ES2059176T3 - Catalizadores de oxidacion conteniendo molibdeno, fosforo y vanadio con canales formados de materiales de fibra combustibles. - Google Patents
Catalizadores de oxidacion conteniendo molibdeno, fosforo y vanadio con canales formados de materiales de fibra combustibles.Info
- Publication number
- ES2059176T3 ES2059176T3 ES92106755T ES92106755T ES2059176T3 ES 2059176 T3 ES2059176 T3 ES 2059176T3 ES 92106755 T ES92106755 T ES 92106755T ES 92106755 T ES92106755 T ES 92106755T ES 2059176 T3 ES2059176 T3 ES 2059176T3
- Authority
- ES
- Spain
- Prior art keywords
- oxidation
- vanadium
- phosphorus
- catalysts
- oxidation catalysts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
- C07C51/377—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/002—Mixed oxides other than spinels, e.g. perovskite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
- B01J27/198—Vanadium
- B01J27/199—Vanadium with chromium, molybdenum, tungsten or polonium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
- B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
- C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
- C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/37—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
- C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Abstract
LA INVENCION CONCIERNE A CATALIZADORES POR OXIDACION CON MOLIBDENO, FOSFORO Y VANADIO COMO ELEMENTOS ESENCIALES EN FORMA DE OXIDO COMO MATERIAL ACTIVO PARA LA OXIDACION DE FASES GASEOSAS DE COMPUESTOS ORGANICOS, EN QUE PARA DARLES FORMA SE ELABORAN MATERIALES FIBROSOS COMBUSTIBLES, COMO FIBRAS DE CARBONO O FIBRAS DE POLIMEROS ORGANICOS, NATURALES O SINTETICOS EN CANTIDADES DE 0,5 A 5% EN PESO REFERIDO AL MATERIAL ACTIVO CATALITICO, FINAMENTE DISTRIBUIDO, Y QUE DESPUES DE QUEMAN EN UN MARGEN DE TEMPERATURA DE 100 A 380 GRADOS C A PARTIR DE LAS FORMAS EN PRESENCIA DE OXIGENO. LOS CATALIZADORES CON SUPERFICIES INTERIORES DE APROX. 0,1 A 5 M2/G MUESTRAN EN LA OXIDACION DE PROPILENO O ISOBUTILENO EN ACROLEINA O METACROLEINA O EN SU OXIDACION POSTERIOR A ACIDO ACRILICO O ACIDO METACRILICO O EN LA OXIHIDROGENACION DE ACIDO ISOBUTILICO O SUS ESTERES EN ACIDO METACRILICO O SUS ESTERES, UN COMPORTAMIENTO DE ACTIVIDAD SELECTIVO Y MEJORADO.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4113423A DE4113423A1 (de) | 1991-04-25 | 1991-04-25 | Mit makroporen durchsetzter oxidationskatalysator |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2059176T3 true ES2059176T3 (es) | 1994-11-01 |
Family
ID=6430285
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES92106755T Expired - Lifetime ES2059176T3 (es) | 1991-04-25 | 1992-04-21 | Catalizadores de oxidacion conteniendo molibdeno, fosforo y vanadio con canales formados de materiales de fibra combustibles. |
Country Status (6)
Country | Link |
---|---|
US (1) | US5215952A (es) |
EP (1) | EP0510566B1 (es) |
JP (1) | JPH05138028A (es) |
AT (1) | ATE109380T1 (es) |
DE (2) | DE4113423A1 (es) |
ES (1) | ES2059176T3 (es) |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5550095A (en) * | 1992-05-08 | 1996-08-27 | Mitsubishi Rayon Co., Ltd. | Process for producing catalyst used for synthesis of methacrylic acid |
DE4240085A1 (de) * | 1992-11-28 | 1994-06-01 | Roehm Gmbh | Katalytische Oxidation von Isobutan zu Methacrylsäure und Methacrolein |
FR2716634B1 (fr) * | 1994-02-28 | 1996-04-05 | Atochem Elf Sa | Système catalytique contenant de l'oxygène, du molybdène, du phosphore et au moins un métal de transition, et son application à l'oxydéshydrogénation d'acides carboxyliques saturés ou de leurs esters. |
US5510308A (en) * | 1994-10-19 | 1996-04-23 | E. I. Du Pont De Nemours And Company | Cation and vanadium substituted heteropolyacid catalysts for vapor phase oxidation |
US6228340B1 (en) | 1997-08-25 | 2001-05-08 | The Regents Of The University Of California | Method for the production of macroporous ceramics |
US5840648A (en) * | 1997-09-02 | 1998-11-24 | The Standard Oil Company | Catalyst for the manufacture of acrylonitrile and hydrogen cyanide |
JP3702710B2 (ja) * | 1999-06-15 | 2005-10-05 | 住友化学株式会社 | メタクリル酸製造用触媒およびメタクリル酸の製造方法 |
