ES2000211A6 - Procedimiento para transesterificar metacrilato de metilo por medio de un alcohol pesado - Google Patents
Procedimiento para transesterificar metacrilato de metilo por medio de un alcohol pesadoInfo
- Publication number
- ES2000211A6 ES2000211A6 ES8600230A ES8600230A ES2000211A6 ES 2000211 A6 ES2000211 A6 ES 2000211A6 ES 8600230 A ES8600230 A ES 8600230A ES 8600230 A ES8600230 A ES 8600230A ES 2000211 A6 ES2000211 A6 ES 2000211A6
- Authority
- ES
- Spain
- Prior art keywords
- transesterification
- preparation
- methacrylic esters
- azeotrope
- methyl methacrylate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 125000005395 methacrylic acid group Chemical group 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- 238000005809 transesterification reaction Methods 0.000 title 1
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 abstract 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 229910052744 lithium Inorganic materials 0.000 abstract 1
- 239000012429 reaction media Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/03—Preparation of carboxylic acid esters by reacting an ester group with a hydroxy group
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
LA PRESENTE INVENCION SE REFIERE A UN PROCEDIMIENTO DE TRANSESTERIFICACION DE METACRILATO DE METILO POR UN ALCOHOL PESADO, EN PRESENCIA DE LITIO COMO CATALIZADOR, CARACTERIZADO PORQUE LA CANTIDAD DE LTIO UTILIZADA ESTA COMPRENDIDA ENTRE 6 Y 30 PPM (EXPRESADA EN LITIO) DE HIDROXIDO O DE CARBONATO DE LITIO, EL COMPUESTO DE LITIO UTILIZADO SE AÑADE PROGRESIVAMENTE AL MEDIO DE REACCION, Y LA REACCION SE EFECTUA EN PRESENCIA DE UN FORMADOR DE AZEOTROPO QUE DA, CON EL METANOL, UN AZEOTROPO QUE HIERVE A TEMPERATURA INFERIOR A UNOS 60JC.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR8510674A FR2584711B1 (fr) | 1985-07-11 | 1985-07-11 | Procede de preparation d'esters methacrylique par transesterification |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2000211A6 true ES2000211A6 (es) | 1988-01-16 |
Family
ID=9321221
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES8600230A Expired ES2000211A6 (es) | 1985-07-11 | 1986-07-10 | Procedimiento para transesterificar metacrilato de metilo por medio de un alcohol pesado |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US4791221A (es) |
| EP (1) | EP0210907B1 (es) |
| AT (1) | ATE46317T1 (es) |
| BR (1) | BR8603245A (es) |
| CA (1) | CA1250591A (es) |
| DE (1) | DE3665576D1 (es) |
| ES (1) | ES2000211A6 (es) |
| FR (1) | FR2584711B1 (es) |
| IN (1) | IN167812B (es) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5072027A (en) * | 1988-10-06 | 1991-12-10 | Hitachi Chemical Company, Ltd. | Process for producing methacrylic acid esters |
| DE3836093A1 (de) * | 1988-10-22 | 1990-04-26 | Degussa | Verfahren zur herstellung von hochsiedenden acrylaten bzw. methacrylaten |
| CA2012935A1 (en) * | 1989-03-31 | 1990-09-30 | Hirozo Segawa | Purification and preparation processes for methyl methacrylate |
| DE4314111A1 (de) * | 1993-04-29 | 1994-11-03 | Goldschmidt Ag Th | alpha,omega-Polymethacrylatdiole, Verfahren zu ihrer Herstellung und deren Verwendung zur Herstellung von Polymeren, insbesondere Polyurethanen und Polyestern |
| US5567838A (en) * | 1995-06-02 | 1996-10-22 | Aristech Chemical Corporation | Transesterification reaction of alkoxylated bisphenol-a and methyl methacrylate |
| DE19930721C2 (de) * | 1999-07-05 | 2001-12-20 | Roehm Gmbh | Verfahren zur Herstellung und Prozeßinhibierung von Isobornylmethacrylat |
| DE10127941A1 (de) | 2001-06-08 | 2002-05-29 | Basf Ag | Verfahren zur Herstellung von (Meth)acrylsäureestern |
| DE10127939A1 (de) | 2001-06-08 | 2002-05-29 | Basf Ag | Verfahren zur Herstellung von (Meth)acrylsäureestern |
| US20060173191A1 (en) * | 2005-01-28 | 2006-08-03 | Curtis Michael A | Transesterification process for production of (meth)acrylate ester monomers |
