ES2008718A6 - Un metodo de preparacion de un sellador de silicona - Google Patents
Un metodo de preparacion de un sellador de siliconaInfo
- Publication number
- ES2008718A6 ES2008718A6 ES8700540A ES8700540A ES2008718A6 ES 2008718 A6 ES2008718 A6 ES 2008718A6 ES 8700540 A ES8700540 A ES 8700540A ES 8700540 A ES8700540 A ES 8700540A ES 2008718 A6 ES2008718 A6 ES 2008718A6
- Authority
- ES
- Spain
- Prior art keywords
- life
- improved self
- silicone elastomeric
- elastomeric sealant
- sealant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/10—Materials in mouldable or extrudable form for sealing or packing joints or covers
- C09K3/1006—Materials in mouldable or extrudable form for sealing or packing joints or covers characterised by the chemical nature of one of its constituents
- C09K3/1018—Macromolecular compounds having one or more carbon-to-silicon linkages
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/541—Silicon-containing compounds containing oxygen
- C08K5/5415—Silicon-containing compounds containing oxygen containing at least one Si—O bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/14—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers in which at least two but not all the silicon atoms are connected by linkages other than oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/10—Materials in mouldable or extrudable form for sealing or packing joints or covers
- C09K2003/1034—Materials or components characterised by specific properties
- C09K2003/1053—Elastomeric materials
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S528/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S528/901—Room temperature curable silicon-containing polymer
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Sealing Material Composition (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
UN METODO DE PREPARACION DE UN SELLADOR DE SILICONA. COMPRENDE: (A) MEZCLAR EN AUSENCIA DE HUMEDAD (1) 100 PARTES EN PESO DE UN POLIMERO DE POLIDIORGANOSILOXANO TERMINADO EN ALCOXISILETILENO, (2) 0,35-90 PARTES EN PESO DE UN ENTRECRUZANTE DE ALCOXITRIALCOXISILANO Y (3) 0,2-6,0 PARTES EN PESO DE CATALIZADOR DE TITANIO, Y (B) ALMACENAR LA MEZCLA EN AUSENCIA DE HUMEDAD, CON LO QUE SE OBTIENE EL MENCIONADO SELLADOR DE SILICONA. LOS PRODUCTOS OBTENIDOS POR ESTE METODO TIENEN UTILIDAD COMO SELLADORES ELASTOMERICOS DE SILICONA QUE CONSERVAN SU CAPACIDAD DE CURADO POR EXPOSICION A LA HUMEDAD DESPUES DE QUE EL SELLADOR HAYA PERMANECIDO ALMACENADO DURANTE UN LARGO TIEMPO EN AUSENCIA DE HUMEDAD.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US06/835,814 US4871827A (en) | 1986-03-03 | 1986-03-03 | Method of improving shelf life of silicone elastomeric sealant |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2008718A6 true ES2008718A6 (es) | 1989-08-01 |
Family
ID=25270537
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES8700540A Expired ES2008718A6 (es) | 1986-03-03 | 1987-02-27 | Un metodo de preparacion de un sellador de silicona |
Country Status (7)
Country | Link |
---|---|
US (1) | US4871827A (es) |
EP (1) | EP0236042B1 (es) |
JP (1) | JP2529237B2 (es) |
AU (1) | AU590394B2 (es) |
CA (1) | CA1282894C (es) |
DE (1) | DE3788966T2 (es) |
ES (1) | ES2008718A6 (es) |
Families Citing this family (77)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4652624A (en) * | 1986-03-03 | 1987-03-24 | Dow Corning Corporation | Room-temperature-curing silicone sealants |
US4687829A (en) * | 1986-03-03 | 1987-08-18 | Dow Corning Corporation | Method of adjusting physical properties in silicone elastomeric sealant |
US4960844A (en) * | 1988-08-03 | 1990-10-02 | Products Research & Chemical Corporation | Silane terminated liquid polymers |
