EP3451030A1 - Rückstrahlende folie - Google Patents

Rückstrahlende folie Download PDF

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Publication number
EP3451030A1
EP3451030A1 EP17789525.7A EP17789525A EP3451030A1 EP 3451030 A1 EP3451030 A1 EP 3451030A1 EP 17789525 A EP17789525 A EP 17789525A EP 3451030 A1 EP3451030 A1 EP 3451030A1
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EP
European Patent Office
Prior art keywords
retroreflective
layer
particles
back face
elements
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP17789525.7A
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English (en)
French (fr)
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EP3451030A4 (de
EP3451030B1 (de
Inventor
Toshiaki Shiomi
Chenyang Jiang
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Carbide Industries Co Inc
Original Assignee
Nippon Carbide Industries Co Inc
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Publication of EP3451030A1 publication Critical patent/EP3451030A1/de
Publication of EP3451030A4 publication Critical patent/EP3451030A4/de
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Publication of EP3451030B1 publication Critical patent/EP3451030B1/de
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    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00—Optical elements other than lenses
    • G02B5/12—Reflex reflectors
    • G02B5/122—Reflex reflectors cube corner, trihedral or triple reflector type
    • G02B5/124—Reflex reflectors cube corner, trihedral or triple reflector type plural reflecting elements forming part of a unitary plate or sheet
    • E—FIXED CONSTRUCTIONS
    • E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01F—ADDITIONAL WORK, SUCH AS EQUIPPING ROADS OR THE CONSTRUCTION OF PLATFORMS, HELICOPTER LANDING STAGES, SIGNS, SNOW FENCES, OR THE LIKE
    • E01F9/00—Arrangement of road signs or traffic signals; Arrangements for enforcing caution
    • E01F9/50—Road surface markings; Kerbs or road edgings, specially adapted for alerting road users
    • E01F9/506—Road surface markings; Kerbs or road edgings, specially adapted for alerting road users characterised by the road surface marking material, e.g. comprising additives for improving friction or reflectivity; Methods of forming, installing or applying markings in, on or to road surfaces
    • E01F9/524—Reflecting elements specially adapted for incorporation in or application to road surface markings

Definitions

  • the present invention relates to a retroreflective sheeting.
  • Retroreflective sheetings have the properties that can reflect incident light to the light source side. Since the retroreflective sheeting has such properties, the retroreflective sheeting is used for the purpose, for example, of easily seeing targets, such as printed materials, when light illuminates the targets at nighttime and at dark places. Examples of the retroreflective sheeting that is used include traffic signs, guide signs, vehicle number plates, advertising signs, pole cones, and delineators.
  • Patent Literature 1 discloses a retroreflective sheeting including an optically transparent layer having retroreflective elements and a resin back face layer formed with a large number of cavities smaller than the retroreflective elements.
  • the cavities are formed on the surface of the resin back face layer on the side of the surface of the optically transparent layer where the retroreflective elements are formed.
  • a low refractive index gas is contained in voids formed between the cavities formed on the resin back face layer and the retroreflective elements.
  • the retroreflective sheeting described in Patent Literature 1 uses no metal deposited film, its lightness can be improved.
  • the retroreflective sheeting excellent in lightness can give printed parts prominence when used for printed materials, such as vehicle number plates.
  • a pressure is applied to the retroreflective sheeting disclosed in Patent Literature 1 in the thickness direction by being bent or embossed, for example, the voids formed between the retroreflective elements and the cavities sometimes collapse.
  • the retroreflectivity is reduced. Therefore, when the retroreflective sheeting disclosed in Patent Literature 1 is used for bent or embossed printed materials, the retroreflectivity is sometimes degraded, compared with the case in which the retroreflective sheeting is used for flat materials.
  • the present invention is to provide a retroreflective sheeting that suppresses the degradation of its retroreflectivity even though a pressure is applied in the thickness direction.
  • a retroreflective sheeting of the present invention includes: a retroreflective layer having a plurality of retroreflective elements on a first face; a back face layer provided opposite to a face of the retroreflective layer on the retroreflective element side, the back face layer having an attachment portion attached to the retroreflective elements; a plurality of particles arranged between the retroreflective elements and the back face layer; and a void formed between the retroreflective elements and the plurality of particles.
  • the plurality of particles is fixed as the particles are sandwiched between the retroreflective elements and the back face layer.
