ES2166553T3 - Procedimiento mejorado para halogenar copolimeros de isomonoolefinas. - Google Patents
Procedimiento mejorado para halogenar copolimeros de isomonoolefinas.Info
- Publication number
- ES2166553T3 ES2166553T3 ES97933558T ES97933558T ES2166553T3 ES 2166553 T3 ES2166553 T3 ES 2166553T3 ES 97933558 T ES97933558 T ES 97933558T ES 97933558 T ES97933558 T ES 97933558T ES 2166553 T3 ES2166553 T3 ES 2166553T3
- Authority
- ES
- Spain
- Prior art keywords
- find
- improved procedure
- reaction
- isomonoolefin
- isomonoolefin copolymers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/18—Introducing halogen atoms or halogen-containing groups
- C08F8/20—Halogenation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/18—Introducing halogen atoms or halogen-containing groups
- C08F8/20—Halogenation
- C08F8/22—Halogenation by reaction with free halogens
Abstract
SE DESCRIBE UN PROCEDIMIENTO PARA HALOGENAR UN COPOLIMERO DE UNA ISOMONOOLEFINA DE C 4 A C 7 , POR EJEMPLO, ISOBUTILENO, Y UNA MULTIOLEFINA, POR EJEMPLO, ISOPRENO O UN PARA - ALQUILESTIRENO, POR EJEMPLO, PARA - METILESTIRENO. EL AUMENTO DE LA EFICIENCIA DE LA HALOGENACION Y LA DISMINUCION DEL TIEMPO DE REACCION SE CONSIGUEN DESARROLLANDOSE LA REACCION EN PRESENCIA DE UNA FUENTE DE HALOGENO Y DE UNA EMULSION ACUOSA QUE CONTIENE UN AGENTE OXIDANTE SOLUBLE EN AGUA, POR EJEMPLO, PEROXIDO DE HIDROGENO, QUE OXIDA EL HALURO DE HIDROGENO GENERADO IN SITU EN LA REACCION, CONVIRTIENDOLO DE NUEVO EN HALOGENO LIBRE.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/685,403 US5681901A (en) | 1996-07-24 | 1996-07-24 | Process for halogenating isomonoolefin copolymers |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2166553T3 true ES2166553T3 (es) | 2002-04-16 |
Family
ID=24752063
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES97933558T Expired - Lifetime ES2166553T3 (es) | 1996-07-24 | 1997-07-18 | Procedimiento mejorado para halogenar copolimeros de isomonoolefinas. |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US5681901A (es) |
| EP (1) | EP0914356B1 (es) |
| JP (1) | JP4689770B2 (es) |
| KR (1) | KR100488327B1 (es) |
| CN (1) | CN1225649A (es) |
| AT (1) | AT406581B (es) |
| BR (1) | BR9710539A (es) |
| CA (1) | CA2257812C (es) |
| DE (1) | DE69709648T2 (es) |
| EA (1) | EA199900111A1 (es) |
| ES (1) | ES2166553T3 (es) |
| HU (1) | HUP9904331A3 (es) |
| PL (1) | PL330990A1 (es) |
| WO (1) | WO1998003562A1 (es) |
Families Citing this family (42)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5670582A (en) * | 1996-07-24 | 1997-09-23 | Exxon Chemical Patents Inc. | Process for halogenation of isomonoolefin/para-alkylstyrene copolymers |
| CA2282900C (en) | 1999-09-20 | 2011-02-01 | Bayer Inc. | Halogenated terpolymers of isobutylene, diolefin monomer and styrenic monomer |
| US20060167184A1 (en) * | 2000-10-18 | 2006-07-27 | Waddell Walter H | Innerliners for use in tires |
