EP3717436A1 - Im wesentlichen im baubereich anwendbare zementzusammensetzung und verfahren zur herstellung davon - Google Patents
Im wesentlichen im baubereich anwendbare zementzusammensetzung und verfahren zur herstellung davonInfo
- Publication number
- EP3717436A1 EP3717436A1 EP17847794.9A EP17847794A EP3717436A1 EP 3717436 A1 EP3717436 A1 EP 3717436A1 EP 17847794 A EP17847794 A EP 17847794A EP 3717436 A1 EP3717436 A1 EP 3717436A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- composition
- cement
- component
- finished product
- materials
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 78
- 239000004568 cement Substances 0.000 title claims abstract description 59
- 238000000034 method Methods 0.000 title claims abstract description 16
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 10
- 239000000463 material Substances 0.000 claims abstract description 41
- 238000002156 mixing Methods 0.000 claims abstract description 21
- 238000009413 insulation Methods 0.000 claims abstract description 4
- 239000011347 resin Substances 0.000 claims abstract description 4
- 229920005989 resin Polymers 0.000 claims abstract description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 17
- 239000004576 sand Substances 0.000 claims description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
- 239000000654 additive Substances 0.000 claims description 11
- 238000010276 construction Methods 0.000 claims description 11
- 239000004033 plastic Substances 0.000 claims description 11
- 229920003023 plastic Polymers 0.000 claims description 11
- 229920000642 polymer Polymers 0.000 claims description 10
- 239000000843 powder Substances 0.000 claims description 10
- 239000002699 waste material Substances 0.000 claims description 10
- 230000000694 effects Effects 0.000 claims description 7
- 239000004411 aluminium Substances 0.000 claims description 6
- 229910052782 aluminium Inorganic materials 0.000 claims description 6
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 claims description 5
- 239000011230 binding agent Substances 0.000 claims description 5
- -1 etc...) Substances 0.000 claims description 5
- 239000001863 hydroxypropyl cellulose Substances 0.000 claims description 5
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 claims description 5
- 239000002245 particle Substances 0.000 claims description 5
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 claims description 4
- 239000004698 Polyethylene Substances 0.000 claims description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L calcium carbonate Substances [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 4
- 239000000945 filler Substances 0.000 claims description 4
- 238000012545 processing Methods 0.000 claims description 4
- 239000004604 Blowing Agent Substances 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 229920001971 elastomer Polymers 0.000 claims description 3
- 238000009415 formwork Methods 0.000 claims description 3
- 239000011521 glass Substances 0.000 claims description 3
- 239000005060 rubber Substances 0.000 claims description 3
- 239000002023 wood Substances 0.000 claims description 3
- CBOCVOKPQGJKKJ-UHFFFAOYSA-L Calcium formate Chemical compound [Ca+2].[O-]C=O.[O-]C=O CBOCVOKPQGJKKJ-UHFFFAOYSA-L 0.000 claims description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 2
- 239000004117 Lignosulphonate Substances 0.000 claims description 2
- 239000004743 Polypropylene Substances 0.000 claims description 2
- 238000010521 absorption reaction Methods 0.000 claims description 2
- 239000012615 aggregate Substances 0.000 claims description 2
- 235000010216 calcium carbonate Nutrition 0.000 claims description 2
- 229940044172 calcium formate Drugs 0.000 claims description 2
- 235000019255 calcium formate Nutrition 0.000 claims description 2
- 239000004281 calcium formate Substances 0.000 claims description 2
- 239000000920 calcium hydroxide Substances 0.000 claims description 2
- 235000011116 calcium hydroxide Nutrition 0.000 claims description 2
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims description 2
- 150000007942 carboxylates Chemical class 0.000 claims description 2
- 239000011111 cardboard Substances 0.000 claims description 2
- LRCFXGAMWKDGLA-UHFFFAOYSA-N dioxosilane;hydrate Chemical compound O.O=[Si]=O LRCFXGAMWKDGLA-UHFFFAOYSA-N 0.000 claims description 2
- 239000000686 essence Substances 0.000 claims description 2
- 239000004794 expanded polystyrene Substances 0.000 claims description 2
- 238000000227 grinding Methods 0.000 claims description 2
- 229920001903 high density polyethylene Polymers 0.000 claims description 2
- 239000004700 high-density polyethylene Substances 0.000 claims description 2
- 239000007970 homogeneous dispersion Substances 0.000 claims description 2
- 238000012994 industrial processing Methods 0.000 claims description 2
- 238000009434 installation Methods 0.000 claims description 2
- 238000004898 kneading Methods 0.000 claims description 2
- 235000019357 lignosulphonate Nutrition 0.000 claims description 2
- 229920001684 low density polyethylene Polymers 0.000 claims description 2
- 239000004702 low-density polyethylene Substances 0.000 claims description 2
- 238000000465 moulding Methods 0.000 claims description 2
- 239000000123 paper Substances 0.000 claims description 2
- 229920000058 polyacrylate Polymers 0.000 claims description 2
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- 238000001179 sorption measurement Methods 0.000 claims description 2
- 239000001913 cellulose Substances 0.000 claims 1
- 229920002678 cellulose Polymers 0.000 claims 1