US4888380A (en) * | 1988-09-26 | 1989-12-19 | Dow Corning Corporation | Clear, non-slumping silicone sealants |
EP0361803A3 (en) * | 1988-09-26 | 1991-03-27 | Dow Corning Corporation | In situ formed titanium chelate catalysts |
US4962174A (en) * | 1990-01-18 | 1990-10-09 | Dow Corning Corporation | Preparation of alkoxysilethylene endblocked polydiorganosiloxane |
CA2076278A1 (en) * | 1991-08-22 | 1993-02-23 | Joseph T. Braun | Curable silicone pressure sensitive adhesive tape |
JP2636616B2 (ja) * | 1991-12-12 | 1997-07-30 | 信越化学工業株式会社 | 室温硬化性シリコーンゴム組成物及びその硬化物 |
US5286815A (en) * | 1992-02-07 | 1994-02-15 | Minnesota Mining And Manufacturing Company | Moisture curable polysiloxane release coating compositions |
US5340897A (en) * | 1993-08-04 | 1994-08-23 | Dow Corning Corporation | Moisture curable organosiloxane coating compositions |
US5340899A (en) * | 1993-11-22 | 1994-08-23 | Dow Corning Corporation | Method for the preparation of polydimethylsiloxanes having low reactivity endgroups and high reactivity endgroups wherein the polydimethylsiloxanes contain ethylene chain linkages |
ES2287938T3 (es) * | 1995-06-08 | 2007-12-16 | Dow Corning S.A. | Metodo para sellar juntas con composiciones de organosiloxano curables por humedad. |
US5908909A (en) * | 1995-06-08 | 1999-06-01 | Dow Corning S. A. | Organosiloxane compositions |
US5545704A (en) * | 1995-07-24 | 1996-08-13 | Dow Corning Corporation | Method for producing alkoxysilalkylene terminated siloxane polymers |
DE19536410A1 (de) * | 1995-09-29 | 1997-04-03 | Wacker Chemie Gmbh | Unter Abspaltung von Alkoholen zu Elastomeren vernetzbare Organopolysiloxanmassen |
US5670560A (en) | 1995-11-29 | 1997-09-23 | Dow Corning Corporation | Method of making a pumpable, stable polydiorganosiloxane-silica foundation mixture and room temperature curing sealant |
US5679725A (en) | 1995-11-29 | 1997-10-21 | Dow Corning Corporation | Method of making a foundation polydiorganosiloxane-silica mixture using a hydrolyzable polydiorganosiloxane surface modifying agent, the resulting mixture and a room temperature curing sealant made from the foundation mixture |
US5679726A (en) | 1995-11-29 | 1997-10-21 | Dow Corning Corporation | Method of making a foundation polydiorganosiloxane-silica mixture, the resulting mixture and a room temperature curing sealant made from the foundation mixture |
DE19548474A1 (de) * | 1995-12-22 | 1997-06-26 | Wacker Chemie Gmbh | Aliphatisch ungesättigte Reste aufweisende Organopolysiloxane, deren Herstellung und deren Verwendung in vernetzbaren Massen |
EP0802222A1 (en) | 1996-04-18 | 1997-10-22 | Dow Corning Corporation | Method of adhesion improvement for silicone compositions |
US5840794A (en) * | 1997-01-10 | 1998-11-24 | Dow Corning Corporation | Alkoxy functional sealants with rapid development of green strength |
US5948854A (en) * | 1997-09-25 | 1999-09-07 | Dow Corning S.A. | Alkoxy-functional RTV compositions with increased green strength and increased storage stability |
GB9721831D0 (en) * | 1997-10-15 | 1997-12-17 | Dow Corning Sa | A method for preparing alkoxysilethylene end-blocked polydiorganosiloxanes |
US6132664A (en) * | 1997-12-23 | 2000-10-17 | Dow Corning Corporation | Method of forming a seal in a confined configuration with an alkoxy-functional RTV composition |
US6008284A (en) * | 1997-12-23 | 1999-12-28 | Dow Corning Corporation | Fast curing alkoxy-functional RTV compositions |
US6072016A (en) * | 1997-12-29 | 2000-06-06 | Dow Corning Toray Silicone Co., Ltd. | Silphenylene polymer and composition containing same |
US6140445A (en) * | 1998-04-17 | 2000-10-31 | Crompton Corporation | Silane functional oligomer |
