Classifications

• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
  • C10M169/04—Mixtures of base-materials and additives
  • C10M169/044—Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
  • C10M169/04—Mixtures of base-materials and additives
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
  • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
  • C10M2203/1006—Petroleum or coal fractions, e.g. tars, solvents, bitumen used as base material
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
  • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
  • C10M2203/102—Aliphatic fractions
  • C10M2203/1025—Aliphatic fractions used as base material
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
  • C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
  • C10M2205/028—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers containing aliphatic monomers having more than four carbon atoms
  • C10M2205/0285—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers containing aliphatic monomers having more than four carbon atoms used as base material
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
  • C10M2207/04—Ethers; Acetals; Ortho-esters; Ortho-carbonates
  • C10M2207/042—Epoxides
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
  • C10M2207/10—Carboxylix acids; Neutral salts thereof
  • C10M2207/24—Epoxidised acids; Ester derivatives thereof
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
  • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
  • C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
  • C10M2209/084—Acrylate; Methacrylate
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
  • C10M2215/08—Amides
  • C10M2215/082—Amides containing hydroxyl groups; Alkoxylated derivatives
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
  • C10M2215/28—Amides; Imides
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
  • C10M2219/10—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
  • C10M2219/102—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon only in the ring
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
  • C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
  • C10N2020/01—Physico-chemical properties
  • C10N2020/04—Molecular weight; Molecular weight distribution
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
  • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
  • C10N2030/02—Pour-point; Viscosity index
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
  • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
  • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
  • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
  • C10N2030/76—Reduction of noise, shudder, or vibrations
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
  • C10N2040/00—Specified use or application for which the lubricating composition is intended
  • C10N2040/04—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
  • C10N2040/045—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives for continuous variable transmission [CVT]
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
  • C10N2060/00—Chemical after-treatment of the constituents of the lubricating composition
  • C10N2060/06—Chemical after-treatment of the constituents of the lubricating composition by epoxydes or oxyalkylation reactions
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
  • C10N2060/00—Chemical after-treatment of the constituents of the lubricating composition
  • C10N2060/14—Chemical after-treatment of the constituents of the lubricating composition by boron or a compound containing boron

Definitions

• the present invention relates to a lubricating oil composition, especially suitable for use in an automobile transmission. More specifically, the present invention relates to a lubricating oil composition for a non-stage transmission.
• Lubricating oil compositions are widely used in the automotive field for internal combustion engines, automatic transmission, gear oil, etc.
• the demand for low-viscosity lubricating oil compositions has recently increased, in order to achieve fuel efficiency.
• CTV non-stage transmission
• metal belt CVT in which a metal belt and a pulley are used for power transmission, has become generally used.
• Patent Literature 1 describes a lubricating oil composition which comprises a specific boron-free succinimide compound and a phosphorus compound, and does not comprise a zinc dialkyl dithiophosphate, which significantly increases the friction coefficient between the metal belt or chain and the pulley, is capable of maintaining a high friction coefficient over a long period of time, and does not cause clogging of the clutch plates.
• Patent Literature 2 describes a lubricant composition comprising a sulfonate-based detergent, a salicylate-based detergent and a boron-containing succinimide-based additive at specific quantities and specific quantity ratios, which maintains satisfactory torque transmission capacity and transmission properties and excels in its shudder prevention performance.
• Patent Literature 3 describes a lubricating oil composition comprising specific quantities of a boronated alkylsuccinimide and/or boronated alkenylsuccinimide having a specific weight-average molecular weight and a metallic detergent having a linear alkyl group, which has a high intermetallic friction coefficient and excellent transmission properties and shudder prevention performance.
• Patent Literature 4 describes a lubricating oil composition comprising specific quantities of at least one selected from a specific sulfolane derivative, calcium sulfonate and calcium phenate, and a specific viscosity index improver, which has both a high intermetallic friction coefficient and combines fuel efficiency, due to low viscosity, and component durability.
• Patent Literature 5 describes that by combining at least 4 additives, namely calcium salicylate, phosphorus anti-wear agent, friction conditioner and dispersion-type viscosity index improving agent, as essential components, both a high intermetallic friction coefficient and shudder prevention can be achieved.
• the first purpose of the present invention is to provide a lubricating oil composition, whose intermetallic friction coefficient does not decrease and which has extended shudder prevention lifespan, even if the viscosity thereof is lowered.
• the inventors arrived at the present invention after discovering that the shudder prevention lifespan can be extended without decreasing the intermetallic friction coefficient, even at low viscosity, if two types of succinimide compounds having specific weight-average molecular weights are combined as an ashless dispersant and used together with a specific friction modifier.
