GB2005252A - A process for the production of esters of methacrylic acid - Google Patents
A process for the production of esters of methacrylic acidInfo
- Publication number
- GB2005252A GB2005252A GB7834883A GB7834883A GB2005252A GB 2005252 A GB2005252 A GB 2005252A GB 7834883 A GB7834883 A GB 7834883A GB 7834883 A GB7834883 A GB 7834883A GB 2005252 A GB2005252 A GB 2005252A
- Authority
- GB
- United Kingdom
- Prior art keywords
- methacrylic acid
- esters
- production
- transesterification catalyst
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 title abstract 2
- 150000002148 esters Chemical class 0.000 title abstract 2
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 abstract 3
- 239000003054 catalyst Substances 0.000 abstract 2
- 238000005809 transesterification reaction Methods 0.000 abstract 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 abstract 1
- 150000001298 alcohols Chemical class 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 239000003112 inhibitor Substances 0.000 abstract 1
- 239000000376 reactant Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/03—Preparation of carboxylic acid esters by reacting an ester group with a hydroxy group
Abstract
Esters of methacrylic acid are produced by transesterifying methacrylic acid methyl ester with alcohols containing at least 2 carbon atoms in the presence of a transesterification catalyst and a polymerisation inhibitor, the transesterification catalyst being lithium hydroxide used in a quantity of from 0.01 to 2% by weight, based on the total weight of the reactants.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE2744641A DE2744641B2 (en) | 1977-10-04 | 1977-10-04 | Process for the preparation of esters of methacrylic acid |
Publications (1)
Publication Number | Publication Date |
---|---|
GB2005252A true GB2005252A (en) | 1979-04-19 |
Family
ID=6020635
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB7834883A Withdrawn GB2005252A (en) | 1977-10-04 | 1978-08-29 | A process for the production of esters of methacrylic acid |
Country Status (8)
Country | Link |
---|---|
JP (1) | JPS5461117A (en) |
BE (1) | BE870998A (en) |
BR (1) | BR7806296A (en) |
DE (1) | DE2744641B2 (en) |
FR (1) | FR2405237A1 (en) |
GB (1) | GB2005252A (en) |
IT (1) | IT1107494B (en) |
NL (1) | NL7807305A (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2566393A1 (en) * | 1984-06-26 | 1985-12-27 | Roehm Gmbh | PROCESS FOR THE PREPARATION OF ESTERS OF ACRYLIC AND METHACRYLIC ACIDS BY TRANS-ESTERIFICATION |
FR2566394A1 (en) * | 1984-06-26 | 1985-12-27 | Roehm Gmbh | PROCESS FOR THE PREPARATION OF ESTERS OF ACRYLIC AND METHACRYLIC ACIDS BY TRANS-ESTERIFICATION |
FR2584711A1 (en) * | 1985-07-11 | 1987-01-16 | Organo Synthese Ste Fse | PROCESS FOR THE PREPARATION OF METHACRYL ESTERS BY TRANSESTERIFICATION |
EP0292215A2 (en) * | 1987-05-19 | 1988-11-23 | Hitachi Chemical Co., Ltd. | Method for production of methacrylate ester |
EP0534666A2 (en) * | 1991-09-27 | 1993-03-31 | International Speciality Chemicals Limited | Process for the preparation of acrylic acid and methacrylic acid esters |
CN106966913A (en) * | 2017-04-06 | 2017-07-21 | 青岛科技大学 | A kind of preparation method of improved methacrylic acid dialkylamino ethyl ester |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5677242A (en) * | 1979-11-29 | 1981-06-25 | Mitsui Toatsu Chem Inc | Production of butyl methacrylate |
JPH0729981B2 (en) * | 1985-09-24 | 1995-04-05 | ダイセル化学工業株式会社 | Method for producing composition comprising glycidol ester unsaturated monomer |
US4780555A (en) * | 1988-01-04 | 1988-10-25 | Dow Corning Corporation | Method for preparing and stabilizing acryl-functional halosilanes |
US5072027A (en) * | 1988-10-06 | 1991-12-10 | Hitachi Chemical Company, Ltd. | Process for producing methacrylic acid esters |
DE3836093A1 (en) * | 1988-10-22 | 1990-04-26 | Degussa | METHOD FOR THE PRODUCTION OF HIGH-SEEDANT ACRYLATES OR METHACRYLATES |