  • the voids are formed between the particles and the retroreflective elements, and a gas, such as air, is contained in the voids.
  • a gas such as air
  • the refractive index difference between the gas and the retroreflective elements With the refractive index difference between the gas and the retroreflective elements, light entered from the retroreflective layer side can be reflected off the interface between the retroreflective elements and the voids to the retroreflective layer side.
  • the retroreflective sheeting even though a pressure is applied in the thickness direction, the voids are supported by the particles, and this suppresses the collapse of the voids. Therefore, in the retroreflective sheeting, even in the case in which a pressure is applied in the thickness direction, the deterioration of retroreflectivity is suppressed.
  • an average particle diameter da of the particles can be a height h of the retroreflective elements or more.
  • the average particle diameter da of the particles is the height h of the retroreflective elements or more.
  • the voids are easily formed between the retroreflective elements and the particles, and hence the retroreflectivity of the retroreflective sheeting is easily improved.
  • the average particle diameter da of the particles can be made smaller than the height h of the retroreflective elements.
  • the average particle diameter da of the particles is smaller than the height h of the retroreflective elements.
  • the area of the attachment portion of the retroreflective elements to the back face layer is easily increased, and hence the adhesive strength between the retroreflective elements and the back face layer is easily improved.
  • a ratio da/h of the average particle diameter da of the particles to the height h of the retroreflective elements is 0.40 or more and 1.25 or less.
  • the average particle diameter means the diameter measured as below.
  • cross sectional pictures are captured at given ten places on the retroreflective sheeting with a microscope (VHX-1000, produced by Keyence Corporation).
  • VHX-1000 produced by Keyence Corporation
  • the particle diameters of 100 particles on the captured cross sectional pictures at ten places are measured.
  • the total length is divided by 100 to calculate the mean value.
  • the mean value is the average particle diameter.
  • the ratio da/h of the average particle diameter da of the particles to the height h of the retroreflective elements is 0.40 or more and 1.25 or less.
  • the ratio da/h is 0.40 or more and 1.25 or less.
  • the area of the attachment portion of the retroreflective elements to the back face layer is easily increased, and hence the adhesive strength between the retroreflective elements and the back face layer is easily improved.
  • a ratio np/nv of a number np of the plurality of particles to a number nv of valleys formed between the retroreflective elements adjacent to each other is 0.50 or more and 5.00 or less.
  • the ratio np/nv of the number np of the particles to the number nv of the valleys formed between the retroreflective elements adjacent to each other is set to 0.50 or more and 5.00 or less.
  • the ratio np/nv is 0.50 or more and 5.00 or less.
  • the area of the attachment portion of the retroreflective elements to the back face layer is easily increased, and hence the adhesive strength between the retroreflective elements and the back face layer is easily improved.
  • the plurality of particles has a spherical shape.
  • the particles have a spherical shape.
  • the voids in a proper size are easily formed between the retroreflective elements and the particles, and hence the retroreflectivity of the retroreflective sheeting is easily improved.
  • the back face layer includes a pigment.
  • the back face layer includes a predetermined pigment, and hence the lightness and chroma of the retroreflective sheeting can be easily improved suitable for the applications of the retroreflective sheeting.
  • the back face layer is formed of an adhesive.
  • the back face layer is formed of an adhesive.
  • the retroreflective sheeting can be attached to a target with no adhesive layer. Consequently, the layer configuration of the retroreflective sheeting can be made simple, and hence an increase in the production cost of the retroreflective sheeting can be suppressed.
  • a retroreflective sheeting that suppresses the degradation of its retroreflectivity even though a pressure is applied in the thickness direction.
  • FIG. 1 is a diagram schematically illustrating a cross section of a retroreflective sheeting according to an embodiment in the thickness direction.
  • FIG. 2 is a diagram of the retroreflective sheeting illustrated in FIG. 1 showing portion II that is enlarged. Note that, in FIGS. 1 and 2 , for easy understanding, the sizes of components are not depicted accurately because the components are sometimes exaggerated, for example. In FIGS. 1 and 2 , components having similar configurations are designated only one reference sign, and repeated reference signs are omitted.
  • a retroreflective sheeting 100 illustrated in FIG. 1 includes a surface protective layer 10, a retroreflective layer 20, a plurality of particles 30, a back face layer 40, an adhesive layer 50, and a releasable sheet 60. In the following, these components will be described in detail.