• the present invention is a lubricating oil composition
• a lubricating oil composition comprising
• the inventors discovered that by further specifying the compositions of the lubricant base oil (A) and the viscosity index improver in the above lubricating oil composition, the shear stability can be improved, in addition to an effect of extending the shudder prevention lifespan without decreasing the intermetallic friction coefficient.
• the lubricating oil composition of the present invention preferably further comprises, as a part or all of component (A), 5 to 30 percent by weight, based on a total weight of the lubricating oil composition, of a poly- ⁇ -olefin or ⁇ -olefin copolymer having a kinematic viscosity at 100°C of 6 to 80 mm 2 /s, and further comprising (B) a polymethacrylate having a weight-average molecular weight of 15,000 to 40,000.
• preferable embodiments of the lubricating oil composition of the present invention have at least one following featues (1) to (11).
• the lubricating oil composition preferably comprises, as a part or all of component (A), 5 to 30 percent by weight, based on a total weight of the lubricating oil composition, of a poly- ⁇ -olefin or ⁇ -olefin copolymer having a kinematic viscosity at 100°C of 6 to 80 mm 2 /s, and (E) an ether sulfolane compound.
• component (A) a poly- ⁇ -olefin or ⁇ -olefin copolymer having a kinematic viscosity at 100°C of 6 to 80 mm 2 /s
• E an ether sulfolane compound.
• synthetic base oil has low affinity to the oil seal rubber called packing and gasket, and the affinity is lower as the base oil has a higher molecular weight, i.e., higher viscosity.
• the affinity is low, the swelling property of the seal rubber decreases, and conversely it is easy to shrink. This causes
• the lubricating oil composition is characterized in that it has superior initial anti-shudder properties, if it further comprises (D-2) a friction modifiercomposed of a reaction product of boric acid or boron oxide with an epoxide.
• the lubricating oil composition of the present invention is capable of extending the shudder prevention lifespan without decreasing the intermetallic friction coefficient. This effect can be achieved even when the kinematic viscosity at 100°C of the lubricating oil composition is lowered to about 5.0.
• the present invention can provide a lubricating oil composition having increased shear stability. Furthermore, it ensures that the seal rubber can sufficiently swell. Moreover, it can improve the initial anti-shudder properties.
• the lubricating oil composition of the present invention can be suitably used especially as a lubricating oil composition for a non-stage transmission.
• the lubricant base oil includes a mineral oil, a synthetic oil or a mixture thereof.
• the lubricating oil composition preferably comprises, as a part or all of the lubricant base oil, 5 to 30 percent by weight, based on a total weight of the lubricating oil composition, of a poly- ⁇ -olefin or ⁇ -olefin copolymer having a kinematic viscosity at 100°C of 6 to 80 mm 2 /s.
• the lower limit of the content of the poly- ⁇ -olefin or ⁇ -olefin copolymer is more preferably 6 percent by weight and still more preferably 8 percent by weight, and the upper limit is more preferably 25 percent by weight, and still more preferably 20 percent by weight. If the content of the above base oil is below the above lower limit, there is a possibility that a satisfactory viscosity index, i.e., a combination of fuel efficiency and protection of the machine elements, cannot be achieved, and if it exceeds the above upper limit, there is a possibility that the shear stability may decrease and the rubber adaptability may deteriorate, i.e., the rubber shrinks.
• the poly- ⁇ -olefin or ⁇ -olefin copolymer has a kinematic viscosity at 100°C of 6 to 80 mm 2 /s, preferably 8 to 80 mm 2 /s, more preferably 8 to 60 mm 2 /s, and still more preferably 9 to 40 mm 2 /s. If the kinematic viscosity at 100°C is below the above lower limit, a satisfactory viscosity index, i.e., a combination of fuel efficiency and protection of the machine elements, cannot be achieved, and if the kinematic viscosity at 100°C exceeds the above upper limit, the shear stability decreases and the rubber adaptability deteriorates, i.e., the rubber shrinks.
• the poly- ⁇ -olefin or ⁇ -olefin copolymer is a (co)polymer or a (co)oligomer of ⁇ -olefin.
• Conventional and commonly-known poly- ⁇ -olefin or ⁇ -olefin copolymers may be used as the lubricant base oil, as long as they have the above kinematic viscosity.
• the ⁇ -olefin is selected, for example, from a C2-14, preferably C4-12, linear or branched olefinic hydrocarbon.
