EP3448828A1 - System zur behandlung eines feuerfesten versatzes, die verwendung eines solchen systems, ein verfahren zur behandlung eines feuerfesten versatzes sowie eine verwendung einer form - Google Patents
System zur behandlung eines feuerfesten versatzes, die verwendung eines solchen systems, ein verfahren zur behandlung eines feuerfesten versatzes sowie eine verwendung einer formInfo
- Publication number
- EP3448828A1 EP3448828A1 EP16720400.7A EP16720400A EP3448828A1 EP 3448828 A1 EP3448828 A1 EP 3448828A1 EP 16720400 A EP16720400 A EP 16720400A EP 3448828 A1 EP3448828 A1 EP 3448828A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- refractory
- offset
- mold
- moisture
- permeable material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000000034 method Methods 0.000 title claims abstract description 13
- 239000000463 material Substances 0.000 claims description 94
- 239000011214 refractory ceramic Substances 0.000 claims description 51
- 239000011111 cardboard Substances 0.000 claims description 28
- 238000004519 manufacturing process Methods 0.000 claims description 23
- 238000000576 coating method Methods 0.000 claims description 13
- 239000011248 coating agent Substances 0.000 claims description 12
- 238000001035 drying Methods 0.000 claims description 11
- 239000004033 plastic Substances 0.000 claims description 6
- 229920003023 plastic Polymers 0.000 claims description 6
- 238000007654 immersion Methods 0.000 claims description 4
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 12
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 8
- 239000000123 paper Substances 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 229910000831 Steel Inorganic materials 0.000 description 6
- 229910052799 carbon Inorganic materials 0.000 description 6
- 239000000395 magnesium oxide Substances 0.000 description 6
- 239000010959 steel Substances 0.000 description 6
- 239000000919 ceramic Substances 0.000 description 5
- 230000006378 damage Effects 0.000 description 5
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 4
- 239000011230 binding agent Substances 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 238000005266 casting Methods 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 238000000462 isostatic pressing Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 238000007493 shaping process Methods 0.000 description 4
- 239000004698 Polyethylene Substances 0.000 description 3
- 239000000470 constituent Substances 0.000 description 3
- 238000009749 continuous casting Methods 0.000 description 3
- 238000009792 diffusion process Methods 0.000 description 3
- 229920001971 elastomer Polymers 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000010304 firing Methods 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 239000011087 paperboard Substances 0.000 description 3
- 230000035699 permeability Effects 0.000 description 3
- -1 polyethylene Polymers 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 229920001169 thermoplastic Polymers 0.000 description 3
- 239000012815 thermoplastic material Substances 0.000 description 3
- 239000004743 Polypropylene Substances 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 230000003078 antioxidant effect Effects 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000011343 solid material Substances 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 101100369915 Drosophila melanogaster stas gene Proteins 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 241000033695 Sige Species 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000013013 elastic material Substances 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229920003986 novolac Polymers 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000004382 potting Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000011819 refractory material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B7/00—Moulds; Cores; Mandrels
- B28B7/0029—Moulds or moulding surfaces not covered by B28B7/0058 - B28B7/36 and B28B7/40 - B28B7/465, e.g. moulds assembled from several parts
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/03—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on magnesium oxide, calcium oxide or oxide mixtures derived from dolomite
- C04B35/04—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on magnesium oxide, calcium oxide or oxide mixtures derived from dolomite based on magnesium oxide
- C04B35/043—Refractories from grain sized mixtures
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B1/00—Producing shaped prefabricated articles from the material
- B28B1/14—Producing shaped prefabricated articles from the material by simple casting, the material being neither forcibly fed nor positively compacted
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B11/00—Apparatus or processes for treating or working the shaped or preshaped articles
- B28B11/24—Apparatus or processes for treating or working the shaped or preshaped articles for curing, setting or hardening
- B28B11/243—Setting, e.g. drying, dehydrating or firing ceramic articles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B7/00—Moulds; Cores; Mandrels
- B28B7/34—Moulds, cores, or mandrels of special material, e.g. destructible materials
- B28B7/342—Moulds, cores, or mandrels of special material, e.g. destructible materials which are at least partially destroyed, e.g. broken, molten, before demoulding; Moulding surfaces or spaces shaped by, or in, the ground, or sand or soil, whether bound or not; Cores consisting at least mainly of sand or soil, whether bound or not