  • the surface protective layer 10 is a layer that protects a face F1 of the retroreflective layer 20 provided on the observer side when the retroreflective sheeting 100 is used.
  • the surface protective layer 10 is the outermost layer of the retroreflective sheeting 100 when the retroreflective sheeting 100 is used.
  • the surface protective layer 10 is preferably a transparent resin layer.
  • the total light transmittance of the surface protective layer 10 is 80% or more, for example.
  • materials that configure the surface protective layer 10 include acrylic resins, alkyd resins, fluororesins, vinyl chloride resins, polyester resins, urethane resins, and polycarbonate resins.
  • acrylic resins may be used alone, or may be used in mixture.
  • acrylic resins polyester resins, and vinyl chloride resins are preferable.
  • coloring agents acrylic resins are preferable.
  • the surface protective layer 10 can be appropriately doped with various additives, such as ultraviolet absorption agents, light stabilizers, heat stabilizers, plasticizers, crosslinkers, antioxidants, fungicides, and coloring agents in the range that does not considerably degrade transparency.
  • the retroreflective layer 20 includes a plate-shaped holding portion 22 and a plurality of retroreflective elements 24.
  • the first face F1 of the holding portion 22 is covered with the surface protective layer 10.
  • a second face F2 of the holding portion 22 is provided with the retroreflective elements 24.
  • the retroreflective elements 24 are non-limiting specifically as long as the retroreflective elements 24 have a reflective surface suitable for retroreflecting incident light. For example, in the case in which the retroreflective elements 24 having a polyhedron, such as a triangular pyramid, or a so-called cube corner shape are arranged in closest packing, this arrangement is preferable because retroreflectivity is excellent.
  • the retroreflective layer 20 is preferably a transparent resin layer.
  • materials that configure the retroreflective layer 20 include acrylic resins, urethane resins, fluororesins, polyester resins, vinyl chloride resins, polycarbonate resins, polyarylate resins, silicone resins, polyolefin resins, and ionomer resins. These resins may be used alone, or may be used in mixture.
  • the retroreflective layer 20 is preferably formed of an acrylic resin, urethane resin, fluororesin, and polycarbonate resin, for example.
  • the retroreflective layer 20 can be appropriately doped with various additives, such as ultraviolet absorption agents, light stabilizers, heat stabilizers, plasticizers, crosslinkers, antioxidants, fungicides, and coloring agents in the range that does not considerably degrade transparency.
  • additives such as ultraviolet absorption agents, light stabilizers, heat stabilizers, plasticizers, crosslinkers, antioxidants, fungicides, and coloring agents in the range that does not considerably degrade transparency.
  • the back face layer 40 is a layer that is provided opposite to the face of the retroreflective layer 20 on the retroreflective elements 24 side and has an attachment portion 42 attached to the retroreflective elements 24.
  • the back face layer 40 is attached to the retroreflective elements 24 on the attachment portion 42, and sandwiches and fixes the particles 30 between the back face layer 40 and the retroreflective elements 24 in the portions other than the attachment portion 42.
  • the back face layer 40 examples include acrylic resins, urethane resins, fluororesins, polyester resins, vinyl chloride resins, polycarbonate resins, polyarylate resins, silicone resins, polyolefin resins, and ionomer resins. These resins may be used alone, or may be used in mixture. From the viewpoint of improving the transparency and weather resistance, for example, of the back face layer 40, the back face layer 40 is preferably formed of an acrylic resin, urethane resin, fluororesin, and polycarbonate resin, for example. Note that, the back face layer 40 can be appropriately doped with various additives, such as ultraviolet absorption agents, light stabilizers, heat stabilizers, plasticizers, crosslinkers, antioxidants, fungicides, and coloring agents.
  • additives such as ultraviolet absorption agents, light stabilizers, heat stabilizers, plasticizers, crosslinkers, antioxidants, fungicides, and coloring agents.
  • the back face layer 40 includes a predetermined pigment, and hence the lightness and chroma of the retroreflective sheeting 100 can be easily improved.
  • the back face layer 40 includes a white pigment, such as titanium oxide, and hence the lightness of the retroreflective sheeting 100 can be improved.
  • the back face layer 40 may include a coloring agent other than the white pigment, such as titanium oxide, described above.
  • the coloring agent that can be used include an inorganic pigment, organic pigment, organic dyestuff, and pearl pigment.