• poly- ⁇ -olefin or ⁇ -olefin copolymer examples include 1-octene oligomer, 1-decene oligomer, ethylene-propylene oligomer, isobutene oligomer, and hydrogenated products thereof.
• the poly- ⁇ -olefin or ⁇ -olefin copolymer may be manufactured using a metallocene catalyst.
• the weight-average molecular weight of the (co)polymer or (co)oligomer should only be such that the kinematic viscosity at 100°C is within the above range. Its weight-average molecular weight may be, for example, 1,000 to 10,000, preferably 1,100 to 7,000.
• One type of poly- ⁇ -olefin or ⁇ -olefin copolymer may be used, or two or more types thereof may be used together.
• the lubricating oil composition of the present invention may comprise other lubricant base oils in combination with the above poly- ⁇ -olefin or ⁇ -olefin copolymer.
• the other lubricant base oils include, but are not limited to, conventional commonly-used mineral oil-based base oils and synthetic base oils other than the above poly- ⁇ -olefin or ⁇ -olefin copolymer.
• Examples of the mineral oil-based base oil include paraffinic or naphthenic lubricant base oils, obtained by distilling a crude oil at a normal atmospheric pressure and under vacuum to prepare a lubricating oil fraction and subjecting the lubricating oil fraction to a suitable combination of purification treatments such as solvent deasphalting, solvent extraction, hydrogenolysis, solvent dewaxing, catalytic dewaxing, hydrorefining, sulfuric acid treatment and clay treatment, and lubricant base oils obtained by isomerizing a wax obtained by solvent dewaxing and dewaxing the isomerized product.
• the kinematic viscosity of the mineral oil-based base oil is preferably, but is not limited to, 1 to 5 mm 2 /s in order to obtained a low-viscosity lubricating oil composition.
• the synthetic base oil examples include isoparaffins, alkylbenzenes, alkylnaphthalenes, monoesters, diesters, polyol esters, polyoxyalkylenglycols, dialkyldiphenyl ethers, polyphenyl ethers, and GTL base oils.
• No particular restrictions are placed on the kinematic viscosity of the synthetic base oil.
• a poly- ⁇ -olefin or ⁇ -olefin copolymer having a kinematic viscosity at 100°C of less than 6 mm 2 /s or more than 80 mm 2 /s can also be used.
• the kinematic viscosity of the synthetic base oil is preferably 1 to 6 mm 2 /s.
• the other base oils used in combination with the poly- ⁇ -olefin or ⁇ -olefin copolymer may be used alone or two or more types thereof may be used together.
• two or more types thereof are used, two or more types of mineral oil-based base oils may be used, two or more types of synthetic base oils may be used, or a combination of a mineral oil-based base oil and a synthetic base oil may be used.
• the use of a single mineral oil-based base oil, the use of two or more types of mineral oil-based base oils, the use of a single synthetic base oil having a kinematic viscosity at 100°C of not less than 1 mm 2 /s and less than 6 mm 2 /s, and the use of two or more types of synthetic base oils having a kinematic viscosity at 100°C of not less than 1 mm 2 /s and less than 6 mm 2 /s are preferable.
• the whole lubricant base oil preferably has a kinematic viscosity at 100°C of 2 to 7 mm 2 /s, more preferably 2.3 to 6 mm 2 /s, and more preferably 2.5 to 5.6 mm 2 /s.
• the lubricating oil composition of the present invention may also comprise conventional commonly-known viscosity index improver.
• the lubricating oil composition preferably comprises a polymethacrylate having a weight-average molecular weight of 15,000 to 40,000 as the viscosity index improver.
• the lower limit of the weight-average molecular weight is preferably 17,000 and more preferably 18,000.
• the upper limit of the weight-average molecular weight is preferably 38,000 and more preferably 36,000. If the weight-average molecular weight is less than the above lower limit, the effect of the viscosity index improver is insufficient, and if the weight-average molecular weight is more than the above upper limit, the effect of viscosity index improvement is achieved, but the shear stability deteriorates.
• the content of the polymethacrylate is preferably, but is not limited to, 0.1 to 20 percent by weight, more preferably 0.1 to 15 percent by weight, and still more preferably 2 to 10 percent by weight, based on the lubricating
• One type of the polymethacrylate may be used alone or two or more types thereof may be used in combination.
• the lubricating oil composition of the present invention may also comprise other viscosity index improvers in combination with the polymethacrylate.
