EP4171231A1 - Agent de soin désinfectant toléré par la peau servant à des fins d'application sur la peau - Google Patents

Agent de soin désinfectant toléré par la peau servant à des fins d'application sur la peau

Info

Publication number
EP4171231A1
EP4171231A1 EP21735699.7A EP21735699A EP4171231A1 EP 4171231 A1 EP4171231 A1 EP 4171231A1 EP 21735699 A EP21735699 A EP 21735699A EP 4171231 A1 EP4171231 A1 EP 4171231A1
Authority
EP
European Patent Office
Prior art keywords
skin
cream
disinfecting
agent
chlorine
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
EP21735699.7A
Other languages
German (de)
English (en)
Inventor
Rainer Pommersheim
Denis Breuch
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Merlin Apotheke Ruth Gebhardt U Dr Frank Ullrich oHG
Tulichem GmbH
Original Assignee
Merlin Apotheke Ruth Gebhardt U Dr Frank Ullrich oHG
Tulichem GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Merlin Apotheke Ruth Gebhardt U Dr Frank Ullrich oHG, Tulichem GmbH filed Critical Merlin Apotheke Ruth Gebhardt U Dr Frank Ullrich oHG
Publication of EP4171231A1 publication Critical patent/EP4171231A1/fr
Pending legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K31/00—Medicinal preparations containing organic active ingredients
    • A61K31/13—Amines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
    • A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
    • A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
    • A01N41/04—Sulfonic acids; Derivatives thereof
    • A01N41/06—Sulfonic acid amides
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
    • A01P1/00—Disinfectants; Antimicrobial compounds or mixtures thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K31/00—Medicinal preparations containing organic active ingredients
    • A61K31/13—Amines
    • A61K31/145—Amines having sulfur, e.g. thiurams (>N—C(S)—S—C(S)—N< and >N—C(S)—S—S—C(S)—N<), Sulfinylamines (—N=SO), Sulfonylamines (—N=SO2)
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K31/00—Medicinal preparations containing organic active ingredients
    • A61K31/16—Amides, e.g. hydroxamic acids
    • A61K31/18—Sulfonamides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K33/00—Medicinal preparations containing inorganic active ingredients
    • A61K33/20—Elemental chlorine; Inorganic compounds releasing chlorine
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/042—Gels
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/20—Halogens; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/29—Titanium; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36—Carboxylic acids; Salts or anhydrides thereof
    • A61K8/361—Carboxylic acids having more than seven carbon atoms in an unbroken chain; Salts or anhydrides thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41—Amines
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A61K8/466—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfonic acid derivatives; Salts
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8147—Homopolymers or copolymers of acids; Metal or ammonium salts thereof, e.g. crotonic acid, (meth)acrylic acid; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K9/00—Medicinal preparations characterised by special physical form
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P31/00—Antiinfectives, i.e. antibiotics, antiseptics, chemotherapeutics
    • A61P31/02—Local antiseptics
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
    • A61Q17/005—Antimicrobial preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
    • A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations

