BR0013556A - Método de produção eletroquìmica de um complexo de fosfito ou difosfito de ni(0), complexo e método de hidrocianação de olefina ou isomerização de alqueno nitrila - Google Patents

Método de produção eletroquìmica de um complexo de fosfito ou difosfito de ni(0), complexo e método de hidrocianação de olefina ou isomerização de alqueno nitrila

Info

Publication number
BR0013556A
BR0013556A BR0013556-9A BR0013556A BR0013556A BR 0013556 A BR0013556 A BR 0013556A BR 0013556 A BR0013556 A BR 0013556A BR 0013556 A BR0013556 A BR 0013556A
Authority
BR
Brazil
Prior art keywords
complex
phosphite
diphosphite
electrochemical production
nitrile
Prior art date
Application number
BR0013556-9A
Other languages
English (en)
Inventor
Andrei Aleksandrovich Stepanov
Vitali Arkad Evich Grinberg
Scott Christopher Jackson
Cynthia Anne Lundgren
Tat Jana L Vovna Kulova
Original Assignee
Du Pont
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Du Pont filed Critical Du Pont
Publication of BR0013556A publication Critical patent/BR0013556A/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/04—Nickel compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/04—Nickel compounds
    • C07F15/045—Nickel compounds without a metal-carbon linkage
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/34—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation
    • B01J37/348—Electrochemical processes, e.g. electrochemical deposition or anodisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/323—Hydrometalation, e.g. bor-, alumin-, silyl-, zirconation or analoguous reactions like carbometalation, hydrocarbation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/52—Isomerisation reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/847—Nickel

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Electrochemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Health & Medical Sciences (AREA)
  • Plasma & Fusion (AREA)
  • Toxicology (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

"MéTODO DE PRODUçãO ELETROQUìMICA DE UM COMPLEXO DE FOSFITO OU DIFOSFITO DE Ni(0), COMPLEXO E MéTODO DE HIDROCIANAçãO DE OLEFINA OU ISOMERIZAçãO DE ALQUENO NITRILA". A presente invenção se refere a um método de produção eletroquímica de complexos de fosfito e difosfito de Ni(0) em um eletrolisador sem diafragma, contendo um anodo e um catodo, através de dissolução do anodo de níquel metálico em solvente aprótico com subseq³ente eletrorredução de íons de níquel no catodo com baixa sobrevoltagem de hidrogênio na presença, por exemplo, de quantidade equimolar de ligantes de fósforo, utilizando-se corrente direta ou alternada. Os complexos são úteis como catalisadores.
BR0013556-9A 1999-08-20 2000-08-17 Método de produção eletroquìmica de um complexo de fosfito ou difosfito de ni(0), complexo e método de hidrocianação de olefina ou isomerização de alqueno nitrila BR0013556A (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
RU99118171/04A RU2226228C2 (ru) 1999-08-20 1999-08-20 Способ электрохимического получения ni(о) фосфитных и дифосфитных комплексов
PCT/US2000/022527 WO2001014392A1 (en) 1999-08-20 2000-08-17 METHOD FOR ELECTROCHEMICAL PRODUCTION OF Ni(0) PHOSPHITE AND DIPHOSPHITE COMPLEXES

Publications (1)

Publication Number Publication Date
BR0013556A true BR0013556A (pt) 2002-04-09

Family

ID=20224153

Family Applications (1)

Application Number Title Priority Date Filing Date
BR0013556-9A BR0013556A (pt) 1999-08-20 2000-08-17 Método de produção eletroquìmica de um complexo de fosfito ou difosfito de ni(0), complexo e método de hidrocianação de olefina ou isomerização de alqueno nitrila

Country Status (14)