• examples of other viscosity index improvers include a polymethacrylate having a weight-average molecular weight of less than 15,000, a polymethacrylate having a weight-average molecular weight of more than 40,000, a polyisobutylene and hydrogenated products thereof, a hydrogenated styrene-diene copolymer, a styrene-maleic anhydride ester copolymer, and a polyalkylstyrene. If other viscosity index improvers are contained, the content thereof is preferably 0.1 to 15 percent by weight based on the lubricating oil composition.
• the lubricating oil composition of the present invention is characterized in that it comprises, as an ashless dispersant, two types of specific succinimide compounds.
• the lubricating oil composition is characterized in that it comprises (C-1) a succinimide compound having a weight-average molecular weight of 4,000 to 7,000, preferably 5,000 to 7,000, and (C-2) a succinimide compound having a weight-average molecular weight of more than 7,000 and not more than 10,000, preferably 7,100 to 9,600.
• above component (C-1) is also referred to as “the 1st succinimide compound”
• above component (C-2) is also referred to as "the 2nd succinimide compound.”
• a part or all of component (C-1) and component (C-2) may be, but not limited to, a boronated succinimide compound.
• the content of component (C) in the composition is preferably 0.5 to 3.0 percent by weight, more preferably 0.6 to 2.5 percent by weight, and still more preferably 0.9 to 2.0 percent by weight, based on the total weight of the composition. If its content is less than the above lower limit, the shudder prevention may not be secured. If it is more than the above upper limit, the viscosity may increase at a low temperature.
• the weight ratio of component (C-1) to component (C-2), i.e., (C-2)/(C-1), is preferably, but not limited to, 1 to 10, more preferably 1.5 to 8, and still more preferably 2 to 6.
• the weight ratio is within the above range, both a favorable friction coefficient and favorable anti-shudder properties can be achieved. If the quantity of (C-1) is insufficient, the shudder prevention becomes insufficient at a low temperature, e.g., at 40°C, which is evident early in endurance testing. If the quantity of (C-2) is insufficient, the shudder prevention becomes insufficient at a high temperature, e.g., at 120°C, which is evident early in endurance testing.
• the 1st and 2nd succinimide compounds the present invention may be a succinimide compound known publicly as an ashless dispersant.
• the succinimide compound is a compound obtained by adding succinic anhydride to polyamine.
• succinic anhydride there are monotype succinimide compounds and bis-type succinimide compounds, and either can be used.
• the monotype succinimide compound can be represented by formula (1) below.
• the bis-type succinimide compound can be represented by formula (2) below. wherein R 1 is each independently an alkyl or alkenyl group having 40 to 400 carbon atoms, m is an integer of 1 to 20, and n is an integer of 0 to 20.
• Bistype succinimide compounds are especially preferable.
• a monotype succinimide compound and a bis-type succinimide compound may be used in combination, or two or more monotype succinimide compounds may be used in combination, or two or more bis-type succinimide compounds may be used in combination.
• the nitrogen content in the succinimide compound is preferably, but not limited to, 0.3 to 10 percent by weight, more preferably 0.5 to 5 percent by weight, and still more preferably 0.8 to 2.5 percent by weight, based on the weight of the compound.
• the optional boronated succinimide compound is more specifically a compound obtained by reacting a succinimide compound represented by the above formula with a boron compound.
• a boron compound include boric acid, boric anhydride, an ester of boric acid, boron oxide, boron halide, etc.
• an example of a boronated succinimide compound is a product obtained by modifying (boronating) a succinimide compound containing in its molecule at least one alkyl or alkenyl group with boric acid, borate, or the like.
• alkyl or alkenyl group examples include monovalent groups derived from an oligomer of an olefin such as propylene, 1-butene, and isobutylene, a co-oligomer of ethylene and propylene, or the like.
• the 1st succinimide compound (C1) has a weight-average molecular weight of 4,000 to 7,000.
• the weight-average molecular weight is preferably 5,000 to 7,000 and more preferably 5,200 to 6,800. If the molecular weight of the 1st succinimide compound is less than the above lower limit, the anti-shudder properties deteriorate.
• the weight-average molecular weight of the 1st succinimide compound is measured using an RI (differential refractometry) detector, with a solvent of THF (tetrahydrofuran), a packed column of styrene-divinyl benzene copolymer, a set temperature of 40°C, and a set flow rate of 1.0 mL/min, and is expressed in polystyrene-converted value.
• RI differential refractometry
• the boron content is preferably, but not limited to, 0.1 to 3 percent by weight, more preferably 0.2 to 2.5 percent by weight, still more preferably 0.2 to 2 percent by weight, and most preferably 0.2 to 1.5 percent by weight, based on the weight of the compound.
