ES2135894T3 - Ferrocenos dihalogenados y procedimientos para su preparacion. - Google Patents
Ferrocenos dihalogenados y procedimientos para su preparacion.Info
- Publication number
- ES2135894T3 ES2135894T3 ES96911992T ES96911992T ES2135894T3 ES 2135894 T3 ES2135894 T3 ES 2135894T3 ES 96911992 T ES96911992 T ES 96911992T ES 96911992 T ES96911992 T ES 96911992T ES 2135894 T3 ES2135894 T3 ES 2135894T3
- Authority
- ES
- Spain
- Prior art keywords
- sub
- alkyl
- formula
- puerto
- ferrocenildifosfinas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title 1
- 150000001875 compounds Chemical class 0.000 abstract 3
- -1 TETRAMETHYLENE, PENTAMETHYLENE Chemical class 0.000 abstract 2
- 239000000543 intermediate Substances 0.000 abstract 2
- 150000003254 radicals Chemical class 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical class [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- CIUQDSCDWFSTQR-UHFFFAOYSA-N [C]1=CC=CC=C1 Chemical group [C]1=CC=CC=C1 CIUQDSCDWFSTQR-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 238000005984 hydrogenation reaction Methods 0.000 abstract 1
- 229910052741 iridium Inorganic materials 0.000 abstract 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 abstract 1
- 239000003446 ligand Substances 0.000 abstract 1
- 229910052703 rhodium Inorganic materials 0.000 abstract 1
- 239000010948 rhodium Substances 0.000 abstract 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
- C07F17/02—Metallocenes of metals of Groups 8, 9 or 10 of the Periodic System
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/1616—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
- B01J31/1625—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts immobilised by covalent linkages, i.e. pendant complexes with optional linking groups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/165—Polymer immobilised coordination complexes, e.g. organometallic complexes
- B01J31/1658—Polymer immobilised coordination complexes, e.g. organometallic complexes immobilised by covalent linkages, i.e. pendant complexes with optional linking groups, e.g. on Wang or Merrifield resins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/189—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms containing both nitrogen and phosphorus as complexing atoms, including e.g. phosphino moieties, in one at least bidentate or bridging ligand
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2282—Unsaturated compounds used as ligands
- B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
- B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B31/00—Reduction in general
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B35/00—Reactions without formation or introduction of functional groups containing hetero atoms, involving a change in the type of bonding between two carbon atoms already directly linked
- C07B35/02—Reduction
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B53/00—Asymmetric syntheses
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F112/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F112/02—Monomers containing only one unsaturated aliphatic radical
- C08F112/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F112/06—Hydrocarbons
- C08F112/08—Styrene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/60—Reduction reactions, e.g. hydrogenation
- B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
- B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
- B01J2231/643—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of R2C=O or R2C=NR (R= C, H)
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/60—Reduction reactions, e.g. hydrogenation
- B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
- B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
