ES2099440T3 - Procedimiento para preparar aminas aromaticas sustituidas. - Google Patents

Procedimiento para preparar aminas aromaticas sustituidas.

Info

Publication number
ES2099440T3
ES2099440T3 ES93911630T ES93911630T ES2099440T3 ES 2099440 T3 ES2099440 T3 ES 2099440T3 ES 93911630 T ES93911630 T ES 93911630T ES 93911630 T ES93911630 T ES 93911630T ES 2099440 T3 ES2099440 T3 ES 2099440T3
Authority
ES
Spain
Prior art keywords
substituted aromatic
compound
base
protic material
aromatic amines
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES93911630T
Other languages
English (en)
Inventor
Michael Keith Stern
Brian Kai-Ming Cheng
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Monsanto Co
Original Assignee
Monsanto Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Monsanto Co filed Critical Monsanto Co
Application granted granted Critical
Publication of ES2099440T3 publication Critical patent/ES2099440T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/02—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of hydrogen atoms by amino groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/30—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds
    • C07C209/42—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitrogen-to-nitrogen bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C211/00—Compounds containing amino groups bound to a carbon skeleton
    • C07C211/43—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
    • C07C211/44—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to only one six-membered aromatic ring
    • C07C211/49—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to only one six-membered aromatic ring having at least two amino groups bound to the carbon skeleton
    • C07C211/50—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to only one six-membered aromatic ring having at least two amino groups bound to the carbon skeleton with at least two amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C245/00—Compounds containing chains of at least two nitrogen atoms with at least one nitrogen-to-nitrogen multiple bond
    • C07C245/02—Azo compounds, i.e. compounds having the free valencies of —N=N— groups attached to different atoms, e.g. diazohydroxides
    • C07C245/06—Azo compounds, i.e. compounds having the free valencies of —N=N— groups attached to different atoms, e.g. diazohydroxides with nitrogen atoms of azo groups bound to carbon atoms of six-membered aromatic rings
    • C07C245/08—Azo compounds, i.e. compounds having the free valencies of —N=N— groups attached to different atoms, e.g. diazohydroxides with nitrogen atoms of azo groups bound to carbon atoms of six-membered aromatic rings with the two nitrogen atoms of azo groups bound to carbon atoms of six-membered aromatic rings, e.g. azobenzene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

