ES2050844T3 - Un procedimiento y un dispositivo para la preparacion de microesferas termoplasticas expandidas. - Google Patents
Un procedimiento y un dispositivo para la preparacion de microesferas termoplasticas expandidas.Info
- Publication number
- ES2050844T3 ES2050844T3 ES89850198T ES89850198T ES2050844T3 ES 2050844 T3 ES2050844 T3 ES 2050844T3 ES 89850198 T ES89850198 T ES 89850198T ES 89850198 T ES89850198 T ES 89850198T ES 2050844 T3 ES2050844 T3 ES 2050844T3
- Authority
- ES
- Spain
- Prior art keywords
- expanded
- microspheres
- heating
- procedure
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B13/00—Conditioning or physical treatment of the material to be shaped
- B29B13/02—Conditioning or physical treatment of the material to be shaped by heating
- B29B13/021—Heat treatment of powders
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
- B29C44/34—Auxiliary operations
- B29C44/3442—Mixing, kneading or conveying the foamable material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
- B29C44/34—Auxiliary operations
- B29C44/3461—Making or treating expandable particles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2027/00—Use of polyvinylhalogenides or derivatives thereof as moulding material
- B29K2027/12—Use of polyvinylhalogenides or derivatives thereof as moulding material containing fluorine
- B29K2027/18—PTFE, i.e. polytetrafluoroethylene, e.g. ePTFE, i.e. expanded polytetrafluoroethylene
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S425/00—Plastic article or earthenware shaping or treating: apparatus
- Y10S425/055—Polytetrafluoroethylene, i.e. PTFE
Landscapes
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Manufacturing Of Micro-Capsules (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
LA PRESENTE INVENCION SE REFIERE A UN METODO PARA PRODUCIR MICROESFERAS TERMOPLASTICAS EXPANDIDAS POR CALENTAMIENTO. LAS MICROESFERAS NO EXPANDIDAS SE SECAN POR AGITACION A UN CONTENIDO EN SOLIDOS SECOS QUE EXCEDE DE 98 % EN PESO, PREFERIBLEMENTE 99 % EN PESO, ANTES DE CALENTAMIENTO. LAS MICROESFERAS SECAS SE PUEDEN REHUMEDECER Y LUEGO EXPANDIR POR CALENTAMIENTO. LA MICROESFERAS ASI PRODUCIDAS CONTIENEN CANTIDADES DE AGLOMERADOS SOLO SIN IMPORTANCIA. LA INVENCION TAMBIEN COMPRENDE UN APARATO PARA EXPANDIR LAS ESFERAS SECAS. EL APARATO TIENE UNA CINTA TRANSPORTADORA (A), UN DISPOSITIVO (B) PARA CALENTAR POR IR, UN DISPOSITIVO DE DOSIFICACION (C) DE ESFERAS EXPANDIDAS, Y UN DISPOSITIVO COLECTOR (D) DE ESFERAS EXPANDIDAS.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SE8802387A SE8802387D0 (sv) | 1988-06-23 | 1988-06-23 | Forfarande for framstellning av expanderade termoplastiska mikrosferer |
| SE8900541A SE8900541L (en) | 1988-06-23 | 1989-02-16 | Producing expanded thermoplastic microspheres without agglomerates - by driving unexpanded microspheres under agitation before heating |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2050844T3 true ES2050844T3 (es) | 1994-06-01 |
Family
ID=26660243
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES89850198T Expired - Lifetime ES2050844T3 (es) | 1988-06-23 | 1989-06-15 | Un procedimiento y un dispositivo para la preparacion de microesferas termoplasticas expandidas. |
Country Status (14)
| Country | Link |
|---|---|
| US (2) | US5484815A (es) |
| EP (1) | EP0348372B1 (es) |
| JP (1) | JPH0829245B2 (es) |
| KR (1) | KR100196539B1 (es) |
| AT (1) | ATE101823T1 (es) |
| AU (1) | AU620879B2 (es) |
| CA (1) | CA1329685C (es) |
| DE (1) | DE68913235T2 (es) |
| DK (1) | DK173520B1 (es) |
