ES2030587T3 - Agente espesante modificador de las caracteristicas reologicas de composiciones acuosas cargadas y/o pigmentadas blancas o de color. - Google Patents

Agente espesante modificador de las caracteristicas reologicas de composiciones acuosas cargadas y/o pigmentadas blancas o de color.

Info

Publication number
ES2030587T3
ES2030587T3 ES198989420237T ES89420237T ES2030587T3 ES 2030587 T3 ES2030587 T3 ES 2030587T3 ES 198989420237 T ES198989420237 T ES 198989420237T ES 89420237 T ES89420237 T ES 89420237T ES 2030587 T3 ES2030587 T3 ES 2030587T3
Authority
ES
Spain
Prior art keywords
functional group
compositions
ethylenically unsaturated
white
aqueous compositions
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES198989420237T
Other languages
English (en)
Inventor
Benoit Simonet
Pierre Fabre
Jacques Laluet
Jean-Bernard Egraz
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
COATEX S A Ste
Original Assignee
COATEX S A Ste
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by COATEX S A Ste filed Critical COATEX S A Ste
Application granted granted Critical
Publication of ES2030587T3 publication Critical patent/ES2030587T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/87—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/04—Acids; Metal salts or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/44—Preparation of metal salts or ammonium salts
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/43—Thickening agents
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00—Materials not provided for elsewhere
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/08—Homopolymers or copolymers of acrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/10—Homopolymers or copolymers of methacrylic acid esters

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Veterinary Medicine (AREA)
  • Public Health (AREA)
  • Engineering & Computer Science (AREA)
  • Dermatology (AREA)
  • Birds (AREA)
  • General Chemical & Material Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Epidemiology (AREA)
  • Paints Or Removers (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Cosmetics (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Dental Preparations (AREA)
  • Medicinal Preparation (AREA)
  • Pigments, Carbon Blacks, Or Wood Stains (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Detergent Compositions (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polyurethanes Or Polyureas (AREA)

Abstract

COPOLIMERO ESPESANTE ASOCIADO HIDROSOLUBLE EN MEDIO NEUTRO O ALCALINO PARA COMPOSICIONES ACUOSAS CARGADAS Y/O PIGMENTADAS, BLANCAS O COLOREADAS, COMPUESTO DE: A) POR LO MENOS UN MONOMERO INSATURADO ETILENICAMENTE, QUE DISPONE DE UNA FUNCION CARBOXILICA POR LO MENOS; B) OTRO MONOMERO POR LO MENOS CON INSATURACION ETILENICA DESPROVISTO DE FUNCION CARBOXILICA; C) POR LO MENOS UN MONOMERO TENSIOACTIVO QUE TIENE UNA FUNCION URETANO POR LO MENOS, QUE RESULTA DE LA REACCION DE UN ISOCIANATO, CON INSATURACION ETILENICA, CON UN COMPUESTO TENSIOACTIVO, QUE TIENE UNA FUNCION HIDROXILO REACTIVA RESPECTO DEL GRUPO -NCO, QUE SE CARACTERIZA PORQUE DICHO POLIMERO PERTENECE AL GRUPO CONSTITUIDO POR LOS QUE, POR DEFINICION, EN DISOLUCION ACUOSA AL 2 % EN PESO DE MATERIA SECA LLEVADA A UN PH 9 POR ADICION DE AMONIACO Y A UNA TEMPERATURA DE 20 (GRADOS) C, TIENEN UNA VISCOSIDAD BROOKFIELD A 100 VUELTAS POR MINUTO COMO MAXIMO IGUAL A 220 CENTIPOISES. EL COPOLIMERO SEGUN LA INVENCION SE APLICA A COMPOSICIONES ACUOSAS CARGADAS Y/O PIGMENTADAS, TALES COMO COMPOSICIONES DE REVESTIMIENTO, Y MAS ESPECIALMENTE PINTURAS, SALSAS PARA UNTAR, PASTAS DE IMPRESION, PRODUCTOS DE ACABADO DE CUERO, COMPOSICIONES PARA COSMETICOS Y DETERGENTES, FLUIDOS PARA PERFORAR.
ES198989420237T 1988-07-07 1989-07-04 Agente espesante modificador de las caracteristicas reologicas de composiciones acuosas cargadas y/o pigmentadas blancas o de color. Expired - Lifetime ES2030587T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR8809509A FR2633930B1 (fr) 1988-07-07 1988-07-07 Agent epaississant modificateur des caracteristiques rheologiques de compositions aqueuses chargees et/ou pigmentees, blanches ou colorees

Publications (1)

Publication Number Publication Date
ES2030587T3 true ES2030587T3 (es) 1992-11-01

Family

ID=9368391

Family Applications (1)

Application Number Title Priority Date Filing Date
ES198989420237T Expired - Lifetime ES2030587T3 (es) 1988-07-07 1989-07-04 Agente espesante modificador de las caracteristicas reologicas de composiciones acuosas cargadas y/o pigmentadas blancas o de color.