SE PREVE UN PROCESO PARA PREPARAR COMPUESTOS AZO AROMATICOS SUSTITUIDOS QUE CONSISTE EN PONER EN CONTACTO UN COMPUESTO NUCLEOFILICO Y UN COMPUESTO QUE CONTIENE AZO EN PRESENCIA DE UN SISTEMA SOLVENTE APROPIADO, Y HACER REACCIONAR EL COMPUESTO NUCLEOFILICO Y EL COMPUESTO QUE CONTIENE AZO EN PRESENCIA DE UNA BASE ACEPTABLE Y UNA CANTIDAD CONTROLADA DE MATERIAL PROTICO A UNA TEMPERATURA DE APROXIMADAMENTE 10 (GRADOS) C A APROXIMADAMENTE 150 (GRADOS) C EN UNA ZONA DE REACCION CONFINADA DONDE LA RELACION MOLAR DE MATERIAL PROTICO A BASE ES 0:1 A APROXIMADAMENTE 5:1. EN OTRA REALIZACION, LOS COMPUESTOS AZO AROMATICOS SUSTITUIDOS REACCIONAN ADICIONALMENTE CON UN COMPUESTO NUCLEOFILICO EN PRESENCIA DE UN SISTEMA SOLVENTE APROPIADO, UNA BASE APROPIADA Y UNA CANTIDAD CONTROLADA DE MATERIAL PROTICO A UNA TEMPERATURA DE APROXIMADAMENTE 70 (GRADOS) C A APROXIMADAMENTE 200 (GRADOS) C EN UNA ZONA DE REACCION CONFINADA EN LA QUE LA RELACION MOLAR DE MATERIAL PROTICO A BASE ES 0: 1 A APROXIMADAMENTE 5:1 PARA PRODUCIR UNA AMINA AROMATICA SUSTITUIDA. EN OTRA REALIZACION, SE PREVE UN PROCESO PARA PREPARA AMINAS AROMATICAS SUSTITUIDAS QUE CONSISTE EN PONER EN CONTACTO UN COMPUESTO NUCLEOFILICO Y EL COMPUESTO AZO AROMATICO SUSTITUIDO EN PRESENCIA DE UN SISTEMA SOLVENTE APROPIADO, Y REACCIONAR EL COMPUESTO NUCLEOFILICO Y EL COMPUESTO AZO AROMATICO SUSTITUIDO EN PRESENCIA DE UNA BASE APROPIADA Y UNA CANTIDAD CONTROLADA DE MATERIAL PROTICO A UNA TEMPERATURA DE APROXIMADAMENTE 70 (GRADOS) C A APROXIMADAMENTE 200 (GRADOS) C EN UNA ZONA DE REACCION CONFINADA EN LA QUE LA RELACION MOLAR DE MATERIAL PROTICO A BASE ES 0:1 A APROXIMADAMENTE 5:1 E OTRA REALIZACION, LAS AMINAS AROMATICAS SUSTITUIDAS DE LA INVENCION SE ALQUILAN REDUCIDAMENTE PARA PRODUCIR DIAMINAS ALQUILADAS O DERIVADOS SUSTITUIDOS DE ESTAS.
ES93911630T 1992-05-22 1993-04-13 Procedimiento para preparar aminas aromaticas sustituidas. Expired - Lifetime ES2099440T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US88706092A 1992-05-22 1992-05-22

Publications (1)

Publication Number Publication Date
ES2099440T3 true ES2099440T3 (es) 1997-05-16

Family

ID=25390367

Family Applications (1)

Application Number Title Priority Date Filing Date
ES93911630T Expired - Lifetime ES2099440T3 (es) 1992-05-22 1993-04-13 Procedimiento para preparar aminas aromaticas sustituidas.

Country Status (18)