| TWI229089B (en) * | 2000-12-12 | 2005-03-11 | Bayer Ag | Halogenated, high molecular weight, gel-free isobutene copolymers with elevated double bond contents |
| ATE428734T1 (de) * | 2001-12-10 | 2009-05-15 | Exxonmobil Chem Patents Inc | Elastomere zusammensetzungen |
| CN100577699C (zh) * | 2002-12-20 | 2010-01-06 | 埃克森美孚化学专利公司 | 具有新序列分布的聚合物 |
| EP1905581A1 (en) | 2003-10-27 | 2008-04-02 | ExxonMobil Chemical Patents Inc. | Microlayered composites and processes for making the same |
| DE602005018269D1 (de) * | 2005-07-01 | 2010-01-21 | Pirelli | Verfahren zur herstellung von reifen |
| US7501460B1 (en) | 2005-07-18 | 2009-03-10 | Exxonmobile Chemical Patents Inc. | Split-stream process for making nanocomposites |
| US7514491B2 (en) | 2005-07-18 | 2009-04-07 | Exxonmobil Chemical Patents Inc. | Functionalized isobutylene polymer-inorganic clay nanocomposites and organic-aqueous emulsion process |
| EP2502742B1 (en) | 2005-10-27 | 2017-06-21 | ExxonMobil Chemical Patents Inc. | Construction comprising tie layer for pneumatic tire |
| US7585914B2 (en) | 2005-11-09 | 2009-09-08 | Exxonmobil Chemical Patents Inc. | Thermoplastic elastomer compositions and methods for making the same |
| JP5210885B2 (ja) * | 2005-12-28 | 2013-06-12 | エクソンモービル・ケミカル・パテンツ・インク | ハロゲン化方法 |
| EP1987962B1 (en) * | 2006-02-23 | 2011-07-13 | The Yokohama Rubber Co., Ltd. | Multilayer body and pneumatic tire using same |
| US7498381B1 (en) | 2006-08-02 | 2009-03-03 | Exxonmobil Chemical Patents Inc. | Low permeability elastomeric-metal phosphate nanocomposites |
| CN103923236A (zh) * | 2007-05-16 | 2014-07-16 | 埃克森美孚化学专利公司 | 用于烯烃聚合的催化剂体系以及由其制得的聚合物 |
| RU2401844C2 (ru) * | 2008-10-13 | 2010-10-20 | ОТКРЫТОЕ АКЦИОНЕРНОЕ ОБЩЕСТВО "СИБУР Холдинг" | Способ получения бромбутилкаучука |
| US8763658B2 (en) | 2008-10-16 | 2014-07-01 | Pirelli Tyre S.P.A. | Tyre comprising an electronic unit |
| KR20150027843A (ko) * | 2010-01-20 | 2015-03-12 | 란세스 인터내쇼날 에스에이 | 중합체 나노복합체의 제조 방법 |
| WO2011089092A1 (en) | 2010-01-20 | 2011-07-28 | Lanxess International Sa | Common solvent process for producing high molecular weight halogenated rubber |
| RU2584424C2 (ru) * | 2010-01-20 | 2016-05-20 | Ланксесс Интернасьональ Са | Способ получения высокомолекулярного бромированного каучука с использованием общего растворителя |
| WO2011089083A1 (en) * | 2010-01-20 | 2011-07-28 | Lanxess International Sa | Process for production of halobutyl ionomers |
| KR101627440B1 (ko) * | 2011-07-20 | 2016-06-03 | 란세스 인터내쇼날 에스에이 | 브로민화 부틸 고무의 제조 방법 |
| EP2892722A1 (en) | 2012-09-06 | 2015-07-15 | ExxonMobil Chemical Patents Inc. | Construction comprising tie layer |
| EP3110883B1 (en) | 2014-02-28 | 2018-10-10 | ExxonMobil Chemical Patents Inc. | Mooney viscosity stable brominated elastomers |
| CN105330776B (zh) * | 2014-06-16 | 2017-11-17 | 中国石油化工股份有限公司 | 制备卤化丁基橡胶的方法 |
