ES2098363T3 - Separador y su metodo de fabricacion. - Google Patents
Separador y su metodo de fabricacion.Info
- Publication number
- ES2098363T3 ES2098363T3 ES91913095T ES91913095T ES2098363T3 ES 2098363 T3 ES2098363 T3 ES 2098363T3 ES 91913095 T ES91913095 T ES 91913095T ES 91913095 T ES91913095 T ES 91913095T ES 2098363 T3 ES2098363 T3 ES 2098363T3
- Authority
- ES
- Spain
- Prior art keywords
- fuel
- plates
- plate
- generating components
- thin plate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
- H01M8/0247—Collectors; Separators, e.g. bipolar separators; Interconnectors characterised by the form
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
- H01M8/0204—Non-porous and characterised by the material
- H01M8/0223—Composites
- H01M8/0228—Composites in the form of layered or coated products
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
- H01M8/0247—Collectors; Separators, e.g. bipolar separators; Interconnectors characterised by the form
- H01M8/0254—Collectors; Separators, e.g. bipolar separators; Interconnectors characterised by the form corrugated or undulated
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/14—Fuel cells with fused electrolytes
- H01M2008/147—Fuel cells with molten carbonates
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0048—Molten electrolytes used at high temperature
- H01M2300/0051—Carbonates
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
- H01M8/023—Porous and characterised by the material
- H01M8/0232—Metals or alloys
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/49002—Electrical device making
- Y10T29/49108—Electric battery cell making
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/49002—Electrical device making
- Y10T29/49108—Electric battery cell making
- Y10T29/49112—Electric battery cell making including laminating of indefinite length material
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/49002—Electrical device making
- Y10T29/49108—Electric battery cell making
- Y10T29/49114—Electric battery cell making including adhesively bonding
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Composite Materials (AREA)
- Fuel Cell (AREA)
Abstract
UN SEPARADOR INTERPUESTO ENTRE EL CUERPO LAMINADO DE COMPONENTES GENERADORES DE POTENCIA QUE COMPRENDE UN ELECTRODO DE COMBUSTIBLE, UNA CAPA DE ELECTROLITO, Y UN ELECTRODO DE AIRE PARA SUMINISTRAR UN GAS COMBUSTIBLE AL ELECTRODO DE COMBUSTIBLE Y UN GAS DE AGENTE DE OXIDACION AL ELECTRODO DE AIRE SEPARADAMENTE, CON LOS CANALES DE LOS GASES AISLADOS UNOS DE OTROS. PLACAS COLECTORAS DE CORRIENTE Y PLACAS LATERALES CONSTITUYEN UNAS CARAS DE PARED Y SUS PERIFERIAS EN CONTACTO CON EL ELECTRODO DE COMBUSTIBLE EN EL CANAL DEL GAS DE COMBUSTIBLE Y CON EL ELECTRODO DE AIRE EN EL CANAL DEL GAS DE AGENTE DE OXIDACION, RESPECTIVAMENTE. LAS PLACAS ESTAN HECHAS DE MATERIALES DE PLACA FINA EXHIBIENDO GRAN FLEXIBILIDAD. COMO LAS PLACAS LATERALES DEL MATERIAL DE PLACA FINA SE PUEDEN DOBLAR FACILMENTE EN UNA DIRECCION EN LA QUE SE LAMINAN LOS COMPONENTES GENERADORES DE ENERGIA, AUN SI LA DIFERENCIA EN EL NIVEL DEBIDO DE A LAS VARIACIONES DE LA PLACA COLECTORA DE CORRIENTE, SU SOPORTE Y LA PLACA LATERAL SE PRODUCEN DESPUES DE LA FABRICACION, LAS DIFERENCIAS EN EL NIVEL SE ELIMINAN POR EL CURVADO DE LAS PLACAS. ASI, EL CONTACTO DE LAS PLACAS CON LOS COMPONENTES GENERADORES DE ENERGIA SE PUEDE UNIFORMAR Y SE PUEDE IMPEDIR A LAS FUERZAS LOCALES