ES2136890T3 - Catalizadores carbocationicos y procedimiento para utilizar dichos catalizadores. - Google Patents

Catalizadores carbocationicos y procedimiento para utilizar dichos catalizadores.

Info

Publication number
ES2136890T3
ES2136890T3 ES95939811T ES95939811T ES2136890T3 ES 2136890 T3 ES2136890 T3 ES 2136890T3 ES 95939811 T ES95939811 T ES 95939811T ES 95939811 T ES95939811 T ES 95939811T ES 2136890 T3 ES2136890 T3 ES 2136890T3
Authority
ES
Spain
Prior art keywords
catalysts
carbocation
procedure
metilboro
halide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES95939811T
Other languages
English (en)
Inventor
Timothy Daniel Shaffer
Maneesh Bahadur
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
Exxon Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Chemical Patents Inc filed Critical Exxon Chemical Patents Inc
Application granted granted Critical
Publication of ES2136890T3 publication Critical patent/ES2136890T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/08—Butenes
    • C08F10/10—Isobutene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02—Monomers containing only one unsaturated aliphatic radical
    • C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/08—Butenes
    • C08F110/10—Isobutene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerization Catalysts (AREA)

Abstract

SE UTILIZA UNA COMPOSICION CARBOCATALIZADORA VIVA, QUE COMPRENDE UN INICIADOR CONSTITUIDO POR UN HALURO DE ALQUILO TERCIARIO, UN HALURO DE ARALQUILO TERCIARIO O UN HALURO POLIMERICO TERCIARIO, UN COINICIADOR DE UN COMPUESTO DE METILBORO O METILALUMINIO, Y UN MEDIO DISOLVENTE, CON UNA CONSTANTE DIELECTRICA ENTRE 2''5 Y 7, PARA PRODUCIR POLIMEROS CON UNA DISTRIBUCION DE PESO MOLECULAR REDUCIDA, ESPECIALMENTE POLIMEROS DE ISOBUTILENO.
ES95939811T 1994-11-07 1995-11-07 Catalizadores carbocationicos y procedimiento para utilizar dichos catalizadores. Expired - Lifetime ES2136890T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US08/335,011 US5506316A (en) 1993-02-19 1994-11-07 Carbocationic catalysts and process for using said catalysts

Publications (1)

Publication Number Publication Date
ES2136890T3 true ES2136890T3 (es) 1999-12-01

Family

ID=23309862

Family Applications (1)

Application Number Title Priority Date Filing Date
ES95939811T Expired - Lifetime ES2136890T3 (es) 1994-11-07 1995-11-07 Catalizadores carbocationicos y procedimiento para utilizar dichos catalizadores.

Country Status (7)

Country Link
US (1) US5506316A (es)
EP (1) EP0791018B1 (es)
JP (1) JPH10508888A (es)
CA (1) CA2203693A1 (es)
DE (1) DE69511281T2 (es)
ES (1) ES2136890T3 (es)
WO (1) WO1996015156A2 (es)

