ES2052875T3 - Procedimiento para preparar acido carboxilico insaturado o sus esteres. - Google Patents
Procedimiento para preparar acido carboxilico insaturado o sus esteres.Info
- Publication number
- ES2052875T3 ES2052875T3 ES89122983T ES89122983T ES2052875T3 ES 2052875 T3 ES2052875 T3 ES 2052875T3 ES 89122983 T ES89122983 T ES 89122983T ES 89122983 T ES89122983 T ES 89122983T ES 2052875 T3 ES2052875 T3 ES 2052875T3
- Authority
- ES
- Spain
- Prior art keywords
- unsaturated carboxylic
- carboxylic acid
- beta
- alpha
- ester
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 150000001732 carboxylic acid derivatives Chemical class 0.000 title abstract 4
- 238000000034 method Methods 0.000 title abstract 3
- 239000002253 acid Substances 0.000 abstract 2
- 229910000323 aluminium silicate Inorganic materials 0.000 abstract 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000006555 catalytic reaction Methods 0.000 abstract 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 abstract 1
- 239000002994 raw material Substances 0.000 abstract 1
- 238000004326 stimulated echo acquisition mode for imaging Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
- C07C57/02—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
- C07C51/377—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
- C07C67/317—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups
- C07C67/327—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups by elimination of functional groups containing oxygen only in singly bound form
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
PROCESO PARA LA PREPARACION DE UN ACIDO CARBOXILICO (ALFA) Y (BETA) SIN SATURAR Y/O UN ESTER DE ACIDO CARBOXILICO (ALFA) Y (BETA) SIN SATURAR, PROCEDENTES DE AL MENOS UN ESTER SELECCIONADO DE UN ESTER DE ACIDO HIDROXICARBOXILICO (ALFA), UN ESTER DE ACIDO ALCOXICARBOXILICO (ALFA) Y UN ESTER DE ACIDO ALCOXICARBOXILICO (BETA) COMO MATERIA PRIMA MEDIANTE UNA REACCION CATALITICA EN FASE DE VAPOR CON PRESENCIA DE UN ALUMINOSILICATO CRISTALINO COMO CATALIZADOR. SEGUN EL PROCESO, EL ACIDO CARBOXILICO (ALFA) Y (BETA) SIN SATURAR Y/O SU ESTER CORRESPONDIENTE PUEDEN PRODUCIRSE BAJO CONDICIONES MODERADAS Y EN GRANDES CANTIDADES.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1015110A JP2727618B2 (ja) | 1989-01-26 | 1989-01-26 | 不飽和カルボン酸エステルの製造方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| ES2052875T3 true ES2052875T3 (es) | 1994-07-16 |
| ES2052875T5 ES2052875T5 (es) | 2001-06-16 |
Family
ID=11879692
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES89122983T Expired - Lifetime ES2052875T5 (es) | 1989-01-26 | 1989-12-13 | Procedimiento para preparar acido carboxilico insaturado o sus esteres. |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US5250729A (es) |
| EP (1) | EP0379691B2 (es) |
| JP (1) | JP2727618B2 (es) |
| KR (1) | KR950004038B1 (es) |
| DE (1) | DE68913714T3 (es) |
| ES (1) | ES2052875T5 (es) |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2727618B2 (ja) † | 1989-01-26 | 1998-03-11 | 三菱瓦斯化学株式会社 | 不飽和カルボン酸エステルの製造方法 |
| JP2884639B2 (ja) * | 1989-11-28 | 1999-04-19 | 三菱瓦斯化学株式会社 | 不飽和カルボン酸エステルの製造法 |
| JP2906547B2 (ja) * | 1990-03-15 | 1999-06-21 | 三菱瓦斯化学株式会社 | α,β―不飽和カルボン酸エステルの製造方法 |
| JP3189858B2 (ja) * | 1992-11-16 | 2001-07-16 | 三菱瓦斯化学株式会社 | メタクリル酸メチルの製造法 |
| US5393918A (en) * | 1993-12-02 | 1995-02-28 | Rohm And Haas Company | High yield process for the production of methacrylic acid esters |
| JP3520878B2 (ja) * | 1995-01-10 | 2004-04-19 | 三菱瓦斯化学株式会社 | メタクリル酸メチルの製造方法 |
| EP1186592A1 (en) * | 2000-09-11 | 2002-03-13 | Mitsubishi Gas Chemical Company, Ltd. | Production of methacrylates |
| US6545175B1 (en) | 2000-10-19 | 2003-04-08 | Battelle Memorial Institute | Ester compounds and their use in forming acrylates |
| US6992209B2 (en) * | 2002-12-09 | 2006-01-31 | Battelle Memorial Institute | Methods of forming alpha, beta-unsaturated acids and esters |
| EP1732874A1 (en) * | 2004-04-02 | 2006-12-20 | Ciba Speciality Chemicals Water Treatments Limited | Preparation of acrylic acid derivatives from alpha or beta-hydroxy carboxylic acids |
| US7687661B2 (en) * | 2006-03-15 | 2010-03-30 | Battelle Memorial Institute | Method for conversion of β-hydroxy carbonyl compounds |