JP4137228B2 (en) * | 1998-04-27 | 2008-08-20 | 旭化成ケミカルズ株式会社 | Method for producing cyclohexyl methacrylate |
US6441220B1 (en) * | 1999-06-16 | 2002-08-27 | Sumitomo Chemical Company, Limited | Methods for producing cyclopropane carboxylates |
DE102005044250A1 (en) * | 2005-09-15 | 2007-03-29 | Röhm Gmbh | Process for the preparation of methacrylates with reactive double bonds |
JP5530606B2 (en) * | 2008-07-10 | 2014-06-25 | 国立大学法人 東京大学 | Method for producing triphenylene carboxylic acid ester |
US9150673B2 (en) | 2011-07-06 | 2015-10-06 | Basf Se | Process for preparing (meth)acrylic esters |
CN103635462B (en) | 2011-07-06 | 2016-09-14 | 巴斯夫欧洲公司 | The method of preparation (methyl) acrylate |
JP2014043418A (en) * | 2012-08-27 | 2014-03-13 | Toho Titanium Co Ltd | Method for producing asymmetric malonic acid diesters |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2902500A (en) * | 1958-05-08 | 1959-09-01 | Baker Castor Oil Co | Production of mono-esters |
FR1544542A (en) * | 1966-11-16 | 1968-10-31 | Lonza Ag | Improvements to acrylic acid ester manufacturing processes |
US3780004A (en) * | 1972-09-25 | 1973-12-18 | Nat Distillers Chem Corp | Process for the accelerated alcoholysis of ethylene-vinyl ester interpolymers in the solid phase |
JPS5855974B2 (en) * | 1975-04-23 | 1983-12-13 | 帝人株式会社 | Polyester material |
-
1977
- 1977-10-04 DE DE2744641A patent/DE2744641B2/en not_active Withdrawn
-
1978
- 1978-07-05 NL NL7807305A patent/NL7807305A/en not_active Application Discontinuation
- 1978-08-22 FR FR7824336A patent/FR2405237A1/en not_active Withdrawn
- 1978-08-29 GB GB7834883A patent/GB2005252A/en not_active Withdrawn
- 1978-09-25 BR BR7806296A patent/BR7806296A/en unknown
- 1978-10-03 BE BE6046628A patent/BE870998A/en unknown
- 1978-10-03 JP JP12191078A patent/JPS5461117A/en active Pending
- 1978-10-03 IT IT51344/78A patent/IT1107494B/en active
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2566393A1 (en) * | 1984-06-26 | 1985-12-27 | Roehm Gmbh | PROCESS FOR THE PREPARATION OF ESTERS OF ACRYLIC AND METHACRYLIC ACIDS BY TRANS-ESTERIFICATION |
FR2566394A1 (en) * | 1984-06-26 | 1985-12-27 | Roehm Gmbh | PROCESS FOR THE PREPARATION OF ESTERS OF ACRYLIC AND METHACRYLIC ACIDS BY TRANS-ESTERIFICATION |
GB2163149A (en) * | 1984-06-26 | 1986-02-19 | Roehm Gmbh | Preparation of esters of acrylic and methacrylic acid |
FR2584711A1 (en) * | 1985-07-11 | 1987-01-16 | Organo Synthese Ste Fse | PROCESS FOR THE PREPARATION OF METHACRYL ESTERS BY TRANSESTERIFICATION |
EP0210907A1 (en) * | 1985-07-11 | 1987-02-04 | Societe Francaise D'organo-Synthese | Process for the preparation of methacrylic esters by transesterification |
EP0292215A2 (en) * | 1987-05-19 | 1988-11-23 | Hitachi Chemical Co., Ltd. | Method for production of methacrylate ester |
EP0292215A3 (en) * | 1987-05-19 | 1990-08-22 | Hitachi Chemical Co., Ltd. | Method for production of methacrylate ester |
EP0534666A2 (en) * | 1991-09-27 | 1993-03-31 | International Speciality Chemicals Limited | Process for the preparation of acrylic acid and methacrylic acid esters |
EP0534666A3 (en) * | 1991-09-27 | 1994-10-19 | Bp Chem Int Ltd | Process for the preparation of acrylic acid and methacrylic acid esters |
CN106966913A (en) * | 2017-04-06 | 2017-07-21 | 青岛科技大学 | A kind of preparation method of improved methacrylic acid dialkylamino ethyl ester |
Also Published As
Publication number | Publication date |
---|---|
FR2405237A1 (en) | 1979-05-04 |
DE2744641A1 (en) | 1979-04-05 |
IT1107494B (en) | 1985-11-25 |
DE2744641B2 (en) | 1979-08-02 |
NL7807305A (en) | 1979-04-06 |
JPS5461117A (en) | 1979-05-17 |
BE870998A (en) | 1979-04-03 |
IT7851344A0 (en) | 1978-10-03 |
BR7806296A (en) | 1979-05-29 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
WAP | Application withdrawn, taken to be withdrawn or refused ** after publication under section 16(1) |