Families Citing this family (60)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19603331A1 (de) * 1996-01-31 1997-08-07 Bayer Ag Verfahren zur Herstellung von Polyisoolefinen mittels neuer Initiatorsysteme vom Metallocen-Typ
US6268446B1 (en) 1997-12-04 2001-07-31 The University Of Western Ontario Initiators for carbocationic polymerization of olefins
JP3527631B2 (ja) * 1997-12-04 2004-05-17 鐘淵化学工業株式会社 アルケニル基含有ブロック共重合体及びその製造方法
US6274689B1 (en) 1998-10-07 2001-08-14 Exxon Chemical Patents, Inc. Random isomonoolefin/allyl styrene copolymers and functionalized derivatives thereof
US6265486B1 (en) * 1998-12-31 2001-07-24 Exxon Mobil Chemical Patents Inc. Triblock copolymers incorporating a styrene/isoolefin copolymer midblock
US6858690B2 (en) * 1999-11-15 2005-02-22 Exxonmobil Chemical Patents Inc. Process for polymerizing cationically polymerizable monomers
KR20020054344A (ko) 1999-11-15 2002-07-06 엑손 케미칼 패턴츠 인코포레이티드 이소부틸렌 공중합체의 제조법
US7256241B2 (en) * 2000-01-21 2007-08-14 Cyclics Corporation Methods for polymerizing macrocyclic polyester oligomers using catalyst promoters
US6906147B2 (en) * 2002-03-20 2005-06-14 Cyclics Corporation Catalytic systems
US7750109B2 (en) 2000-09-01 2010-07-06 Cyclics Corporation Use of a residual oligomer recyclate in the production of macrocyclic polyester oligomer
US7767781B2 (en) 2000-09-01 2010-08-03 Cyclics Corporation Preparation of low-acid polyalkylene terephthalate and preparation of macrocyclic polyester oligomer therefrom
US6525164B2 (en) * 2000-09-01 2003-02-25 Cyclics Corporation Methods for converting linear polyesters to macrocyclic oligoester compositions and macrocyclic oligoesters
US6462131B1 (en) * 2000-10-16 2002-10-08 Exxonmobil Chemical Patents Inc. Polymer blend compatibilization using isobutylene-based block copolymers
US20060167184A1 (en) * 2000-10-18 2006-07-27 Waddell Walter H Innerliners for use in tires
WO2002050129A1 (en) * 2000-12-20 2002-06-27 Exxonmobil Chemical Patents Inc. Process for polymerizing cationically polymerizable monomers
WO2002050141A1 (en) * 2000-12-20 2002-06-27 Exxonmobil Chemical Patents Inc. Process for polymerizing cationically polymerizable monomers
US7304123B2 (en) * 2001-06-27 2007-12-04 Cyclics Corporation Processes for shaping macrocyclic oligoesters
DE60226789D1 (de) * 2001-06-27 2008-07-03 Cyclics Corp Formgebende Verarbeitung von makrozyklischen Oligoestern
US6787632B2 (en) * 2001-10-09 2004-09-07 Cyclics Corporation Organo-titanate catalysts for preparing pure macrocyclic oligoesters
US7423100B2 (en) * 2002-12-20 2008-09-09 Exxonmobil Chemical Patents Inc. Polymerization processes
US7196149B2 (en) * 2003-04-17 2007-03-27 The University Of Akron Polymerization of i-butane in hydrocarbon media using bis(borane) co-initiators
US7202317B2 (en) * 2003-04-17 2007-04-10 The University Of Akron Polymerization of i-butene in hydrocarbon media using bis(borane) co-initiators
US6969744B2 (en) * 2003-06-19 2005-11-29 University Of Southern Mississippi Living and quasiliving cationic telechelic polymers quenched by N-substituted pyrrole and methods for their preparation
EP1905581A1 (en) 2003-10-27 2008-04-02 ExxonMobil Chemical Patents Inc. Microlayered composites and processes for making the same
AU2005277275B2 (en) * 2004-08-20 2011-10-20 Chevron Oronite Company Llc Method for preparation of polyolefins containing exo-olefin chain ends
US7705090B2 (en) * 2004-08-20 2010-04-27 Chevron Oronite Company Llc Method for preparing polyolefins containing a high percentage of exo-olefin chain ends
CA2627338C (en) 2005-10-27 2011-08-02 Exxonmobil Chemical Patents Inc. Construction comprising tie layer
EP2502742B1 (en) 2005-10-27 2017-06-21 ExxonMobil Chemical Patents Inc. Construction comprising tie layer for pneumatic tire
US8013073B2 (en) * 2005-12-30 2011-09-06 Chevron Oronite Company Llc Method for preparing polyolefins containing vinylidine end groups using nonaromatic heterocyclic compounds
US7816459B2 (en) * 2005-12-30 2010-10-19 Chevron Oronite Company Llc Method for preparing polyolefins containing vinylidine end groups using polymeric nitrogen compounds
US7893176B2 (en) * 2007-03-23 2011-02-22 Exxonmobil Chemical Patents Inc. Polydispersity-controlled isoolefin polymerization with polymorphogenates
EP2152764A1 (en) * 2007-05-16 2010-02-17 ExxonMobil Chemical Patents Inc. Catalyst system for olefin polymerization and polymers produced therefrom
US8394897B2 (en) * 2008-03-25 2013-03-12 Chevron Oronite Company Llc Production of vinylidene-terminated polyolefins via quenching with monosulfides
JP4435253B2 (ja) * 2008-03-26 2010-03-17 住友ゴム工業株式会社 インナーライナーおよび空気入りタイヤ
JP2010013647A (ja) * 2008-03-26 2010-01-21 Sumitomo Rubber Ind Ltd サイドウォール保護膜および空気入りタイヤ
US8063154B2 (en) 2008-06-24 2011-11-22 The University Of Southern Mississippi Preparation of exo-olefin terminated polyolefins via quenching with alkoxysilanes or ethers
JP5172597B2 (ja) * 2008-10-21 2013-03-27 株式会社カネカ 空気入りタイヤ用インナーライナー
US8133954B2 (en) 2008-10-22 2012-03-13 Chevron Oronite Company Llc Production of vinylidene-terminated and sulfide-terminated telechelic polyolefins via quenching with disulfides
US8344073B2 (en) 2009-01-16 2013-01-01 The University Of Southern Mississippi Functionalization of polyolefins with phenoxy derivatives
US8552122B2 (en) 2009-03-31 2013-10-08 The University Of Southern Mississippi Amine-terminated telechelic polymers and precursors thereto and methods for their preparation
US8394898B2 (en) 2009-07-31 2013-03-12 The University Of Southern Mississippi In situ formation of hydroxy chain end functional polyolefins
JP4831706B2 (ja) 2009-09-04 2011-12-07 住友ゴム工業株式会社 ポリマー積層体およびそれをインナーライナーに用いた空気入りタイヤ
JP4888868B2 (ja) 2009-09-08 2012-02-29 住友ゴム工業株式会社 空気入りタイヤ
JP5004196B2 (ja) 2009-09-18 2012-08-22 住友ゴム工業株式会社 空気入りタイヤの製造方法
JP5300679B2 (ja) 2009-09-30 2013-09-25 住友ゴム工業株式会社 インナーライナー用ポリマー組成物およびそれを用いた空気入りタイヤ
EP2513202B1 (en) 2009-12-17 2013-10-23 ExxonMobil Chemical Patents Inc. Elastomeric nanocomposites, nanocomposite compositions, and methods of manufacture
US8461240B2 (en) 2010-04-30 2013-06-11 Exxonmobil Chemical Patents Inc. Elastomeric nanocomposites, nanocomposite compositions, and methods of manufacture
CA2796282C (en) 2010-04-30 2015-02-03 Yu Feng Wang Method for elastomer finishing
US8242236B2 (en) 2010-05-26 2012-08-14 Exxonmobil Chemical Patents Inc. Elastomeric nanocomposite manufacturing
US8492491B2 (en) 2010-06-10 2013-07-23 Chevron Oronite Company Llc Methods for producing telechelic polyolefins from terpene initiators
US8592527B2 (en) 2010-06-14 2013-11-26 University Of Southern Mississippi Vinyl ether end-functionalized polyolefins
JP5247852B2 (ja) 2010-11-05 2013-07-24 住友ゴム工業株式会社 空気入りタイヤの製造方法
JP5225431B2 (ja) 2010-12-06 2013-07-03 住友ゴム工業株式会社 ストリップ、その製造方法および空気入りタイヤの製造方法
US9200152B2 (en) 2011-01-25 2015-12-01 Exxonmobil Chemical Patents Inc. Elastomeric nanocomposites, nanocomposite compositions, and methods of manufacture
US8969484B2 (en) 2011-07-08 2015-03-03 Chevron Oronite Company Llc Methods of producing mono- and multi-functional polymers from terpene-based initiators
KR20140056372A (ko) 2011-10-05 2014-05-09 엑손모빌 케미칼 패턴츠 인코포레이티드 타이어 경화 블래더
WO2015130392A1 (en) 2014-02-28 2015-09-03 Exxonmobil Chemical Patents Inc. Nanocomposite mooney viscosity stability
CA2940970C (en) 2014-02-28 2019-03-19 Exxonmobil Chemical Patents Inc. Mooney viscosity stable brominated elastomers
EP3288735B1 (en) 2015-04-30 2024-07-03 ExxonMobil Chemical Patents Inc. Process for halogenating olefinic-derived elastomers in the bulk phase
CA3010059C (en) 2016-01-29 2020-10-27 Exxonmobil Chemical Patents Inc. System and process for the production of functionalized olefinic-based polymer