US6156285A (en) * | 1998-11-12 | 2000-12-05 | Dow Corning Corporation | Method for densifying particulate silica |
US6127502A (en) * | 1998-12-21 | 2000-10-03 | Dow Corning Corporation | Polyorganosiloxanes having at least one organofunctional group with multiple hydrolyzable groups |
US6235832B1 (en) | 1998-12-21 | 2001-05-22 | Dow Corning Corporation | RTV silicone compositions with rapid development of green strength |
US6303811B1 (en) | 1998-12-21 | 2001-10-16 | Dow Corning Corporation | Cyclic organosilicon endcapper having one aliphatic unsaturation |
US6013753A (en) * | 1998-12-21 | 2000-01-11 | Dow Corning Corporation | Organosilicon endcapper having one aliphatic unsaturation |
US6265518B1 (en) | 1998-12-21 | 2001-07-24 | Dow Corning Corporation | Organosilicon endcapper having one silicon-bonded hydrogen atom |
US6160150A (en) * | 1998-12-21 | 2000-12-12 | Dow Corning Corporation | Cyclic organosilicon endcapper having one silicon-bonded hydrogen atom |
EP1210384B1 (de) * | 1999-08-20 | 2004-11-24 | Bayer MaterialScience AG | Anorganische beschichtungszusammensetzung, ein verfahren zu deren herstellung sowie deren verwendung |
US6512072B1 (en) | 2000-06-12 | 2003-01-28 | Dow Corning Corporation | Fast cure film forming formulation |
US7144937B2 (en) * | 2002-05-09 | 2006-12-05 | Cph Innovations Corp. | Adhesion promoters for sealants |
JP3900267B2 (ja) * | 2002-05-09 | 2007-04-04 | 信越化学工業株式会社 | 室温硬化性オルガノポリシロキサン組成物 |
JP4096174B2 (ja) * | 2002-11-28 | 2008-06-04 | 信越ポリマー株式会社 | 建築用ゴム部材 |
US7422791B2 (en) * | 2003-11-19 | 2008-09-09 | Hallstar Innovations Corp. | Joint assemblies, methods for installing joint assemblies, and jointing compositions |
JP4811562B2 (ja) * | 2005-05-13 | 2011-11-09 | 信越化学工業株式会社 | 室温硬化性オルガノポリシロキサン組成物 |
US7279589B2 (en) * | 2005-08-15 | 2007-10-09 | Shin-Etsu Chemical Co., Ltd. | Preparation of 1-(alkoxysilyl)ethyl-1,1,3,3-tetramethyldisiloxane |
FR2910295B3 (fr) * | 2006-12-20 | 2009-09-18 | Oreal | Procede de maquillage des matieres keratiniques et kit pour la mise en oeuvre d'un tel procede |
FR2910299A1 (fr) | 2006-12-20 | 2008-06-27 | Oreal | Traitement de fibres capillaires a partir d'une composition comprenant des pigments et des composes silicones reactifs |
FR2910303A1 (fr) * | 2006-12-20 | 2008-06-27 | Oreal | Composition comprenant un compose x et un compose y dont l'un au moins est silicone et un colorant direct hydrophobe |
FR2910314B1 (fr) | 2006-12-20 | 2009-05-08 | Oreal | Traitement de fibres capillaires a partir d'une composition comprenant des composes silicones reactifs avant ou apres un procede de coloration |
FR2910345A1 (fr) | 2006-12-20 | 2008-06-27 | Oreal | Particules coeur/ecorce a base de composes silicones |
FR2910312A1 (fr) * | 2006-12-20 | 2008-06-27 | Oreal | Procede de traitement des cheveux par une silicone reactive vinylique capable de reagir par hydrosilylation |
FR2910301B1 (fr) * | 2006-12-20 | 2009-04-03 | Oreal | Procede de traitement des fibres capillaires avec des compositions contenant des silicones reactives |
FR2910286B1 (fr) | 2006-12-20 | 2009-04-17 | Oreal | Composition comprenant des composes silicones encapsules |
FR2910298A1 (fr) * | 2006-12-20 | 2008-06-27 | Oreal | Composition tinctoriale contenant une silicone reactive, un colorant fluorescent ou azurant optique, procede de coloration utilisant la composition |
FR2910311B1 (fr) | 2006-12-20 | 2009-02-13 | Oreal | Composition comprenant un compose silicone et un organosilane particulier |
FR2910300B1 (fr) * | 2006-12-20 | 2009-04-10 | Oreal | Procede de traitement de la peau par application de composes silicones |