Definitions

  • the invention relates to a disinfecting, skin-friendly, caring agent for application to the skin and for treating it, comprising one or more water-soluble chlorine derivatives as disinfecting active ingredient, a cream based on such an agent and a dispenser, jar, tube or packaging with a disinfectant or a related cream or gel according to the teaching of the independent claims.
  • Products which can be applied to the skin and which have a disinfecting, germ-reducing effect when applied to the skin.
  • Well-known preparations are based on the active ingredients isopropanol, ethanol or other alcohols.
  • gels are known in which the alcohol has been thickened.
  • the alcohol In order to develop a sufficient disinfecting effect here, the alcohol must be present in a concentration of at least 70%. Such a concentration can easily be achieved with gels. A cream cannot be manufactured with regard to these concentrations.
  • a chloramine-containing wound treatment agent is previously known from DE 10 2006 043 245 A1.
  • a wound compress containing 10% chloramine is obtained by spraying with a chloramine-T solution.
  • the presented system can be primarily suitable for bleeding wounds with simultaneous disinfection by the aqueous chloramine solution for supply.
  • EP 1 955 591 A1 reference is made to a benzalkonium chloride as a disinfectant and an antimicrobial skin treatment agent in a cream base with regard to the agent for the care and antimicrobial treatment of the skin.
  • This cream has the aforementioned benzalkonium chloride as the only pharmaceutically active ingredient.
  • a related ointment is based on viscous to solid paraffin, wool wax and / or white vaseline.
  • the agent according to EP 1 955 591 A1 should also be suitable for caring disinfection of the skin, in particular for doctors or medical personnel.
  • the object of the invention to provide a further developed, disinfectant, skin-friendly, caring agent, in particular a cream, for application to the skin, which, in addition to good skin compatibility and a caring and greasy effect, also has a demonstrably sufficient disinfecting effect unfolded, whereby it is primarily not about a wound disinfection, but about the everyday use for hand disinfection and thus to interrupt possible chains of infection.
  • a cream is understood to be an oil-in-water emulsion or water-in-oil emulsion that makes ingredients applicable. Compared to ointments, creams have a lower viscosity, i.e. more liquid, and are well absorbed by the skin. Emulsifiers or emulsion stabilizers are often used in creams. In common parlance, creams are also referred to as non-medical, purely care products.
  • a disinfecting, skin-friendly, caring agent for application to the skin or for treating the skin according to the combination of features according to claim 1, a cream or gel according to claim 4 or a dispenser, a can, a tube or a packaging according to claim 8 solved.
  • the agent according to the invention does not rely on an alcohol as the disinfecting active ingredient, but on a chlorine derivative. Such an active ingredient is recommended and suitable as a disinfectant in appropriate concentrations when applied to the skin.
  • the chlorine derivatives used in the formulation according to the invention are readily soluble in water and can be incorporated very easily into the cream in the recommended concentrations.
  • Tests carried out with test persons who were carried out with the cream according to the invention demonstrate the germicidal effect with good skin tolerance at the same time.
  • the disinfecting, skin-friendly care agent is based on one or more water-soluble chlorine derivatives as the disinfecting agent.
  • the chlorine derivative (s) are incorporated into a base cream or gel matrix.
  • the cream or gel contains a mixture of substances to mask the odor of the otherwise olfactory perceptible chlorine component.
  • the means has at least one fragrance or a mixture of fragrances.
  • a defined amount of functional active ingredients can be added to the specified formulation.
  • This can be, for example, an active ingredient for moistening or for protection against harmful radiation, in particular ultraviolet radiation.
  • the cream according to the invention based on the agent explained is characterized in that the amount of the chlorine derivative used, in particular chloramine-T, is essentially up to 5% by weight, preferably and in particular up to 2% by weight.
  • the base cream contains at least glycerides, vaseline and stearates.
  • the gel matrix contains at least sodium polyacrylate or water.
  • the disinfecting component i.e. the chlorine derivatives
  • the chlorine derivatives is preferably chloramine-T, sodium hypochlorite or similar substances.
  • the proposed agent or the corresponding cream is free of alcohols with regard to the disinfectant active ingredient.
  • the skin is not degreased as is the case with conventional liquid disinfectants.
  • a dispenser, a can, a tube or similar packaging with the proposed agent or a corresponding cream for different applications, in particular for application to the human skin, is in accordance with the invention.
  • the base cream matrix used combines all of the ingredients required for skin care and ensures that the cream has a greasy and nourishing effect.
  • the disinfecting agent is based on water-soluble chlorine derivatives, which are recognized disinfectants and meet official requirements.
  • the substance mixture for odor marking is a mixture of dermatologically approved components with the aim of masking the chlorine odor released by the disinfecting agent.
  • Usable fragrances give the cream a pleasant smell. These can be essential oils or other fragrances or mixtures made from them. Urea, for example, can be used with the functional active ingredients to achieve an additional moisturizing effect. However, a means for absorbing ultraviolet radiation can also be used.
  • a commercially available product can be used in particular for the base cream.
  • Such a base cream includes the following exemplary ingredients:
  • Glycerol Monostearate 60 Cetyl Alcohol, Medium Chain Triglycerides, White Vaseline, Macrogol 20 Glycerol Monostearate, Propylene Glycol, and Purified Water.
  • Chlorine derivatives such as chloramine-T or sodium hypochlorite are used for the disinfecting agent.
  • concentration in the cream is 2% by weight. This is a harmless upper limit at which a sufficient disinfecting effect is demonstrably given.
  • compositions are exemplary:
  • Ingredients mixture B Hexyl salicylate, 3,7-dimethyloctan-3-ol, l- (l, 2,3,4,5,6,7,80ctahydro- 2,3,8,8tetramethyl-2naphthyl) ethan-l-one, 2H- Pyran-4-ol, tetrahydro-4-methyl-2 (2-methylpropyl) -, benzenepentanol, b-methyl-, benzenepropanol, .beta.,.
  • Essential oils such as rose oil, lavender oil or the like or mixtures of such essential oils are used as fragrances.
  • the functional active ingredients mentioned do not have to be part of the cream, but can improve its effect and ensure further applications.
  • a titanium dioxide can be added to the cream as a means of protection against ultraviolet radiation in order to ensure an appropriate sun protection factor.
  • a ready-to-sell cream as a disinfectant, skin-friendly and caring agent comprises at least the base cream and the disinfectant active ingredient in the form of water-soluble chlorine derivatives.
  • the cream according to the invention is bottled after processing and production.
  • a filling can be carried out here in a suitable dispenser, in a can, a tube or similar packaging.
  • the cream is applied by applying it to the skin and gently rubbing it in, which unfolds its disinfecting and, at the same time, nourishing effect.
  • the cream presented can either be used on its own or for subsequent skin care after using alcohol-based disinfecting products.
  • this is transparent or translucent.
  • the spheres which are encapsulated, create a special optical effect.
  • the beads are of a different color than the base cream or are particularly noticeable visually with regard to the transparent cream.
  • the beads which contain additional active ingredients, float within the gel or are distributed in the volume of the cream.
  • the beads with encapsulated additives incorporated therein are substantially 2 mm in diameter.

