ES2068451T3 - Catalizador a base de oxidos de hierro y de antimonio y procedimiento de fabricacion de este. - Google Patents

Catalizador a base de oxidos de hierro y de antimonio y procedimiento de fabricacion de este.

Info

Publication number
ES2068451T3
ES2068451T3 ES91115741T ES91115741T ES2068451T3 ES 2068451 T3 ES2068451 T3 ES 2068451T3 ES 91115741 T ES91115741 T ES 91115741T ES 91115741 T ES91115741 T ES 91115741T ES 2068451 T3 ES2068451 T3 ES 2068451T3
Authority
ES
Spain
Prior art keywords
sum
group
selected element
iron
antimony
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES91115741T
Other languages
English (en)
Inventor
Yutaka C O Nitto Chem I Sasaki
Hiroshi C O Nitto Chem Utsumi
Kenichi C O Nitto Chem Miyaki
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nitto Chemical Industry Co Ltd
Original Assignee
Nitto Chemical Industry Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nitto Chemical Industry Co Ltd filed Critical Nitto Chemical Industry Co Ltd
Application granted granted Critical
Publication of ES2068451T3 publication Critical patent/ES2068451T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
    • C01C3/00—Cyanogen; Compounds thereof
    • C01C3/02—Preparation, separation or purification of hydrogen cyanide
    • C01C3/0208—Preparation in gaseous phase
    • C01C3/0212—Preparation in gaseous phase from hydrocarbons and ammonia in the presence of oxygen, e.g. the Andrussow-process
    • C01C3/0216—Preparation in gaseous phase from hydrocarbons and ammonia in the presence of oxygen, e.g. the Andrussow-process characterised by the catalyst used
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/881—Molybdenum and iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8876—Arsenic, antimony or bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8877—Vanadium, tantalum, niobium or polonium
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
    • C01C3/00—Cyanogen; Compounds thereof
    • C01C3/02—Preparation, separation or purification of hydrogen cyanide
    • C01C3/0208—Preparation in gaseous phase
    • C01C3/0241—Preparation in gaseous phase from alcohols or aldehydes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

UNA COMPOSICION DE HIERRO DE ANIMONIO CONTENIENDO UN CATALIZADOR DE OXIDO DE METAL INCLUYE COMO COMPONENTE ESENCIAL HIERRO, ANTIMONIO, Y AL MENOS UN ELEMENTO SELECCIONADO DEL GRUPO CONSISTENTE EN VANADIO, MOLIBDENO, Y TUNGTENO, Y UN PROCESO PARA LA PRODUCCION DE LO MISMO SON REVELADOS, LA COMPOSICION ESTANDO REPRESENTADA POR LA FORMULA EMPIRICA: EN DONDE Q REPRESENTA AL MENOS UN ELEMENTO SELECCIONADO DEL GRUPO CONSISTENTE EN LI, NA, K, RB, CS, BE, MG, CA, SR, BA, SC, Y, LA, CE, PR, ND , SM, TH, U, TI, ZR, HF, NB, TA, CR, MN, RE, CO, NI, RU, RH, PD, OS, IR, PT , CU, AG, AU, ZN, CD, HG, AL, GA, IN, TI, GE, SN, Y PB; R REPRESENTA AL MENOS UN ELEMENTO SELECCIONADO DEL GRUPO CONSISTENTE EN B, AS, BI, Y SE; Y A, B, C, D, E, F, G, H, Y I CADA UNO REPRESENTA UNA RAZON ATOMICA DEL ELEMENTO RESPECTIVO, EN DONDE A ESTA ENTRE 5-15, B ESTA ENTRE 5-100, LA SUMA DE C, D, Y E ESTA ENTRE 3-15, CONSIDERANDO QUE (I) CUANDO LA SUMA C Y E ES 0, D/A ES MAS DE 1, (II) CUANDO LA SUMA DE C Y E NO ES 0, (C + E)/A ESMAS DE 0.3, F ESTA ENTRE 0-15, LA SUMA DE G Y H ESTA ENTRE 0-10, CONSIDERANDO QUE CUANDO H NO ES 0, (C + D + E)/H ES MAYOR DE 1, Y I ES UN NUMERO DE ATOMOS DE OXIGENO CORRESPONDIENTE A LOS OXIDOS FORMADOS POR LA COMBINACION DE LOS COMPONENTES ARRIBA MENCIONADOS, Y DICHA COMPOSICION DE CATALISIS CONTIENE UN ANTIMONATO DE HIERRO CRISTALINO. EL PROCESO INCLUYE LA PREPARACION DE UNA LECHADA CONTENIENDO ESENCIALMENTE (I) ANTIMONATO DE HIERRO CRISTALINO Y (II) AL MENOS UN ELEMENTO SELECCIONADO DEL GRUPO CONSISTENTE EN VANADIO, MOLIBDENO Y TUNGSTENO Y OPCIONALMENTE CONTENIENDO (III) AL MENOS UN ELEMENTO SELECCIONADO DEL GRUPO CONSISTENTE EN LOS ELEMENTOS DE CATALISIS REPRESENTADOS POR Q, R, Y P, SECANDO LA LECHADA ACUOSA, Y CALCINANDO UN MATERIAL DESECADO. EL CATALIZADOR MUESTRA EXCELENTES PROPIEDADES DE ACTIVIDAD Y FISICAS. EL PROCESO TIENE REPRODUCIBILIDAD PERFECCIONADA.
ES91115741T 1990-09-18 1991-09-17 Catalizador a base de oxidos de hierro y de antimonio y procedimiento de fabricacion de este. Expired - Lifetime ES2068451T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP24630590A JP3371112B2 (ja) 1990-09-18 1990-09-18 鉄・アンチモン含有金属酸化物触媒組成物およびその製法