FR2910294B1 (fr) * | 2006-12-20 | 2009-04-17 | Oreal | Emulsion cosmetique contenant des composes silicones |
FR2910284B1 (fr) * | 2006-12-20 | 2009-04-17 | Oreal | Produit cosmetique comprenant des composes silicones et un polymere amphiphile |
FR2910313A1 (fr) | 2006-12-20 | 2008-06-27 | Oreal | Obtention de coiffures structurees mettant en oeuvre une composition comprenant des composes silicones reactifs |
DE102007034726A1 (de) * | 2007-07-23 | 2009-01-29 | Henkel Ag & Co. Kgaa | Entfernung von Nebenprodukten aus vernetzbaren Zubereitungen |
FR2924939B1 (fr) | 2007-12-13 | 2010-02-26 | Oreal | Procede de coloration des cheveux a partir d'une composition comprenant un polymere filmogene hydrophobe, un pigment et un solvant volatil |
FR2933614B1 (fr) * | 2008-07-10 | 2010-09-10 | Oreal | Kit de protection solaire. |
FR2973236B1 (fr) | 2011-03-31 | 2013-12-13 | Oreal | Utilisation d'un dispositif de transfert d'un film cosmetique anti-transpirant applique sur la peau |
FR2973244B1 (fr) | 2011-03-31 | 2014-01-24 | Oreal | Procede comprenant l'application d'un materiau anti-transpirant contenant au moins deux zones de polymeres differents |
JP2012219113A (ja) | 2011-04-04 | 2012-11-12 | Dow Corning Toray Co Ltd | 室温硬化性シリコーンゴム組成物 |
FR2984089B1 (fr) | 2011-12-20 | 2014-01-10 | Oreal | Dispositif d'application comprenant une composition a base de polymere filmogene hydrophobe et un solvant volatil, procede de traitement des fibres keratiniques le mettant en oeuvre |
FR2984132B1 (fr) | 2011-12-20 | 2014-08-01 | Oreal | Composition de coloration pigmentaire a base de polymere acrylique particulier et de copolymere silicone, procede de coloration |
FR2984143B1 (fr) | 2011-12-20 | 2014-07-11 | Oreal | Procede d'application d'une composition de coloration pigmentaire a base de polymere acrylique particulier et de copolymere silicone, et dispositif approprie |
FR2984142B1 (fr) | 2011-12-20 | 2013-12-20 | Oreal | Composition comprenant un polymere acrylique particulier et copolymere silicone, procede de traitement des fibres keratiniques le mettant en oeuvre |
FR2992558B1 (fr) | 2012-06-29 | 2014-06-20 | Oreal | Procede pour former un motif colore sur les fibres keratiniques avec une composition comprenant un polymere filmogene hydrophobe, au moins un solvant volatil et au moins un pigment. |
FR2992559B1 (fr) | 2012-06-29 | 2014-06-20 | Oreal | Procede bicouche de coloration des fibres keratiniques |
US10066138B2 (en) | 2013-12-27 | 2018-09-04 | Dow Corning Toray Co., Ltd. | Room-temperature-curable silicone rubber composition, the use thereof, and method for repairing electronic device |
US10072151B2 (en) * | 2013-12-27 | 2018-09-11 | Dow Corning Toray Co., Ltd. | Room-temperature-curable silicone rubber composition, and the use thereof |
WO2015155949A1 (ja) | 2014-04-09 | 2015-10-15 | 東レ・ダウコーニング株式会社 | 接着促進剤、それを含有してなる硬化性オルガノポリシロキサン組成物 |
EP3493887B1 (de) | 2016-08-04 | 2020-06-03 | Wacker Chemie AG | Entflüchtigung von hochviskosen siliconflüssigkeiten im kurzwegverdampfer |
WO2018209039A1 (en) | 2017-05-11 | 2018-11-15 | Chem Link, Inc. | Click chemistry for sealants and adhesives |
US10968317B2 (en) | 2017-06-26 | 2021-04-06 | Dow Silicones Corporation | Method for hydrosilylation of aliphatically unsaturated alkoxysilanes and hydrogen terminated organosiloxane oligomers to prepare alkoxysilyl terminated polymers useful for functionalizing polyorganosiloxanes using an iridium catalyst |
US11098163B2 (en) | 2017-06-26 | 2021-08-24 | Dow Silicones Corporation | Method for hydrosilylation of aliphatically unsaturated alkoxysilanes and hydrogen terminated organosiloxane oligomers to prepare alkoxysilyl terminated polymers useful for functionalizing polyorganosiloxanes using a rhodium catalyst |
