ES2117371T3 - Procedimiento de recuperacion de productos nobles ligeros contenidos en los residuos de destilacion de los procedimientos de fabricacion del acido acrilico y de sus esteres. - Google Patents

Procedimiento de recuperacion de productos nobles ligeros contenidos en los residuos de destilacion de los procedimientos de fabricacion del acido acrilico y de sus esteres.

Info

Publication number
ES2117371T3
ES2117371T3 ES95402777T ES95402777T ES2117371T3 ES 2117371 T3 ES2117371 T3 ES 2117371T3 ES 95402777 T ES95402777 T ES 95402777T ES 95402777 T ES95402777 T ES 95402777T ES 2117371 T3 ES2117371 T3 ES 2117371T3
Authority
ES
Spain
Prior art keywords
acrylic acid
recovery
distillation
esters
waste
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES95402777T
Other languages
English (en)
Inventor
Michel Fauconet
Norbert Richard
Patrick Delafin
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Arkema France SA
Original Assignee
Elf Atochem SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Elf Atochem SA filed Critical Elf Atochem SA
Application granted granted Critical
Publication of ES2117371T3 publication Critical patent/ES2117371T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
    • C07C69/533—Monocarboxylic acid esters having only one carbon-to-carbon double bond
    • C07C69/54—Acrylic acid esters; Methacrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C07C51/487—Separation; Purification; Stabilisation; Use of additives by treatment giving rise to chemical modification
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C07C51/43—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation
    • C07C51/44—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation by distillation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/317—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups
    • C07C67/327—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups by elimination of functional groups containing oxygen only in singly bound form
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/48—Separation; Purification; Stabilisation; Use of additives
    • C07C67/60—Separation; Purification; Stabilisation; Use of additives by treatment giving rise to chemical modification

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Manufacture And Refinement Of Metals (AREA)

Abstract

PARA RECUPERAR ESTOS PRODUCTOS NOBLES CONSTITUIDOS POR EL ACIDO ACRILICO MONOMERO, ESTERES ACRILICOS MONOMEROS Y ALCOHOLES, SE OPERA UN CRAKING TERMICO, EN AUSENCIA DE CATALIZADOR, SOBRE UNA MEZCLA DE RESIDUOS PESADOS DE DESTILACION OBTENIDOS, POR UNA PARTE, DE LA FABRICACION DEL ACIDO ACRILICO, Y POR OTRA PARTE, DE LA FABRICACION DE LOS ESTERES, SE VAPORIZA CONTINUAMENTE, DURANTE LA OPERACION DE CRAKING, LA FRACCION LIGERA OBTENIDA DE LAS REACCIONES DE DISOCIACION, Y SE DESTILA ESTA FRACCION LIGERA CON EL FIN DE RECUPERAR, TRAS LA CONDENSACION, LOS PRODUCTOS BUSCADOS. EL PROCESO SEGUN LA INVENCION PUEDE CONSISTIR EN REALIZAR EL CRAKING DE LA MEZCLA DE RESIDUOS PESADOS, EVENTUALMENTE PRECALENTADOS, EN UN REACTOR (R{SUB,1}), ALIMENTAR UNA COLUMNA DE DESTILACION (C{SUB,1}) POR LOS PRODUCTOS LIGEROS DEL CRAKING; RECUPERAR, EN CABEZA DE COLUMNA (C{SUB,1}), LA MEZCLA DE PRODUCTOS NOBLES LIGEROS DESEADOS; RECICLAR EN EL REACTOR (R{SUB,1}) EL FLUJO RECUPERADO A PIE DE COLUMNA (C{SUB,1}); RECUPERAREL RESIDUO PESADO DEL REACTOR (R{SUB,1}) Y DIRIGIRLO A UN TRATAMIENTO DE ELIMINACION, EN SU CASO TRAS HABERLO DILUIDO CON UNA PARTE DEL FLUJO RECUPERADO A PIE DE COLUMNA (C{SUB,1}), SIENDO EL RESTO DE DICHO FLUJO RECICLADO EN EL REACTOR (R{SUB,1}).
ES95402777T 1994-12-12 1995-12-11 Procedimiento de recuperacion de productos nobles ligeros contenidos en los residuos de destilacion de los procedimientos de fabricacion del acido acrilico y de sus esteres. Expired - Lifetime ES2117371T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR9414935A FR2727964B1 (fr) 1994-12-12 1994-12-12 Procede de recuperation des produits nobles legers contenus dans les residus de distillation des procedes de fabrication de l'acide acrylique et de ses esters

Publications (1)

Publication Number Publication Date
ES2117371T3 true ES2117371T3 (es) 1998-08-01

Family

ID=9469713

Family Applications (1)

Application Number Title Priority Date Filing Date
ES95402777T Expired - Lifetime ES2117371T3 (es) 1994-12-12 1995-12-11 Procedimiento de recuperacion de productos nobles ligeros contenidos en los residuos de destilacion de los procedimientos de fabricacion del acido acrilico y de sus esteres.