US7732367B2 (en) * | 2005-07-25 | 2010-06-08 | Saudi Basic Industries Corporation | Catalyst for methacrolein oxidation and method for making and using same |
JP5301110B2 (ja) * | 2007-05-15 | 2013-09-25 | 三菱レイヨン株式会社 | メタクロレインの製造方法 |
CN103861640B (zh) * | 2014-03-13 | 2015-07-29 | 万华化学集团股份有限公司 | 一种杂多酸催化剂及其制备方法 |
CN105772087B (zh) * | 2014-12-26 | 2019-03-22 | 上海华谊新材料有限公司 | 杂多酸盐催化剂及其制备方法 |
CN109985649B (zh) * | 2018-01-02 | 2021-05-04 | 上海华谊新材料有限公司 | (甲基)丙烯醛氧化催化剂及其制备方法 |
SG11202008534XA (en) * | 2018-03-14 | 2020-10-29 | Mitsubishi Chem Corp | Catalyst molded body, and method for producing unsaturated aldehyde and unsaturated carboxylic acid using same |
Family Cites Families (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA943944A (en) * | 1967-10-27 | 1974-03-19 | Michael C. Chervenak | Catalysts, methods of preparation of same and processes for using same |
FR1582730A (es) * | 1967-10-31 | 1969-10-03 | ||
JPS52138499A (en) * | 1976-05-17 | 1977-11-18 | Mitsubishi Chem Ind Ltd | Production of heteropolyacid |
US4092269A (en) * | 1976-10-15 | 1978-05-30 | Monsanto Company | Phosphorus-vanadium-oxygen catalysts having a specific pore volume |
DE2962547D1 (en) * | 1978-05-31 | 1982-06-03 | Nippon Kayaku Kk | A process for producing methacrolein and methacrylic acid |
JPS55124734A (en) * | 1979-03-22 | 1980-09-26 | Nippon Kayaku Co Ltd | Preparation of methacrylic acid |
US4329520A (en) * | 1980-03-21 | 1982-05-11 | Union Carbide Corporation | Process and catalyst for olefin hydration |
DE3145091A1 (de) * | 1981-11-13 | 1983-05-19 | Röhm GmbH, 6100 Darmstadt | Verfahren zur herstellung von methacrylsaeure |
DE3248600A1 (de) * | 1982-12-30 | 1984-07-12 | Röhm GmbH, 6100 Darmstadt | Verwendung von mo-v-cu-p-katalysatoren zur oxydehydrierung von isobuttersaeure oder deren estern |
JPS60150834A (ja) * | 1984-01-17 | 1985-08-08 | Nippon Shokubai Kagaku Kogyo Co Ltd | メタクリル酸合成用触媒の製造法 |
DE3508649A1 (de) * | 1985-03-12 | 1986-09-18 | Röhm GmbH, 6100 Darmstadt | Heteropolysaeure h(pfeil abwaerts)8(pfeil abwaerts)pmo(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)0(pfeil abwaerts)vo(pfeil abwaerts)3(pfeil abwaerts)(pfeil abwaerts)9(pfeil abwaerts), deren anhydrid pmo(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)0(pfeil abwaerts)vo(pfeil abwaerts)3(pfeil abwaerts)(pfeil abwaerts)5(pfeil abwaerts)und ihre verwendung |
JPS62201643A (ja) * | 1986-02-28 | 1987-09-05 | Nippon Oil Co Ltd | 水素化触媒の製造法 |
DE3626256A1 (de) * | 1986-08-02 | 1988-02-11 | Roehm Gmbh | Heteropolymolybdat-gemische und ihre verwendung als katalysatoren |
JPH0753686B2 (ja) * | 1986-10-27 | 1995-06-07 | 三菱レイヨン株式会社 | メタクリル酸の製造法 |
DE3710784A1 (de) * | 1987-03-31 | 1988-10-13 | Roehm Gmbh | Heteropolysaeure-oxidations-katalysatoren mit verbessertem langzeit-aktivitaets-verhalten |
US4968877A (en) * | 1988-09-14 | 1990-11-06 | Sensor Frame Corporation | VideoHarp |
DE3844087A1 (de) * | 1988-12-28 | 1990-07-05 | Basf Ag | Verfahren zur herstellung von methacrylsaeure durch oxidation von methacrolein |
DD284947A5 (de) * | 1989-09-28 | 1990-11-28 | Veb Maschinen- Und Apparatebau,Dd | Zentralelastisch gelagertes ventilatoraggregat mit spiralgehaeuse und keilriemenantrieb |
-
1991
- 1991-04-25 DE DE4113423A patent/DE4113423A1/de not_active Withdrawn
-
1992
- 1992-04-21 DE DE59200339T patent/DE59200339D1/de not_active Expired - Fee Related
- 1992-04-21 EP EP92106755A patent/EP0510566B1/de not_active Expired - Lifetime
- 1992-04-21 ES ES92106755T patent/ES2059176T3/es not_active Expired - Lifetime
- 1992-04-21 AT AT92106755T patent/ATE109380T1/de active
- 1992-04-22 JP JP4102909A patent/JPH05138028A/ja active Pending
- 1992-04-24 US US07/873,373 patent/US5215952A/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
ATE109380T1 (de) | 1994-08-15 |
EP0510566B1 (de) | 1994-08-03 |
DE4113423A1 (de) | 1992-10-29 |
US5215952A (en) | 1993-06-01 |
DE59200339D1 (de) | 1994-09-08 |
EP0510566A1 (de) | 1992-10-28 |
JPH05138028A (ja) | 1993-06-01 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG2A | Definitive protection |
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