| ES (1) | ES2050844T3 (es) |
| FI (1) | FI95354C (es) |
| NO (1) | NO177089C (es) |
| NZ (1) | NZ229644A (es) |
| PT (1) | PT90950B (es) |
Families Citing this family (69)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5792398A (en) * | 1991-06-12 | 1998-08-11 | Glasis Holding Ab | Hot pressing method of forming a composite laminate containing expanded thermoplastic particles |
| FR2722095B1 (fr) | 1994-07-11 | 1996-08-30 | Oreal | Composition gommante contenant des particules de polymere expanse |
| FR2722102B1 (fr) | 1994-07-11 | 1996-08-23 | Cird Galderma | Utilisation de particules creuses deformables dans une composition cosmetique et/ou dermatologique, contenant des matieres grasses |
| FR2722097B1 (fr) | 1994-07-11 | 1997-05-16 | Oreal | Composition cosmetique et/ou dermatologique gelifiee, riche en solvant et contenant des particules creuses, ses application |
| FR2740334B1 (fr) | 1995-10-25 | 1997-12-05 | Oreal | Composition cosmetique contenant un monoester d'acide en c4-c10 et d'alcool en c16-c18 et des particules creuses |
| DE19540886A1 (de) | 1995-11-02 | 1997-05-07 | Wacker Chemie Gmbh | Kompressibler Siliconkautschuk |
| US6004641A (en) * | 1997-07-11 | 1999-12-21 | Sinclair & Rush, Inc. | Molded plastisol article with textured exterior |
| DE19735813A1 (de) * | 1997-08-18 | 1999-02-25 | Wacker Chemie Gmbh | Kompressiblen Schwefel enthaltender Siliconkautschuk |
| JP4620812B2 (ja) * | 1998-01-26 | 2011-01-26 | 株式会社クレハ | 発泡性マイクロスフェアーの製造方法 |
| US6235801B1 (en) | 1999-04-02 | 2001-05-22 | Miguel A. Morales | Method of expanding a gel material |
| FR2801502B1 (fr) | 1999-11-25 | 2002-01-18 | Oreal | Composition cosmetique deodorante anhydre |
| US6866906B2 (en) | 2000-01-26 | 2005-03-15 | International Paper Company | Cut resistant paper and paper articles and method for making same |
| US6911484B1 (en) | 2000-07-25 | 2005-06-28 | Earlychildhood.Com Llc | Expanding medium, system and method for decorating surfaces |
| FR2821016B1 (fr) * | 2001-02-22 | 2003-12-26 | Oreal | Procede d'impression par depot d'encre a effet relief |
| US6884507B2 (en) * | 2001-10-05 | 2005-04-26 | General Electric Company | Use of high modulus, impact resistant foams for structural components |
| CA2464692A1 (en) | 2001-11-02 | 2003-05-15 | The Procter & Gamble Company | Composition containing a cationic polymer and water insoluble solid material |
| CN1604885A (zh) * | 2001-12-17 | 2005-04-06 | 萨所化学工业有限公司 | 敏化炸药的制备方法 |
| KR20030070297A (ko) * | 2002-02-23 | 2003-08-30 | 윤혁중 | 폐스티로폼 감융 재생방법 및 그 재생장치 |
| RU2387752C2 (ru) | 2002-09-13 | 2010-04-27 | Интернэшнл Пейпер Компани | Бумага с улучшенной жесткостью и пухлостью и способ для ее изготовления |
| US7074029B2 (en) * | 2003-07-23 | 2006-07-11 | 3D Systems, Inc. | Accumulation, control and accounting of fluid by-product from a solid deposition modeling process |
| US7998465B2 (en) | 2003-10-24 | 2011-08-16 | L'oreal S.A. | Heat-swelling cosmetic composition |
| US7807729B2 (en) | 2003-11-19 | 2010-10-05 | Matsumoto Yushi-Seiyaku Co., Ltd. | Heat-expanded microspheres, production process thereof, heat-expandable microspheres and application thereof |
| KR100569417B1 (ko) * | 2004-08-13 | 2006-04-07 | 현대자동차주식회사 | 마이크로웨이브를 이용한 폐고무분말의 연속식표면개질장치와 이를 이용한 표면개질방법 |
| US7531497B2 (en) | 2004-10-08 | 2009-05-12 | The Procter & Gamble Company | Personal care composition containing a cleansing phase and a benefit phase |
| US20060085924A1 (en) | 2004-10-13 | 2006-04-27 | Gaelle Brun | Coloring composition comprising at least one pigment and at least one electrophilic cyanoacrylate monomer |