Country Link
US (3) US5552531A (es)
EP (1) EP0641313B1 (es)
JP (1) JP3476818B2 (es)
KR (1) KR0164628B1 (es)
AT (1) ATE148100T1 (es)
BR (1) BR9306401A (es)
CA (1) CA2135491C (es)
CZ (1) CZ283594A3 (es)
DE (1) DE69307699T2 (es)
EE (1) EE03056B1 (es)
ES (1) ES2099440T3 (es)
GE (1) GEP19991703B (es)
HU (1) HUT70869A (es)
PL (1) PL176660B1 (es)
RU (1) RU2126380C1 (es)
TW (1) TW239118B (es)
UA (1) UA44224C2 (es)
WO (1) WO1993024450A1 (es)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5552531A (en) * 1992-05-22 1996-09-03 Monsanto Company Process for preparing substituted aromatic azo compounds
US5451702A (en) * 1993-04-26 1995-09-19 Monsanto Company Process for preparing substituted aromatic amines
JPH07149695A (ja) * 1993-09-30 1995-06-13 Seiko Kagaku Kk ４−アミノジフェニルアミン類の製造方法
US5382691A (en) * 1993-11-05 1995-01-17 Monsanto Company Process for preparing substituted aromatic amines
DE19709124A1 (de) * 1997-03-06 1998-09-10 Bayer Ag Verfahren zur Herstellung von 4-Aminodiphenylamin
TW500712B (en) * 1997-08-06 2002-09-01 Bayer Ag Process for the preparation of 4-aminodiphenylamine
DE19810929A1 (de) * 1998-03-13 1999-09-16 Bayer Ag Verfahren zur Herstellung von 4-Aminodiphenylamin
DE10055221A1 (de) 2000-11-08 2002-05-29 Bayer Ag Verfahren zur Herstellung von 4-Aminodiphenylamin
US20040039181A1 (en) * 2002-07-29 2004-02-26 Rains Roger Keranen Process for preparing aromatic azo and hydrazo compounds, aromatic amides and aromatic amines
US8486223B2 (en) * 2003-07-04 2013-07-16 Jiangsu Sinorgchem Technology Co., Ltd. Falling film evaporator
KR100612922B1 (ko) 2003-07-04 2006-08-14 농유 왕 4-아미노 디페닐아민의 제조방법
US8686188B2 (en) 2003-07-04 2014-04-01 Jiangsu Sinorgchem Technology Co., Ltd. Process for preparing 4-aminodiphenylamine
EP2368558A1 (en) * 2010-03-23 2011-09-28 Mdc Max-Delbrück-Centrum Für Molekulare Medizin Berlin - Buch Azo compounds reducing formation and toxicity of amyloid beta aggregation intermediates
CN102259029B (zh) 2010-05-24 2014-12-10 江苏圣奥化学科技有限公司 固体碱催化剂
KR101358605B1 (ko) 2010-12-21 2014-02-04 금호석유화학 주식회사 4-니트로아닐린을　이용한 4,4'-디니트로디페닐아민 및 4,4'-비스(알킬아미노)디페닐아민의 제조방법
KR101358519B1 (ko) 2010-12-21 2014-02-05 금호석유화학 주식회사 복합염기촉매를　이용한 4,4'-디니트로디페닐아민 및 4,4'-비스(알킬아미노)디페닐아민의 제조방법
CN102796011A (zh) * 2012-08-25 2012-11-28 山西翔宇化工有限公司 一种对氨基二苯胺的制备方法
WO2014098775A1 (en) 2012-12-19 2014-06-26 Slovenská Technická Univerzita V Bratislave, Strojnícka Fakulta Automobile bodies and their manufacturing processes
CN111039822B (zh) * 2018-10-12 2022-11-11 北京工商大学 一种芳香族偶氮化合物的光化学催化合成方法