- B01J2231/645—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of C=C or C-C triple bonds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/822—Rhodium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/827—Iridium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/842—Iron
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
Abstract
LA INVENCION SE REFIERE A UN COMPUESTO DE FORMULA (I), EN LA QUE R SUP,1} ES ALQUILO C SUB,1} UB,4} O ALCOXI C SUB,1} DA UNO DE ELLOS INDEPENDIENTMENTE DE LOS OTROS HIDROGENO O ALQUILO C SUB,1} DE FORMULA (I) SON VALIOSOS INTERMEDIOS PARA LOS COMPUESTOS DE FORMULA (III), LOS CUALES SON TAMBIEN OBJETO DE ESTA INVENCION, EN LA QUE R SUB,1}, R SUB,2} Y R SUB,3} Y HAL SON LO DEFINIDO ANTERIORMENTE; R SUB,10} Y R SUB,11} SON IDENTICOS O DIFERENTES Y SON ALQUILO C SUB,1} IDO CON ALQUILO C SUB,1} SUB,4} O FENILO SUSTITUIDO CON UNO A TRES SUSTITUYENTES ALQUILO C SUB,1} SUB,5}R SUB,6}, HALOGENO, SO SUB,3}M, }M, X SUP,-} O FLUOROALQUILO C SUB,1} SUB,10}R SUB,11} ES UN RADICAL DE FORMULA (IV, IVA, IVB O IVC); R SUB,4}, R SUB,5} Y R SUB,6} SON CADA UNO DE ELLOS INDEPENDIENTEMENTE DE LOS OTROS ALQUILO C SUB,1} R SUB,7} Y R SUB,8} SON H, ALQUILO C SUB,1} LO O R SUB,7} Y R SUB,8} SON JUNTOS TETRAMETILENO, PENTAMETILENO O 3 DE UN ACIDO MONOBASICO. LOS COMPUESTOS DE FORMULA (III) SON POR SI MISMOS IMPORTANTES INTERMEDIOS PARA LAS FERROCENILDIFOSFINAS SILILADAS Y SUS COMPLEJOS METALICOS. LAS FERROCENILDIFOSFINAS QUE CONTIENEN UN RADICAL ORGANICO UNIDO MEDIANTE UN GRUPO SILENO A UN ANILLO CICLOPENTADIENILO SE PUEDEN INMOVILIZAR DE FORMA SIMPLE TANTO SOBRE SOPORTES INORGANICOS COMO SOBRE SOPORTES ORGANICOS POLIMERICOS O, DESPUES DE LA INTRODUCCION DE UN GRUPO POLIMERIZABLE, SE PUEDEN INMOVILIZAR TAMBIEN POR COPOLIMERIZACION. CON RODIO E IRIDIO LOS LIGANDOS INMOVILIZDOS DE FERROCENILDIFOSFINA FORMAN COMPLEJOS QUE SE PUEDEN UTILIZAR COMO CATALIZADORES ALTAMENTE ACTIVOS EN LA HIDROGENACION ENANTIOSELECTIVA DE DOBLES ENLACES CARBONO-CARBONO, CARBONONITROGENO O CARBONO-OXIGENO.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH106795 | 1995-04-11 |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2135894T3 true ES2135894T3 (es) | 1999-11-01 |
Family
ID=4201677
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES96911992T Expired - Lifetime ES2135894T3 (es) | 1995-04-11 | 1996-04-02 | Ferrocenos dihalogenados y procedimientos para su preparacion. |
Country Status (14)
Country | Link |
---|---|
US (2) | US5925778A (es) |
EP (1) | EP0820460B1 (es) |
JP (1) | JP3854638B2 (es) |
KR (1) | KR100416359B1 (es) |
AT (1) | ATE182595T1 (es) |
AU (1) | AU5499296A (es) |
BR (1) | BR9608128A (es) |
CA (1) | CA2216153C (es) |
CZ (1) | CZ291280B6 (es) |
DE (1) | DE69603466T2 (es) |
ES (1) | ES2135894T3 (es) |
HU (1) | HU221611B (es) |
PL (1) | PL322745A1 (es) |
WO (1) | WO1996032400A1 (es) |
Families Citing this family (25)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1996032400A1 (en) * | 1995-04-11 | 1996-10-17 | Novartis Ag | Dihalogenated ferrocenes and processes for the preparation thereof |
ATE212032T1 (de) * | 1996-07-10 | 2002-02-15 | Syngenta Participations Ag | Funktionalisierte ferrocenyldiphospine, verfahren zu ihrer herstellung und ihre verwendung |
CA2263715C (en) * | 1996-10-07 | 2007-05-01 | Novartis Ag | Chiral ferrocenyls |
DE19952348A1 (de) * | 1998-12-19 | 2000-06-21 | Degussa | Liganden und Komplexe zur enantioselektiven Hydrierung |
US6378830B1 (en) * | 2000-10-05 | 2002-04-30 | Lu Sheng-Nan | Adjustable support for an LCD monitor |
US6620954B1 (en) * | 2002-03-25 | 2003-09-16 | Eastman Chemical Company | Phosphinometallocenylamides as novel ligands for asymmetric catalysis |
JP4218261B2 (ja) * | 2002-06-11 | 2009-02-04 | ダイキン工業株式会社 | ポンプユニット |
GB0228018D0 (en) * | 2002-11-30 | 2003-01-08 | Lucite Int Uk Ltd | Carbonylation of ester |
KR100924521B1 (ko) * | 2002-09-12 | 2009-11-02 | 루싸이트 인터내셔날 유케이 리미티드 | 촉매 시스템 |
WO2005003070A1 (en) | 2003-07-03 | 2005-01-13 | Lucite International Uk Limited | Process for the hydroformylation of ethylenically unsaturated compounds |
