ES2136265T3 - Procedimiento de preparacion electroquimica de catalizadores a base de metal de transicion y de fosfina. - Google Patents
Procedimiento de preparacion electroquimica de catalizadores a base de metal de transicion y de fosfina.Info
- Publication number
- ES2136265T3 ES2136265T3 ES95420339T ES95420339T ES2136265T3 ES 2136265 T3 ES2136265 T3 ES 2136265T3 ES 95420339 T ES95420339 T ES 95420339T ES 95420339 T ES95420339 T ES 95420339T ES 2136265 T3 ES2136265 T3 ES 2136265T3
- Authority
- ES
- Spain
- Prior art keywords
- phosphine
- transitional metal
- preparation procedure
- electrochemical preparation
- catalyzers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 title abstract 6
- 238000000034 method Methods 0.000 title abstract 3
- 229910000073 phosphorus hydride Inorganic materials 0.000 title abstract 3
- 238000002360 preparation method Methods 0.000 title abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 3
- 239000003054 catalyst Substances 0.000 abstract 2
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 238000005868 electrolysis reaction Methods 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 238000003786 synthesis reaction Methods 0.000 abstract 1
- 229910052723 transition metal Inorganic materials 0.000 abstract 1
- 150000003624 transition metals Chemical class 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/185—Phosphorus; Compounds thereof with iron group metals or platinum group metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/34—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation
- B01J37/348—Electrochemical processes, e.g. electrochemical deposition or anodisation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
- B01J2231/32—Addition reactions to C=C or C-C triple bonds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/847—Nickel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/90—Catalytic systems characterized by the solvent or solvent system used
- B01J2531/96—Water
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Electrochemistry (AREA)
- Physics & Mathematics (AREA)
- Health & Medical Sciences (AREA)
- Plasma & Fusion (AREA)
- Toxicology (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Abstract
LA PRESENTE INVENCION SE REFIERE A UN PROCESO ELECTROQUIMICO DE PREPARACION DE COMPUESTOS QUE PUEDEN SER UTILIZADOS COMO CATALIZADORES. LOS COMPUESTOS DE OBJETIVO COMPRENDEN MAS ESPECIFICAMENTE AL MENOS UN METAL DE TRANSICION EN GRADO DE OXIDACION 0 O 1 ASOCIADO A AL MENOS UNA FOSFINA SULFONADA. EL PROCESO DE SINTESIS ELECTROQUIMICA DE LOS CATALIZADORES CONSISTE EN TRATAR POR ELECTROLISIS UNA SOLUCION ACUOSA QUE CONTIENE AL MENOS UN COMPUESTO DE UN METAL DE TRANSICION Y UNA FOSFINA SULFONADA, COLOCADA EN EL COMPARTIMENTO CATODICO DE UNA CELULA DE ELECTROLISIS DE UN ELECTROLIZADOR.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR9414884A FR2727637B1 (fr) | 1994-12-06 | 1994-12-06 | Procede de preparation electrochimique de catalyseurs a base de metal de transition et de phosphine |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2136265T3 true ES2136265T3 (es) | 1999-11-16 |
Family
ID=9469674
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES95420339T Expired - Lifetime ES2136265T3 (es) | 1994-12-06 | 1995-12-01 | Procedimiento de preparacion electroquimica de catalizadores a base de metal de transicion y de fosfina. |
Country Status (12)
Country | Link |
---|---|
US (1) | US5679237A (es) |
EP (1) | EP0715890B1 (es) |
JP (1) | JP2914487B2 (es) |
KR (1) | KR100372376B1 (es) |
CN (1) | CN1078496C (es) |
AR (1) | AR000284A1 (es) |
BR (1) | BR9505666A (es) |
CA (1) | CA2164470C (es) |
DE (1) | DE69512357T2 (es) |
ES (1) | ES2136265T3 (es) |
FR (1) | FR2727637B1 (es) |
RU (1) | RU2154529C2 (es) |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2743011B1 (fr) * | 1995-12-29 | 1998-02-20 | Rhone Poulenc Fibres | Procede de preparation electrochimique de catalyseurs a base de metal de transition et de phosphine |
JP3816241B2 (ja) | 1998-07-14 | 2006-08-30 | 株式会社大和化成研究所 | 金属を還元析出させるための水溶液 |