| JP5302670B2 (ja) | 2005-03-11 | 2013-10-02 | インターナショナル・ペーパー・カンパニー | 膨張可能な微小球体とイオン性化合物とを含有する組成物、およびこれらの組成物の製造法と使用法 |
| US7820609B2 (en) | 2005-04-13 | 2010-10-26 | The Procter & Gamble Company | Mild, structured, multi-phase personal cleansing compositions comprising density modifiers |
| US8318627B2 (en) * | 2005-08-10 | 2012-11-27 | Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg | Process for preparation of a catalyst carrier |
| DE102005040851B3 (de) | 2005-08-29 | 2007-04-05 | Vibra Maschinenfabrik Schultheis Gmbh & Co. | Verfahren und Vorrichtung zum Kristallisieren von zum Verkleben neigenden Kunststoffgranulaten, insbesondere PET- und PU-Granulaten |
| US7786181B2 (en) | 2005-12-21 | 2010-08-31 | Akzo Nobel N.V. | Chemical composition and process |
| US20070155859A1 (en) * | 2006-01-04 | 2007-07-05 | Zhengzhe Song | Reactive polyurethane hot melt adhesive |
| US7956096B2 (en) | 2006-02-10 | 2011-06-07 | Akzo Nobel N.V. | Microspheres |
| US8388809B2 (en) | 2006-02-10 | 2013-03-05 | Akzo Nobel N.V. | Microspheres |
| US8104616B2 (en) | 2006-02-11 | 2012-01-31 | The Procter & Gamble Company | Clamshell package for holding and displaying consumer products |
| US8153144B2 (en) | 2006-02-28 | 2012-04-10 | The Proctor & Gamble Company | Stable multiphase composition comprising alkylamphoacetate |
| US20080057294A1 (en) * | 2006-09-01 | 2008-03-06 | Fina Technology, Inc. | High impact polystyrene tile |
| US20080057295A1 (en) * | 2006-09-01 | 2008-03-06 | Fina Technology, Inc. | Engravable board |
| US7381261B1 (en) * | 2006-12-21 | 2008-06-03 | United States Gypsum Company | Expanded perlite annealing process |
| CN102137878B (zh) | 2008-08-28 | 2014-06-18 | 国际纸业公司 | 可膨胀微球及其制造和使用方法 |
| EP2334721A4 (en) * | 2008-09-30 | 2013-09-25 | Henkel Corp | SHEAR AND / OR PRESSURE-RELATED MICROBALLS |
| WO2010076489A2 (fr) | 2008-12-15 | 2010-07-08 | L'oreal | Composition cosmétique comprenant une polyamine portant des groupes diazirines et utilisation pour le photo-greffage de pigments et/ou de micro ou nanoparticules |
| WO2011074129A1 (en) | 2009-12-16 | 2011-06-23 | L'oreal | Powdery cosmetic composition |
| CN103314601A (zh) | 2010-11-05 | 2013-09-18 | 日本电气株式会社 | 信息处理设备 |
| WO2012077241A1 (en) | 2010-12-06 | 2012-06-14 | L'oreal | Powdery cosmetic composition |
| US8956633B2 (en) | 2011-05-13 | 2015-02-17 | L'oreal | Powdery cosmetic composition |
| US9511523B2 (en) * | 2012-03-28 | 2016-12-06 | Sabic Global Technologies B.V. | Static-dissipative foam extrusion calibration with minimized expansion loss |
| JP6043427B2 (ja) | 2012-05-30 | 2016-12-14 | アクゾ ノーベル ケミカルズ インターナショナル ベスローテン フエンノートシャップAkzo Nobel Chemicals International B.V. | 微小球体 |
| US20160115290A1 (en) * | 2013-06-12 | 2016-04-28 | Akzo Nobel Chemicals International B.V. | Method and a Device for Preparation of Expanded Microspheres |
| FR3011740B1 (fr) | 2013-10-11 | 2015-10-23 | Oreal | Composition cosmetique de revetement des fibres keratiniques |
| FR3011741B1 (fr) | 2013-10-11 | 2015-10-23 | Oreal | Composition cosmetique de revetement des fibres keratiniques |
| JP6532646B2 (ja) | 2013-12-06 | 2019-06-19 | ロレアル | パウダー状化粧用組成物 |
| FR3015251B1 (fr) | 2013-12-20 | 2016-01-22 | Oreal | Composition cosmetique comprenant un polymere a motif dendrimere carbosiloxane et des particules de polymeres expanses |
| US9707799B2 (en) | 2014-03-19 | 2017-07-18 | The Procter & Gamble Company | Process for printing and securing three-dimensional pattern on non-fibrous substrates and article comprising non-fibrous surface having three-dimensional pattern thereon |