  • the back face layer 40 may use one kind of these coloring agents alone or may use two kinds or more in combination.
  • examples of the inorganic pigment other than titanium oxide can include carbonic acid calcium, barium sulfate, zinc oxidize, zinc sulfide, carbon black, cadmium red, molybdenum red, ultramarine, cobalt blue, red iron oxide, chromium oxide, iron black, cadmium yellow, titanium yellow, nickel titanium yellow, chromium titanium yellow, chrome yellow, yellow iron oxide, chromium orange, cadmium orange, gold powder, silver powder, copper powder, aluminum powder, and bronze powder.
  • organic pigment and the organic dyestuff can include organic compounds, such as anthraquinones, phthalocyanines, quinacridons, isoindolinones, dioxazines, quinophthalones, quinoimines, perylenes, perinones, azos, quinolines, methines, indigos, and naphthol imides.
  • organic compounds such as anthraquinones, phthalocyanines, quinacridons, isoindolinones, dioxazines, quinophthalones, quinoimines, perylenes, perinones, azos, quinolines, methines, indigos, and naphthol imides.
  • pearl pigment can include titanium oxide coated mica, bismuth chloride oxide, fish scale powder, and basic lead carbonate.
  • the retroreflective layer is doped with a coloring agent, or the surface of the retroreflective layer to which light is entered is provided with a printed layer or a colored layer.
  • the coloring agent or printing scatters light or prevents light from being entered to the retroreflective layer. This hampers the reflection of light at the retroreflective layer, resulting in the deterioration of retroreflectivity.
  • deep coloring agents such as red, blue, and green
  • the retroreflective sheeting 100 in the case in which, for example, the retroreflective layer 20 is made transparent and the back face layer 40 is doped with a coloring agent as described above, the factors that prevent light from being entered to the retroreflective layer 20 or light from being reflected off the retroreflective layer 20 are decreased, compared with the previously existing retroreflective sheeting. Thus, the degradation of retroreflectivity can be suppressed.
  • the particles 30 are arranged between the retroreflective elements 24 and the back face layer 40. Since the particles 30 are arranged between the retroreflective elements 24 and the back face layer 40, the positions of the particles 30 are fixed as the particles 30 are sandwiched between the retroreflective elements 24 and the back face layer 40, and voids 32 are formed between the particles 30 and the retroreflective elements 24.
  • the shape, size, and number of the particles 30 are not limited specifically as long as the attachment portion 42 is provided between the retroreflective elements 24 and the back face layer 40 and the voids 32 are formed between the particles 30 and the retroreflective elements 24.
  • An example of the particle 30 that can be used includes a glass bead.
  • the particle 30 is preferably a glass bead that is not easily charged.
  • examples of particles that can be used as the particles 30 other than glass beads include inorganic particles including talc, titanium oxide, carbonic acid calcium, silica, barium sulfate, mica, and wollastonite and organic particles including acrylic resins, epoxy resins, polyimide resins, PPS (polyphenylene sulfide) resins, silicone resins, melamine resins, and fluororesins.
  • the particles 30 may be colored. The colored particles 30 can improve the lightness and chroma of the retroreflective sheeting 100.
  • Hollow particles may be used as the particles 30.
  • the term "hollow particle” means a particle having a hollow formed in the inside of its shell. Note that, the inside of the hollow may be vacuum, or may be filled with a gas.
  • the adhesive layer 50 is a layer that is provided on the back face layer 40 on the opposite side to the retroreflective layer 20 and attached to a product to which the retroreflective sheeting 100 is mounted when used.
  • Examples of materials that configure the adhesive layer 50 can be appropriately selected from adhesives, such as pressure sensitive adhesives, thermosensitive adhesives, and cross-linking adhesives.
  • the pressure sensitive adhesives include polyacrylic ester pressure sensitive adhesives, silicone resin pressure sensitive adhesives, and rubber pressure sensitive adhesives; the polyacrylic ester pressure sensitive adhesives are obtained, for example, by copolymerization of acrylic acid or vinyl acetate with acrylic acid ester, such as butylacrylate, 2-ethyl hexyl acrylate, isooctyl acrylate, and nonyl acrylate.
  • Examples of the thermosensitive adhesives include acrylic resins, polyester resins, and epoxy resins. From the viewpoint of providing the adhesive layer 50 with excellent weather resistance and the adhesion properties, acrylic resins or silicone resins are preferably used.