GB0400720D0 (en) * | 2004-01-14 | 2004-02-18 | Stylacats Ltd | Novel ferrocene-based phosphorus chiral phosphines |
GB0403592D0 (en) * | 2004-02-18 | 2004-03-24 | Lucite Int Uk Ltd | A catalyst system |
GB0411951D0 (en) * | 2004-05-28 | 2004-06-30 | Lucite Int Uk Ltd | Carbonylation of ester |
GB0504851D0 (en) * | 2005-03-09 | 2005-04-13 | E2V Tech Uk Ltd | Biosensor labelling groups |
GB0516556D0 (en) * | 2005-08-12 | 2005-09-21 | Lucite Int Uk Ltd | Improved catalyst system |
AU2006314268C1 (en) | 2005-11-17 | 2014-01-09 | Lucite International Uk Limited | Carbonylation of ethylenically unsaturated compounds |
GB0607494D0 (en) | 2006-04-13 | 2006-05-24 | Lucite Int Uk Ltd | Metal complexes |
AU2007327051B2 (en) * | 2006-12-02 | 2013-07-04 | Lucite International Uk Limited | Novel carbonylation ligands and their use in the carbonylation of ethylenically unsaturated compounds |
GB0625518D0 (en) * | 2006-12-21 | 2007-01-31 | Lucite Int Uk Ltd | Carbonylation of conjugated dienes |
GB0812297D0 (en) * | 2008-07-04 | 2008-08-13 | Lucite Int Uk Ltd | Novel carbonylation ligand sand thier use of in the carbonylation of ethylenically unsaturated compounds |
JP5493346B2 (ja) * | 2008-12-11 | 2014-05-14 | 東ソー株式会社 | フェロセン誘導体およびその用途 |
GB0905995D0 (en) * | 2009-04-06 | 2009-05-20 | Univ Gent | Cyclic imidate ligands |
GB201000078D0 (en) | 2010-01-05 | 2010-02-17 | Lucite Int Uk Ltd | Process for the carbonylation of ethylenically unsaturated compounds, novel carbonylation ligands and catalyst systems incorporatng such ligands |
GB201211157D0 (en) | 2012-06-22 | 2012-08-08 | Atlas Genetics Ltd | Novel compounds and their use in analytical methods |
JP2023130917A (ja) * | 2022-03-08 | 2023-09-21 | 国立大学法人 東京大学 | コア/シェル型不均一系触媒およびそれを用いた光学活性化合物の製造方法 |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0496700B1 (de) * | 1991-01-25 | 1996-03-06 | Ciba-Geigy Ag | Silangruppen enthaltende Diphosphine, immobilisierte Diophoshine und deren Verwendung als Hydrierkatalysatoren |
EP0496699B1 (de) * | 1991-01-25 | 1995-04-26 | Ciba-Geigy Ag | Silangruppen enthaltende Diphosphine, immobilisierte Diphosphine und deren Verwendung als Hydrierkatalysatoren |
SG42936A1 (en) * | 1992-04-02 | 1997-10-17 | Ciba Geigy Ag | Ferrocenyl diphosphines as ligands for homogeneous catalysts |
EP0612758B1 (de) * | 1993-02-26 | 2003-04-09 | Syngenta Participations AG | Ferrocenyldiphosphine als Liganden für homogene Katalysatoren |
EP0646590B1 (de) * | 1993-10-01 | 1999-08-25 | Novartis AG | Mit Fluoralkyl substituierte Ferrocenyldiphosphine als Liganden für homogene Katalysatoren |
ATE179178T1 (de) * | 1994-11-29 | 1999-05-15 | Lonza Ag | Verfahren zur herstellung optisch aktiver metallocenylphosphine |
ATE195525T1 (de) * | 1995-02-24 | 2000-09-15 | Novartis Ag | Silylierte ferrocenyldiphosphine, an anorganische oder polymere organische träger gebundene silylierte ferrocenyldiphosphine sowie metallkomplexe davon, ihre herstellung und verwendung |
WO1996032400A1 (en) * | 1995-04-11 | 1996-10-17 | Novartis Ag | Dihalogenated ferrocenes and processes for the preparation thereof |
HRP960295A2 (en) * | 1995-07-06 | 1997-08-31 | Ciba Geigy Ag | Process for the hydrogenation of imines in the presence of immobilized iridium-diphosphine catalysts |
-
1996
- 1996-04-02 WO PCT/EP1996/001439 patent/WO1996032400A1/en active IP Right Grant
- 1996-04-02 KR KR1019970707184A patent/KR100416359B1/ko not_active IP Right Cessation
- 1996-04-02 CA CA002216153A patent/CA2216153C/en not_active Expired - Fee Related
- 1996-04-02 AU AU54992/96A patent/AU5499296A/en not_active Abandoned
- 1996-04-02 JP JP53068896A patent/JP3854638B2/ja not_active Expired - Fee Related
- 1996-04-02 US US08/930,171 patent/US5925778A/en not_active Expired - Fee Related
- 1996-04-02 BR BR9608128A patent/BR9608128A/pt not_active IP Right Cessation