Country Status (14)

Country Link
US (2) US5015711A (es)
EP (1) EP0350414B1 (es)
JP (1) JPH0299573A (es)
AT (1) ATE75234T1 (es)
AU (1) AU612275B2 (es)
CA (1) CA1334776C (es)
DE (1) DE68901315D1 (es)
DK (1) DK174670B1 (es)
ES (1) ES2030587T3 (es)
FI (1) FI95281C (es)
FR (1) FR2633930B1 (es)
GR (1) GR3004447T3 (es)
NO (1) NO173018C (es)
PT (1) PT91085B (es)

Families Citing this family (66)

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US4801671A (en) * 1987-06-25 1989-01-31 Desoto, Inc. Production of alkali-soluble, carboxyl-functional aqueous emulsion thickeners
US4797223A (en) * 1988-01-11 1989-01-10 Rohm And Haas Company Water soluble polymers for detergent compositions
US5589534A (en) * 1990-10-16 1996-12-31 Akzo Nobel N.V. Aqueous coating compositions including a reactive emulsifier
US5739378A (en) * 1992-05-29 1998-04-14 Union Carbide Chemicals & Plastics Technology Corporation Complex hydrophobe-containing oligomers
US5292843A (en) * 1992-05-29 1994-03-08 Union Carbide Chemicals & Plastics Technology Corporation Polymers containing macromonomers
US5488180A (en) * 1992-05-29 1996-01-30 Union Carbide Chemicals & Plastics Technology Corporation Complex hydrophobe compounds
US5461100A (en) * 1992-05-29 1995-10-24 Union Carbide Chemicals & Plastics Technology Corporation Aircraft anti-icing fluids
CA2136975A1 (en) * 1992-05-29 1993-12-09 Gregory D. Shay Aqueous latexes containing macromonomeres
US5426182A (en) * 1992-05-29 1995-06-20 Union Carbide Chemical & Plastics Technology Corporation Polysaccharides containing complex hydrophobic groups
US5292828A (en) * 1992-05-29 1994-03-08 Union Carbide Chemicals & Plastics Technology Corporation Polymers containing complex hydrophobic groups
FR2693203B1 (fr) * 1992-07-01 1994-08-26 Coatex Sas Copolymère acrylique partiellement ou totalement hydrosoluble, réticulé ou non et son utilisation.
US5454956A (en) * 1993-04-01 1995-10-03 Deluxe Corporation Method of cleaning waste water and recovery of contaminants therefrom
US5431721A (en) 1992-09-17 1995-07-11 Deluxe Corporation Ink varnish and composition and method of making the same
US5549741A (en) 1992-09-17 1996-08-27 Deluxe Corporation Ink varnish composition
US5308390A (en) * 1992-09-17 1994-05-03 Deluxe Corporation Ink composition and method of making and using such composition
US5411596A (en) * 1993-04-01 1995-05-02 Deluxe Corporation Oil based composition clean up method and composition for use therein
US5369145A (en) * 1993-06-14 1994-11-29 Block Drug Company Denture adhesive
US5399618A (en) * 1993-06-28 1995-03-21 Union Carbide Chemical & Plastics Technology Corporation Processes for preparing aqueous polymer emulsions
EP0657524B1 (en) * 1993-12-01 1999-03-31 AUSIMONT S.p.A. Mineral or synthetic, hydrogen-based greases, having improved properties
EP0688822B1 (en) * 1994-06-21 1999-12-15 The BFGOODRICH COMPANY Degradable blend of composition
GB9415075D0 (en) * 1994-07-27 1994-09-14 Cookson Group Plc Paste or printable ink compositions
CA2157691C (en) † 1994-09-29 1998-08-18 Joseph Doolan High performance alkali-swellable rheological additives for aqueous systems
US5874495A (en) * 1994-10-03 1999-02-23 Rhodia Inc. Polymers useful as PH responsive thickeners and monomers therefor
US5708068A (en) * 1995-01-16 1998-01-13 Union Carbide Chemicals & Plastics Technology Corporation Aircraft deicing/anti-icing fluids thickened by associative polymers
US5639841A (en) * 1995-02-28 1997-06-17 Union Carbide Chemicals & Plastics Technology Corporation Polymers containing macromonomer mixtures
AU759271B2 (en) * 1995-04-28 2003-04-10 Rhodia Chimie Latex dispersions containing a hydroxyl functional group and a carboxylic functional group and their use for the manufacture of coatings
US6127471A (en) * 1995-06-07 2000-10-03 Carchalk, Inc. Coating system composition
DE19601763A1 (de) * 1996-01-19 1997-07-24 Hoechst Ag Verwendung von Tensiden bei der Trocknung von hydrophilen, hochquellfähigen Hydrogelen
JPH1053633A (ja) * 1996-05-22 1998-02-24 Hb Fuller Licensing & Financing Inc 構造化反応性ラテックス
DE19629941C2 (de) * 1996-07-24 1998-11-26 Schulz Gmbh Farben Und Lackfab Alkydharz-Decklack
WO1999000338A1 (en) * 1997-06-27 1999-01-07 Elk Corporation Coated structural articles
CA2241120A1 (en) 1997-07-03 1999-01-03 Ward Thomas Brown Coating method and coating composition used therein