  • the adhesive layer 50 includes a predetermined pigment, and hence the lightness and chroma of the retroreflective sheeting 100 can be easily improved suitable for the applications of the retroreflective sheeting 100.
  • the adhesive layer 50 includes a white pigment, such as titanium oxide, and hence the lightness of the retroreflective sheeting 100 can be improved.
  • the releasable sheet 60 is a layer that is provided on the adhesive layer 50 on the opposite side to the back face layer 40.
  • the releasable sheet 60 covers the adhesive layer 50 before the retroreflective sheeting 100 is used, and this prevents dust and dirt from attaching to the adhesive layer 50 or prevents the adhesive layer 50 from being attached to an undesired place.
  • the retroreflective sheeting 100 when used, the releasable sheet 60 is peeled off from the adhesive layer 50.
  • the releasable sheet 60 can be configured of a polyester film or configured of a polypropylene film, for example, which are non-limiting.
  • the retroreflective sheeting 100 described above can be manufactured as below, which is an example.
  • a stacked sheet having a stack of the releasable sheet 60, the adhesive layer 50, and the back face layer 40 in this order is prepared.
  • the particles 30 are almost uniformly sprinkled on the surface on the back face layer 40 side of the stacked sheet with the back face layer 40 provided with viscosity.
  • the retroreflective layer 20 is laid on the back face layer 40, and the retroreflective elements 24 are attached to the back face layer 40.
  • the surface protective layer 10 may be formed before the retroreflective layer 20 is laid on the back face layer 40, or may be formed after the retroreflective layer 20 is laid on the back face layer 40. Methods of forming the layers are not limited specifically.
  • a method of manufacturing the retroreflective sheeting 100 is not limited to the methods described above.
  • the retroreflective sheeting 100 can also be manufactured by a method with which the particles 30 are sprinkled on the face on which the retroreflective elements 24 of the retroreflective layer 20 are formed, and then the back face layer 40, the adhesive layer 50, and the releasable sheet 60 are stacked in this order.
  • the back face layer 40, the adhesive layer 50, and the releasable sheet 60 may be stacked before the retroreflective elements 24 are attached to the back face layer 40, or may be stacked in this order after the retroreflective elements 24 are attached to the back face layer 40.
  • the surface protective layer 10 may be formed before the retroreflective layer 20 is laid on the back face layer 40, or may be formed after the retroreflective layer 20 is laid on the back face layer 40.
  • the positions of the particles 30 are fixed as the particles 30 are sandwiched between the retroreflective elements 24 and the back face layer 40.
  • the voids 32 are formed between the particles 30 and the retroreflective elements 24, and a gas, such as air, is contained in the voids 32.
  • the retroreflective layer 20 can reflect light entered from the holding portion 22 side off the interface IF between the retroreflective elements 24 and the voids 32, and can retroreflect the incident light.
  • the voids 32 are formed by the particles 30 that are sandwiched between the retroreflective elements 24 and the back face layer 40.
  • the voids 32 are supported by the particles 30, and this suppresses the collapse of the voids 32. Therefore, in the retroreflective sheeting 100, even in the case in which a pressure is applied in the thickness direction, the deterioration of retroreflectivity is suppressed.
  • the voids 32 that contribute to retroreflection are formed with the particles 30.
  • the size, shape, number, and distribution of the particles 30 are adjusted, and this easily controls the size and distribution of the voids 32 on the entire retroreflective sheeting 100. Therefore, in the retroreflective sheeting 100, the retroreflectivity of the entire retroreflective sheeting 100 is easily controlled, such as providing nearly uniform retroreflectivity and controlling the degree of the retroreflectivity of the retroreflective sheeting 100.
  • an average particle diameter da of the particles 30 is a height h of the retroreflective elements 24 or more
  • the voids 32 are easily formed between the retroreflective elements 24 and the particles 30, and hence the retroreflectivity of the retroreflective sheeting 100 is easily improved.
  • the average particle diameter da of the particles 30 is smaller than the height h of the retroreflective elements 24, the area of the attachment portion 42 between the retroreflective elements 24 and the back face layer 40 is easily increased, and hence the adhesive strength of the retroreflective elements 24 to the back face layer 40 is easily improved.
