ES2107201T3 - Preparacion de catalizadores de polimerizacion por adicion mediante oxidacion de un centro metalico atenuado con un acido de lewis. - Google Patents

Preparacion de catalizadores de polimerizacion por adicion mediante oxidacion de un centro metalico atenuado con un acido de lewis.

Info

Publication number
ES2107201T3
ES2107201T3 ES94911386T ES94911386T ES2107201T3 ES 2107201 T3 ES2107201 T3 ES 2107201T3 ES 94911386 T ES94911386 T ES 94911386T ES 94911386 T ES94911386 T ES 94911386T ES 2107201 T3 ES2107201 T3 ES 2107201T3
Authority
ES
Spain
Prior art keywords
oxidation
lewis acid
polymerization catalysts
attenuated
preparation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES94911386T
Other languages
English (en)
Spanish (es)
Inventor
Peter N Nickias
Francis J Timmers
David D Devore
Robert K Rosen
Robert D Mussell
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Chemical Co
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Application granted granted Critical
Publication of ES2107201T3 publication Critical patent/ES2107201T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/14—Monomers containing five or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
ES94911386T 1993-03-19 1994-02-10 Preparacion de catalizadores de polimerizacion por adicion mediante oxidacion de un centro metalico atenuado con un acido de lewis. Expired - Lifetime ES2107201T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US08/034,434 US5347024A (en) 1993-03-19 1993-03-19 Preparation of addition polymerization catalysts via Lewis acid mitigated metal center oxidation

Publications (1)

Publication Number Publication Date
ES2107201T3 true ES2107201T3 (es) 1997-11-16

Family

ID=21876391

Family Applications (1)

Application Number Title Priority Date Filing Date
ES94911386T Expired - Lifetime ES2107201T3 (es) 1993-03-19 1994-02-10 Preparacion de catalizadores de polimerizacion por adicion mediante oxidacion de un centro metalico atenuado con un acido de lewis.

Country Status (12)

Country Link
US (1) US5347024A (Direct)
EP (1) EP0641360B1 (Direct)
JP (1) JP3547440B2 (Direct)
KR (1) KR950701651A (Direct)
CA (1) CA2134890A1 (Direct)
DE (1) DE69405952T2 (Direct)
ES (1) ES2107201T3 (Direct)
FI (1) FI945435A0 (Direct)
HK (1) HK1003598A1 (Direct)
NO (1) NO944420D0 (Direct)
TW (1) TW273557B (Direct)
WO (1) WO1994021693A1 (Direct)

Families Citing this family (41)