JP7201625B2 (ja) | 2017-06-26 | 2023-01-10 | ダウ シリコーンズ コーポレーション | 脂肪族不飽和アルコキシシラン及び水素末端オルガノシロキサンオリゴマーをヒドロシリル化して、コバルト触媒を使用してポリオルガノシロキサンを官能化するのに有用なアルコキシシリル末端ポリマーを調製する方法 |
KR20220024582A (ko) | 2019-06-21 | 2022-03-03 | 다우 실리콘즈 코포레이션 | 요변성 경화성 실리콘 조성물을 생성하는 방법 |
Family Cites Families (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3122522A (en) * | 1961-10-16 | 1964-02-25 | Dow Corning | One-component room temperature curing system employing new silicone intermediates |
BE623601A (es) * | 1961-10-16 | 1900-01-01 | ||
GB1154724A (en) * | 1965-08-11 | 1969-06-11 | Midland Silicones Ltd | Improvements in or relating to Organopolysiloxanes |
US3334067A (en) * | 1966-04-08 | 1967-08-01 | Dow Corning | Method of making one component room temperature curing siloxane rubbers |
DE1745171A1 (de) * | 1967-02-22 | 1971-09-23 | Midland Silicones Ltd | Verfahren zur Herstellung von Elastomere bildenden Siloxanmassen |
US3542901A (en) * | 1968-06-26 | 1970-11-24 | Midland Silicones Ltd | Organosilicon compositions |
US3856839A (en) * | 1971-01-06 | 1974-12-24 | Gen Electric | Alkanedioxy titanium chelates |
US4111890A (en) * | 1977-12-19 | 1978-09-05 | Sws Silicones Corporation | Curable organopolysiloxane compositions containing titanium esters |
JPS5543119A (en) * | 1978-09-20 | 1980-03-26 | Sws Silicones Corp | Titanium ester contained vulcanizable organopolysiloxane composition and its manufacture |
US4438039A (en) * | 1980-07-02 | 1984-03-20 | General Electric Company | Titanium chelate catalyst for silicone compositions |
US4525400A (en) * | 1982-09-27 | 1985-06-25 | General Electric Company | Composition for promoting adhesion of curable silicones to substrates |
US4599394A (en) * | 1982-12-02 | 1986-07-08 | General Electric Company | Process for producing alkoxy-terminated polysiloxanes |
ZA837448B (en) * | 1982-12-02 | 1984-05-30 | Gen Electric | Process for producing alkoxy-terminated polysiloxanes |
US4579964A (en) * | 1983-03-31 | 1986-04-01 | Union Carbide Corporation | Alkoxysilyl functional silicones |
JPS61200167A (ja) * | 1985-03-01 | 1986-09-04 | Shin Etsu Chem Co Ltd | 湿気硬化性シリコ−ン組成物 |
JPS61247756A (ja) * | 1985-04-26 | 1986-11-05 | Toray Silicone Co Ltd | 室温硬化性オルガノポリシロキサン組成物 |
US4652624A (en) * | 1986-03-03 | 1987-03-24 | Dow Corning Corporation | Room-temperature-curing silicone sealants |
US4711928A (en) * | 1986-03-03 | 1987-12-08 | Dow Corning Corporation | Moisture cured one-part RTV silicone sealant |
US4687829A (en) * | 1986-03-03 | 1987-08-18 | Dow Corning Corporation | Method of adjusting physical properties in silicone elastomeric sealant |
-
1986
- 1986-03-03 US US06/835,814 patent/US4871827A/en not_active Expired - Lifetime
-
1987
- 1987-01-21 CA CA000527789A patent/CA1282894C/en not_active Expired - Lifetime
- 1987-02-09 JP JP62026531A patent/JP2529237B2/ja not_active Expired - Lifetime
- 1987-02-24 EP EP87301569A patent/EP0236042B1/en not_active Expired - Lifetime
- 1987-02-24 DE DE3788966T patent/DE3788966T2/de not_active Expired - Lifetime
- 1987-02-27 ES ES8700540A patent/ES2008718A6/es not_active Expired
- 1987-03-03 AU AU69618/87A patent/AU590394B2/en not_active Ceased
Also Published As
Publication number | Publication date |
---|---|
JP2529237B2 (ja) | 1996-08-28 |
AU590394B2 (en) | 1989-11-02 |
DE3788966D1 (de) | 1994-03-17 |
JPS62207383A (ja) | 1987-09-11 |
AU6961887A (en) | 1987-09-10 |
DE3788966T2 (de) | 1994-08-11 |
US4871827A (en) | 1989-10-03 |
EP0236042A3 (en) | 1989-01-25 |
EP0236042B1 (en) | 1994-02-02 |
EP0236042A2 (en) | 1987-09-09 |
CA1282894C (en) | 1991-04-09 |
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