EJERCER EN LOS COMPONENTES GENERADORES DE ENERGIA. UN METODO DE FABRICACION DEL GENERADOR SE CARACTERIZA EN QUE UN TOQUEL METALICO Y UN TROQUEL EXTERNO RODEANDO EL TROQUEL METALICO SE SITUAN EN UNA CABEZA DE PRENSA, UNA PLACA FINA DE MATERIAL EN BRUTO Y UNA PLACA FLEXIBLE CON UNA DUREZA PREDETERMINADA SE PONEN UNA SOBRE OTRA EN EL TROQUEL METALICO, Y LA PLACA FINA SE PRENSA Y SE FORMA A TRAVES DE LA PLACA FLEXIBLE. AL FABRICARSE LA PLACA COLECTORA DE CORRIENTE Y LA PLACA LATERAL MEDIANTE EL TRABAJO DE LA PRENSA, NO SE REQUIERE NINGUN TRABAJO DE CORTADO Y NINGUN TRABAJO DE UNION POR FUSION, ETC, Y NO SE PRODUCE UNA TENSION RESIDUAL CAUSADA POR ESTOS TRABAJOS. SIN EMBARGO, LA TENSION RESIDUAL, SI EXISTE, ES LIBERADA POR LA ELEVACION DE TEMPERATURA ACOMPAÑADA POR LA PUESTA EN MARCHA DE UNA CELULA DE COMBUSTIBLE, Y LOS MIEMBROS NO SE DEFORMAN. MAS ADELANTE, ESTE METODO DE FABRICACION ES EXCELENTE EN PRODUCTIVIDAD EN MASA.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP19824190 | 1990-07-24 |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2098363T3 true ES2098363T3 (es) | 1997-05-01 |
Family
ID=16387855
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES91913095T Expired - Lifetime ES2098363T3 (es) | 1990-07-24 | 1991-07-23 | Separador y su metodo de fabricacion. |
Country Status (5)
Country | Link |
---|---|
US (1) | US5378247A (es) |
EP (1) | EP0496889B1 (es) |
DE (1) | DE69125265T2 (es) |
ES (1) | ES2098363T3 (es) |
WO (1) | WO1992002057A1 (es) |
Families Citing this family (29)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH07220743A (ja) * | 1994-01-27 | 1995-08-18 | Kansai Electric Power Co Inc:The | 燃料電池、そのバイポーラ板、およびバイポーラ板の製造方法 |
US5567544A (en) * | 1995-05-26 | 1996-10-22 | Boundless Corp. | Battery |
DE19853911A1 (de) * | 1998-11-23 | 2000-05-25 | Forschungszentrum Juelich Gmbh | Brennstoffzelle mit Zuführung eines Betriebsmittels über eine gelochte Platte |
US6815116B2 (en) * | 2001-03-08 | 2004-11-09 | The Regents Of The University Of California | Flexible interconnects for fuel cell stacks |
US6720101B1 (en) | 2001-06-08 | 2004-04-13 | Palcan Fuel Cell Co. Ltd | Solid cage fuel cell stack |
DE10135235C2 (de) * | 2001-07-24 | 2003-05-28 | Forschungszentrum Juelich Gmbh | Verfahren zur Herstellung einer gasdichten Verbindung zwischen einem metallischen und einem keramischen Substrat |
JP3906673B2 (ja) * | 2001-11-15 | 2007-04-18 | トヨタ自動車株式会社 | 燃料電池及びその組付方法 |
DE10158772C1 (de) * | 2001-11-23 | 2003-06-26 | Reinz Dichtungs Gmbh & Co Kg | Brennstoffzellensystem |
DE10238857A1 (de) * | 2002-08-24 | 2004-03-04 | Bayerische Motoren Werke Ag | Verfahren zum Herstellen einer Einzel-Brennstoff-Zelle |
JP2005285350A (ja) * | 2004-03-26 | 2005-10-13 | Matsushita Electric Ind Co Ltd | 高分子電解質型燃料電池 |
US7632595B1 (en) * | 2004-04-05 | 2009-12-15 | General Electric Company | Compliant fuel cell system |
JP2005353421A (ja) * | 2004-06-10 | 2005-12-22 | Nissan Motor Co Ltd | 燃料電池 |
JP4854237B2 (ja) * | 2004-10-22 | 2012-01-18 | 日産自動車株式会社 | 固体電解質型燃料電池及びスタック構造体 |
WO2006067971A2 (en) * | 2004-12-21 | 2006-06-29 | Nissan Motor Co., Ltd. | Startup method for fuel cell stack structure, temperature control method for fuel cell stack structure, and fuel cell stack structure |
EP1872427B1 (en) * | 2005-04-21 | 2009-08-19 | Ansaldo Fuel Cells S.p.A. | Fuel cell separator plate |
TWM296484U (en) * | 2006-01-20 | 2006-08-21 | Antig Tech Co Ltd | Fuel cell device |
