ES2104182T3 - Despolimerizacion de nilon 6,6 y (opcionalmente) nilon 6 para obtener hexametilendiamina (y caprolactama). - Google Patents
Despolimerizacion de nilon 6,6 y (opcionalmente) nilon 6 para obtener hexametilendiamina (y caprolactama).Info
- Publication number
- ES2104182T3 ES2104182T3 ES93923278T ES93923278T ES2104182T3 ES 2104182 T3 ES2104182 T3 ES 2104182T3 ES 93923278 T ES93923278 T ES 93923278T ES 93923278 T ES93923278 T ES 93923278T ES 2104182 T3 ES2104182 T3 ES 2104182T3
- Authority
- ES
- Spain
- Prior art keywords
- nylon
- depolymerization
- hexamethylendiamine
- caprolactam
- optionally
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920002292 Nylon 6 Polymers 0.000 title abstract 2
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 title 2
- 229920002302 Nylon 6,6 Polymers 0.000 title 1
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 title 1
- 239000004677 Nylon Substances 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 229920001778 nylon Polymers 0.000 abstract 1
- 238000001256 steam distillation Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D201/00—Preparation, separation, purification or stabilisation of unsubstituted lactams
- C07D201/02—Preparation of lactams
- C07D201/12—Preparation of lactams by depolymerising polyamides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/62—Preparation of compounds containing amino groups bound to a carbon skeleton by cleaving carbon-to-nitrogen, sulfur-to-nitrogen, or phosphorus-to-nitrogen bonds, e.g. hydrolysis of amides, N-dealkylation of amines or quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J11/00—Recovery or working-up of waste materials
- C08J11/04—Recovery or working-up of waste materials of polymers
- C08J11/10—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation
- C08J11/14—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with steam or water
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2377/00—Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
- C08J2377/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Polyamides (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
Abstract
SE PRESENTA UN PROCESO PARA LA DESPOLIMERIZACION SIMULTANEA DEL NYLON 6 Y DEL 6,6 Y PARA RECUPERAR LOS VALORES MONOMERICOS MEDIANTE UNA DESTILACION CON VAPOR, EN PRESENCIA DE UN CATALIZADOR DE DESPOLIMERIZACION DE NYLON BASICO.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/963,224 US5266694A (en) | 1992-10-19 | 1992-10-19 | Nylon component reclamation |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2104182T3 true ES2104182T3 (es) | 1997-10-01 |
Family
ID=25506940
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES93923278T Expired - Lifetime ES2104182T3 (es) | 1992-10-19 | 1993-10-13 | Despolimerizacion de nilon 6,6 y (opcionalmente) nilon 6 para obtener hexametilendiamina (y caprolactama). |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US5266694A (es) |
| EP (1) | EP0664787B1 (es) |
| JP (1) | JP3285582B2 (es) |
| AU (1) | AU672062B2 (es) |
| CA (1) | CA2146630C (es) |
| DE (1) | DE69311734T2 (es) |
| ES (1) | ES2104182T3 (es) |
| WO (1) | WO1994008942A1 (es) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5457197A (en) * | 1994-04-08 | 1995-10-10 | Alliedsignal Inc. | Monomer recovery from multi-component materials |
| US5536831A (en) * | 1994-12-12 | 1996-07-16 | Basf Aktiengesellschaft | Obtaining caprolactam by cleavage of molten polycaprolactam |
| KR100316687B1 (ko) * | 1994-12-27 | 2002-02-19 | 전 원 중 | 유기불순물을함유한저순도카프로락탐의정제방법 |
| FR2736637B1 (fr) * | 1995-07-12 | 1997-08-22 | Rhone Poulenc Fibres & Polymer | Procede de transformation de polyamides en composes comprenant de l'azote |
| US5656757A (en) * | 1995-08-10 | 1997-08-12 | Alliedsignal Inc. | Monomer recovery from multi-component materials |
| US5681952A (en) * | 1995-12-08 | 1997-10-28 | Alliedsignal Inc. | Process for depolymerizing nylon-containing waste to form caprolactam |
| NL1005942C2 (nl) * | 1997-05-01 | 1998-11-03 | Dsm Nv | Depolymeriseren van polyamiden. |