• the content of the 1st succinimide compound in the lubricating oil composition is preferably, but not limited to, 0.05 to 2.00 percent by weight, more preferably 0.08 to 1.80 percent by weight, and still more preferably 0.10 to 1.50 percent by weight, based on the total weight of the lubricating oil composition. If the content is less than the above lower limit, there is a possibility that sufficient washability may not be secured, and if it is more than the above upper limit, there is a possibility that sludge may be generated.
• the 1st succinimide compound can be at least one selected from a succinimide compound which is not boronated and a boronated succinimide compound. Therefore, it may be selected from a single succinimide compound which is not boronated, and two or more succinimide compounds which are not boronated, a single boronated succinimide compound, two or more boronated succinimide compounds, and a combination of at least one succinimide compound which is not boronated and at least one boronated succinimide compound.
• the 2nd succinimide compound (C-2) has a weight-average molecular weight of more than 7,000 and not more than 10,000.
• the weight-average molecular weight is preferably 7,100 to 9,600, and more preferably 7,500 to 9,200. If the molecular weight of the 2nd succinimide compound is more than the above upper limit, the low-temperature viscosity of the compound becomes inconveniently high.
• the weight-average molecular weight of the 2nd succinimide compound is measured using an RI (differential refractometry) detector, with a solvent of THF (tetrahydrofuran), a packed column of styrenedivinyl benzene copolymer, and a set temperature of 40°C set flow rate of 1.0 mL/min, and is expressed in polystyrene-converted value.
• RI differential refractometry
• the boron content is preferably, but not limited to, 0.1 to 3 percent by weight, more preferably 0.2 to 2.5 percent by weight, still more preferably 0.2 to 2 percent by weight, and most preferably 0.2 to 1.5 percent by weight, based on the weight of the compound.
• the nitrogen content in the succinimide compound is preferably, but not limited to, 0.2 to 5.0 percent by weight, more preferably 0.3 to 2.5 percent by weight, and still more preferably 0.5 to 2.0 percent by weight.
• the content of the 2nd succinimide compound in the lubricating oil composition is preferably, but not limited to, 0.2 to 3.0 percent by weight, more preferably 0.4 to 2.5 percent by weight, and still more preferably 0.6 to 2.0 percent by weight, based on the total weight of the lubricating oil composition. If the content is less than the above lower limit, there is a possibility that sufficient washability may not be secured, and if it is more than the above upper limit, the low-temperature viscosity of the composition becomes inconveniently high.
• the 2nd succinimide compound can be at least one selected from a succinimide compound which is not boronated and a boronated succinimide compound. Therefore, it may be selected from a single succinimide compound which is not boronated, two or more succinimide compounds which are not boronated, a single boronated succinimide compound, two or more boronated succinimide compounds, and a combination of at least one succinimide compound which is not boronated and at least one boronated succinimide compound.
• the lubricating oil composition of the present invention may further comprise other ashless dispersants in combination with above component (C-1) and above component (C-2).
• a typical example of the other ashless dispersant includes a succinamide compound.
• the lubricating oil composition of the present invention further comprises (D)(D-1) an amide friction modifier as an indispensable component, and optionally (D-2) a friction modifiercomposed of a reaction product of boric acid or boron oxide with an epoxide in addition to above components (A) to (C).
• an amide friction modifier (D-1) is an essential component, and a friction modifiercomposed of a reaction product of boric acid or boron oxide with an epoxide (D-2) is optionally used.
• Preferable amide friction modifier (D-1) include, but is not limited to, fatty acid amide compounds.
• amides of a linear fatty acid and an aliphatic monoamine or aliphatic polyamine can be used.
• fatty acid amide compounds having an C6-30 alkyl or alkenyl group having 6 to 30 carbon atoms can be preferably used.
• This amide friction modifier (D-1) is an essential component.
• lubricating oil composition of the present invention must comprise an amide friction modifier (D-1) as an essential component, it may also comprise other friction modifiers. It may comprise, for example, other ester friction modifiers, amine friction modifiers, alcohol friction modifiers, molybdate friction modifiers and other optional friction modifiers.
• a friction modifier composed of a reaction product of boric acid or boron oxide with an epoxide (D-2) is preferably used, since the initial anti-shudder properties is improved by using it.
• (D-2) a friction modifier composed of a reaction product of boric acid or boron oxide with an epoxide.
• Friction modifiers composed of said reaction products are commonly known, and are disclosed, for example, in JP 2000-87068 A .