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1441610A (fr) * 1964-05-01 1966-06-10 Exxon Research Engineering Co Procédé de polymérisation de monooléfines à l'aide d'un système catalysant nouveau
US4278822A (en) * 1975-12-19 1981-07-14 Exxon Research & Engineering Co. Low molecular weight terminally-functional saturated hydrocarbon polymer
US4276394A (en) * 1979-09-10 1981-06-30 The University Of Akron Novel telechelic polymers, block copolymers and processes for the preparation thereof
DE3300155A1 (de) * 1983-01-05 1984-07-05 Basf Ag, 6700 Ludwigshafen Verfahren zur kontinuierlichen herstellung von isobutylenpolymerisaten
US4910321A (en) * 1985-06-20 1990-03-20 University Of Akron Living catalysts, complexes and polymers therefrom
DE3541408A1 (de) * 1985-11-23 1987-05-27 Bayer Ag Herstellung von polymeren durch kationische polymerisation
US4929683A (en) * 1986-08-25 1990-05-29 University Of Akron Living polymerization of olefin to end-functionalized polymers
CA1326322C (en) * 1988-05-03 1994-01-18 Gabor Kaszas Uniform molecular weight polymers
US5169914A (en) * 1988-05-03 1992-12-08 Edison Polymer Innovation Corporation Uniform molecular weight polymers
US4946899A (en) * 1988-12-16 1990-08-07 The University Of Akron Thermoplastic elastomers of isobutylene and process of preparation
JPH0759601B2 (ja) * 1989-05-08 1995-06-28 日本ゼオン株式会社 重合体の製造方法
CA2033328C (en) * 1989-06-06 2002-04-02 Hiroshi Fujisawa Process for preparation of a polymer having reactive terminal group
US5350819A (en) * 1993-02-19 1994-09-27 Exxon Chemical Patents Inc. Carbocationic catalysts and process for using said catalysts