  • the voids 32 in a proper size are formed between the retroreflective elements 24 and the particles 30, and hence the retroreflectivity of the retroreflective sheeting 100 is easily improved. Also in this case, the area of the attachment portion 42 between the retroreflective elements 24 and the back face layer 40 is easily increased, and hence the adhesive strength of the retroreflective elements 24 to the back face layer 40 is easily improved.
  • a ratio np/nv of a number np of the particles 30 to a number nv of the valleys 26 formed between the retroreflective elements 24 adjacent to each other is 0.50 or more and 5.00 or less
  • the voids 32 in a proper size are formed between the retroreflective elements 24 and the particles 30, and hence the retroreflectivity of the retroreflective sheeting 100 is easily improved.
  • the ratio np/nv is 0.50 or more and 5.00 or less, the area of the attachment portion 42 between the retroreflective elements 24 and the back face layer 40 is easily increased, and hence the adhesive strength of the retroreflective elements 24 to the back face layer 40 is easily improved. From these viewpoints, the ratio np/nv is more preferably 0.50 or more and 2.00 or less.
  • the particles 30 have a spherical shape, the voids 32 in a proper size are easily formed between the retroreflective elements 24 and the particles 30, and hence the retroreflectivity of the retroreflective sheeting 100 is easily improved.
  • the voids 32 are formed between the retroreflective elements 24 and the particles 30 as well as the particles 30 themselves have a hollow with a refractive index lower than the refractive index of the retroreflective elements 24. That is, the volume of a space having a refractive index lower than the refractive index of the retroreflective elements 24 can be increased between the retroreflective elements 24 and the back face layer 40. Thus, the retroreflectivity of the retroreflective sheeting 100 can be further improved.
  • the refractive index of the material configuring the retroreflective elements 24 is preferably higher than the refractive index of the material configuring the back face layer 40. Since the refractive index of the material configuring the retroreflective elements 24 is higher than the refractive index of the material configuring the back face layer 40, light can be reflected off the attachment portion 42 as well. From the similar viewpoint, the refractive index of the material configuring the particles 30 is preferably higher than the refractive index of the material configuring the back face layer 40.
  • the refractive index of the material configuring the particles 30 is higher than the refractive index of the material configuring the back face layer 40, light entered from the retroreflective elements 24 to the particles 30 can be reflected off the interface between the particles 30 and the back face layer 40 to the retroreflective layer 20 side.
  • the present invention is described taking the preferred embodiment as an example. However, the present invention is not limited to this embodiment.
  • the description is made taking an example that the surface protective layer 10 is included.
  • the surface protective layer 10 is no essential component.
  • the description is made taking an example that the adhesive layer 50 is included.
  • the adhesive layer 50 is no essential component.
  • the retroreflective sheeting can be attached to a target with no adhesive layer 50.
  • the layer configuration of the retroreflective sheeting can be made simple, and hence an increase in the production cost of the retroreflective sheeting can be suppressed.
  • Retroreflective sheetings of the examples were prepared as below.
  • a retroreflective layer (made of a polycarbonate resin in a thickness of 200 ⁇ m) was prepared in which retroreflective elements in a triangular pyramid cube corner shape having a height of 80 ⁇ m were provided on a first face and a second face was covered with a surface protective layer (made of an acrylic resin in a thickness of 50 ⁇ m).
  • a stacked sheet was prepared. The sheet had a layer of a releasable sheet (made of a cast polypropylene film in a thickness of 75 ⁇ m), an adhesive layer (made of an acrylic resin in a thickness of 45 ⁇ m), and a back face layer (made of an acrylic resin in a thickness of 80 ⁇ m) in this order.
  • the back face layer was attached to the retroreflective elements, and a retroreflective sheeting in a thickness of 420 ⁇ m was prepared.
  • the ratio np/nv of the number np of the particles to the number nv of the valleys formed between the retroreflective elements adjacent to each other was set to 1.00.
  • the ratio da/h of the average particle diameter da of the particles to the height h of the retroreflective elements was set to 0.38. Note that, all the layers were colorless and transparent.
  • a retroreflective sheeting was prepared similarly to example 1 except that the average particle diameter da of the particles was set to 35 ⁇ m and the ratio da/h of the average particle diameter da of the particles to the height h of the retroreflective elements was set to 0.44.
  • a retroreflective sheeting was prepared similarly to example 1 except that the average particle diameter da of the particles was set to 45 ⁇ m and the ratio da/h of the average particle diameter da of the particles to the height h of the retroreflective elements was set to 0.56.