| WO2016044013A1 (en) | 2014-09-16 | 2016-03-24 | Henkel IP & Holding GmbH | Use of hollow polymeric microspheres in composite materials requiring flame resistance |
| AT518099A1 (de) * | 2015-12-22 | 2017-07-15 | Fill Gmbh | Verfahren zur Herstellung eines geschäumten Partikelschaummaterials |
| WO2019043235A1 (en) | 2017-09-04 | 2019-03-07 | Akzo Nobel Chemicals International B.V. | THERMO-EXPANDABLE MICROSPHERES PREPARED FROM MONOMERS OF BIOLOGICAL ORIGIN |
| CN111315473B (zh) | 2017-11-21 | 2022-01-11 | 诺力昂化学品国际有限公司 | 由生物基单体制备的可热膨胀微球 |
| AT520316B1 (de) | 2018-02-13 | 2019-03-15 | Fill Gmbh | Verfahren und Vorrichtung zum Aufschäumen eines expansionsfähigen Partikelschaummaterials |
| PL3774259T3 (pl) | 2018-04-05 | 2022-12-27 | Nouryon Chemicals International B.V. | Urządzenie i sposób przygotowania rozszerzonych mikrosfer |
| DE102018123703A1 (de) * | 2018-09-26 | 2020-03-26 | Parat Beteiligungs Gmbh | Verfahren zur Herstellung eines flächenhaft ausgebildeten Bauelementes |
| DE102020101976A1 (de) | 2020-01-28 | 2021-07-29 | Forbo Siegling Gmbh | Flächenelement mit einer expandierbare Mikrohohlkugeln enthaltenden Nutzschicht und ein Verfahren zu seiner Herstellung |
| EP4126334A1 (en) | 2020-04-03 | 2023-02-08 | Nouryon Chemicals International B.V. | Thermally expandable microspheres prepared from bio-based monomers |
| KR20220132671A (ko) | 2020-04-03 | 2022-09-30 | 누리온 케미칼즈 인터내셔널 비.브이. | 생물-기반 단량체로부터 제조된 열 팽창성 미소구체 |
| AT525186A1 (de) | 2021-06-21 | 2023-01-15 | Fill Gmbh | Aufschäumvorrichtung zum Aufschäumen eines expansionsfähigen Partikelschaummaterials |
| DE102022121413A1 (de) | 2022-08-24 | 2024-02-29 | Forbo Siegling Gmbh | Verfahren zur Herstellung eines flexiblen Flächenelements sowie ein dadurch hergestelltes Flächenelement |
| DE102022133622A1 (de) | 2022-12-16 | 2024-06-27 | Elringklinger Ag | Formelement, Energiespeichervorrichtung, Strukturbauteil und Verfahren zur Herstellung eines Formelements |
| EP4534196A1 (en) | 2023-10-06 | 2025-04-09 | Nouryon Chemicals International B.V. | Biodegradable core-shell microspheres |
| EP4584014B1 (en) | 2023-11-27 | 2026-02-11 | Nouryon Chemicals International B.V. | Device and method for pre-expanding thermally expandable microspheres |
| CN118403601B (zh) * | 2023-12-29 | 2024-12-31 | 江苏长泰药业股份有限公司 | 一种微球干燥固化成型方法 |
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| US994875A (en) * | 1910-01-26 | 1911-06-13 | Rudolph Schilling | Measuring and filling apparatus. |
| US2488446A (en) * | 1945-12-12 | 1949-11-15 | Westinghouse Electric Corp | Polytetrafluoroethylene casting mold |
| US3227424A (en) * | 1964-01-23 | 1966-01-04 | Tri Mfg & Sales Co | Apparatus for pre-expanding plastic material |
| US3386716A (en) * | 1965-03-05 | 1968-06-04 | Kohler General Inc | Apparatus for prefoaming of expandable synthetic resin such as styrene polymer composition containing a volatile organic liquid |
| FR93618E (fr) * | 1965-04-14 | 1969-04-25 | Saint Gobain | Procédé pour l'obtention de perles en polystyrene expansé. |
| US3471603A (en) * | 1967-03-07 | 1969-10-07 | Pillsbury Co | Agglomerating process |
| US3615972A (en) * | 1967-04-28 | 1971-10-26 | Dow Chemical Co | Expansible thermoplastic polymer particles containing volatile fluid foaming agent and method of foaming the same |
| NO135308L (es) * | 1968-10-07 | 1900-01-01 | ||
| US3821342A (en) * | 1970-12-29 | 1974-06-28 | Motch Merryweather Machinery | Method for expanding synthetic plastic beads in a fluid bed |