JP5343307B2 (ja) * | 2006-05-16 | 2013-11-13 | 日産自動車株式会社 | 燃料電池スタックおよび燃料電池セパレータ並びにその製造方法 |
KR100901568B1 (ko) * | 2006-12-12 | 2009-06-08 | 현대자동차주식회사 | 연료전지용 금속분리판의 제조방법 |
US8026020B2 (en) | 2007-05-08 | 2011-09-27 | Relion, Inc. | Proton exchange membrane fuel cell stack and fuel cell stack module |
EP1998396B1 (en) * | 2007-05-22 | 2013-05-22 | NGK Insulators, Ltd. | Solid oxide fuel cell |
US9293778B2 (en) | 2007-06-11 | 2016-03-22 | Emergent Power Inc. | Proton exchange membrane fuel cell |
US8003274B2 (en) * | 2007-10-25 | 2011-08-23 | Relion, Inc. | Direct liquid fuel cell |
EP2384784B1 (fr) | 2010-05-05 | 2012-09-26 | Sorin CRM SAS | Ensemble de stimulation/défibrillation endocavitaire du ventricule gauche |
US9306225B2 (en) | 2011-06-01 | 2016-04-05 | Fuelcell Energy, Inc. | Bipolar separator assembly for fuel cells and method of making same |
JP6158683B2 (ja) * | 2013-10-30 | 2017-07-05 | 京セラ株式会社 | セルスタック装置、モジュールおよびモジュール収納装置 |
JP6172524B2 (ja) * | 2014-02-14 | 2017-08-02 | トヨタ自動車株式会社 | 燃料電池用セパレータ |
CA3020251C (en) * | 2016-04-08 | 2020-10-06 | Nissan Motor Co., Ltd. | Fuel cell single cell with a current collection assisting layer |
JP7052593B2 (ja) * | 2018-06-21 | 2022-04-12 | トヨタ自動車株式会社 | 燃料電池単セルの製造方法 |
JP7074025B2 (ja) * | 2018-11-06 | 2022-05-24 | トヨタ自動車株式会社 | ガスリーク検査装置 |
Family Cites Families (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5628471A (en) * | 1979-08-17 | 1981-03-20 | Furukawa Battery Co Ltd:The | Grid base-plate for electrode plate of battery and its manufacture |
US4514475A (en) * | 1984-03-30 | 1985-04-30 | The United States Of America As Represented By The United States Department Of Energy | Fuel cell separator with compressible sealing flanges |
JPS6192840A (ja) * | 1984-10-12 | 1986-05-10 | 森沢 哲雄 | エンボス加工方法 |
JPS61216257A (ja) * | 1985-03-22 | 1986-09-25 | Hitachi Ltd | 燃料電池用セパレ−タ |
JPH084008B2 (ja) * | 1986-08-21 | 1996-01-17 | 石川島播磨重工業株式会社 | 燃料電池用セパレ−タ |
JPS6353857A (ja) * | 1986-08-22 | 1988-03-08 | Ishikawajima Harima Heavy Ind Co Ltd | 燃料電池のセパレ−タ |
JP2569541B2 (ja) * | 1987-03-30 | 1997-01-08 | 石川島播磨重工業株式会社 | 燃料電池用セパレ−タ |
JPS6484578A (en) * | 1987-09-28 | 1989-03-29 | Ishikawajima Harima Heavy Ind | Fuel cell |
JPH0626127B2 (ja) * | 1987-10-01 | 1994-04-06 | 石川島播磨重工業株式会社 | 燃料電池用セパレータの製造方法 |
JPH01140559A (ja) * | 1987-11-27 | 1989-06-01 | Hitachi Ltd | 燃料電池 |
JPH01211862A (ja) * | 1988-02-19 | 1989-08-25 | Ishikawajima Harima Heavy Ind Co Ltd | 燃料電池用セパレータ |
JPH01211864A (ja) * | 1988-02-19 | 1989-08-25 | Ishikawajima Harima Heavy Ind Co Ltd | 燃料電池用セパレータのウェットシール部の接合方法 |
JP2768698B2 (ja) * | 1988-09-09 | 1998-06-25 | 三菱電機株式会社 | 内部マニホールド方式の溶融炭酸塩型燃料電池 |
JP2708500B2 (ja) * | 1988-09-27 | 1998-02-04 | 三菱電機株式会社 | 積層形燃料電池 |
JPH02168563A (ja) * | 1988-12-21 | 1990-06-28 | Ishikawajima Harima Heavy Ind Co Ltd | 燃料電池用セパレータ |
US4920019A (en) * | 1989-03-24 | 1990-04-24 | Eveready Battery Company, Inc. | Battery pack assembly having a circuit board |
JPH035658U (es) * | 1989-06-06 | 1991-01-21 | ||
JPH0335658A (ja) * | 1989-06-30 | 1991-02-15 | Mitsubishi Electric Corp | ファクシミリ放送受信装置 |
US5064583A (en) * | 1989-08-01 | 1991-11-12 | Zycon Corporation | Method for applying mold release coating to separator plates for molding printed circuit boards |
-
1991
- 1991-07-23 WO PCT/JP1991/000982 patent/WO1992002057A1/ja active IP Right Grant
- 1991-07-23 EP EP91913095A patent/EP0496889B1/en not_active Expired - Lifetime