| DE102007031473A1 (de) * | 2007-07-05 | 2009-01-08 | Evonik Röhm Gmbh | Verfahren zur Herstellung von Ethylenglycoldimethacrylat |
| DE102008040221A1 (de) * | 2008-07-07 | 2010-01-14 | Evonik Röhm Gmbh | Verfahren zur Herstellung von (Meth)acrylsäureestern |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2406561A (en) * | 1943-12-27 | 1946-08-27 | Nasa | Azeotropic distillation of methanol from admixture with acrylic esters |
| GB1573071A (en) * | 1977-02-10 | 1980-08-13 | Mitsubishi Rayon Co | Process for producing unsaturated carbocylic acid esters |
| DE2744641B2 (de) * | 1977-10-04 | 1979-08-02 | Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler, 6000 Frankfurt | Verfahren zur Herstellung von Estern der Methacrylsäure |
| EP0044409B1 (en) * | 1980-06-20 | 1984-01-11 | Asahi Kasei Kogyo Kabushiki Kaisha | Process for purifying methyl methacrylate |
-
1985
- 1985-07-11 FR FR8510674A patent/FR2584711B1/fr not_active Expired
-
1986
- 1986-07-09 AT AT86401520T patent/ATE46317T1/de not_active IP Right Cessation
- 1986-07-09 DE DE8686401520T patent/DE3665576D1/de not_active Expired
- 1986-07-09 EP EP86401520A patent/EP0210907B1/fr not_active Expired
- 1986-07-10 ES ES8600230A patent/ES2000211A6/es not_active Expired
- 1986-07-10 CA CA000513517A patent/CA1250591A/fr not_active Expired
- 1986-07-10 BR BR8603245A patent/BR8603245A/pt not_active IP Right Cessation
- 1986-07-10 IN IN529/MAS/86A patent/IN167812B/en unknown
- 1986-07-11 US US06/884,631 patent/US4791221A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| ATE46317T1 (de) | 1989-09-15 |
| EP0210907A1 (fr) | 1987-02-04 |
| IN167812B (es) | 1990-12-22 |
| BR8603245A (pt) | 1987-02-24 |
| FR2584711B1 (fr) | 1987-10-30 |
| FR2584711A1 (fr) | 1987-01-16 |
| CA1250591A (fr) | 1989-02-28 |
| DE3665576D1 (en) | 1989-10-19 |
| US4791221A (en) | 1988-12-13 |
| EP0210907B1 (fr) | 1989-09-13 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| BR9712940A (pt) | Processo para a produção de acetato de etila de etanol | |
| ES2000211A6 (es) | Procedimiento para transesterificar metacrilato de metilo por medio de un alcohol pesado | |
| GB2005252A (en) | A process for the production of esters of methacrylic acid | |
| JPS5217448A (en) | Symmetric synthesis of chrysanthemumic acid primary alcohol ester | |
| MORTENSON et al. | Hydrogenase | |
| ES8507460A1 (es) | Procedimiento para preparar esteres de alquilo c8-c20 de acido 3,5-di-terc-butil-4-hidroxibenzoico | |
| MX9604040A (es) | Esterificacion de acido (met)acrilico con un alcanol. | |
| JPS5799556A (en) | Preparation of methacrylic and acrylic ester | |
| JPS53141216A (en) | Preparation of methacrylic acid ester | |
| JPS5424821A (en) | Preparation of fluoric acid fluoride containing ester group | |
| JPS5793930A (en) | Preparation of methacrylic ester | |
| JPS5334714A (en) | Preparation of dialkylaminoalkyl acrylate and dialkylaminoalkyl methacrylate | |
| JPS5531046A (en) | Preparation of acrylic or methacrylic ester | |
| ES476885A1 (es) | Procedimiento de preparacion de esteres etilicos de acidos -carboxilicos. | |
| JPS55323A (en) | Preparation of methyl tertiary-butyl ether | |
| GB1492338A (en) | Production of methacrylic and acrylic acid and derivatives thereof | |
| JPS54163517A (en) | Production of dialkylaminoalkyl acrylate or dialkylaminoalkyl methacrylate | |
| JPS5750888A (en) | Preparation of alcohol by fermentation | |
| JPS5559122A (en) | Preparation of diol | |
| Piepre | WATER AND CORROSION TECHNOLOGY OF LIGHT WATER RESEARCH REACTOR | |
| JPS5344517A (en) | Preparation of dialkylaminoalkyl esters of acrylic or methacrylic acid | |
| JPS5439009A (en) | Preparation of methacrylate | |
| JPS5379090A (en) | Preparation of yeast cells | |
| JPS57156439A (en) | Continuous preparation of monochloroacetic acid ester | |
| JPS56112954A (en) | Stabilizer for halogen-containing resin |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PC1A | Transfer granted |
Owner name: GREAT LAKES CHEMICAL FRANCE S.A. |