FR2779647B1 (fr) 1998-06-15 2000-08-04 Oreal Composition cosmetique contenant un polymere anionique et un terpolymere acrylique et utilisation de cette composition pour le traitement des matieres keratiniques
FR2779638B1 (fr) 1998-06-15 2000-08-04 Oreal Composition cosmetique contenant un polysaccharide et un terpolymere acrylique et utilisation de cette composition pour le traitement des matieres keratiniques
FR2779640B1 (fr) 1998-06-15 2000-08-04 Oreal Composition cosmetique contenant un polymere cationique et un terpolymere acrylique et utilisation de cette composition pour le traitement des matieres keratiniques
CN1227275C (zh) * 1998-06-15 2005-11-16 联合碳化化学品及塑料技术公司 碱溶性胶乳增稠剂
FR2779637B1 (fr) * 1998-06-15 2000-09-01 Oreal Compositions cosmetiques photoprotectrices, contenant un nanopigment d'oxyde metallique et un terpolymere acrylique et utilisation de ces compositions pour proteger les matieres keratiniques contre le rayonnement ultraviolet
FR2779639B1 (fr) 1998-06-15 2000-08-04 Oreal Composition cosmetique contenant un polyorganosiloxane et un terpolymere acrylique et utilisation de cette composition pour le traitement des matieres keratiniques
US6762269B1 (en) * 1998-08-13 2004-07-13 National Starch And Chemical Investment Holding Corporation High temperature viscosity stable thickener
US6586353B1 (en) 1999-11-30 2003-07-01 Elk Corp. Of Dallas Roofing underlayment
US6708456B2 (en) * 1999-11-30 2004-03-23 Elk Premium Building Products, Inc. Roofing composite
US6673432B2 (en) 1999-11-30 2004-01-06 Elk Premium Building Products, Inc. Water vapor barrier structural article
US6500560B1 (en) 1999-11-30 2002-12-31 Elk Corporation Of Dallas Asphalt coated structural article
US6872440B1 (en) 1999-11-30 2005-03-29 Elk Premium Building Products, Inc. Heat reflective coated structural article
US6573325B1 (en) * 2000-04-28 2003-06-03 David York Aqueous surface treatment compositions
US20040198915A1 (en) * 2000-08-25 2004-10-07 Takao Uehara Defoamers for top coat paints for motor vehicles
JP4673962B2 (ja) * 2000-08-25 2011-04-20 楠本化成株式会社 クリアー型塗料塗膜の耐水白化性を有する消泡剤或いは平滑剤
FR2894261B1 (fr) 2005-12-02 2008-02-22 Clariant France Soc Par Action Composition aqueuse insolubilisante a base de glyoxal pour le traitement de surface des papiers et cartons.
FR2922452B1 (fr) * 2007-10-19 2010-01-22 Coatex Sas Formulations de composes organoplatiniques en presence de polymeres associatifs, produits obtenus et leurs utilisations
ITVA20080005A1 (it) * 2008-01-16 2009-07-17 Lamberti Spa Addensanti associativi
FR2931161B1 (fr) * 2008-05-14 2010-04-23 Coatex Sas Utilisation d'un couple dispersant acrylique-epaississant associatif dans une peinture alkyde pour ameliorer la retention du niveau de brillant
FR2956862B1 (fr) 2010-02-26 2013-03-15 Coatex Sas Monomere associatif a base d'alcools oxo, polymere acrylique contenant ce monomere, utilisation dudit polymere comme epaississant dans une formulation aqueuse, formulation obtenue.
ES2764439T3 (es) * 2010-05-25 2020-06-03 Archroma Ip Gmbh Composición de recubrimiento de papel, papel recubierto con esta y método para producir papel recubierto
FR2961816B1 (fr) 2010-06-25 2012-07-06 Coatex Sas Emulsions acryliques alkali gonflables sans tensio-actif, leur utilisation dans des formulations aqueuses et formulations les contenant.
FR2961815B1 (fr) 2010-06-25 2013-05-10 Coatex Sas Emulsions acryliques alkali gonflables a l'acide acrylique, leur utilisation dans des formulations aqueuses et formulations les contenant.
WO2013020049A1 (en) 2011-08-03 2013-02-07 Air Products And Chemicals, Inc. Ionic/ionogenic comb copolymer compositions and personal care products containing the same
US9556405B2 (en) 2012-11-29 2017-01-31 Conopco, Inc. Polymer structured aqueous detergent compositions
WO2014082955A1 (en) 2012-11-29 2014-06-05 Unilever Plc Thickened aqueous detergent liquid
CA2972143C (en) 2015-01-29 2023-09-05 Unilever Plc Thickened aqueous detergent liquid
CN108025021A (zh) * 2015-04-13 2018-05-11 A·沙尼 用于治疗皮肤病症的组合物和方法
WO2018210524A1 (en) 2017-05-15 2018-11-22 Unilever Plc Composition
WO2018210700A1 (en) 2017-05-15 2018-11-22 Unilever Plc Composition
WO2018210522A1 (en) 2017-05-15 2018-11-22 Unilever Plc Composition
WO2018210523A1 (en) 2017-05-15 2018-11-22 Unilever Plc Composition
WO2020176565A1 (en) 2019-02-28 2020-09-03 Ecolab Usa Inc. Stabilizing system for laundry emulsions
WO2022120174A1 (en) 2020-12-04 2022-06-09 Ecolab Usa Inc. Improved stability and viscosity in high active high caustic laundry emulsion with low hlb surfactant