Family Cites Families (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE275068C (es) *
US2822395A (en) * 1954-03-05 1958-02-04 Ici Ltd Production of amines
GB770299A (en) * 1954-03-05 1957-03-20 Ici Ltd Improvements in and relating to the production of amines
US3340302A (en) * 1964-04-01 1967-09-05 Hercules Inc Process for manufacture of p-nitroson-phenylanilines
BE789273A (fr) * 1971-09-28 1973-03-26 Bayer Ag Procede de preparation de derives de nitrodiphenylamine
GB1440767A (en) * 1972-11-24 1976-06-23 Ici Ltd Oxidation process for the manufacture of 4-aminodiphenylamine and related higher amines
DE2633811C2 (de) * 1976-07-28 1983-11-10 Bayer Ag, 5090 Leverkusen Verfahren zur Herstellung von Nitrodiphenylaminen
DE2713602C3 (de) * 1977-03-28 1980-03-20 Akzo Gmbh, 5600 Wuppertal Verfahren zur Herstellung von Nitrosobenzol
US4187248A (en) * 1977-11-23 1980-02-05 Monsanto Company Making a nitrodiarylamine by reacting an alkali metal salt of a formamide with a nitrohaloarene
US4209463A (en) * 1977-12-27 1980-06-24 Monsanto Company Promoting the formation of nitrodiarylamines from nitrohaloarenes, activated aryl amines and sodium carbonates
US4187249A (en) * 1977-12-27 1980-02-05 Monsanto Company Promoting the reaction of sodium salts of formyl derivatives of aromatic amines to form nitrodiarylamines
US4140716A (en) * 1978-01-05 1979-02-20 Monsanto Company Process for making an amide of formic acid and forming nitrodiarylamine therefrom
US4155936A (en) * 1978-03-08 1979-05-22 The Goodyear Tire & Rubber Company Para-nitrodiphenylamines synthesis using Polyethers and macrocyclic esters as solubilizing agents
US4196146A (en) * 1978-03-13 1980-04-01 Monsanto Company Making nitrodiarylamines from formyl derivatives of aromatic amines and nitrohaloarenes by admixing with certain aqueous salt solutions
US4404401A (en) * 1979-02-23 1983-09-13 Akzona Incorporated Process for the preparation of para-amino-diphenylamine
EP0035815B1 (en) * 1980-03-12 1983-06-08 Akzo N.V. Process for the preparation of p-aminoazobenzene from aniline
US4900868A (en) * 1982-01-18 1990-02-13 Monsanto Company Process for producing N,N'-disubstituted paraphenylene diamine mixtures by sequential reductive alkylation
US4518803A (en) * 1982-09-30 1985-05-21 Uniroyal, Inc. Process for the preparation of p-nitrosodiphenylamine
US4479008A (en) * 1982-09-30 1984-10-23 Uniroyal, Inc. Preparation of p-nitrosodiphenylamine
US4614817A (en) * 1983-12-19 1986-09-30 Monsanto Company Making nitrodiarylamines
DE3504479A1 (de) * 1985-02-09 1986-08-14 Bayer Ag, 5090 Leverkusen Verfahren zur herstellung von 4-nitrodiphenylaminen
US4683332A (en) * 1985-05-20 1987-07-28 The Goodyear Tire & Rubber Company Para-nitrodiphenylamine synthesis
DE3609342A1 (de) * 1986-03-20 1987-09-24 Bayer Ag Verfahren zur herstellung von azoverbindungen
US4760186A (en) * 1986-09-15 1988-07-26 Monsanto Company Preparation of substituted aromatic amines
DD275068A1 (de) * 1988-08-22 1990-01-10 Tech Hochschule C Schorlemmer Verfahren zur herstellung von n-monosubstituierten 4-aryl-azo-1-naphthylaminen
DE4021960A1 (de) * 1990-07-10 1992-01-16 Basf Ag Thiophenazofarbstoffe
US5117063A (en) * 1991-06-21 1992-05-26 Monsanto Company Method of preparing 4-aminodiphenylamine
US5331099A (en) * 1992-05-22 1994-07-19 Monsanto Company Process for preparing p-nitroaromatic amides and products thereof
US5552531A (en) * 1992-05-22 1996-09-03 Monsanto Company Process for preparing substituted aromatic azo compounds
US5252737A (en) * 1992-05-22 1993-10-12 Monsanto Company Process for preparing N-aliphatic substituted p-phenylenediamines
US5451702A (en) * 1993-04-26 1995-09-19 Monsanto Company Process for preparing substituted aromatic amines

Also Published As

Publication number Publication date
EP0641313B1 (en) 1997-01-22
US5552531A (en) 1996-09-03
BR9306401A (pt) 1995-07-11
WO1993024450A1 (en) 1993-12-09
KR950701616A (ko) 1995-04-28
TW239118B (es) 1995-01-21
CA2135491C (en) 2004-06-22
ATE148100T1 (de) 1997-02-15
HUT70869A (en) 1995-11-28
US5618979A (en) 1997-04-08
KR0164628B1 (ko) 1999-03-20
PL176660B1 (pl) 1999-07-30
RU2126380C1 (ru) 1999-02-20
HU9403339D0 (en) 1995-02-28
RU94046135A (ru) 1996-11-27
UA44224C2 (uk) 2002-02-15
JPH07507297A (ja) 1995-08-10
CA2135491A1 (en) 1993-12-09
JP3476818B2 (ja) 2003-12-10
CZ283594A3 (en) 1995-03-15
EE03056B1 (et) 1997-12-15
DE69307699T2 (de) 1997-06-05
US5633407A (en) 1997-05-27
DE69307699D1 (de) 1997-03-06
GEP19991703B (en) 1999-08-05
EP0641313A1 (en) 1995-03-08

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