ES2097699B1 - Procedimiento continuo para la captacion y precipitacion simultanea de mercurio en gases que lo contienen. - Google Patents

Procedimiento continuo para la captacion y precipitacion simultanea de mercurio en gases que lo contienen.

Info

Publication number
ES2097699B1
ES2097699B1 ES09402221A ES9402221A ES2097699B1 ES 2097699 B1 ES2097699 B1 ES 2097699B1 ES 09402221 A ES09402221 A ES 09402221A ES 9402221 A ES9402221 A ES 9402221A ES 2097699 B1 ES2097699 B1 ES 2097699B1
Authority
ES
Spain
Prior art keywords
mercury
precipitation
gases containing
simultaneous collection
continuous procedure
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
ES09402221A
Other languages
English (en)
Other versions
ES2097699A1 (es
Inventor
Menendez Fernando Sitges
Tamargo Francisco Alvarez
Garcia Francisco Tamargo
Valcarcel Matias Rodriguez
Sitges Covadonga Muruzabal
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Asturiana de Zinc SA
Original Assignee
Asturiana de Zinc SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Asturiana de Zinc SA filed Critical Asturiana de Zinc SA
Priority to ES09402221A priority Critical patent/ES2097699B1/es
Priority to PE1995279153A priority patent/PE18596A1/es
Priority to EP95500125A priority patent/EP0709475A1/en
Priority to CA002158671A priority patent/CA2158671C/en
Priority to CA002158672A priority patent/CA2158672A1/en
Priority to AU32878/95A priority patent/AU692912B2/en
Priority to KR1019950035775A priority patent/KR100287744B1/ko
Priority to NO954141A priority patent/NO317171B1/no
Priority to RU95118139A priority patent/RU2139752C1/ru
Priority to CN95119137A priority patent/CN1088608C/zh
Priority to JP7300789A priority patent/JPH08206452A/ja
Priority to BR9504559A priority patent/BR9504559A/pt
Priority to US08/614,540 priority patent/US5744109A/en
Publication of ES2097699A1 publication Critical patent/ES2097699A1/es
Application granted granted Critical
Publication of ES2097699B1 publication Critical patent/ES2097699B1/es
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/64—Heavy metals or compounds thereof, e.g. mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/96—Regeneration, reactivation or recycling of reactants
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B43/00—Obtaining mercury

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Environmental & Geological Engineering (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Treating Waste Gases (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Gas Separation By Absorption (AREA)

Abstract

PROCEDIMIENTO PARA LA CAPTACION Y PRECIPITACION SIMULTANEA DE MERCURIO EN GASES QUE LO CONTIENEN. CONSISTE EN PASAR EL GAS CON MERCURIO A TRAVES DE UNA TORRE DE LAVADO DONDE SE INYECTA SULFURO DE HIDROGENO (GAS) DE FORMA CONTINUA O INTERMITENTE A LA VEZ QUE SE RIEGA CON UNA SOLUCION QUE CONTENGA UN COMPLEJO DE MERCURIO (II) ESTABLE EN MEDIO ACIDO, TAL COMO [I2HG]2- O [CSCN)4HG]2-, SIN NECESIDAD DE UTILIZAR UN OXIDANTE ADICIONAL. TANTO LA CAPTACION Y PRECIPITACION DEL MERCURIO COMO LE REGENERACION DE LA SOLUCION QUE CONTIENE EL COMPLEJO DE MERCURIO (II) TIENE LUGAR SIMULTANEAMENTE EN UNA SOLA ETAPA.
ES09402221A 1994-10-26 1994-10-26 Procedimiento continuo para la captacion y precipitacion simultanea de mercurio en gases que lo contienen. Expired - Fee Related ES2097699B1 (es)

Priority Applications (13)