• boric acid include various types of boric acid (including metaboric acid, HBO 2 , orthoboric acid, H 3 BO 3 and tetraboric acid H 2 B 4 O 7 ), and alkyl borates represented by the formula (RO)xB(OH)y where x is 1 to 3, y is 0 to 2, the total of x and y is 3 and R is an alkyl group having 1 to 6 carbon atoms.
• the epoxide include epoxides themselves, and equivalents thereof from the reaction viewpoint, for example, diols and halohydrins. As described in detail in United States Patent No.
• epoxide preferably hydrocarbyl epoxide
• boric acid or boron trioxide preferably hydrocarbyl epoxide
• An epoxide can be represented by the following formula: wherein R1, R2, R3 and R4 each independently represent a hydrogen atom or a hydrocarbon group having 1 to 30 carbon atoms, and at least one of R1, R2, R3 and R4 is a hydrocarbon group. Any two of R1, R2, R3 and R4 may form a cyclic group, which may be alicyclic or heterocyclic, together with the same bonding atom.
• R1, R2, R3 and R4 is a hydrocarbon group having 6 to 30 carbon atoms, and the rest are hydrogen atoms, to which they are not limited.
• the hydrocarbon group having 1 to 30 carbon atoms include, but is not limited to, an alkyl group, alkenyl group, alkynyl group, and aryl group, as well as saturated or unsaturated fatty acid residues.
• saturated fatty acid residues include a caproic acid residue, caprylic acid residue, capric acid residue, lauric acid residue, myristic acid residue, palmitic acid residue, stearic acid residue and isostearic acid residue.
• unsaturated fatty acid residues include linoleic acid residue, ⁇ -linolenic acid residue, ⁇ -linolenic acid residue, arachidonic acid residue, docosapentaenoic acid residue, palmitoleic acid residue, vaccenoic acid residue, paullinic acid residue, oleic acid residue (oleyl group), elaidic acid residue, erucic acid residue and nervonic acid residue.
• Such epoxides can be commercially available mixtures of C14-16 or C14-18 epoxides, which are available from ELF-Atochem or UnionCarbide, or prepared from the corresponding olefins using commonly-known methods.
• the reaction product can be prepared by mixing boric acid or boron oxide (hereinafter referred to collectively as “boric acid”) and an epoxide or an equivalent thereof (hereinafter referred to collectively as "epoxide”) and heating them at an appropriate temperature (typically 80°C to 250°C).
• the molar ratio of boric acid to an epoxide is generally 4:1 to 1:4, preferably 1:1 to 1:3, more preferably 1:2.
• an inert liquid may be used as the reaction media.
• Examples of such a liquid include toluene, xylene, chlorobenzene and dimethyl formamide.
• Water forms during the reaction and is typically evaporated during the reaction process. Hydroxide may be used in order to facilitate the reaction.
• the epoxide ring may have been opened.
• a preparation method of the reaction product is disclosed also in JP S57-200496 A .
• the thus-obtained compound may be effectively used as a friction modifier and provides excellent anti-shudder properties.
• component (D-2) include, but are not limited to, a borate chloride of a fatty acid epoxy ester or a ring-opened product thereof.
• a borate chloride of glycidyl caprate borate chloride of glycidyl caproate
• borate chloride of glycidyl myristate borate chloride of glycidyl palmitate
• borate chloride of glycidyl oleate borate chloride of ethyleneoxide oleate
• borate chloride of glycidyl stearate borate chloride of glycidyl isostearate and borate chloride of glycidyl laurate.
• the added quantity of component (D-1) is preferably, but not limited to, be 0.01 to 5 percent by weight, more preferably 0.02 to 4 percent by weight, and still more preferably 0.1 to 3 percent by weight, based on the total weight of the lubricating oil composition.
• Component (D-2) is not essential, but when it is added, the added quantity thereof is preferably 0.01 to 5 percent by weight, more preferably 0.02 to 4 percent by weight, and still more preferably 0.1 to 3 percent by weight, based on the total weight of the lubricating oil composition.
• the lubricating oil composition of the present invention further comprises (E) a metallic detergent and/or (F) an ether sulfolane compound in addition to above components (A) to (D).
• a metallic detergent includes a detergent containing an alkali metal or alkaline earth metal.
• a detergent containing an alkali metal or alkaline earth metal examples thereof include, but are not limited to, sulfonates containing an alkali metal or alkaline earth metal, salicylates containing an alkali metal or alkaline earth metal, and phenates containing an alkali metal or alkaline earth metal.