Also Published As

Publication number Publication date
DE69511281T2 (de) 2000-04-13
WO1996015156A3 (en) 1996-10-24
EP0791018B1 (en) 1999-08-04
CA2203693A1 (en) 1996-05-23
JPH10508888A (ja) 1998-09-02
US5506316A (en) 1996-04-09
WO1996015156A2 (en) 1996-05-23
DE69511281D1 (de) 1999-09-09
EP0791018A2 (en) 1997-08-27

Similar Documents

Publication Publication Date Title
ES2136890T3 (es) Catalizadores carbocationicos y procedimiento para utilizar dichos catalizadores.
ES2173138T3 (es) Composicion adhesiva antimicrobiana para uso dental.
AU1735692A (en) Tetravalent bispecific receptors, the preparation and use thereof
ES2138691T3 (es) Procedimiento para la obtencion de derivados de n-acil-5-fluorocitidina.
ES2051682T3 (es) Un procedimiento para la preparacion de una composicion de liberacion mantenida.
ES2089822T3 (es) Polimeros para productos cosmeticos y de cuidado personal.
ES2058523T3 (es) Hidrodeshalogenacion de 1,1,1,2-tetrafluorocloroetano en presencia de paladio sobre soporte.
DK0562107T3 (da) Oligosid afledt af et antigenetisk polyosid fra et patogent agens
ES2140779T3 (es) Procedimiento para la fabricacion de una composicion que comprende un polimero vinilaromatico y un caucho por polimerizacion en presencia de un radical libre estable.
ES2162951T3 (es) Estabilizacion de composiciones de prostaglandina.
FI971746A0 (fi) Booriesteri- ja -happoyhdisteet sekä näiden synteesi ja käyttö
ES2185879T3 (es) Composiciones de resina fotocromicas.
ATE67084T1 (de) Mittel zur mundhygiene.
ES2196395T3 (es) Copolimeros cicloolefinicos, su empleo y articulos moldeados preparados a partir de ellos.
MX9202166A (es) Derivados de amidino fenil alanina, procedimiento para su preparacion su empleo y agentes que los con tienen en calidad de anticoagulantes.
ES2155640T3 (es) Compuestos de xantina con cadenas laterales de alquinol aminadas en los extremos.
ES2160757T3 (es) Catalizadores para la polimerizacion de alfa-olefinas.
AU3871195A (en) Monomers and composition which can be crosslinked and croslinked polymers
ES2195073T3 (es) Metalocenos, su preparacion y su utilizacion en la polimerizacion de alfa-olefinas.
CO4930284A1 (es) Formulaciones novedosas solidas de calcitonina
TR200001288T2 (tr) Östrojen yoksunluğu sendromunun tedavisinde faydalı 2-arilbenzo (b) tiyofenler.
ES2145946T3 (es) Producto organoaluminoxi, sistemas cataliticos, preparacion y uso.
AR000056A1 (es) Proceso para la preparación de polimeros de olefina estabilizados y poliolefinas estabilizadas, particularmente polietileno y polipropileno de alto peso molecular preparada segun dicho proceso.
FI841825A (fi) Foerbaettringar med avseende pao peresterfoereningar.
DK7284A (da) Ortopaedisk bandage

Legal Events

Date Code Title Description
FG2A Definitive protection

Ref document number: 791018

Country of ref document: ES