Application Number Priority Date Filing Date Title
ES09402221A ES2097699B1 (es) 1994-10-26 1994-10-26 Procedimiento continuo para la captacion y precipitacion simultanea de mercurio en gases que lo contienen.
PE1995279153A PE18596A1 (es) 1994-10-26 1995-09-15 Procedimiento continuo para la captacion y precipitacion simultanea de mercurio en gases que lo contienen
EP95500125A EP0709475A1 (en) 1994-10-26 1995-09-15 Procedure to obtain mercury metal from products containing mercuric chloride
CA002158671A CA2158671C (en) 1994-10-26 1995-09-20 Continuous procedure for the simultaneous collection and precipitation of mercury in gases containing it
CA002158672A CA2158672A1 (en) 1994-10-26 1995-09-20 Procedure to obtain mercury metal from products containing mercurous chloride
AU32878/95A AU692912B2 (en) 1994-10-26 1995-09-22 Continuous procedure for the simultaneous collection and precipitation of mercury in gases containing it
KR1019950035775A KR100287744B1 (ko) 1994-10-26 1995-10-17 수은을함유하는기체중에서수은을동시에수집및석출하기위한연속방법
NO954141A NO317171B1 (no) 1994-10-26 1995-10-18 Kontinuerlig fremgangsmate for samtidig oppsamling og utfelling av kvikksolv i gasser
RU95118139A RU2139752C1 (ru) 1994-10-26 1995-10-25 Способ непрерывного и одновременного сбора и осаждения ртути из содержащих ее газов
CN95119137A CN1088608C (zh) 1994-10-26 1995-10-25 同时收集和沉淀含汞气体中汞的连续方法
JP7300789A JPH08206452A (ja) 1994-10-26 1995-10-25 水銀を含むガス中の水銀を同時に捕集、沈殿させる連続処理方法
BR9504559A BR9504559A (pt) 1994-10-26 1995-10-26 Processo continuo para a captaçao e precipitaçao simultanea de mercúrio em gases que o contem
US08/614,540 US5744109A (en) 1994-10-26 1996-03-13 Continuous procedure for the simultaneous collection and precipitation of mercury in gases containing it

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ES09402221A ES2097699B1 (es) 1994-10-26 1994-10-26 Procedimiento continuo para la captacion y precipitacion simultanea de mercurio en gases que lo contienen.

Publications (2)

Publication Number Publication Date
ES2097699A1 ES2097699A1 (es) 1997-04-01
ES2097699B1 true ES2097699B1 (es) 1997-12-16

Family

ID=8287811

Family Applications (1)

Application Number Title Priority Date Filing Date
ES09402221A Expired - Fee Related ES2097699B1 (es) 1994-10-26 1994-10-26 Procedimiento continuo para la captacion y precipitacion simultanea de mercurio en gases que lo contienen.

Country Status (12)

Country Link
US (1) US5744109A (es)
EP (1) EP0709475A1 (es)
JP (1) JPH08206452A (es)
KR (1) KR100287744B1 (es)
CN (1) CN1088608C (es)
AU (1) AU692912B2 (es)
BR (1) BR9504559A (es)
CA (2) CA2158672A1 (es)
ES (1) ES2097699B1 (es)
NO (1) NO317171B1 (es)
PE (1) PE18596A1 (es)
RU (1) RU2139752C1 (es)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6328939B1 (en) * 1999-03-31 2001-12-11 Mcdermott Technology, Inc. Mercury removal in utility wet scrubber using a chelating agent
US6503470B1 (en) * 1999-03-31 2003-01-07 The Babcock & Wilcox Company Use of sulfide-containing liquors for removing mercury from flue gases
US6855859B2 (en) 1999-03-31 2005-02-15 The Babcock & Wilcox Company Method for controlling elemental mercury emissions
KR100760236B1 (ko) 2006-02-28 2007-10-04 한국과학기술연구원 할로겐화 화합물 첨착 활성탄을 이용한 연소 설비 배출가스 중 수은의 저감 방법
RU2441905C2 (ru) * 2007-07-03 2012-02-10 Альбемарл Корпорейшн Применение соединений, содержащих галоген и азот, для снижения выбросов ртути при сжигании угля
PL2033702T3 (pl) * 2007-09-04 2011-06-30 Steag Energy Services Gmbh Sposób usuwania rtęci ze spalinowych gazów odlotowych
US11298657B2 (en) 2010-10-25 2022-04-12 ADA-ES, Inc. Hot-side method and system
US8951487B2 (en) 2010-10-25 2015-02-10 ADA-ES, Inc. Hot-side method and system
US8496894B2 (en) 2010-02-04 2013-07-30 ADA-ES, Inc. Method and system for controlling mercury emissions from coal-fired thermal processes
CN102249291B (zh) * 2011-04-07 2013-06-19 四川大学 基于羊抗人抗体为软模板控制合成纳米粒子硫化汞的方法
US8845986B2 (en) 2011-05-13 2014-09-30 ADA-ES, Inc. Process to reduce emissions of nitrogen oxides and mercury from coal-fired boilers
US8883099B2 (en) 2012-04-11 2014-11-11 ADA-ES, Inc. Control of wet scrubber oxidation inhibitor and byproduct recovery
US9957454B2 (en) 2012-08-10 2018-05-01 ADA-ES, Inc. Method and additive for controlling nitrogen oxide emissions
AU2012388418B2 (en) * 2012-08-30 2016-04-14 Metso Metals Oy Method and apparatus for removing mercury from gas
US9889451B2 (en) 2013-08-16 2018-02-13 ADA-ES, Inc. Method to reduce mercury, acid gas, and particulate emissions
CN104531231B (zh) * 2014-12-25 2017-01-25 清华大学 适合高灰分煤气化的高效复合碳黑洗涤塔
RU2632956C1 (ru) * 2016-05-06 2017-10-11 Владимир Глебович Венгерцев Устройство и способ обезвреживания ртутьсодержащих отходов