FR2787349B1 (fr) * | 1998-12-22 | 2001-02-02 | Rhone Poulenc Fibres | Procede de fabrication d'un catalyseur d'hydrocyanation |
FR2787446B1 (fr) | 1998-12-22 | 2001-02-02 | Rhone Poulenc Fibres | Procede d'hydrocyanation de composes organiques a insaturations ethyleniques |
RU2226228C2 (ru) * | 1999-08-20 | 2004-03-27 | Дю Пон Де Немур Энтернасьональ С.А. | Способ электрохимического получения ni(о) фосфитных и дифосфитных комплексов |
US6428676B1 (en) | 2000-11-08 | 2002-08-06 | Enthone Inc. | Process for producing low alpha lead methane sulfonate |
JP2010504202A (ja) * | 2006-09-21 | 2010-02-12 | アルベマール・コーポレーシヨン | メタンを有用な炭化水素に変化させる方法およびこの方法で用いるための触媒およびこの触媒の再生 |
FR2932476B1 (fr) * | 2008-06-17 | 2010-07-30 | Rhodia Operations | Procede de fabrication de composes nitriles a partir de composes a insaturation ethylenique |
CA2974985C (en) * | 2015-02-04 | 2022-06-28 | Spraying Systems Co. | Electrolytic cartridge, systems and methods of using same |
CN105063659B (zh) * | 2015-09-15 | 2018-05-08 | 苏州铂瑞电极工业有限公司 | 一种电解装置 |
JP7228411B2 (ja) * | 2019-03-06 | 2023-02-24 | 上村工業株式会社 | 無電解金めっき浴 |
CN110368966B (zh) * | 2019-08-01 | 2022-05-24 | 南方科技大学 | 一种纳米棒状亚磷酸钴水裂解催化剂的制备方法及其应用 |
CN115125552B (zh) * | 2022-08-30 | 2022-11-22 | 江苏欣诺科催化剂股份有限公司 | 叔膦化合物的合成方法 |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2007076C3 (de) * | 1970-02-17 | 1979-12-13 | Studiengesellschaft Kohle Mbh | Verfahren zur elektrochemischen Herstellung von CO-freien metallorganischen Komplexen von Übergangsmetallen der IV. bis VIII. Gruppe |
US3887441A (en) * | 1971-12-29 | 1975-06-03 | Phillips Petroleum Co | Electro-chemical synthesis of organonickel compounds |
FR2338253A1 (fr) * | 1976-01-13 | 1977-08-12 | Rhone Poulenc Ind | Procede d'hydrocyanation de composes organiques insatures comportant au moins une double liaison ethylenique |
FR2616810B1 (fr) * | 1987-03-25 | 1989-08-18 | Rhone Poulenc Sante | Procede electrochimique pour recuperer le rhodium metallique a partir de solutions aqueuses de catalyseurs usages |
JP2660284B2 (ja) * | 1988-02-16 | 1997-10-08 | 株式会社ササクラ | 触媒電極及びその製造法 |
FR2635317B1 (fr) * | 1988-08-11 | 1990-10-19 | Norsolor Sa | Hydrures de platine de structure bimetallique pontee, leur procede de preparation et leur application a la catalyse de reactions chimiques |
DE4242723A1 (de) * | 1992-12-17 | 1994-06-23 | Hoechst Ag | Verfahren zur Herstellung von Aldehyden |
-
1994
- 1994-12-06 FR FR9414884A patent/FR2727637B1/fr not_active Expired - Fee Related
-
1995
- 1995-12-01 EP EP95420339A patent/EP0715890B1/fr not_active Expired - Lifetime
- 1995-12-01 ES ES95420339T patent/ES2136265T3/es not_active Expired - Lifetime
- 1995-12-01 DE DE69512357T patent/DE69512357T2/de not_active Expired - Fee Related
- 1995-12-05 RU RU95121108/04A patent/RU2154529C2/ru not_active IP Right Cessation
- 1995-12-05 AR AR33450095A patent/AR000284A1/es unknown
- 1995-12-05 BR BR9505666A patent/BR9505666A/pt not_active IP Right Cessation
- 1995-12-05 CA CA002164470A patent/CA2164470C/fr not_active Expired - Fee Related
- 1995-12-05 JP JP7339920A patent/JP2914487B2/ja not_active Expired - Fee Related
- 1995-12-06 CN CN95120532A patent/CN1078496C/zh not_active Expired - Fee Related
- 1995-12-06 KR KR1019950047171A patent/KR100372376B1/ko not_active IP Right Cessation
- 1995-12-06 US US08/568,295 patent/US5679237A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
JP2914487B2 (ja) | 1999-06-28 |
FR2727637A1 (fr) | 1996-06-07 |
KR960021146A (ko) | 1996-07-18 |
JPH08257418A (ja) | 1996-10-08 |
US5679237A (en) | 1997-10-21 |
KR100372376B1 (ko) | 2003-04-26 |
CA2164470A1 (fr) | 1996-06-07 |
DE69512357T2 (de) | 2000-02-24 |
FR2727637B1 (fr) | 1997-01-03 |
CA2164470C (fr) | 2000-02-15 |
RU2154529C2 (ru) | 2000-08-20 |
CN1078496C (zh) | 2002-01-30 |
AR000284A1 (es) | 1997-06-18 |
EP0715890A1 (fr) | 1996-06-12 |
EP0715890B1 (fr) | 1999-09-22 |
BR9505666A (pt) | 1997-11-04 |
DE69512357D1 (de) | 1999-10-28 |
CN1132115A (zh) | 1996-10-02 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG2A | Definitive protection |
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