- 1996-04-02 ES ES96911992T patent/ES2135894T3/es not_active Expired - Lifetime
- 1996-04-02 CZ CZ19973203A patent/CZ291280B6/cs not_active IP Right Cessation
- 1996-04-02 HU HU9801601A patent/HU221611B/hu not_active IP Right Cessation
- 1996-04-02 AT AT96911992T patent/ATE182595T1/de not_active IP Right Cessation
- 1996-04-02 PL PL96322745A patent/PL322745A1/xx unknown
- 1996-04-02 DE DE69603466T patent/DE69603466T2/de not_active Expired - Fee Related
- 1996-04-02 EP EP96911992A patent/EP0820460B1/en not_active Expired - Lifetime
-
1999
- 1999-02-08 US US09/246,203 patent/US6015919A/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
AU5499296A (en) | 1996-10-30 |
DE69603466T2 (de) | 1999-11-18 |
US5925778A (en) | 1999-07-20 |
CZ291280B6 (cs) | 2003-01-15 |
KR19980703784A (ko) | 1998-12-05 |
EP0820460B1 (en) | 1999-07-28 |
JP3854638B2 (ja) | 2006-12-06 |
CA2216153C (en) | 2008-02-05 |
DE69603466D1 (de) | 1999-09-02 |
KR100416359B1 (ko) | 2004-04-21 |
HU221611B (hu) | 2002-11-28 |
CA2216153A1 (en) | 1996-10-17 |
BR9608128A (pt) | 1999-02-09 |
EP0820460A1 (en) | 1998-01-28 |
HUP9801601A2 (hu) | 1998-10-28 |
PL322745A1 (en) | 1998-02-16 |
US6015919A (en) | 2000-01-18 |
HUP9801601A3 (en) | 1999-03-29 |
CZ320397A3 (cs) | 1998-02-18 |
WO1996032400A1 (en) | 1996-10-17 |
JPH11503439A (ja) | 1999-03-26 |
ATE182595T1 (de) | 1999-08-15 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
ES2135894T3 (es) | Ferrocenos dihalogenados y procedimientos para su preparacion. | |
PT92717A (pt) | Processo de preparacao de compostos de heterociclicos derivados da quinoxalina e de composicoes farmaceuticas que os contem | |
ATE371659T1 (de) | Pyrazolotriazinderivate als gaba-rezeptorliganden | |
ATE58896T1 (de) | Neue zwischenprodukte und verfahren zur herstellung von 3-acylamino-1-hydroxy-2azetidinonen. | |
ES2021027B3 (es) | Compuestos sustituidos de piridinosulfonamida, composicion herbicida que los contiene, y metodo de preparacion de estos compuestos. | |
DE3769399D1 (de) | Verfahren zur herstellung von optisch aktiven benzensulfonamid-derivaten. | |
DE69821622D1 (de) | Verfahren zur herstellung von phosphinverbindungen | |
DE68917708D1 (de) | Chinoxalin-Verbindungen, ihre Herstellung und Verwendung. | |
AR246512A1 (es) | Procedimiento para la produccion de 2,2,6,6-tetraalquil-4-piperidilaminas. | |
MX173379B (es) | Proceso quimico | |
ES2130736T3 (es) | Derivados del pirrolilbencimidazol. | |
DE60205769D1 (de) | Verfahren zur herstellung von amphetaminen aus phenylpropanolaminen | |
PT934261E (pt) | Processo para a producao de ditiobis-alcanossulfonatos e fosfonatos | |
ES2195544T3 (es) | Proceso para la preparacion de bisfosfinas. | |
ES2037668T3 (es) | Un procedimiento para la produccion de compuestos benzotiazolilazolidinas. | |
YU45662B (sh) | Postupak za dobijanje fenmedifama ili dezmedifama | |
ES2124269T3 (es) | Procedimiento de preparacion de un colorante monoazoico. | |
EP1227085A4 (en) | PROCESS FOR PRODUCING OPTICALLY ACTIVE NAPHTHALENE DERIVATIVE AND ITS OPTICAL SEPARATOR | |
ATE27143T1 (de) | Verfahren zur herstellung von nitrosubstituierten benzotrifluoridverbindungen. | |
KR840006233A (ko) | 티오펜 유도체의 제조방법 | |
BR0206982A (pt) | Composto, processo para a preparação do mesmo, uso de um composto, sistema adequado como um catalisador, e, processo para a carbonilação de compostos olefinicamente insaturados | |
ES2058067T3 (es) | Proceso para la produccion de 2,6-didesoxi-2-fluoro-l-talopiranosa y sus derivados. | |
ES2180171T3 (es) | Procedimiento para la obtencion de compuestos del acido vinilfosfonico. | |
DE69902521T2 (de) | Herstellung von phosphin-liganden | |
DE69808922D1 (de) | Thiazolobenzoheterocyclen, ihre herstellung und diese enthaltende phatrmazeutische zubereitungen |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG2A | Definitive protection |
Ref document number: 820460 Country of ref document: ES |