Family Cites Families (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA624090A (en) * 1961-07-18 F. Gilbert Jeffrey Recovery of mercury from aqueous solutions
FR452178A (fr) * 1912-12-19 1913-05-09 North East Electric Co Mécanisme de transmission de mouvement par engrenage
DE319476C (de) * 1918-05-14 1920-03-03 Consortium Elektrochem Ind Verfahren zur UEberfuehrung der bei katalytischen Prozessen anfallenden Quecksilberschlaemme in Quecksilber-Regulus
DE1075953B (de) * 1957-02-08 1960-02-18 Sigma Lutin Filtermasse gegen Quecksilberdaempfe
US3039865A (en) * 1959-03-20 1962-06-19 Dow Chemical Co Recovery of mercury from aqueous solutions
SE360986B (es) * 1971-02-23 1973-10-15 Boliden Ab
US4057423A (en) * 1971-09-10 1977-11-08 Mitsui Mining & Smelting Co., Ltd. Method for the manufacture of mercury free sulfuric acid
BE788615A (fr) * 1971-09-10 1973-01-02 Mitsui Mining & Smelting Co Procede de production d'acide sulfurique exempt de mercure
JPS548191B2 (es) * 1972-10-24 1979-04-13
ES411067A1 (es) * 1973-01-29 1976-01-01 Patronato De Investigacion Cie Procedimiento para depuracion del mercurio de gases meta- lurgicos conteniendo anhidrido sufuroso.
DE2305522C2 (de) * 1973-02-05 1979-06-28 Preussag Ag Metall, 3380 Goslar Verfahren zur Gewinnung von Quecksilber aus SO2 -haltigen Röstgasen
JPS5020997A (es) * 1973-06-27 1975-03-05
US3855387A (en) * 1973-09-05 1974-12-17 St Joe Minerals Corp Method for removing mercury from industrial gases
JPS5348162B2 (es) * 1974-02-27 1978-12-27
SE396772B (sv) * 1975-09-16 1977-10-03 Boliden Ab Forfarande for extraktion och utvinning av kvicksilver ur gaser
US4336237A (en) * 1980-11-03 1982-06-22 Asarco Incorporated Removal of mercury from sulfuric acid
SE432361B (sv) * 1981-05-08 1984-04-02 Boliden Ab Forfarande for avskiljning av gasformigt elementert kvicksilver ur en gas
NO157543C (no) * 1984-10-19 1988-04-06 Norzink As Fremgangsmaate ved rensing av kvikksoelvholdige gasser og samtidig gjenvinning av kvikksoelvet i metallisk form.
US4764219A (en) * 1986-10-27 1988-08-16 Mobil Oil Corporation Clean up and passivation of mercury in gas liquefaction plants
US5130108A (en) * 1989-04-27 1992-07-14 Mobil Oil Corporation Process for the production of natural gas condensate having a reduced amount of mercury from a mercury-containing natural gas wellstream
US4985137A (en) * 1989-04-27 1991-01-15 Mobil Oil Corporation Process for the removal of mercury from natural gas condensate
ES2021960A6 (es) * 1990-03-05 1991-11-16 Consejo Superior Investigacion Procedimiento para la depuracion y recuperacion de mercurio en forma metalica a partir de gases de tostacion que lo contienen.
FR2660936B1 (fr) * 1990-04-13 1992-09-11 Vieille Montagne France Sa Procede de preparation de mercure metallique a partir de calomel.
US5120515A (en) * 1991-01-22 1992-06-09 Mobil Oil Corporation Simultaneous dehydration and removal of residual impurities from gaseous hydrocarbons

Also Published As

Publication number Publication date
CA2158671A1 (en) 1996-04-27
JPH08206452A (ja) 1996-08-13
CN1133201A (zh) 1996-10-16
BR9504559A (pt) 1997-02-25
PE18596A1 (es) 1996-05-27
KR100287744B1 (ko) 2001-04-16
CA2158672A1 (en) 1996-04-27
ES2097699A1 (es) 1997-04-01
US5744109A (en) 1998-04-28
NO954141L (no) 1996-04-29
EP0709475A1 (en) 1996-05-01
AU3287895A (en) 1996-05-09
CA2158671C (en) 2001-07-31
NO317171B1 (no) 2004-09-06
NO954141D0 (no) 1995-10-18
KR960013434A (ko) 1996-05-22
CN1088608C (zh) 2002-08-07
AU692912B2 (en) 1998-06-18
RU2139752C1 (ru) 1999-10-20

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