  • a retroreflective sheeting was prepared similarly to example 1 except that the average particle diameter da of the particles was set to 60 ⁇ m and the ratio da/h of the average particle diameter da of the particles to the height h of the retroreflective elements was set to 0.75.
  • a retroreflective sheeting was prepared similarly to example 1 except that the average particle diameter da of the particles was set to 100 ⁇ m and the ratio da/h of the average particle diameter da of the particles to the height h of the retroreflective elements was set to 1.25.
  • a retroreflective sheeting was prepared similarly to example 1 except that the average particle diameter da of the particles was set to 110 ⁇ m and the ratio da/h of the average particle diameter da of the particles to the height h of the retroreflective elements was set to 1.38.
  • a retroreflective sheeting was prepared similarly to example 3 except that the ratio np/nv of the number np of the particles to the number nv of the valleys formed between the retroreflective elements adjacent to each other was set to 0.40.
  • a retroreflective sheeting was prepared similarly to example 3 except that the ratio np/nv of the number np of the particles to the number nv of the valleys formed between the retroreflective elements adjacent to each other was set to 0.50.
  • a retroreflective sheeting was prepared similarly to example 3 except that the ratio np/nv of the number np of the particles to the number nv of the valleys formed between the retroreflective elements adjacent to each other was set to 2.00.
  • a retroreflective sheeting was prepared similarly to example 3 except that the ratio np/nv of the number np of the particles to the number nv of the valleys formed between the retroreflective elements adjacent to each other was set to 2.10.
  • a retroreflective sheeting was prepared similarly to example 1 except that the ratio np/nv of the number np of the particles to the number nv of the valleys formed between the retroreflective elements adjacent to each other was set to 5.00.
  • a retroreflective sheeting was prepared similarly to example 3 except that a plate-shaped talc was used as the particles.
  • a retroreflective sheeting was prepared similarly to example 3 except that a white pigment (titanium oxide particles having an average particle diameter of 0.20 ⁇ m) was contained in the back face layer by 15 percent by weight.
  • a white pigment titanium oxide particles having an average particle diameter of 0.20 ⁇ m
  • a retroreflective sheeting was prepared similarly to example 1 except that no particles were used. That is, in the retroreflective sheeting according to comparative example 1, the retroreflective elements of the retroreflective layer are entirely in intimate contact with the back face layer.
  • a portable spectrocolorimeter "MiniScan EZ (registered trademark)" produced by Hunter Associates Laboratory, Inc. was used, and the lightness of the retroreflective sheetings was evaluated.
  • the retroreflective sheeting was cut in a 100-by-100-millimeter sheet.
  • the Y value was measured at five points in conformance with JIS Z 9117. The measured values at the five points were expressed by an XYZ color specification system. The mean value of the Y values was taken as the lightness of the retroreflective sheeting.
  • Table 1 reveals that in the retroreflective sheeting according to comparative example 1 with no void, the lightness was low because a large quantity of light was transmitted. All the retroreflective sheetings of examples 1 to 13 had lightness higher than the lightness of the retroreflective sheeting according to comparative example 1. Note that, in example 13, the back face layer that had been colored white enabled the improvement of lightness.
  • Retroreflective property measurement device "Model 920" produced by Gamma Scientific Inc. was used, and the retroreflective properties of the retroreflective sheetings were evaluated. First, only a retroreflective layer cut in a 100-by-100-millimeter sheet without stacking another layer was prepared. Only on the retroreflective layer, the retroreflection coefficient was measured at five points in conformance with JIS Z 9117 at an observation angle of 0.2 degrees and an entrance angle of five degrees. The mean value of the measured values was taken as the retroreflection coefficient of the retroreflective layer alone.
  • the retroreflection coefficient of the retroreflective layer alone means a retroreflection coefficient in the case in which the face of the retroreflective layer on the retroreflective element side was air.
  • the retroreflection coefficient was measured at five points in conformance with JIS Z 9117 at an observation angle of 0.2 degrees and an entrance angle of five degrees. The mean value of the measured values was taken as the retroreflection coefficient of the retroreflective sheeting.
  • the retroreflective properties [%] were calculated based on the measured retroreflection coefficients using an equation below.
  • the retroreflective properties [%] ⁇ (the retroreflection coefficient of the retroreflective sheeting)/(the retroreflection coefficient of the retroreflective layer alone) ⁇ ⁇ 100
  • the retroreflectivity is more excellent as the retroreflective properties are higher.