| SG11201701313UA (en) * | 2014-09-30 | 2017-04-27 | Exxonmobil Chemical Patents Inc | Process for preparing a brominated elastomer with improved mooney viscosity stability |
| CN105820281B (zh) * | 2015-01-09 | 2018-03-02 | 中国石油化工股份有限公司 | 一种卤化聚合物的制备方法 |
| CN105111347B (zh) * | 2015-09-15 | 2017-08-29 | 黄河三角洲京博化工研究院有限公司 | 一种溴化丁基橡胶的生产方法 |
| JP6591666B2 (ja) * | 2015-09-30 | 2019-10-16 | エクソンモービル ケミカル パテンツ インコーポレイテッド | グラフェン及びグラファイトを分散させるための多環式芳香族炭化水素官能化イソブチレンコポリマー |
| WO2018217294A1 (en) | 2017-05-22 | 2018-11-29 | Exxonmobil Chemical Patents Inc. | Halogenated elastomers with mooney viscosity stability and method for preparing same |
| US10889704B2 (en) | 2017-05-22 | 2021-01-12 | Exxonmobil Chemical Patents Inc. | Halogenated elastomers with Mooney viscosity stability and method for preparing same |
| WO2019036085A1 (en) | 2017-08-18 | 2019-02-21 | Exxonmobil Chemical Patents Inc | HYDROCARBON RESINS FOR BUTYL BASED COMPOSITIONS AND PROCESSES FOR PREPARING THE SAME |
| SG11202009506SA (en) | 2018-04-03 | 2020-10-29 | Exxonmobil Chemical Patents Inc | Solvent-free process for functionalizing isobutylene-based polymers |
| WO2019195116A1 (en) | 2018-04-03 | 2019-10-10 | Exxonmobil Chemical Patents Inc. | Isobutylene-based polymers with olefinic side chain substituents and curable compositions containing the same |
| CN112119120B (zh) | 2018-04-03 | 2023-05-26 | 埃克森美孚化学专利公司 | 硫代乙酸酯官能化基于异丁烯的聚合物及含有它的可固化组合物 |
| EP3898715A4 (en) * | 2018-12-21 | 2023-01-11 | Arlanxeo Singapore Pte. Ltd. | RECOVERY OF HALOGEN IN A PROCESS FOR THE HALOGENATION OF AN UNSATURATED ISOOLEFIN COPOLYMER |
| JP7254183B2 (ja) | 2018-12-27 | 2023-04-07 | アランセオ・シンガポール・プライヴェート・リミテッド | 塩素化ブチルゴムを生成するための方法 |
| CN114423838B (zh) | 2019-07-17 | 2023-11-24 | 埃克森美孚化学专利公司 | 包含丙烯-乙烯(-二烯)共聚物的压敏粘合剂 |
| WO2021262838A1 (en) | 2020-06-26 | 2021-12-30 | Exxonmobil Chemical Patents Inc. | Copolymers composed of ethylene, a-olefin, non-conjugated diene, and substituted styrene and articles therefrom |
| WO2021262842A1 (en) | 2020-06-26 | 2021-12-30 | Exxonmobil Chemical Patents Inc. | COPOLYMERS OF ETHYLENE, α-OLEFIN, NON-CONJUGATED DIENE, AND ARYL-SUBSTITUTED CYCLOALKENE, METHODS TO PRODUCE, BLENDS, AND ARTICLES THEREFROM |
| EP4259668A1 (en) | 2020-12-11 | 2023-10-18 | Arlanxeo Singapore Pte. Ltd. | Halogen recovery with k-containing oxidant in a process for halogenating unsaturated isoolefin copolymer |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3018275A (en) * | 1958-12-30 | 1962-01-23 | Exxon Research Engineering Co | Halogenation of low unsaturation rubbery polymers in the presence of oxidizing agen |
| DE2651435C3 (de) * | 1976-11-11 | 1980-11-27 | Basf Ag, 6700 Ludwigshafen | Verfahren zur Herstellung von bromierten Polymerisationsprodukten des Styrols |
| US4129699A (en) * | 1977-08-25 | 1978-12-12 | The Firestone Tire & Rubber Company | Process for the hydrohalogenation of buta-diene-containing polymers |