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Publication number Priority date Publication date Assignee Title
IT1273753B (it) * 1994-02-11 1997-07-10 Eniriceche Spa Sistema catalitico e processo per la produzione di polidiolefine
US6111020A (en) * 1994-09-02 2000-08-29 The Dow Chemical Company Crosslinked foams from blends of ethylene vinyl acetate and ethylene-styrene interpolymers
FI104825B (fi) 1996-01-26 2000-04-14 Borealis As Olefiinien polymerointikatalysaattorisysteemi, sen valmistus ja käyttö
DE19622207A1 (de) * 1996-06-03 1997-12-04 Hoechst Ag Chemische Verbindung
US5811379A (en) * 1996-06-17 1998-09-22 Exxon Chemical Patents Inc. Polymers derived from olefins useful as lubricant and fuel oil additives, processes for preparation of such polymers and additives and use thereof (PT-1267)
US6194341B1 (en) 1996-06-17 2001-02-27 Exxon Chemical Patents Inc. Mixed transition metal catalyst systems for olefin polymerization
US6066603A (en) * 1996-06-17 2000-05-23 Exxon Chemical Patents Inc. Polar monomer containing copolymers derived from olefins useful as lubricant and useful as lubricant and fuel oil additivies process for preparation of such copolymers and additives and use thereof
US5939503A (en) * 1996-08-09 1999-08-17 California Institute Of Technology Group IV zwitterion ansa metallocene (ZAM) catalysts for α-olefin polymerization
ATE202365T1 (de) * 1996-08-13 2001-07-15 Basell Polyolefine Gmbh Geträgertes katalysatorsystem, verfahren zu seiner herstellung und seine verwendung zur polymerisation von olefinen
DE59712644D1 (de) 1996-08-13 2006-06-14 Basell Polyolefine Gmbh Geträgerte chemische Verbindung
BR9712009A (pt) 1996-09-04 2000-01-18 Dow Chemical Co Revestimento para piso, parede ou teto.
TW412560B (en) 1996-09-04 2000-11-21 Dow Chemical Co Compositions and adhesives comprising a substantially random interpolymer of at least one vinylidene and at least one vinylidene aromatic monomer or hindered aliphatic vinylidene monomer, and coextruded or laminated multilayer film and tape
US6319969B1 (en) 1997-06-26 2001-11-20 The Dow Chemical Company Interpolymer compositions for use in sound management
US6262161B1 (en) 1997-06-26 2001-07-17 The Dow Chemical Company Compositions having improved ignition resistance
US6172015B1 (en) 1997-07-21 2001-01-09 Exxon Chemical Patents, Inc Polar monomer containing copolymers derived from olefins useful as lubricant and fuel oil additives, processes for preparation of such copolymers and additives and use thereof
US6380294B1 (en) 1997-10-17 2002-04-30 The Dow Chemical Company COMPOSITIONS OF INTERPOLYMERS OF α-OLEFIN MONOMERS WITH ONE OR MORE VINYL OR VINYLIDENE AROMATIC MONOMERS AND/OR ONE OR MORE HINDERED ALIPHATIC OR CYCLOALIPHATIC VINYL OR VINYLIDENE MONOMERS BLENDED WITH A CONDUCTIVE ADDITIVE
BR9908805A (pt) 1998-03-11 2000-10-31 Dow Chemical Co Composições termoplásticas de misturas de materiais poliméricos com termoplásticos de engenharia
WO2000018808A1 (en) 1998-09-30 2000-04-06 Exxon Chemical Patents Inc. Cationic group 3 catalyst system
US5993707A (en) * 1998-12-04 1999-11-30 The Dow Chemical Company Enlarged cell size foams made from blends of alkenyl aromatic polymers and alpha-olefin/vinyl or vinylidene aromatic and/or sterically hindered aliphatic or cycloaliphatic vinyl or vinylidene interpolymers
US6187232B1 (en) * 1998-12-04 2001-02-13 The Dow Chemical Company Acoustical insulation foams
US6231795B1 (en) 1998-12-04 2001-05-15 The Dow Chemical Company Soft and flexible foams made from blends of alkenyl aromatic polymers and alpha-olefin/vinyl or vinylidene aromatic and/or sterically hindered aliphatic or cycloaliphatic vinyl or vinylidene interpolymers
US6048909A (en) * 1998-12-04 2000-04-11 The Dow Chemical Company Foams having increased heat distortion temperature made from blends of alkenyl aromatic polymers and alpha-olefin/vinyl or vinylidene aromatic and/or sterically hindered aliphatic or cycloaliphatic vinyl or vinylidene interpolymers
JP2002531721A (ja) 1998-12-08 2002-09-24 ザ ダウ ケミカル カンパニー 熔融接合可能なポリプロピレン／エチレン重合体の繊維および該繊維製造用組成物
US6331597B1 (en) 1999-08-09 2001-12-18 The Dow Chemical Company Azidosilane-modified, moisture-curable polyolefin polymers, process for making, and articles obtained therefrom
US6524702B1 (en) 1999-08-12 2003-02-25 Dow Global Technologies Inc. Electrical devices having polymeric members
US6362270B1 (en) 1999-08-12 2002-03-26 The Dow Chemical Company Thermoplastic compositions for durable goods applications
ES2570753T3 (es) 1999-08-17 2016-05-20 Dow Global Technologies Llc Composición polimérica fluida
US6239062B1 (en) 1999-09-02 2001-05-29 Equistar Chemicals, L.P. Olefin polymerization catalysts containing indolyl-amido ligands
AU2731701A (en) 2000-01-07 2001-07-24 Dow Global Technologies Inc. Thermoformable ethylene/styrene interpolymer-based polymer blend film for three-dimensional transfer finish foil
US6160029A (en) * 2000-03-08 2000-12-12 The Dow Chemical Company Olefin polymer and α-olefin/vinyl or α-olefin/vinylidene interpolymer blend foams
US6649671B2 (en) 2000-03-13 2003-11-18 Dow Global Technologies Inc. Concrete and process to make same
US6767931B2 (en) 2000-07-20 2004-07-27 Dow Global Technologies Inc. Foam compositions from blend of alkenyl aromatic polymers and alpha-olefin/vinyl or vinylidene aromatic interpolymers
AU2002244184A1 (en) * 2001-02-27 2002-09-12 Dow Global Technologies Inc. Fabricated articles prepared from blends of substantially random ethylene/propylene/vinyl aromatic interpolymers with polypropylene
WO2003013806A1 (en) 2001-08-10 2003-02-20 Dow Global Technologies Inc. Wood treatment composition and method of use
US20040106739A1 (en) * 2002-02-19 2004-06-03 Cheung Yunwa Wilson Blends of substantially random interpolymers with enhanced thermal performance
DE102007057854A1 (de) * 2007-11-28 2009-06-04 Philipps-Universität Marburg Cyclopentadienylphosphazen-Komplexe (CpPN-Komplexe) von Metallen der 3. und 4. Gruppe und der Lanthanoide
KR102635095B1 (ko) 2018-03-30 2024-02-13 다우 글로벌 테크놀로지스 엘엘씨 이핵 올레핀 중합 활성화제
US11787880B2 (en) 2018-03-30 2023-10-17 Dow Global Technologies Llc Highly soluble alkyl substituted carbenium borate as co-catalysts for olefin polymerizations
EP3774934A1 (en) 2018-03-30 2021-02-17 Dow Global Technologies LLC Highly soluble bis-borate as binuclear co-catalysts for olefin polymerizations
SG11202008672QA (en) 2018-03-30 2020-10-29 Dow Global Technologies Llc Olefin polymerization activators
CN111918717B (zh) 2018-03-30 2024-04-09 陶氏环球技术有限责任公司 烯烃聚合活化剂

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5064802A (en) * 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
US5189192A (en) * 1991-01-16 1993-02-23 The Dow Chemical Company Process for preparing addition polymerization catalysts via metal center oxidation

Also Published As

Publication number Publication date
JP3547440B2 (ja) 2004-07-28
FI945435A7 (fi) 1994-11-18
NO944420L (no) 1994-11-18
DE69405952T2 (de) 1998-04-16
KR950701651A (ko) 1995-04-28
WO1994021693A1 (en) 1994-09-29
EP0641360A1 (en) 1995-03-08
NO944420D0 (no) 1994-11-18
FI945435L (fi) 1994-11-18
TW273557B (Direct) 1996-04-01
DE69405952D1 (de) 1997-11-06
EP0641360B1 (en) 1997-10-01
FI945435A0 (fi) 1994-11-18
CA2134890A1 (en) 1994-09-29
US5347024A (en) 1994-09-13
JPH07507099A (ja) 1995-08-03
HK1003598A1 (en) 1998-10-30

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