  • Table 1 reveals that all the retroreflective sheetings of examples 1 to 13 had the retroreflective properties higher than the retroreflective properties of the retroreflective sheeting according to comparative example 1. This can be considered that voids were formed between the retroreflective elements and the particles and light was reflected off the interface between the retroreflective elements and the voids.
  • the retroreflective sheeting was cut in a 75-by-70-millimeter sheet.
  • the sheet was attached to an A5052P aluminum plate defined in JIS H 4000, and then a test sample was obtained. Subsequently, with a xenon lamp accelerated weathering tester (Ci65A) produced by Atlas Electric Devices Co., light was applied to the test sample for 1,000 hours under the conditions in which the application intensity was 550 W/m 2 at a wavelength of 300 to 800 nm and the black panel temperature was 63°C. After that, the appearance of the test sample was visually confirmed. In the case in which no abnormality was observed in the appearance, the layer-to-layer adhesion of the retroreflective sheeting was expressed by excellent. In the case in which the end portion of the retroreflective sheeting was peeled or warped, the layer-to-layer adhesion of the retroreflective sheeting was expressed by fair.
  • Table 1 reveals the correlation of the lightness and the retroreflective properties with the ratio np/nv of the number np of the particles to the number nv of the valleys formed between the retroreflective elements adjacent to each other.
  • FIG. 3 is a graph of the relationship of the retroreflective properties and the lightness with the ratio np/nv of the number of the particles to the valleys based on the evaluation result of examples 7 to 10. Table 1 and FIG.
  • Table 1 reveals the correlation of the lightness and the retroreflective properties with the ratio da/h of the average particle diameter da of the particles to the height h of the retroreflective elements.
  • FIG. 4 is a graph of the relationship of the retroreflective properties and the lightness with the ratio da/h of the average particle diameter to the height of the element based on the evaluation result of examples 1 to 6. Table 1 and FIG.
  • the ratio da/h of the average particle diameter da of the particles to the height h of the retroreflective elements was 0.40 or more and 1.25 or less approximately, and hence the voids in a proper size are formed between the retroreflective elements and the particles and the retroreflective properties are easily improved as well as the adhesive strength of the retroreflective elements to the back face layer is easily improved.

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Engineering & Computer Science (AREA)
  • Architecture (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Optical Elements Other Than Lenses (AREA)
  • Laminated Bodies (AREA)
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EP3696580A4 (de) * 2017-10-12 2020-12-02 Nippon Carbide Industries Co., Inc. Rücktrahlfolie

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JP7043212B2 (ja) * 2017-10-12 2022-03-29 日本カーバイド工業株式会社 再帰反射シート及び再帰反射シートの製造方法

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US5272562A (en) * 1993-02-05 1993-12-21 Minnesota Mining And Manufacturing Company Cube-corner retroreflective articles
JP3123693B2 (ja) * 1993-06-11 2001-01-15 日本カーバイド工業株式会社 再帰反射性シート
WO1996008737A1 (en) * 1994-09-16 1996-03-21 Minnesota Mining And Manufacturing Company Retroreflective article that has phenolic resin in chemical association with reflective aluminum layer
JP2008249962A (ja) * 2007-03-30 2008-10-16 Nippon Carbide Ind Co Inc 再帰反射シート
JP6073781B2 (ja) * 2010-06-01 2017-02-01 スリーエム イノベイティブ プロパティズ カンパニー 多層封止フィルム
JP5717276B2 (ja) * 2010-09-01 2015-05-13 創イノベーション株式会社 酷暑環境用農林資材として使用する方法
CN102902001B (zh) * 2012-09-17 2014-11-12 恩希爱(杭州)化工有限公司 微小玻璃球型逆反射片
JP2017083480A (ja) * 2014-03-14 2017-05-18 日本カーバイド工業株式会社 再帰反射シート

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EP3696580A4 (de) * 2017-10-12 2020-12-02 Nippon Carbide Industries Co., Inc. Rücktrahlfolie
US11280941B2 (en) 2017-10-12 2022-03-22 Nippon Carbide Industries Co., Inc. Retroreflective sheet having particles disposed between retroreflective elements and back face layer

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US20190079222A1 (en) 2019-03-14
CN109073796A (zh) 2018-12-21
JPWO2017188243A1 (ja) 2018-12-13
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