• an alkali metal or alkaline earth metal include, but are not limited to, magnesium, barium, sodium and calcium.
• a sulfonate containing an alkali metal or alkaline earth metal include, but are not limited to, calcium sulfonate and magnesium sulfonate.
• a salicylate containing an alkali metal or alkaline earth metal include, but are not limited to, calcium salicylate and magnesium salicylate.
• a phenate containing an alkali metal or alkaline earth metal include, but are not limited to, calcium phenate and magnesium phenate.
• the quantity of the alkali metal or alkaline earth metal in the metallic detergent is preferably, but not limited to, 0.1 to 20 percent by weight, more preferably 0.5 to 15 percent by weight, and still more preferably 1.0 to 15 percent by weight, based on the weight of the metallic detergent.
• the metallic detergent has a total base number of preferably, but not limited to, 10 to 500 mgKOH/g, more preferably 50 to 400 mgKOH/g, still more preferably 150 to 400 mgKOH/g, still more preferably 200 to 400 mgKOH/g, still more preferably 300 to 400 mgKOH/g, and most preferably 310 to 400 mgKOH/g.
• the total base number is within the above range, the washability effect is high and sludge generation can be prevented.
• the metallic detergent may be contained at any ratio in the lubricating oil composition.
• the content thereof is, for example, 0 to 5 percent by weight, preferably 0.1 to 2 percent by weight, and still more preferably 0.2 to 1 percent by weight, based on the total weight of the lubricating oil composition.
• a single metallic detergent may be used alone, or two or more metallic detergents may be used in combination.
• examples of the combination include, but are not limited to, a combination of two or more sulfonate compounds, a combination of two or more salicylate compounds, a combination of two or more phenate compounds, a combination of at least one sulfonate compound and at least one salicylate compound, a combination of at least one sulfonate compound and at least one phenate compound, and a combination of at least one salicylate compound and at least one phenate compound.
• the lubricating oil composition of the present invention can secure moderate seal rubber swelling properties.
• the ether sulfolane compound is a compound represented by the following formula: wherein R is an alkyl group having 1 to 20 carbon atoms, preferably an alkyl group having 8 to 16 carbon atoms.
• the content of the ether sulfolane compound is preferably 0 to 5 percent by weight, more preferably 0.1 to 2 percent by weight, and still more preferably 0.2 to 1 percent by weight, based on the total weight of the lubricating oil composition.
• the lubricating oil composition of the present invention may further comprise additives other than above components (B) to (F).
• additives other than above components (B) to (F) include oiliness agents, anti-wear agents, extreme pressure agents, rust-preventive agents, friction modifiers other than the above friction modifiers, antioxidants, corrosion inhibitors, metal deactivators, pour point depressants, antifoaming agents, coloring agents, and package additives for automatic transmission fluid.
• Package additives for lubricating oil containing at least one of the above additives can be added.
• the extreme pressure agent includes, but is not limited to, a phosphorus-based extreme pressure agent.
• the phosphorus-based extreme pressure agent is preferably at least one selected from acidic phosphate, acidic phosphate phosphite, phosphate, phosphite, amine salts thereof, phosphoric acid, and phosphorous acid.
• an unlimited preferable example of the extreme pressure agent is a combination of at least one selected from acidic phosphate, acidic phosphate phosphite, phosphate, phosphite, and amine salts thereof, and at least one selected from phosphoric acid and phosphorus acid.
• an unlimited preferable example of the extreme pressure agent is a combination of at least one selected from acidic phosphate, acidic phosphate phosphite, phosphate, phosphite, amine salts thereof, and at least one selected from phosphoric acid and phosphorus acid.
• an acidic phosphate and at least one compound selected from phosphoric acid and phosphorous acid is also preferable.
• an acidic phosphate include acidic butyl phosphate, acidic hexyl phosphate, acidic octyl phosphate, and acidic dodecyl phosphate.
• the quantity of the phosphorus-based extreme pressure agent is preferably, but not limited to, 0.01 to 2.5 percent by weight, more preferably 0.02 to 1.5 percent by weight, and still more preferably 0.02 to 1.0 percent by weight, based on the total weight of the lubricating oil composition.
• the kinematic viscosity at 100°C of the lubricating oil composition of the present invention is preferably, but not limited to, 3 to 10 mm 2 /s, more preferably 3 to 8 mm 2 /s, still more preferably 4 to 7.5 mm 2 /s, and most preferably 4 to 6 mm 2 /s.