| NL1006575C2 (nl) * | 1997-07-14 | 1999-01-15 | Dsm Nv | Depolymeriseren van polyamiden. |
| DE60121948T2 (de) | 2000-06-08 | 2007-03-15 | E.I. Du Pont De Nemours And Co., Wilmington | Auf lösungsmittel basierende rückgewinnung und wiederverwertung eines polyamidmaterials |
| DE10029422A1 (de) * | 2000-06-15 | 2001-12-20 | Andreas Hornung | Einstufiges Verfahren zur Rückgewinnung von hochreinem epsilon-Caprolactam aus Teppichböden oder Mischfasern |
| BRPI1011227A8 (pt) | 2009-05-07 | 2019-02-26 | Genomatica Inc | microorganismos e métodos para a biossíntese de adipato, hexametilenodiamina e ácido 6-aminocapróico. |
| US8080506B2 (en) * | 2009-07-14 | 2011-12-20 | MSI Technology LLC. | Reactive purge compound for polymer purging |
| CA3044099A1 (en) | 2018-05-23 | 2019-11-23 | 2569924 Ontario Inc. | Compositions and methods for removing contaminants from plastics processing equipment |
| US12090420B2 (en) | 2018-09-18 | 2024-09-17 | Inv Nylon Chemicals Americas, Llc | Systems and methods for recovering amines and their derivatives from aqueous mixtures |
| US20240228737A1 (en) * | 2021-05-14 | 2024-07-11 | Research Triangle Institute | Depolymerization of polymers with ammonia and amines |
| US20260042730A1 (en) * | 2022-08-19 | 2026-02-12 | Northwestern University | Catalytic chemical recycling of polyamide-based plastics |
| EP4669694A1 (en) * | 2023-02-22 | 2025-12-31 | Basf Se | DEPOLYMERIZATION PROCESS FOR POLYAMIDE PREPARED FROM CAPROLACTAM |
| EP4606787A1 (en) * | 2024-02-21 | 2025-08-27 | Covestro Deutschland AG | Method for efficient purification of hexamethylene diamine obtained from a recycling process |
| EP4606786A1 (en) * | 2024-02-21 | 2025-08-27 | Covestro Deutschland AG | Extraction of 1,6-hexamethylenediamine using combinations of solvents |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE518416A (es) * | ||||
| NL260459A (es) * | 1960-01-25 | 1964-04-27 | ||
| NL283077A (es) | 1961-09-12 | |||
| US3317519A (en) * | 1965-05-21 | 1967-05-02 | Allied Chem | Simultaneous depolymerization of polycaproamide and polyester with recovery of caprolactam |
| JPS53132585A (en) * | 1977-04-21 | 1978-11-18 | Toyobo Co Ltd | Recovery of epsilon-caprolactam |
| SE451464B (sv) * | 1981-12-01 | 1987-10-12 | Lumalampan Ab | Forfarande och anordning for atervinning av kvicksilver ur avfall innehallande organiskt material |
| US4605762A (en) * | 1982-04-23 | 1986-08-12 | Celanese Mexicana S.A. | Depolymerization of condensation polymers |
| DE3502105A1 (de) * | 1985-01-23 | 1986-07-24 | Bayer Ag, 5090 Leverkusen | Verfahren zur herstellung von schiff'schen basen |
| CN87101541A (zh) * | 1987-04-21 | 1988-11-02 | 营口县博洛铺助剂厂 | 一种生产己二酸、己二胺盐酸盐技术 |
| JPH07131541A (ja) * | 1993-11-02 | 1995-05-19 | Oki Electric Ind Co Ltd | ボイススイッチ |
-
1992
- 1992-10-19 US US07/963,224 patent/US5266694A/en not_active Expired - Lifetime
-
1993
- 1993-10-13 JP JP51010694A patent/JP3285582B2/ja not_active Expired - Lifetime
- 1993-10-13 AU AU53218/94A patent/AU672062B2/en not_active Expired - Fee Related
- 1993-10-13 EP EP93923278A patent/EP0664787B1/en not_active Expired - Lifetime
- 1993-10-13 ES ES93923278T patent/ES2104182T3/es not_active Expired - Lifetime
- 1993-10-13 DE DE69311734T patent/DE69311734T2/de not_active Expired - Lifetime
- 1993-10-13 WO PCT/US1993/009543 patent/WO1994008942A1/en not_active Ceased
- 1993-10-13 CA CA002146630A patent/CA2146630C/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| DE69311734D1 (de) | 1997-07-24 |
| AU5321894A (en) | 1994-05-09 |
| DE69311734T2 (de) | 1998-01-15 |
| AU672062B2 (en) | 1996-09-19 |
| US5266694A (en) | 1993-11-30 |
| CA2146630C (en) | 2003-05-27 |
| EP0664787A1 (en) | 1995-08-02 |
| EP0664787B1 (en) | 1997-06-18 |
| CA2146630A1 (en) | 1994-04-28 |
| JP3285582B2 (ja) | 2002-05-27 |
| JPH08502296A (ja) | 1996-03-12 |
| WO1994008942A1 (en) | 1994-04-28 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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