Country Status (11)

Country Link
US (1) US5734075A (es)
EP (1) EP0717031B1 (es)
JP (1) JP2663413B2 (es)
KR (1) KR0165931B1 (es)
CN (1) CN1092635C (es)
AT (1) ATE165081T1 (es)
CA (1) CA2164912C (es)
DE (1) DE69502076T2 (es)
DK (1) DK0717031T3 (es)
ES (1) ES2117371T3 (es)
FR (1) FR2727964B1 (es)

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SG81213A1 (en) * 1995-12-15 2001-06-19 Rohm & Haas Process for producing butyle acrylate
US5877345A (en) 1997-02-07 1999-03-02 Rohm And Haas Company Process for producing butyl acrylate
FR2780966B1 (fr) * 1998-07-10 2000-09-08 Rhodia Chimie Sa Procede de recuperation de composes dans les produits lourds issus de leur fabrication
BR0008823B1 (pt) 1999-03-06 2010-11-03 processo para a preparação de ácido acrìlico.
JP3787261B2 (ja) * 1999-04-16 2006-06-21 株式会社日本触媒 易重合性化合物の重合防止方法
AU2002366017A1 (en) * 2001-11-20 2003-06-10 Mitsubishi Chemical Corporation Process for producing (meth)acrylic acid compounds
AU2002355041A1 (en) * 2001-11-28 2003-06-10 Mitsubishi Chemical Corporation Process for producing (meth)acrylic acid compound
EP2311791B1 (en) * 2001-12-04 2019-01-23 Mitsubishi Chemical Corporation Process for producing (meth)acrylic acids
WO2003057660A1 (fr) 2001-12-26 2003-07-17 Mitsubishi Chemical Corporation Procede de decomposition d'un sous-produit de la production d'ester(meth)acrylique
JP4056336B2 (ja) * 2002-09-19 2008-03-05 株式会社日本触媒 アクリル酸及びアクリル酸エステルプロセス廃棄物の処理方法
DE102004008575A1 (de) * 2004-02-19 2005-09-08 Stockhausen Gmbh Spaltung oligomerer (Meth)acrylsäure in flüssiger Phase unter Druck
KR100714631B1 (ko) * 2004-04-29 2007-05-07 주식회사 엘지화학 아크릴산의 회수 방법
JP2005336065A (ja) * 2004-05-25 2005-12-08 Mitsubishi Chemicals Corp （メタ）アクロレイン又は（メタ）アクリル酸の製造方法
JP2005336066A (ja) * 2004-05-25 2005-12-08 Mitsubishi Chemicals Corp （メタ）アクロレイン又は（メタ）アクリル酸の製造方法
KR101314205B1 (ko) * 2010-08-23 2013-10-02 주식회사 엘지화학 모노머 회수방법, 및 이를 위한 장치
FR2980476B1 (fr) * 2011-09-27 2013-08-30 Arkema France Procede de valorisation de produits nobles dans un procede de production de (meth)acrylates de dialkylaminoalkyle
FR3008971B1 (fr) * 2013-07-29 2016-08-19 Arkema France Procede de production en continu d'acrylates legers par esterification d'un acide acrylique de grade ester brut
FR3012447B1 (fr) * 2013-10-29 2017-01-20 Arkema France Procede de production d'esters (meth)acryliques legers
KR101990058B1 (ko) 2015-12-22 2019-06-17 주식회사 엘지화학 (메트)아크릴산의 연속 회수 방법
WO2021092311A1 (en) * 2019-11-07 2021-05-14 Eastman Chemical Company Recycle content glycol ether and glycol ether ester compositons
FR3110571B1 (fr) 2020-05-19 2022-04-15 Arkema France Procédé de valorisation de lourds d’acide acrylique et d’esters dudit acide par craquage thermique avec condensation partielle
FR3126416B1 (fr) 2021-08-25 2023-07-14 Arkema France Procede perfectionne de fabrication d’acrylate de butyle de purete elevee
FR3137090B1 (fr) 2022-06-24 2024-05-10 Arkema France Procede de valorisation de sous-produits lourds issus de la fabrication d’acide acrylique
FR3137091B1 (fr) 2022-06-24 2024-05-10 Arkema France Procede de valorisation continu de sous-produits lourds issus de la fabrication d’acide acrylique
FR3137089B1 (fr) 2022-06-24 2024-05-10 Arkema France Procede de valorisation de sous-produits lourds issus de la fabrication d’acide acrylique
FR3137088B1 (fr) 2022-06-24 2024-05-10 Arkema France Procede de valorisation en batch de sous-produits lourds issus de la fabrication d’acide acrylique
FR3140083B1 (fr) 2022-09-26 2024-08-09 Arkema France Procede de fabrication d’acide (meth)acrylique

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3086046A (en) * 1959-01-30 1963-04-16 Basf Ag Cleavage of diacrylic acid to form acrylic acid
GB923595A (en) * 1960-12-03 1963-04-18 Distillers Co Yeast Ltd Improvements in and relating to the production of acrylic esters
US3868410A (en) * 1972-08-03 1975-02-25 Celanese Corp Conversion of oligomeric acrylates to acrylate monomers
DE2407236C2 (de) * 1974-02-15 1983-02-03 Hoechst Ag, 6000 Frankfurt Verfahren zur Herstellung monomerer Acrylsäure aus Rückständen, die bei der Aufarbeitung roher Acrylsäure anfallen
US4317926A (en) * 1978-01-19 1982-03-02 Nippon Shokubai Kagaku Kogyo Co., Ltd. Process for preparing and recovering acrylic acid

Also Published As

Publication number Publication date
FR2727964B1 (fr) 1997-01-24
FR2727964A1 (fr) 1996-06-14
JP2663413B2 (ja) 1997-10-15
CN1140162A (zh) 1997-01-15
KR960022444A (ko) 1996-07-18
DE69502076T2 (de) 1998-10-22
EP0717031B1 (fr) 1998-04-15
CA2164912C (fr) 2000-02-15
US5734075A (en) 1998-03-31
EP0717031A1 (fr) 1996-06-19
JPH08225486A (ja) 1996-09-03
ATE165081T1 (de) 1998-05-15
KR0165931B1 (ko) 1999-03-20
DE69502076D1 (de) 1998-05-20
CN1092635C (zh) 2002-10-16
DK0717031T3 (da) 1999-01-18
CA2164912A1 (fr) 1996-06-13

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