• the kinematic viscosity at 100°C of the lubricating oil composition is less than the above lower limit, it may not be possible to secure the friction coefficient.
• it is more than the above upper limit the anti-shudder properties may deteriorate.
• the viscosity index of the lubricating oil composition of the present invention is preferably, but not limited to, not less than 150, more preferably not less than 160.
• the upper limit thereof is preferably, but not limited to, 250.
• the lubricating oil composition of the present invention has not only a sufficiently high intermetallic friction coefficient but also anti-shudder properties.
• the shear stability can also be secured.
• it can secure moderate seal rubber swelling properties.
• a metallic detergent having a total base number of 200 to 400 mgKOH/g, it can favorably secure washability while preventing sludge generation.
• the lubricating oil composition of the present invention can be suitably used for a non-stage transmission.
• Lubricating oil compositions were prepared by mixing the components shown below at the amounts shown in Table 1 or Table 2.
• KV100 means a kinematic viscosity at 100°C
• VI means the viscosity index
• PMA means polymethacrylate.
• PMA-based viscosity index improver 1 having an Mw of 30,000 and a structure of - (CH 2 -C(CH 3 )(COOR)) n -
• Anti-wear agent friction modifier, antioxidant, antifoaming agent, metal deactivator, and coloring agent.
• Friction modifier (D) Friction modifier (D-1) Amide friction modifier (D-1a) Reaction product of isostearic acid and tris(hydroxymethyl) aminomethane 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 (D-1b) Isostearic acid diethanolamide (D-1c) Stearic acid diethanolamide (D-1d) Oleic acid diethanolamide (D-1e) Lauric acid diethanolamide (D) Friction modifier (D-2) Friction modifier composed of a borate of epoxide or a ring-opened product thereof (D-2a) Borate of ethylene oxide oleate 0.20 0.20 0.20 0.20 0.20 0.20 0.20 0.20 0.20 (D-2b) Borate of ethylene oxide stearate (D-2c) Borate of glycidyl oleate (D-2d) Borate of glycidyl laurate (D) Friction modifiers (other than the above friction modifiers
• Example 18 (A) Base oil Mineral oil 1 70.39 70.39 70.39 70.39 70.39 70.39 70.39 70.39 70.39 70.39 Mineral oil 2 Mineral oil 3 Mineral oil 4 Mineral oil 5 Synthetic base oil 1 20.95 20.95 20.95 20.95 20.95 20.95 20.95 20.95 20.95 20.95 20.95 20.95 20.95 20.95 20.95 20.95 20.95 20.95 20.95 20.95 20.95 20.95 20.95 20.95 20.95 20.95 20.95 20.95 20.95 20.95 20.95 20.95 20.95 20.95 20.95 20.95 20.95 20.95 20.95 20.95 (95 (95)
• Synthetic base oil 2 Synthetic base oil 3 Synthetic base oil 4
• Friction modifier D-1a Amide friction modifier (D-1a) Reaction product of isostearic acid and tris(hydroxymethyl) aminomethane 0.95 0.75 0.75 0.75 0.75 0.75 (D-1b) Isostearic acid diethanolamide 0.75 (D-1c) Stearic acid diethanolamide 0.75 (D-1d) Oleic acid diethanolamide 0.75 (D-1e) Lauric acid diethanolamide 0.75 (D) Friction modifier (D-2) Friction modifier composed of a borate of epoxide or a ring-opened product thereof (D-2a) Borate of ethylene oxide oleate 0.20 0.20 0.20 0.20 0.20 0.20 (D-2b) Borate of ethylene oxide stearate 0.20 (D-2c) Borate of glycidyl oleate 0.20 (D-2d) Borate of glycidyl laurate 0.20 (D) Friction
• Friction modifier (D) Friction modifier (D-1) Amide friction modifier (D-1a) Reaction product of isostearic acid and tris(hydroxymethyl) aminomethane 0.75 (D-1b) Isostearic acid diethanolamide (D-1c) Stearic acid diethanolamide (D-1d) Oleic acid diethanolamide (D-1e) Lauric acid diethanolamide (D) Friction modifier (D-2) Friction modifier composed of a borate of epoxide or a ring-opened product thereof (D-2a) Borate of ethylene oxide oleate 0.20 0.95 (D-2b) Borate of ethylene oxide stearate 0.95 (D-2c) Borate of glycidyl oleate 0.95 (D-2d) Borate of glycidyl laurate 0.95 (D) Friction modifiers (other than the above friction modifiers) Glycerin monoole

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• Lubricants (AREA)

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