- 239000000047 product Substances 0.000 description 18
- 238000005266 casting Methods 0.000 description 6
- 239000010440 gypsum Substances 0.000 description 3
- 229910052602 gypsum Inorganic materials 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 2
- 239000013543 active substance Substances 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 240000006909 Tilia x europaea Species 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 239000010813 municipal solid waste Substances 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/04—Portland cements
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/18—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing mixtures of the silica-lime type
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00034—Physico-chemical characteristics of the mixtures
- C04B2111/00103—Self-compacting mixtures
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/34—Non-shrinking or non-cracking materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/60—Flooring materials
- C04B2111/62—Self-levelling compositions
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Definitions
- the invention relates to a composition of cement, applicable substantially in the building field with the function of self-levelling screed both for internal and for external environments, with remarkable mechanical strength and with excellent quality of acoustic insulation and thermal conductivity, for the consecutive laying of tiles, parquet, linoleum, resin or equivalent materials, and it also relates to a process for manufacturing this composition of cement.
- these screeds have to be reinforced with electro-welded or galvanized metallic nets, that on the one hand they are needed to increase the bending strength, on the other hand they are problematic for the workability of the screed, wherein the thickness are generally very small.
- compositions of cement applicable onto the floors of inhabited environments which are constituted substantially by the combination and the mixing into water of a set on mainly components, as for example waste materials, binder materials of various kind for construction, and aerating additives.
- Said waste materials are substantially constituted by the following elements and their derived products, previously ground into particles of reduced grain, waste of heterogeneous plastic materials, wastes of elastomeric materials (rubbers, etc%), municipal solid waste, wastes of wood of various type, aggregate materials for building industry of various kind, glass remainders of various kind, whereas said binder material for construction are substantially constituted by cement, limes, gypsum of various kind, epoxy resins, and/or acrylic resins, whereas said airing additives are substantially constituted by organic and inorganic surface-active substances, and are adapted to help the mixing and the wettability of the same composition.
- the obtained composition is introduced into cement mixers of similar containers, and is pourable on to the floor by means of pumping through supply means, and it is also pourable into moulds or formworks for forming preformed panels with different shapes and dimensions, which are then applicable into the relative application positions.
- the presence of the airing surface-active substances adapted to increase the wettability of and to help the mixing of the composition of cement, during the mixing phase of the composition of cement, produce very damp air bubbles in a non-controllable quantity that, once the screed has been laid, they tend to go up, that is toward the upper surface of the same screed, therefore, during the plastic shrinkage of the composition, there is formed a body with a very stiff lower part and very fragile upper superficial part and subjected to cracks and/or exhaustion, so not perfect for the laying of any additional upper layer, as for example tails, parquet, ecc..
- the stiffness of the lower part of the screed make this latter more fragile during the thermohygrometric deformations, by producing easily internal cracks and/or a swelling thereof in correspondence of the same cracks or the screed comers.
- the scope of the present invention is to realize a composition of cement that deletes all the above- described drawbacks.
- composition of cement applicable substantially in the building field with the function of self-levelling screed both the internal environments and external environments, with remarkable mechanic strength and with great acoustic insulation and thermic conductance qualities, for the subsequent lying of tiles, parquet, linoleum resin or equivalent materials, and it also relates to a process for manufacturing this composition of cement.
- composition of cement according to this invention is substantially constituted by the following main components mixed to each other, the quantities of which added to each other are always 100% of the final product :
- plastic materials of the heterogeneous type i.e. coloured, light blue, transparent PET bottles, bottles neolithes, aggregates, PE, PP, LDPE, HDPE, EPS etc.
- elastomeric materials rubbers, etc
- polymeric plastic compositions poly- coupled materials, etc
- paper, cardboard, wood and wooden essences of various kind aggregate materials for building
- the above-said materials are ground into grinding means of traditional type (grinder mills, etc%) into particles of reduced grain, in the order of from 2 to 20 mm on average, with subsequent homogeneous mixing of all the ground materials, by means of the use of mixing machines of the traditional type, thereby obtaining a mixture of these waste materials.
