溴源生产溴化胶粉的方法
EP2734555B1 (en) * 2011-07-20 2020-05-27 ARLANXEO Deutschland GmbH Process for producing brominated butyl rubber
US10781295B2 (en) 2014-02-28 2020-09-22 Exxonmobil Chemical Patents Inc. Mooney viscosity stable brominated elastomers
WO2015130392A1 (en) 2014-02-28 2015-09-03 Exxonmobil Chemical Patents Inc. Nanocomposite mooney viscosity stability
SG11201701313UA (en) 2014-09-30 2017-04-27 Exxonmobil Chemical Patents Inc Process for preparing a brominated elastomer with improved mooney viscosity stability
NL2013819B1 (nl) 2014-11-17 2016-10-10 Lankhorst Eng Products B V Bekledingskoker voor het omhullen van een onderwater-leiding.
WO2016099694A1 (en) 2014-12-19 2016-06-23 Exxonmobil Chemical Patents Inc. Polymerization quenching
CN107709374B (zh) * 2015-07-01 2020-07-10 株式会社钟化 卤代异烯烃系聚合物的制造方法
CN108472618B (zh) 2016-01-29 2020-04-28 埃克森美孚化学专利公司 用于生产官能化烯烃基聚合物的系统和方法
RU2733381C2 (ru) * 2016-03-31 2020-10-01 Тояма Кемикал Ко., Лтд. Способ получения 5-(бромметил)-1-бензотиофена
WO2018217294A1 (en) 2017-05-22 2018-11-29 Exxonmobil Chemical Patents Inc. Halogenated elastomers with mooney viscosity stability and method for preparing same
JP2020152739A (ja) * 2017-07-13 2020-09-24 株式会社カネカ 臭素化ポリイソブチレン系重合体および製造方法
CN113366027A (zh) 2018-12-17 2021-09-07 阿朗新科新加坡私人有限公司 使用叔醚生产异烯烃聚合物的方法
EP3898716A4 (en) * 2018-12-21 2023-01-11 Arlanxeo Singapore Pte. Ltd. HALOGEN RECOVERY IN A WET PROCESS FOR HALOGENATION OF UNSATURATED ISOOLEFIN COPOLYMERS
WO2020132742A1 (en) 2018-12-27 2020-07-02 ARLANXEO Canada Inc. Process for producing chlorinated butyl rubber
CN110272514A (zh) * 2019-07-05 2019-09-24 黄河三角洲京博化工研究院有限公司 一种溴化异丁烯-对甲基苯乙烯共聚物及其制备方法
JP2023552480A (ja) * 2020-12-11 2023-12-15 アランセオ・シンガポール・プライヴェート・リミテッド 不飽和イソオレフィンコポリマーをハロゲン化する方法におけるk+含有酸化剤によるハロゲン回収

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3018275A (en) * 1958-12-30 1962-01-23 Exxon Research Engineering Co Halogenation of low unsaturation rubbery polymers in the presence of oxidizing agen
FR2427343A1 (fr) * 1978-05-31 1979-12-28 Dia Prosim Procede de bromation de resines a base de copolymeres vinylaromatiques reticules
US5162445A (en) * 1988-05-27 1992-11-10 Exxon Chemical Patents Inc. Para-alkylstyrene/isoolefin copolymers and functionalized copolymers thereof
CA1338546C (en) * 1988-05-27 1996-08-20 Kenneth William Powers Para-alkylstyrene/isoolefin copolymers
US5077345A (en) * 1990-03-01 1991-12-31 Exxon Chemical Patents Inc. Halogenation of polymers with improved neutralization
DE4213164A1 (de) * 1992-04-22 1993-10-28 Bayer Ag Verfahren zur Herstellung von bromiertem chlorsubstituiertem Poly-1,3-butadien
JPH06208743A (ja) * 1992-12-14 1994-07-26 Olympus Optical Co Ltd 情報再生装置
DE4437931A1 (de) * 1994-10-24 1996-04-25 Bayer Ag Verfahren zur Bromierung von Alkylkautschuken
IT1271048B (it) * 1994-10-27 1997-05-26 Caffaro Spa Ind Chim Procedimento per la preparazione di polimeri alifatici clorurati
US5681901A (en) * 1996-07-24 1997-10-28 Exxon Chemical Patents Inc. Process for halogenating isomonoolefin copolymers