| US3667665A (en) * | 1971-05-20 | 1972-06-06 | West Point Pepperell Inc | Apparatus for preparing flocked fabric |
| BE787211A (fr) * | 1971-08-05 | 1973-02-05 | Dow Chemical Co | Procede de dilatation de spherules creuses en resine synthetique thermoplastique et produits obtenus par sa mise en oeuvre |
| US4108806A (en) * | 1971-12-06 | 1978-08-22 | The Dow Chemical Company | Thermoplastic expandable microsphere process and product |
| US4073843A (en) * | 1972-09-11 | 1978-02-14 | Foster Grant Co., Inc. | Process of partially expanding thermoplastic particles using a mixture of steam and a hot dry gas |
| US3914360A (en) * | 1973-04-23 | 1975-10-21 | Dow Chemical Co | Expansion of expandable synthetic resinous microspheres |
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| SE439599B (sv) * | 1981-01-14 | 1985-06-24 | Kema Nord Ab | Sett att torka och expandera i vetska dispergerade, termoplastiska mikrosferer innehallande, flyktiga, flytande jesmedel |
| AU547069B2 (en) * | 1981-05-04 | 1985-10-03 | Monsanto Australia Limited | Foaming agent for styrene |
| FR2505798B1 (fr) * | 1981-05-14 | 1986-07-25 | Pari Symac | Perfectionnement aux dispositifs comportant un ressort helicoidal utilise comme organe de transfert, d'extraction, de dosage ou de melange |
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-
1989
- 1989-06-15 ES ES89850198T patent/ES2050844T3/es not_active Expired - Lifetime
- 1989-06-15 EP EP89850198A patent/EP0348372B1/en not_active Expired - Lifetime
- 1989-06-15 DE DE68913235T patent/DE68913235T2/de not_active Expired - Lifetime
- 1989-06-15 AT AT89850198T patent/ATE101823T1/de not_active IP Right Cessation
- 1989-06-19 CA CA000603173A patent/CA1329685C/en not_active Expired - Fee Related
- 1989-06-21 AU AU36707/89A patent/AU620879B2/en not_active Expired
- 1989-06-21 NZ NZ229644A patent/NZ229644A/xx unknown
- 1989-06-21 FI FI893040A patent/FI95354C/fi not_active IP Right Cessation
- 1989-06-22 PT PT90950A patent/PT90950B/pt not_active IP Right Cessation
- 1989-06-22 NO NO892604A patent/NO177089C/no unknown
- 1989-06-23 JP JP1159842A patent/JPH0829245B2/ja not_active Expired - Fee Related
- 1989-06-23 DK DK198903136A patent/DK173520B1/da not_active IP Right Cessation
-
1994
- 1994-03-28 US US08/218,232 patent/US5484815A/en not_active Expired - Lifetime
-
1995
- 1995-06-07 US US08/478,390 patent/US5585119A/en not_active Expired - Lifetime
-
1997
- 1997-06-09 KR KR1019970023596A patent/KR100196539B1/ko not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| EP0348372A2 (en) | 1989-12-27 |
| DK173520B1 (da) | 2001-01-29 |
| AU3670789A (en) | 1990-01-04 |
| PT90950B (pt) | 1994-06-30 |
| FI893040A7 (fi) | 1989-12-24 |
| US5484815A (en) | 1996-01-16 |
| NO177089C (no) | 1995-07-19 |
| DK313689D0 (da) | 1989-06-23 |
| US5585119A (en) | 1996-12-17 |
| AU620879B2 (en) | 1992-02-27 |
| NO892604D0 (no) | 1989-06-22 |
| EP0348372B1 (en) | 1994-02-23 |
| KR19990000592A (ko) | 1999-01-15 |
| DE68913235T2 (de) | 1994-07-14 |
| JPH0256240A (ja) | 1990-02-26 |
| FI95354B (fi) | 1995-10-13 |
| PT90950A (pt) | 1989-12-29 |
| EP0348372A3 (en) | 1991-09-04 |
| JPH0829245B2 (ja) | 1996-03-27 |
| NZ229644A (en) | 1991-08-27 |
| CA1329685C (en) | 1994-05-24 |
| NO177089B (no) | 1995-04-10 |
| DE68913235D1 (de) | 1994-03-31 |
| FI95354C (fi) | 1996-01-25 |
| FI893040A0 (fi) | 1989-06-21 |
| DK313689A (da) | 1989-12-24 |
| ATE101823T1 (de) | 1994-03-15 |
| KR100196539B1 (ko) | 1999-06-15 |
| NO892604L (no) | 1989-12-27 |
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