| FR2427343A1 (fr) * | 1978-05-31 | 1979-12-28 | Dia Prosim | Procede de bromation de resines a base de copolymeres vinylaromatiques reticules |
| US5162445A (en) * | 1988-05-27 | 1992-11-10 | Exxon Chemical Patents Inc. | Para-alkylstyrene/isoolefin copolymers and functionalized copolymers thereof |
| US4975496A (en) * | 1989-08-10 | 1990-12-04 | The Dow Chemical Company | Process for brominating aromatic resins |
| BR8907906A (pt) * | 1989-10-03 | 1992-07-21 | Exxon Chemical Patents Inc | Copolimero de enxerto,processo para a compatibilizacao de uma mistura de polimeros,e mistura de polimeros |
| US5077345A (en) * | 1990-03-01 | 1991-12-31 | Exxon Chemical Patents Inc. | Halogenation of polymers with improved neutralization |
| DE4213164A1 (de) * | 1992-04-22 | 1993-10-28 | Bayer Ag | Verfahren zur Herstellung von bromiertem chlorsubstituiertem Poly-1,3-butadien |
| DE4437931A1 (de) * | 1994-10-24 | 1996-04-25 | Bayer Ag | Verfahren zur Bromierung von Alkylkautschuken |
-
1996
- 1996-07-24 US US08/685,403 patent/US5681901A/en not_active Expired - Lifetime
-
1997
- 1997-07-18 DE DE69709648T patent/DE69709648T2/de not_active Expired - Lifetime
- 1997-07-18 JP JP50711998A patent/JP4689770B2/ja not_active Expired - Lifetime
- 1997-07-18 KR KR10-1999-7000418A patent/KR100488327B1/ko not_active IP Right Cessation
- 1997-07-18 WO PCT/US1997/012638 patent/WO1998003562A1/en active IP Right Grant
- 1997-07-18 EP EP97933558A patent/EP0914356B1/en not_active Expired - Lifetime
- 1997-07-18 CA CA002257812A patent/CA2257812C/en not_active Expired - Lifetime
- 1997-07-18 BR BR9710539A patent/BR9710539A/pt not_active Application Discontinuation
- 1997-07-18 PL PL97330990A patent/PL330990A1/xx unknown
- 1997-07-18 EA EA199900111A patent/EA199900111A1/ru unknown
- 1997-07-18 AT AT0907597A patent/AT406581B/de not_active IP Right Cessation
- 1997-07-18 ES ES97933558T patent/ES2166553T3/es not_active Expired - Lifetime
- 1997-07-18 CN CN97196597A patent/CN1225649A/zh active Pending
- 1997-07-18 HU HU9904331A patent/HUP9904331A3/hu unknown
Also Published As
| Publication number | Publication date |
|---|---|
| PL330990A1 (en) | 1999-06-21 |
| JP4689770B2 (ja) | 2011-05-25 |
| CA2257812A1 (en) | 1998-01-29 |
| CN1225649A (zh) | 1999-08-11 |
| DE69709648T2 (de) | 2002-08-22 |
| EP0914356B1 (en) | 2002-01-16 |
| HUP9904331A3 (en) | 2000-07-28 |
| DE69709648D1 (de) | 2002-02-21 |
| CA2257812C (en) | 2003-01-07 |
| KR100488327B1 (ko) | 2005-05-11 |
| ATA907597A (de) | 1999-11-15 |
| WO1998003562A1 (en) | 1998-01-29 |
| BR9710539A (pt) | 1999-08-17 |
| EA199900111A1 (ru) | 1999-08-26 |
| HUP9904331A2 (hu) | 2000-05-28 |
| JP2000515192A (ja) | 2000-11-14 |
| US5681901A (en) | 1997-10-28 |
| EP0914356A1 (en) | 1999-05-12 |
| AT406581B (de) | 2000-06-26 |
| KR20000067939A (ko) | 2000-11-25 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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