ES2168019T3 - Procedimiento para el pretratamiento de superficies de cobre. - Google Patents
Procedimiento para el pretratamiento de superficies de cobre.Info
- Publication number
- ES2168019T3 ES2168019T3 ES99934222T ES99934222T ES2168019T3 ES 2168019 T3 ES2168019 T3 ES 2168019T3 ES 99934222 T ES99934222 T ES 99934222T ES 99934222 T ES99934222 T ES 99934222T ES 2168019 T3 ES2168019 T3 ES 2168019T3
- Authority
- ES
- Spain
- Prior art keywords
- acid
- copper surfaces
- selenium
- copper
- solution containing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/38—Improvement of the adhesion between the insulating substrate and the metal
- H05K3/389—Improvement of the adhesion between the insulating substrate and the metal by the use of a coupling agent, e.g. silane
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/48—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 not containing phosphates, hexavalent chromium compounds, fluorides or complex fluorides, molybdates, tungstates, vanadates or oxalates
- C23C22/52—Treatment of copper or alloys based thereon
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/82—After-treatment
- C23C22/83—Chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F1/00—Etching metallic material by chemical means
- C23F1/10—Etching compositions
- C23F1/14—Aqueous compositions
- C23F1/16—Acidic compositions
- C23F1/18—Acidic compositions for etching copper or alloys thereof
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/38—Improvement of the adhesion between the insulating substrate and the metal
- H05K3/382—Improvement of the adhesion between the insulating substrate and the metal by special treatment of the metal
- H05K3/383—Improvement of the adhesion between the insulating substrate and the metal by special treatment of the metal by microetching
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K2203/00—Indexing scheme relating to apparatus or processes for manufacturing printed circuits covered by H05K3/00
- H05K2203/07—Treatments involving liquids, e.g. plating, rinsing
- H05K2203/0779—Treatments involving liquids, e.g. plating, rinsing characterised by the specific liquids involved
- H05K2203/0786—Using an aqueous solution, e.g. for cleaning or during drilling of holes
- H05K2203/0796—Oxidant in aqueous solution, e.g. permanganate
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K2203/00—Indexing scheme relating to apparatus or processes for manufacturing printed circuits covered by H05K3/00
- H05K2203/12—Using specific substances
- H05K2203/122—Organic non-polymeric compounds, e.g. oil, wax, thiol
- H05K2203/124—Heterocyclic organic compounds, e.g. azole, furan
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/46—Manufacturing multilayer circuits
- H05K3/4611—Manufacturing multilayer circuits by laminating two or more circuit boards
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Manufacturing Of Printed Wiring (AREA)
- Adhesives Or Adhesive Processes (AREA)
- ing And Chemical Polishing (AREA)
- Chemical Treatment Of Metals (AREA)
- Laminated Bodies (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Prostheses (AREA)
Abstract
Procedimiento para el pretratamiento de superficies de cobre para la subsiguiente formación de una unión adhesiva entre las superficies de cobre y substratos de plástico mediante la puesta en contacto de las superficies de cobre con una primera solución, que contiene a. peróxido de hidrógeno, b. por lo menos un ácido, y c. un compuesto heterocíclico de cinco miembros, que contiene por lo menos un nitrógeno, y no tiene ningún átomo de azufre, selenio o telurio en el heterociclo, caracterizado porque a continuación, las superficies de cobre se ponen en contacto con una segunda solución, que contiene, d. por lo menos un compuesto mediador de la adhesividad, del grupo formado por los ácidos sulfínicos, ácidos selénicos, ácidos telúricos, compuestos heterocíclicos, que contiene por lo menos un átomo de azufre, selenio y/o telurio en el heterociclo, así como sales de sulfonio, selenonio y teluronio, en donde los compuestos de sulfonio, selenonio y teluronio, son compuestos con la fórmula generalA: R1 j A + / n R3 R2 X A en donde A = S, Se ó Te, R1, R2 y R3 = alquilo, alquilo substituido, alquenilo, fenilo, fenilo substituido, bencilo, cicloalquilo, cicloalquilo substituido, en donde R1, R2 y R3 son iguales o diferentes, y X = anión de un ácido o hidróxido inorgánico u orgánico.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19806190 | 1998-02-03 | ||
DE19830037A DE19830037C2 (de) | 1998-02-03 | 1998-06-26 | Verfahren zum Vorbehandeln von Kupferoberflächen |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2168019T3 true ES2168019T3 (es) | 2002-05-16 |
Family
ID=26043881
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES99934222T Expired - Lifetime ES2168019T3 (es) | 1998-02-03 | 1999-01-25 | Procedimiento para el pretratamiento de superficies de cobre. |
