ES2136265T3 - Procedimiento de preparacion electroquimica de catalizadores a base de metal de transicion y de fosfina. - Google Patents

Procedimiento de preparacion electroquimica de catalizadores a base de metal de transicion y de fosfina.

Info

Publication number
ES2136265T3
ES2136265T3 ES95420339T ES95420339T ES2136265T3 ES 2136265 T3 ES2136265 T3 ES 2136265T3 ES 95420339 T ES95420339 T ES 95420339T ES 95420339 T ES95420339 T ES 95420339T ES 2136265 T3 ES2136265 T3 ES 2136265T3
Authority
ES
Spain
Prior art keywords
phosphine
transitional metal
preparation procedure
electrochemical preparation
catalyzers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES95420339T
Other languages
English (en)
Inventor
Alex Chamard
Dominique Horbez
Marc Huser
Robert Perron
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rhone Poulenc Fibres SA
Rhodia Fiber and Resin Intermediates SAS
Original Assignee
Rhone Poulenc Fibres SA
Rhodia Fiber and Resin Intermediates SAS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rhone Poulenc Fibres SA, Rhodia Fiber and Resin Intermediates SAS filed Critical Rhone Poulenc Fibres SA
Application granted granted Critical
Publication of ES2136265T3 publication Critical patent/ES2136265T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/185—Phosphorus; Compounds thereof with iron group metals or platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/34—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation
    • B01J37/348—Electrochemical processes, e.g. electrochemical deposition or anodisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/847—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/90—Catalytic systems characterized by the solvent or solvent system used
    • B01J2531/96—Water

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Electrochemistry (AREA)
  • Physics & Mathematics (AREA)
  • Health & Medical Sciences (AREA)
  • Plasma & Fusion (AREA)
  • Toxicology (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

Abstract

LA PRESENTE INVENCION SE REFIERE A UN PROCESO ELECTROQUIMICO DE PREPARACION DE COMPUESTOS QUE PUEDEN SER UTILIZADOS COMO CATALIZADORES. LOS COMPUESTOS DE OBJETIVO COMPRENDEN MAS ESPECIFICAMENTE AL MENOS UN METAL DE TRANSICION EN GRADO DE OXIDACION 0 O 1 ASOCIADO A AL MENOS UNA FOSFINA SULFONADA. EL PROCESO DE SINTESIS ELECTROQUIMICA DE LOS CATALIZADORES CONSISTE EN TRATAR POR ELECTROLISIS UNA SOLUCION ACUOSA QUE CONTIENE AL MENOS UN COMPUESTO DE UN METAL DE TRANSICION Y UNA FOSFINA SULFONADA, COLOCADA EN EL COMPARTIMENTO CATODICO DE UNA CELULA DE ELECTROLISIS DE UN ELECTROLIZADOR.
ES95420339T 1994-12-06 1995-12-01 Procedimiento de preparacion electroquimica de catalizadores a base de metal de transicion y de fosfina. Expired - Lifetime ES2136265T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR9414884A FR2727637B1 (fr) 1994-12-06 1994-12-06 Procede de preparation electrochimique de catalyseurs a base de metal de transition et de phosphine

Publications (1)

Publication Number Publication Date
ES2136265T3 true ES2136265T3 (es) 1999-11-16

Family

ID=9469674

Family Applications (1)

Application Number Title Priority Date Filing Date
ES95420339T Expired - Lifetime ES2136265T3 (es) 1994-12-06 1995-12-01 Procedimiento de preparacion electroquimica de catalizadores a base de metal de transicion y de fosfina.