Publications (1)

Publication Number Publication Date
ES2068451T3 true ES2068451T3 (es) 1995-04-16

Family

ID=17146582

Family Applications (1)

Application Number Title Priority Date Filing Date
ES91115741T Expired - Lifetime ES2068451T3 (es) 1990-09-18 1991-09-17 Catalizador a base de oxidos de hierro y de antimonio y procedimiento de fabricacion de este.

Country Status (5)

Country Link
US (1) US5139988A (es)
EP (1) EP0476579B1 (es)
JP (1) JP3371112B2 (es)
DE (1) DE69105890T2 (es)
ES (1) ES2068451T3 (es)

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4428595A1 (de) * 1994-08-12 1996-02-15 Basf Ag Für die Ammonoxidation geeignete Trägerkatalysatoren
US5498588A (en) * 1994-09-09 1996-03-12 The Standard Oil Company Surface modification and promotion of vanadium antimony oxide catalysts
US5840648A (en) * 1997-09-02 1998-11-24 The Standard Oil Company Catalyst for the manufacture of acrylonitrile and hydrogen cyanide
DE69920437T2 (de) * 1998-04-23 2005-10-06 Mitsubishi Rayon Co., Ltd. Katalysator zur herstellung von ungesättigten nitrilen
US6235678B1 (en) 1999-06-11 2001-05-22 Saudi Basic Industries Corporation Catalyst system for oxidative dehydrogenation of paraffins
JP2001029788A (ja) * 1999-07-21 2001-02-06 Mitsubishi Rayon Co Ltd モリブデン−ビスマス−鉄含有金属酸化物流動層触媒の製法
KR100731944B1 (ko) * 1999-10-18 2007-06-25 미쯔비시 레이온 가부시끼가이샤 아크릴로니트릴의 제조 방법, 여기에 사용되는 촉매, 및그 촉매의 제조 방법
JP4030740B2 (ja) * 2001-10-11 2008-01-09 ダイヤニトリックス株式会社 アンモ酸化用触媒の製造方法
US7649111B2 (en) 2005-07-25 2010-01-19 Saudi Basic Industries Corporation Catalyst for the oxidation of a mixed aldehyde feedstock to methacrylic acid and methods for making and using same
US7732367B2 (en) 2005-07-25 2010-06-08 Saudi Basic Industries Corporation Catalyst for methacrolein oxidation and method for making and using same
US7851397B2 (en) 2005-07-25 2010-12-14 Saudi Basic Industries Corporation Catalyst for methacrolein oxidation and method for making and using same
US7649112B2 (en) 2005-07-25 2010-01-19 Saudi Basic Industries Corporation Integrated plant for producing 2-ethyl-hexanol and methacrylic acid and a method based thereon
EP2021125A1 (de) * 2006-04-28 2009-02-11 Basf Se Neuer trägerkatalysator für die ammonoxidation
FR2931477B1 (fr) * 2008-05-21 2012-08-17 Arkema France Acide cyanhydrique derive de matiere premiere renouvable