Landscapes

  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Public Health (AREA)
  • Animal Behavior & Ethology (AREA)
  • Chemical & Material Sciences (AREA)
  • Epidemiology (AREA)
  • Pharmacology & Pharmacy (AREA)
  • Medicinal Chemistry (AREA)
  • Birds (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental Sciences (AREA)
  • Plant Pathology (AREA)
  • Pest Control & Pesticides (AREA)
  • Inorganic Chemistry (AREA)
  • Agronomy & Crop Science (AREA)
  • Dentistry (AREA)
  • Dispersion Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Dermatology (AREA)
  • Oncology (AREA)
  • Organic Chemistry (AREA)
  • Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
  • Communicable Diseases (AREA)
  • Toxicology (AREA)
  • Emergency Medicine (AREA)
  • Cosmetics (AREA)
  • Medicinal Preparation (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

L'invention concerne un agent de soin désinfectant toléré par la peau servant à des fins d'application sur la peau ou à des fins de traitement de celle-ci, comprenant un ou plusieurs dérivés de chlore solubles dans l'eau en tant que substance active désinfectante, le(s) dérivé(s) de chlore étant incorporé(s) dans une matrice de crème ou de gel de base et contenant en outre un mélange de substances servant à masquer les odeurs du composant de chlore.
EP21735699.7A 2020-06-30 2021-06-24 Agent de soin désinfectant toléré par la peau servant à des fins d'application sur la peau Pending EP4171231A1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE202020103775 2020-06-30
DE202020104277.7U DE202020104277U1 (de) 2020-06-30 2020-07-24 Desinfizierendes, hautverträgliches, pflegendes Mittel zum Auftragen auf die Haut
PCT/EP2021/067357 WO2022002752A1 (fr) 2020-06-30 2021-06-24 Agent de soin désinfectant toléré par la peau servant à des fins d'application sur la peau

Publications (1)

Publication Number Publication Date
EP4171231A1 true EP4171231A1 (fr) 2023-05-03

Family

ID=72289608

Family Applications (1)

Application Number Title Priority Date Filing Date
EP21735699.7A Pending EP4171231A1 (fr) 2020-06-30 2021-06-24 Agent de soin désinfectant toléré par la peau servant à des fins d'application sur la peau

Country Status (7)

Country Link
US (1) US20230310497A1 (fr)
EP (1) EP4171231A1 (fr)
KR (1) KR20230054661A (fr)
CN (1) CN116133521A (fr)
CA (1) CA3184364A1 (fr)
DE (1) DE202020104277U1 (fr)
WO (1) WO2022002752A1 (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE202021103593U1 (de) * 2021-07-05 2021-08-10 Merlin Apotheke am Hochhaus Ruth Gebhardt & Dr. Frank Ullrich OHG Hautverträgliches, pflegendes und schützendes Mittel zum Auftragen auf die Haut

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2223049A1 (en) * 1973-03-30 1974-10-25 Conditionnement Cosmetologie N Halogenate antibacterial compns. - potentiated with alkali metal salts or capric, caproic and caprylic acids
DE19934585A1 (de) * 1999-07-23 2001-01-25 Rapp Horst Salbe zur Behandlung von dermatologischen Erkrankungen
RU2235535C2 (ru) * 2001-06-18 2004-09-10 Набокин Игорь Иванович Средство для лечения местных гнойно-воспалительных процессов кожи и слизистых оболочек
DE102006043245A1 (de) 2006-09-11 2008-03-27 Dunzendorfer, Udo, Priv.-Doz. Dr.med. Chloraminhaltiges Wundbehandlungsmittel
DE102007002073A1 (de) 2007-01-09 2008-07-10 Matthias Habenicht Mittel zur Pflege und antimikrobiellen Behandlung der Haut
EP3446693B1 (fr) * 2015-02-19 2020-11-11 Hiantis S.r.l. Compositions pharmaceutiques et formulations comprenant de l´acétate d'aluminium pour application topique avec effet astringent et antimicrobien
CN109418289A (zh) * 2017-09-05 2019-03-05 上海利康消毒高科技有限公司 一种次氯酸钠凝胶及其制备方法

Also Published As

Publication number Publication date
WO2022002752A1 (fr) 2022-01-06
KR20230054661A (ko) 2023-04-25
US20230310497A1 (en) 2023-10-05
DE202020104277U1 (de) 2020-08-11
CN116133521A (zh) 2023-05-16
CA3184364A1 (fr) 2022-01-06

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