| US20070219397A1 (en) * | 2006-03-15 | 2007-09-20 | Battelle Memorial Institute | Method for conversion of beta-hydroxy carbonyl compounds |
| WO2012047883A1 (en) | 2010-10-07 | 2012-04-12 | Rohm And Haas Company | Process for production of methacrylic acid ester |
| US9029596B2 (en) | 2010-12-28 | 2015-05-12 | Nippon Shokubai Co., Ltd. | Methods for producing acrylic acid and/or ester thereof and polymer of the acrylic acid and/or ester thereof |
| WO2013184345A1 (en) | 2012-06-04 | 2013-12-12 | Rohm And Haas Company | Process for production of methacrylic acid esters |
| US20160102043A1 (en) | 2013-06-26 | 2016-04-14 | Rohm And Haas Company | Process for production of methacrylic acid esters |
| US9630904B2 (en) | 2013-12-24 | 2017-04-25 | Mitsubishi Gas Chemical Company, Inc. | Catalyst for use in production of methyl methacrylate, and method for producing methyl methacrylate |
| EP3130400B1 (en) | 2014-04-10 | 2019-01-02 | Mitsubishi Gas Chemical Company, Inc. | Molded catalyst for use in manufacture of methyl methacrylate, and method for manufacture of methyl methacrylate using same |
| WO2016026763A1 (en) | 2014-08-18 | 2016-02-25 | Basf Se | Process for preparing acrylic acid using a heterogeneous alumina catalyst |
| JP2021503444A (ja) * | 2017-11-17 | 2021-02-12 | ピュラック バイオケム ビー. ブイ. | 乳酸メチルからアクリル酸メチルを製造する方法 |
| KR20220132671A (ko) | 2020-04-03 | 2022-09-30 | 누리온 케미칼즈 인터내셔널 비.브이. | 생물-기반 단량체로부터 제조된 열 팽창성 미소구체 |
| EP4126334A1 (en) | 2020-04-03 | 2023-02-08 | Nouryon Chemicals International B.V. | Thermally expandable microspheres prepared from bio-based monomers |
| KR102448165B1 (ko) | 2020-10-21 | 2022-09-28 | 한국화학연구원 | 활성 및 안정성이 향상된 젖산 탈수 반응용 촉매, 이의 제조방법 및 이를 적용한 아크릴산 제조방법 |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB539163A (en) † | 1940-03-08 | 1941-08-29 | Distillers Co Yeast Ltd | Improvements in or relating to the production of halogenated organic compounds |
| GB584607A (en) * | 1943-04-15 | 1947-01-20 | Charles Weizmann | Process for the preparation of methacrylic acid and its esters |
| FR1080212A (fr) † | 1952-07-01 | 1954-12-07 | Ru Tgerswerke Ag | Procédé pour la fabrication d'éthers de l'acide acrylique |
| US3657331A (en) * | 1969-06-10 | 1972-04-18 | Sir Soc Italiana Resine Spa | Process for preparing acrylic or methacrylic acid |
| DE2411440B2 (de) * | 1974-03-11 | 1977-12-15 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von methacrylsaeure und butyrolacton |
| JPS57149239A (en) * | 1981-03-13 | 1982-09-14 | Mitsubishi Gas Chem Co Inc | Preparation of methacrylic acid |
| DE3364195D1 (en) * | 1982-09-07 | 1986-07-24 | British Petroleum Co Plc | Improved method of preparing crystalline aluminosilicates |
| US4613684A (en) † | 1983-10-06 | 1986-09-23 | Mitsubishi Gas Chemical Company, Inc. | Process for the preparation of carboxylic acid esters |
| JPS6078939A (ja) * | 1983-10-06 | 1985-05-04 | Mitsubishi Gas Chem Co Inc | メタアクリル酸メチルの製造法 |
| JPS60184047A (ja) * | 1984-02-13 | 1985-09-19 | イー・アイ・デユポン・ド・ネモアース・アンド・コンパニー | メタクリル酸エステルの製造方法 |
| JPS6172727A (ja) * | 1984-09-17 | 1986-04-14 | Nippon Sheet Glass Co Ltd | スチレンの製造方法 |
| JP2727618B2 (ja) † | 1989-01-26 | 1998-03-11 | 三菱瓦斯化学株式会社 | 不飽和カルボン酸エステルの製造方法 |
-
1989
- 1989-01-26 JP JP1015110A patent/JP2727618B2/ja not_active Expired - Lifetime
- 1989-12-04 US US07/445,543 patent/US5250729A/en not_active Expired - Lifetime
- 1989-12-13 EP EP89122983A patent/EP0379691B2/en not_active Expired - Lifetime
- 1989-12-13 ES ES89122983T patent/ES2052875T5/es not_active Expired - Lifetime
- 1989-12-13 DE DE68913714T patent/DE68913714T3/de not_active Expired - Lifetime
-
1990
- 1990-01-24 KR KR1019900000913A patent/KR950004038B1/ko not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPH02196753A (ja) | 1990-08-03 |
| KR900011702A (ko) | 1990-08-01 |
| DE68913714D1 (de) | 1994-04-14 |
| EP0379691A1 (en) | 1990-08-01 |
| JP2727618B2 (ja) | 1998-03-11 |
| KR950004038B1 (ko) | 1995-04-22 |
| EP0379691B1 (en) | 1994-03-09 |
| DE68913714T3 (de) | 2001-04-19 |
| EP0379691B2 (en) | 2001-01-03 |
| DE68913714T2 (de) | 1994-06-23 |
| ES2052875T5 (es) | 2001-06-16 |
| US5250729A (en) | 1993-10-05 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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