Country Link
EP (1) EP1218389B1 (pt)
JP (1) JP2003507582A (pt)
KR (1) KR100760788B1 (pt)
CN (1) CN1211393C (pt)
AU (1) AU6779000A (pt)
BR (1) BR0013556A (pt)
CA (1) CA2376294A1 (pt)
CZ (1) CZ2002501A3 (pt)
DE (1) DE60006144T2 (pt)
MX (1) MXPA02001756A (pt)
PL (1) PL202487B1 (pt)
RU (1) RU2226228C2 (pt)
SK (1) SK286309B6 (pt)
WO (1) WO2001014392A1 (pt)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10136488A1 (de) 2001-07-27 2003-02-06 Basf Ag Ni(O) enthaltendes Katalysatorsystem
MY138064A (en) 2002-01-24 2009-04-30 Basf Ag Method for the separation of acids from chemical reaction mixtures by means of ionic fluids
US7253298B2 (en) 2002-07-15 2007-08-07 Rhodia Polyamide Intermediates Process for preparing nitrile compounds from ethylenically unsaturated compounds
FR2842197A1 (fr) 2002-07-15 2004-01-16 Rhodia Polyamide Intermediates Procede de fabrication de composes nitriles a partir de composes a insaturation ethylenique
US6897329B2 (en) * 2003-01-14 2005-05-24 Invista North America S.A.R.L. Process for the preparation of nickel/phosphorous ligand catalyst for olefin hydrocyanation
CN1313641C (zh) * 2003-12-09 2007-05-02 南开大学 化学镀镍磷合金的方法
DE102004004718A1 (de) 2004-01-29 2005-08-18 Basf Ag Verfahren zur Hydrocyanierung
EP1825914A1 (de) * 2006-02-22 2007-08-29 Basf Aktiengesellschaft Verbessertes Verfahren zur Herstellung von Nickel(0)-Phophorligand-Komplexen
WO2012033555A1 (en) 2010-09-07 2012-03-15 Invista Technologies S.A.R.L. Nickel compositions for preparing nickel metal and nickel complexes

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5512695A (en) 1994-04-14 1996-04-30 E. I. Du Pont De Nemours And Company Bidentate phosphite and nickel catalyst compositions for hydrocyanation of monoolefins
FR2727637B1 (fr) * 1994-12-06 1997-01-03 Rhone Poulenc Chimie Procede de preparation electrochimique de catalyseurs a base de metal de transition et de phosphine
US5602228A (en) * 1995-06-06 1997-02-11 Maxdem Incorporated Nickel phosphate catalysts
FR2743011B1 (fr) * 1995-12-29 1998-02-20 Rhone Poulenc Fibres Procede de preparation electrochimique de catalyseurs a base de metal de transition et de phosphine
DE19740180A1 (de) * 1997-09-12 1999-03-18 Basf Ag Katalysator, umfassend wenigstens einen Nickel(0)Komplex auf Basis eines Phosphonitliganden und Verfahren zur Herstellung von Nitrilen

Also Published As

Publication number Publication date
DE60006144D1 (de) 2003-11-27
CN1211393C (zh) 2005-07-20
CN1370177A (zh) 2002-09-18
PL353637A1 (en) 2003-12-01
CA2376294A1 (en) 2001-03-01
EP1218389B1 (en) 2003-10-22
WO2001014392A1 (en) 2001-03-01
KR20020023423A (ko) 2002-03-28
JP2003507582A (ja) 2003-02-25
SK2182002A3 (en) 2002-06-04
EP1218389A1 (en) 2002-07-03
CZ2002501A3 (cs) 2002-06-12
AU6779000A (en) 2001-03-19
MXPA02001756A (es) 2002-10-23
RU2226228C2 (ru) 2004-03-27
PL202487B1 (pl) 2009-06-30
DE60006144T2 (de) 2004-07-22
KR100760788B1 (ko) 2007-10-04
SK286309B6 (en) 2008-07-07

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Legal Events

Date Code Title Description
B25A Requested transfer of rights approved

Owner name: INVISTA TECHNOLOGIES S.A.R.L. (US)

Free format text: TRANSFERIDO DE: E. I. DUPONT DE NEMOURS AND COMPANY

B25G Requested change of headquarter approved

Owner name: INVISTA TECHNOLOGIES S.A.R.L. (CH)

Free format text: SEDE ALTERADA CONFORME SOLICITADO NA PETICAO NO 018050042913/SP DE 21/10/2005.

B06A Patent application procedure suspended [chapter 6.1 patent gazette]
B11B Dismissal acc. art. 36, par 1 of ipl - no reply within 90 days to fullfil the necessary requirements