Also Published As

Publication number Publication date
WO1998003563A1 (en) 1998-01-29
KR20000067959A (ko) 2000-11-25
DE69715424T2 (de) 2003-05-15
JP2000515193A (ja) 2000-11-14
DE69715424D1 (de) 2002-10-17
US5670582A (en) 1997-09-23
HUP9904350A3 (en) 2000-09-28
CN1225648A (zh) 1999-08-11
CA2257820A1 (en) 1998-01-29
PL330991A1 (en) 1999-06-21
CZ21299A3 (cs) 1999-12-15
ATA907697A (de) 1999-11-15
EP0914357A2 (en) 1999-05-12
AT406582B (de) 2000-06-26
EP0914357B1 (en) 2002-09-11
EA199900132A1 (ru) 1999-08-26
BR9710883A (pt) 1999-08-17
CA2257820C (en) 2003-09-23
HUP9904350A2 (hu) 2000-04-28
JP4233607B2 (ja) 2009-03-04

Similar Documents

Publication Publication Date Title
ES2179356T3 (es) Procedimiento para la halogenacion de copolimeros de isomonoolefina/para alquilestireno.
ES2166553T3 (es) Procedimiento mejorado para halogenar copolimeros de isomonoolefinas.
MXPA03005517A (es) Composicion oxidante para tratamiento de materias queratinicas a base de polimeros anfifilos de al menos un monomero de insaturacion etilenica con grupo sulfonico y que comprende una parte hidrofoba.
ATE324417T1 (de) Polyphenolisches protein enthaltende bioadhäsive zusammensetzung
ES2076292T3 (es) Composiciones blanqueantes y de activacion de blanqueantes.
ES2101942T3 (es) Procedimiento de epoxidacion.
TR200101823T2 (tr) Polioksometalatlar ve hava ya da moleküler oksijen ile ağartma yapılması.
MX166909B (es) Cable ascendente para la comunicacion en edificios
DK1003534T3 (da) Reovirus til behandling af neoplasi
HUP9702512A1 (hu) Keratintartalmú rostok oxidációs festésére való készítmény és festési eljárás a készítmény alkalmazásával
AR016240A1 (es) Metodo para generar un compuesto de bromo oxidante estable y metodos para utilizarlo
FI964748A0 (fi) Huoneenlämpötilan sterilointiaine
BR9914993A (pt) Processo de alocar códigos de embaralhar em um sistema de comunicações celular por difusão de espectros e o respectivo sistema de comunicações celular por difusão de espectros
KR960012336A (ko) 반도체 장치의 제조 방법
ES554221A0 (es) Procedimiento para la obtencion de una composicion absorbente del hidrogeno para cables de fibras opticas y sus componentes
TR199802389T2 (xx) Kumaş kıvamlandırma bileşimi.
TR199900176T2 (xx) Bir perasit olu�turmak i�in y�ntem ve bu perasidi ihtiva eden bir terkip.
ES2150155T3 (es) Procedimiento para la preparacion de perfluoropolioxialquilenos peroxidicos.
ES2186215T3 (es) Cepillo de dientes.
SE8503201L (sv) Rostomvandlings- och rostskyddsmedel
ES2111628T3 (es) Composiciones detergentes liquidas acuosas y concentradas que comprenden polivinilpirrolidona y un polimero de liberacion de suciedad a base de tereftalato.
ES2140246T3 (es) Colorante sustituido con copolimero de polisiloxano-polioxialquileno.
DE60107457D1 (de) Vorvernetzungshemmende zusammensetzung
ES2152974T3 (es) Composiciones blanqueantes basadas en mezclas de tensioactivos cationicos y no ionicos.
PE20001223A1 (es) Composiciones blanqueadoras