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JPS60132641A (ja) * 1983-12-20 1985-07-15 Dainippon Ink & Chem Inc ビニル共重合樹脂の水分散液の製造方法
US4514552A (en) * 1984-08-23 1985-04-30 Desoto, Inc. Alkali soluble latex thickeners
CA1285685C (en) * 1985-02-04 1991-07-02 Ching-Jen Chang Method for preparation of hydrophobe containing alkali soluble or swellable emulsion copolymers
US4600761A (en) * 1985-04-04 1986-07-15 Alco Chemical Corporation Acrylic emulsion copolymers for thickening aqueous systems and copolymerizable surfactant monomers for use therein
US4735981A (en) * 1986-10-03 1988-04-05 Desoto, Inc. Combinations of associative thickeners and aqueous latex paints containing the same
US4801671A (en) * 1987-06-25 1989-01-31 Desoto, Inc. Production of alkali-soluble, carboxyl-functional aqueous emulsion thickeners
US4797223A (en) * 1988-01-11 1989-01-10 Rohm And Haas Company Water soluble polymers for detergent compositions

Also Published As

Publication number Publication date
NO173018C (no) 1993-10-13
AU612275B2 (en) 1991-07-04
EP0350414B1 (fr) 1992-04-22
FR2633930A1 (fr) 1990-01-12
AU3788489A (en) 1990-01-11
DK174670B1 (da) 2003-08-25
NO892254D0 (no) 1989-06-02
US5066710A (en) 1991-11-19
NO892254L (no) 1990-01-08
FR2633930B1 (fr) 1991-04-19
GR3004447T3 (es) 1993-03-31
DK335289D0 (da) 1989-07-06
DK335289A (da) 1990-01-08
CA1334776C (fr) 1995-03-14
US5015711A (en) 1991-05-14
PT91085B (pt) 1995-01-31
NO173018B (no) 1993-07-05
FI95281C (fi) 1996-01-10
FI893310A (fi) 1990-01-08
FI893310A0 (fi) 1989-07-06
JPH0299573A (ja) 1990-04-11
PT91085A (pt) 1990-02-08
EP0350414A1 (fr) 1990-01-10
FI95281B (fi) 1995-09-29
ATE75234T1 (de) 1992-05-15
DE68901315D1 (de) 1992-05-27

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