- Such a first component a) is used in the quantity comprised between Kg. 0,1 and Kg. 4,5 for each Kg. 100,00 of finished product, according to the desired noise abatement and the thermal conductance ;
- a second component constituted by the materials that will be described and that are mixed with the above-said materials of various kind, described in the point a).
- such a second component is constitute by the following materials :
- both the Portland and the Pozzolanico type adapted to act as binder of the composition ;
- Fluidizer and super-fluidizer additives per se known, adapted to improve the workability of the composition of cement and to reduce the use of water ;
- - Hydroxypropyl cellulose having a viscosity comprised between mPas. 100 and 30.000, preferably between mPas. 5.000 and 15.000, and adapted to include the air bubbles formed during the mixing of the composition of cement, in such a way that the resulting screed be lighter and with a low elastic modulus, and that this produced air doesn’t go up toward the upper surface of the same screed, thereby preventing that such a upper surface is friable.
- this latter is less stiff and therefore it may acquire controlled deformations and thermohygrometric variations without cracks of the obtained finished product, namely the screed.
- composition of cement is constituted by the materials of the two above-said component in the quantities comprised in the following limit- values, and it as already previously indicated with a total value of the 100% of finished product : first component from Kg. 0,100 to Kg. 4,50 for each Kg. 100,00 of finished product ; concrete : from Kg. 15,00 to Kg. 30,00 for each Kg. 100,00 of finished product ; fine sand : from Kg. 60,00 to Kg. 80,00 for each Kg. 100,00 of finished product ;
- aluminium powder from Kg. 0,005 to Kg. 1,00 for each Kg. 100,00 of finished product ;
- Hydroxypropyl cellulose from Kg. 0,030 to Kg. 3,00 for each Kg. 100,00 of finished product ; fluidizer and super-fluidizer additives : from Kg. 0,050 to kg. 3,50 for each Kg. 100,00 of finished product .
- fluidizer and super-fluidizer additives from Kg. 0,050 to kg. 3,50 for each Kg. 100,00 of finished product .
- - Third component constituted by per se known filler, that for example may be constituted by finest siliceous sand, or by calcium carbonates, or by silica, hydrated lime, per se known super- fluidizer additives, such as for example the acrylic polymers (i.e. the Primium PC 20), the poly- carboxylates, the naphthalene polymers such as the naphthalen-sulphonated polymers, and the ligno-sulphonates polymers and further known polymers, and melaminic polymers, in quantity comprised in the following limit- values from Kg. 5,00 to Kg. 30,00 for each Kg.
- such a filler being adapted to regulate, when it is needed, the granulometric scale of the sand according to the component, namely by ensuring the stability of the mixture, and by increasing also the compressive strength of the composition of cement at finished product ;
- Fourth component constituted by retarders of the per se known natural type in the form of powder, and adapted to be used when it is planned the kneading of the composition of cement, object of the present invention, in advance to the processing into construction site, as for example into the concrete mixing pant, in such a way to reduce the moisturization grade of the concrete during the first hours, in the case there aren’t sufficient the ftuidizer and super-fluidizer additives, namely by obtaining a mixture where it is produced an adsorption of the organic products onto the concrete, thereby preventing the moisturization of this latter and by allowing the process of the composition of cement also after various hours and therefore be able to perform a possible transportation, said fourth component being in a quantity from Kg. 0,030 to Kg. 3,00 for each Kg.
- - Fifth component constituted by accelerators, constituted as for example by powder of calcium formate, and adapted to reduce the setting time of the composition of cement and to increase its mechanical strength, and so it is adapted to be mixed with the other components of the composition of cement directly on the working construction site, during climates with low temperatures, by accelerating the setting time of the concrete and/or subsequently the use of the above-said fourth component, in such a way that the concrete is moisturized and the setting time of the composition of cement is brought back to the starting state, said fifth component being in a quantity from Kg. 0,100 to Kg. 5,00 for each Kg. 100,00 of finished product.
- the above-said components used for obtaining the desired composition of cement are mixed with water, which is in a quantity comprised in the limit values from Kg. 10,00 and Kg. 30,00 for each Kg. 100,00 of finished product, according to the sand absorption.