Country Status (10)
Country | Link |
---|---|
US (1) | US6723385B1 (es) |
EP (1) | EP1055355B1 (es) |
JP (1) | JP4143262B2 (es) |
AT (1) | ATE210366T1 (es) |
CA (1) | CA2318862A1 (es) |
DK (1) | DK1055355T3 (es) |
ES (1) | ES2168019T3 (es) |
HK (1) | HK1032507A1 (es) |
TW (1) | TW470785B (es) |
WO (1) | WO1999040765A1 (es) |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7351353B1 (en) | 2000-01-07 | 2008-04-01 | Electrochemicals, Inc. | Method for roughening copper surfaces for bonding to substrates |
JP4101609B2 (ja) * | 2001-12-07 | 2008-06-18 | 大日本スクリーン製造株式会社 | 基板処理方法 |
US6716281B2 (en) | 2002-05-10 | 2004-04-06 | Electrochemicals, Inc. | Composition and method for preparing chemically-resistant roughened copper surfaces for bonding to substrates |
US20050067378A1 (en) * | 2003-09-30 | 2005-03-31 | Harry Fuerhaupter | Method for micro-roughening treatment of copper and mixed-metal circuitry |
KR100817973B1 (ko) | 2004-02-05 | 2008-03-31 | 닛코킨조쿠 가부시키가이샤 | 금속의 표면처리제 |
EP1820884B1 (en) * | 2006-02-17 | 2009-10-07 | Atotech Deutschland Gmbh | Solution and process to treat surfaces of copper alloys in order to improve the adhesion between the metal surface and the bonded polymeric material |
JP2011020284A (ja) * | 2009-07-13 | 2011-02-03 | Mitsui Chemicals Inc | 金属積層体 |
EP2453041B1 (en) | 2010-11-10 | 2014-02-12 | Atotech Deutschland GmbH | Solution and process for the pre-treatment of copper surfaces using an N-alkoxylated adhesion-promoting compound |
US9338896B2 (en) * | 2012-07-25 | 2016-05-10 | Enthone, Inc. | Adhesion promotion in printed circuit boards |
CN109928904A (zh) * | 2017-11-30 | 2019-06-25 | 罗门哈斯电子材料有限责任公司 | 两性离子化合物和包括其的光致抗蚀剂 |
CN111360450B (zh) * | 2020-03-13 | 2021-08-17 | 电子科技大学 | 一种有机可焊性保护剂及有机铜配位聚合物膜的制备方法 |
EP4279634A1 (en) * | 2022-05-17 | 2023-11-22 | Atotech Deutschland GmbH & Co. KG | Method for nano etching of copper and copper alloy surfaces |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3645772A (en) | 1970-06-30 | 1972-02-29 | Du Pont | Process for improving bonding of a photoresist to copper |
JPS5221460B1 (es) | 1971-04-26 | 1977-06-10 | ||
SE400575B (sv) | 1974-12-13 | 1978-04-03 | Nordnero Ab | Bad for betning av koppar och dess legeringar |
US4140646A (en) | 1977-11-08 | 1979-02-20 | Dart Industries Inc. | Dissolution of metals with a selenium catalyzed H2 O2 -H2 SO4 etchant containing t-butyl hydroperoxide |
US4158593A (en) | 1977-11-08 | 1979-06-19 | Dart Industries Inc. | Dissolution of metals utilizing a H2 O2 -sulfuric acid solution catalyzed with selenium compounds |
JPS57164984A (en) | 1981-04-06 | 1982-10-09 | Metsuku Kk | Exfoliating solution for tin or tin alloy |
DE68923904T2 (de) | 1988-05-20 | 1996-03-14 | Mitsubishi Gas Chemical Co | Verfahren zur Herstellung eines mit einer dünnen Kupferfolie kaschierten Substrats für Schaltungsplatten. |
JP3387528B2 (ja) | 1992-08-07 | 2003-03-17 | 朝日化学工業株式会社 | 銅または銅合金のエッチング用組成物およびそのエッチング方法 |
JP3332047B2 (ja) * | 1993-07-22 | 2002-10-07 | 三菱瓦斯化学株式会社 | 内層銅箔の処理方法 |
JP2781954B2 (ja) * | 1994-03-04 | 1998-07-30 | メック株式会社 | 銅および銅合金の表面処理剤 |
JPH0897559A (ja) * | 1994-09-26 | 1996-04-12 | Okuno Chem Ind Co Ltd | 多層プリント配線板の内層用回路板の銅箔処理方法、及び該内層用回路板の銅箔処理液 |
GB9425090D0 (en) * | 1994-12-12 | 1995-02-08 | Alpha Metals Ltd | Copper coating |
US5869130A (en) * | 1997-06-12 | 1999-02-09 | Mac Dermid, Incorporated | Process for improving the adhesion of polymeric materials to metal surfaces |
JPH11140669A (ja) * | 1997-11-04 | 1999-05-25 | Ebara Densan Ltd | エッチング液 |
US6036758A (en) * | 1998-08-10 | 2000-03-14 | Pmd (U.K.) Limited | Surface treatment of copper |
US6506314B1 (en) * | 2000-07-27 | 2003-01-14 | Atotech Deutschland Gmbh | Adhesion of polymeric materials to metal surfaces |
-
1999
- 1999-01-20 TW TW088100841A patent/TW470785B/zh not_active IP Right Cessation
- 1999-01-25 AT AT99934222T patent/ATE210366T1/de active
- 1999-01-25 CA CA002318862A patent/CA2318862A1/en not_active Abandoned
- 1999-01-25 WO PCT/DE1999/000244 patent/WO1999040765A1/de active IP Right Grant
- 1999-01-25 US US10/129,705 patent/US6723385B1/en not_active Expired - Lifetime
- 1999-01-25 JP JP2000531043A patent/JP4143262B2/ja not_active Expired - Lifetime
- 1999-01-25 EP EP99934222A patent/EP1055355B1/de not_active Expired - Lifetime
- 1999-01-25 DK DK99934222T patent/DK1055355T3/da active
- 1999-01-25 ES ES99934222T patent/ES2168019T3/es not_active Expired - Lifetime
-
2001
- 2001-05-02 HK HK01103100A patent/HK1032507A1/xx not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
JP4143262B2 (ja) | 2008-09-03 |
EP1055355B1 (de) | 2001-12-05 |
CA2318862A1 (en) | 1999-08-12 |
JP2002503041A (ja) | 2002-01-29 |
US6723385B1 (en) | 2004-04-20 |
DK1055355T3 (da) | 2002-04-02 |
ATE210366T1 (de) | 2001-12-15 |
EP1055355A1 (de) | 2000-11-29 |
TW470785B (en) | 2002-01-01 |
WO1999040765A1 (de) | 1999-08-12 |
HK1032507A1 (en) | 2001-07-20 |
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