FR2938838B1 (fr) 2008-11-27 2012-06-08 Arkema France Procede de fabrication d'un methacrylate de methyle derive de la biomasse
CN102219711A (zh) * 2010-04-15 2011-10-19 中国石油化工股份有限公司 用于制备间苯二甲腈的方法
CN102219710A (zh) * 2010-04-15 2011-10-19 中国石油化工股份有限公司 用于制备苯甲腈的方法
JP5609254B2 (ja) * 2010-05-14 2014-10-22 三菱レイヨン株式会社 複合酸化物触媒の製造方法
US8921257B2 (en) 2011-12-02 2014-12-30 Saudi Basic Industries Corporation Dual function partial oxidation catalyst for propane to acrylic acid conversion
US8722940B2 (en) 2012-03-01 2014-05-13 Saudi Basic Industries Corporation High molybdenum mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins
SG11201405984TA (en) 2012-03-29 2014-10-30 Tpc Group Llc Low emissions oxidative dehydrogenation process for producing butadiene

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3591620A (en) * 1967-11-28 1971-07-06 Nitto Chemical Industry Co Ltd Process for producing acrylonitrile
DE1939633C3 (de) * 1968-08-05 1975-03-13 Nitto Chemical Industry Co. Ltd., Tokio Verfahren zur Herstellung von abriebsbeständigen, festen ein Antimonoxyd enthaltenden Katalysatoren, die für Wirbelschichtbettumsetzungen geeignet sind
JPS5318014B2 (es) * 1974-02-09 1978-06-13
JPS52125124A (en) * 1976-04-10 1977-10-20 Nitto Chem Ind Co Ltd Manufacture of acrylonitrile
DE2909597A1 (de) * 1979-03-12 1980-09-25 Basf Ag Verfahren zur herstellung von 3 bis 4 c-atome enthaltenden alpha , beta -olefinisch ungesaettigten aldehyden
JPS5647456A (en) * 1979-09-26 1981-04-30 Dainippon Ink & Chem Inc Resin composition for powder coating material
JPS5715842A (en) * 1980-06-30 1982-01-27 Nitto Chem Ind Co Ltd Manufacture of highly active fluid catalyst from coarse grained catalyst
DE3270713D1 (en) * 1982-02-15 1986-05-28 Standard Oil Co Ohio Production of catalysts by impregnation and use thereof in oxidation type reactions
US4814478A (en) * 1987-04-20 1989-03-21 The Standard Oil Company Method for ammoxidation of paraffins and catalyst system therefor
JP2950851B2 (ja) * 1989-06-23 1999-09-20 三菱レイヨン株式会社 鉄・アンチモン・リン含有金属酸化物触媒組成物およびその製法

Also Published As

Publication number Publication date
EP0476579A1 (en) 1992-03-25
DE69105890D1 (de) 1995-01-26
JP3371112B2 (ja) 2003-01-27
EP0476579B1 (en) 1994-12-14
US5139988A (en) 1992-08-18
DE69105890T2 (de) 1995-05-18
JPH04126548A (ja) 1992-04-27

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