Country Status (12)

Country Link
US (1) US5679237A (es)
EP (1) EP0715890B1 (es)
JP (1) JP2914487B2 (es)
KR (1) KR100372376B1 (es)
CN (1) CN1078496C (es)
AR (1) AR000284A1 (es)
BR (1) BR9505666A (es)
CA (1) CA2164470C (es)
DE (1) DE69512357T2 (es)
ES (1) ES2136265T3 (es)
FR (1) FR2727637B1 (es)
RU (1) RU2154529C2 (es)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2743011B1 (fr) * 1995-12-29 1998-02-20 Rhone Poulenc Fibres Procede de preparation electrochimique de catalyseurs a base de metal de transition et de phosphine
JP3816241B2 (ja) 1998-07-14 2006-08-30 株式会社大和化成研究所 金属を還元析出させるための水溶液
FR2787349B1 (fr) * 1998-12-22 2001-02-02 Rhone Poulenc Fibres Procede de fabrication d'un catalyseur d'hydrocyanation
FR2787446B1 (fr) 1998-12-22 2001-02-02 Rhone Poulenc Fibres Procede d'hydrocyanation de composes organiques a insaturations ethyleniques
RU2226228C2 (ru) * 1999-08-20 2004-03-27 Дю Пон Де Немур Энтернасьональ С.А. Способ электрохимического получения ni(о) фосфитных и дифосфитных комплексов
US6428676B1 (en) 2000-11-08 2002-08-06 Enthone Inc. Process for producing low alpha lead methane sulfonate
RU2009114847A (ru) * 2006-09-21 2010-10-27 Альбермарл Корпорейшн (Us) Способы превращения метана в пригодные углеводороды, катализаторы для применения в таких способах и регенерация катализаторов
FR2932476B1 (fr) * 2008-06-17 2010-07-30 Rhodia Operations Procede de fabrication de composes nitriles a partir de composes a insaturation ethylenique
CA2974985C (en) * 2015-02-04 2022-06-28 Spraying Systems Co. Electrolytic cartridge, systems and methods of using same
CN105063659B (zh) * 2015-09-15 2018-05-08 苏州铂瑞电极工业有限公司 一种电解装置
JP7228411B2 (ja) * 2019-03-06 2023-02-24 上村工業株式会社 無電解金めっき浴
CN110368966B (zh) * 2019-08-01 2022-05-24 南方科技大学 一种纳米棒状亚磷酸钴水裂解催化剂的制备方法及其应用
CN115125552B (zh) * 2022-08-30 2022-11-22 江苏欣诺科催化剂股份有限公司 叔膦化合物的合成方法

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2007076C3 (de) * 1970-02-17 1979-12-13 Studiengesellschaft Kohle Mbh Verfahren zur elektrochemischen Herstellung von CO-freien metallorganischen Komplexen von Übergangsmetallen der IV. bis VIII. Gruppe
US3887441A (en) * 1971-12-29 1975-06-03 Phillips Petroleum Co Electro-chemical synthesis of organonickel compounds
FR2338253A1 (fr) * 1976-01-13 1977-08-12 Rhone Poulenc Ind Procede d'hydrocyanation de composes organiques insatures comportant au moins une double liaison ethylenique
FR2616810B1 (fr) * 1987-03-25 1989-08-18 Rhone Poulenc Sante Procede electrochimique pour recuperer le rhodium metallique a partir de solutions aqueuses de catalyseurs usages
JP2660284B2 (ja) * 1988-02-16 1997-10-08 株式会社ササクラ 触媒電極及びその製造法
FR2635317B1 (fr) * 1988-08-11 1990-10-19 Norsolor Sa Hydrures de platine de structure bimetallique pontee, leur procede de preparation et leur application a la catalyse de reactions chimiques
DE4242723A1 (de) * 1992-12-17 1994-06-23 Hoechst Ag Verfahren zur Herstellung von Aldehyden

Also Published As

Publication number Publication date
CA2164470A1 (fr) 1996-06-07
AR000284A1 (es) 1997-06-18
CN1078496C (zh) 2002-01-30
RU2154529C2 (ru) 2000-08-20
JPH08257418A (ja) 1996-10-08
JP2914487B2 (ja) 1999-06-28
US5679237A (en) 1997-10-21
KR960021146A (ko) 1996-07-18
DE69512357T2 (de) 2000-02-24
DE69512357D1 (de) 1999-10-28
FR2727637B1 (fr) 1997-01-03
KR100372376B1 (ko) 2003-04-26
EP0715890A1 (fr) 1996-06-12
CN1132115A (zh) 1996-10-02
BR9505666A (pt) 1997-11-04
FR2727637A1 (fr) 1996-06-07
EP0715890B1 (fr) 1999-09-22
CA2164470C (fr) 2000-02-15

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