- the process for manufacturing the above-said composition of cement, object of the present invention may consider that, the materials of the above-said first and second components, mixed in a homogenous manner to each other at the dried state, be introduced with the above specified quantities, into suitable per se known containers, as for example barrels, silos, bags or receptacles of various kind of the concrete mixing plants of the traditional type, that are then transported, at a dried state with the sole sand humidity, to construction site where there are present the inhabited buildings into which the foreseen works must be effected, where the water is then added with the above-specified quantities into suitable containers wherein there are contained said first and second components mixed to each other at the dried state, and the obtained mixture is further mixed by obtaining the composition of cement, object of the present invention.
- suitable per se known containers as for example barrels, silos, bags or receptacles of various kind of the concrete mixing plants of the traditional type, that are then transported, at a dried state with the sole sand humidity, to construction site
- the materials of the above said first, second and possible third components may be also mixed together the fourth component and the water, with the above specified quantities, into above said suitable containers and with provide quantities, directly into the concrete mixing plants as already described and then transported to the working construction sites where the foreseen works must be effected, in such a way that the fourth component allows a delay of the setting of the composition of cement, making this latter workable also after various hours ; after, the fifth component is then added and mixed together the mixture obtained up to now, with the above specified quantities, in such a way that the setting time of the composition of cement be brought back at the starting state, namely by cancelling the effect of the fourth component since is no longer necessary.
- composition of cement obtained with one of the above said manners is subsequently introduced into a mixing and delivering pump, or similar means, from which the same composition of cement is applied at work by being poured onto the floor and/or on to the walls and/or onto the floor foundations, for fonning the self-levelling screed, or in alternative from which said composition of cement may also be poured into moulding means (moulds, formworks, etc%), for forming preformed panels of forms, dimensions and different appearing, that are applicable subsequently in the relative installation positions.
- moulding means moulding means
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/IT2017/000272 WO2019106699A1 (en) | 2017-11-30 | 2017-11-30 | Composition of cement applicable substantially in the building field and process for manufacturing it |
Publications (1)
Publication Number | Publication Date |
---|---|
EP3717436A1 true EP3717436A1 (de) | 2020-10-07 |
Family
ID=61569304
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP17847794.9A Withdrawn EP3717436A1 (de) | 2017-11-30 | 2017-11-30 | Im wesentlichen im baubereich anwendbare zementzusammensetzung und verfahren zur herstellung davon |
Country Status (3)
Country | Link |
---|---|
EP (1) | EP3717436A1 (de) |
PE (1) | PE20201471A1 (de) |
WO (1) | WO2019106699A1 (de) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US11692082B2 (en) | 2021-02-02 | 2023-07-04 | EcoGensus LLC | Compositions containing solid waste material |
WO2022169896A1 (en) | 2021-02-02 | 2022-08-11 | EcoGensus LLC | Powders comprising solid waste materials |
CN114057434A (zh) * | 2021-11-25 | 2022-02-18 | 东莞市欧丽亚环保材料有限公司 | 隔墙板专用粘结剂及其制备方法 |
CN114133189B (zh) * | 2021-12-24 | 2022-10-18 | 深圳市深建混凝土有限公司 | 一种高强度再生混凝土 |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102005004362C5 (de) * | 2005-01-31 | 2009-06-10 | Elotex Ag | Fliesenkleberzusammensetzung mit Leichtfüllstoff und Verfahren zu ihrer Herstellung |
ITPN20060064A1 (it) * | 2006-08-24 | 2008-02-25 | Sergio Fregonese | Composizione cementizia di materiali isolanti di vario genere |
CN101648797B (zh) * | 2009-06-29 | 2013-02-20 | 上海东升新材料有限公司 | 自流坪干粉砂浆组合物 |
ITPN20120020A1 (it) * | 2012-04-19 | 2013-10-20 | Sergio Fregonese | Procedimento di fabbricazione di una composizione cementizia di materiali di scarto oppure vergini di vario genere, e composizione cementizia cosi¿ ottenuta |
CN104402348B (zh) * | 2014-10-23 | 2016-04-06 | 天元建设集团有限公司 | 铁尾矿粉泡沫混凝土及其制备方法 |
-
2017
- 2017-11-30 EP EP17847794.9A patent/EP3717436A1/de not_active Withdrawn
- 2017-11-30 WO PCT/IT2017/000272 patent/WO2019106699A1/en unknown
- 2017-11-30 PE PE2020000641A patent/PE20201471A1/es unknown
Also Published As
Publication number | Publication date |
---|---|
WO2019106699A1 (en) | 2019-06-06 |
PE20201471A1 (es) | 2020-12-18 |
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