- 1991-07-23 ES ES91913095T patent/ES2098363T3/es not_active Expired - Lifetime
- 1991-07-23 DE DE69125265T patent/DE69125265T2/de not_active Expired - Fee Related
-
1992
- 1992-02-05 US US07/828,939 patent/US5378247A/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
EP0496889A4 (en) | 1992-09-16 |
DE69125265T2 (de) | 1997-09-04 |
DE69125265D1 (de) | 1997-04-24 |
EP0496889B1 (en) | 1997-03-19 |
US5378247A (en) | 1995-01-03 |
WO1992002057A1 (en) | 1992-02-06 |
EP0496889A1 (en) | 1992-08-05 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
ES2098363T3 (es) | Separador y su metodo de fabricacion. | |
SE9101467D0 (sv) | Electrochemical cells | |
ES2045446T3 (es) | Un aparato generador electroquimico que contiene electrodos de combustible modificados para usarse con combustibles hidrocarbonados. | |
IT7827616A0 (it) | Attrezzatura per la generazione di energia termica ed energia elettrica. | |
ES2045447T3 (es) | Aparato generador electroquimico que contiene aislamiento modificado de altas temperaturas. | |
ATE386492T1 (de) | Heizkissen und ein solches kissen enthaltende vorrichtung | |
BR8103280A (pt) | Processo para interromper o fluxo de energia eletrica,processo de derivacao para uma celula eletroquimicamente falha,processo para isolar um cordao de baterias secundarias de armazenamento de energia e sistema para a instalacao de baterias | |
ES2079637T3 (es) | Aparato de toma de corriente de una pila de combustible. | |
ES2033293T3 (es) | Pila de combustible con placas terminales de presion. | |
ES2175501T3 (es) | Bateria de celulas de combustible refrigerada por liquido. | |
ES2183612T3 (es) | Util de conformacion con superficie estructurada para la generacion de estructuras sobre vidrio y su aplicacion en la estructuracion de placas acanaladas. | |
TWI241275B (en) | Ozonizer | |
ES2156022T3 (es) | Pila de combustible del tipo de distribuidores de reactivos en forma de placas. | |
BR8100827A (pt) | Processo para a fabricacao de caixilhos arredondados com costuras de solda longitudinais e transformador de solar destinado a fonte eletrica de energia para a execucao do processo | |
ES2140218T3 (es) | Cuerpo alveolar metalico soldado, con distanciadores en los espacios de soldadura, y procedimiento y material de soldadura para su fabricacion. | |
ES455830A1 (es) | Disposicion para la captacion de la energia solar aplicable a la aclimatacion de todo tipo de edificios. | |
ES2081149T3 (es) | Placas de plastico celular con mejoradas propiedades de aislamiento termico y un procedimiento para su obtencion. | |
ES2155198T3 (es) | Procedimiento para fabricar un cuerpo alveolar soldado, con el empleo de chapas estratificadas. | |
ES2094547T3 (es) | Celulas energeticas. | |
ES2195256T3 (es) | Procedimiento y dispositivo para la fijacion estanca de un electrodo de un quemador. | |
DK1273065T3 (da) | Fremgangsmåde til fremstilling af en fastoxidbrændselscelle | |
ES2100750T3 (es) | Electrodo para celdas electroliticas. | |
ES2107028T3 (es) | Procedimiento para fabricar laminados plasticos con laminas de metal especialmente para circuitos impresos, con calentamiento endotermico. | |
KR910020960A (ko) | 고온 재충전성 전기화학 전력 저장 전지 | |
IT8021171A0 (it) | Procedimento e dispositivo per il funzionamento di celle a energia elevata galvaniche, acquose. |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG2A | Definitive protection |
Ref document number: 496889 Country of ref document: ES |