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B7/00—Moulds; Cores; Mandrels
- B28B7/34—Moulds, cores, or mandrels of special material, e.g. destructible materials
- B28B7/344—Moulds, cores, or mandrels of special material, e.g. destructible materials from absorbent or liquid- or gas-permeable materials, e.g. plaster moulds in general
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B7/00—Moulds; Cores; Mandrels
- B28B7/34—Moulds, cores, or mandrels of special material, e.g. destructible materials
- B28B7/348—Moulds, cores, or mandrels of special material, e.g. destructible materials of plastic material or rubber
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/64—Burning or sintering processes
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3418—Silicon oxide, silicic acids or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/42—Non metallic elements added as constituents or additives, e.g. sulfur, phosphor, selenium or tellurium
- C04B2235/428—Silicon
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/48—Organic compounds becoming part of a ceramic after heat treatment, e.g. carbonising phenol resins
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/60—Aspects relating to the preparation, properties or mechanical treatment of green bodies or pre-forms
- C04B2235/602—Making the green bodies or pre-forms by moulding
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/60—Aspects relating to the preparation, properties or mechanical treatment of green bodies or pre-forms
- C04B2235/606—Drying
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
Definitions
- a refractory coating treatment system the use of such a system, a method of treating a refractory offset, and use of a mold
- the invention relates to a system for treating a refractory
- Offset a use of the system, a method of treating a refractory offset, and a use of a mold.
- the system according to the invention serves to treat a refractory
- refractory ceramic product in the context of the invention refers in particular refractory products with an operating temperature of about 600 ° C and preferably refractory materials according to DIN 5 1060: 2000-6, ie materials with a cone drop point> SK 17.
- the determination of the cone drop point can especially according to DIN EN 993-12: 1997-06.
- a "refractory offset” is a composition of one or more components or raw materials
- a refractory ceramic product can be produced.
- Refractory ceramic products are known in several ways.
- refractory ceramic products may be in the form of unshaped products (so-called "masses") or in the form of shaped articles
- Pressed green body which has the shape of the functional product to be produced. After Pres sen of such a green body in the elastic shape of the green body is removed from the mold and then processed into a refractory ceramic functional product.
- Such a method is known, for example, for the production of monobloc stoppers for the tundish (tundish) in continuous casting plants.
- An isostatically pressed green body is used to produce a
- Green body to be produced functional product and when arranging the green body at the site. Because the unfired green body is very sensitive, so that it can be easily damaged or even destroyed in connection with these treatment steps.
- the invention has for its object to provide a technology by which a refractory offset for the production of a refractory ceramic molded body formable and at the same time to later use of the producible from the offset refractory ceramic
- the invention provides a refractory offset treatment system comprising the following features:
- the mold is designed to receive a refractory offset and consists at least from sections of a moisture-permeable material
- a basic idea of the system according to the invention is a refractory offset for the production of a refractory ceramic
- a refractory ceramic product in the form of a functional product in that it is not formed by isostatic pressing of the refractory offset in an elastic shape to a green body, but by entering the refractory offset into a shape that at least partially from a
- the shape consists, at least in sections, of a moisture-permeable material.
- This moisture permeability of the material of the mold allows the fireproof offsetting in the mold dries so that it does not have to be removed from the mold to dry it, as in isostatic pressing.
- a particular advantage of this transport possibility of the system consists in particular in the fact that the recorded during this transport and the arrangement in the form offset during transport and the arrangement is protected by the form from damage or destruction.
- the shape of the system according to the invention is designed such that it has a cavity into which the refractory offset can be introduced.
- the geometry or spatial configuration of this cavity corresponds to the geometry or spatial design of the refractory ceramic product ses that can be produced from the recorded in the form or entered into the cavity of the mold refractory offset.
- the inner contour of the mold or the inner surface of the cavity of the mold thus corresponds to the geometry or the outer contour of the refractory ceramic product ses, which can be produced from the recorded in the form refractory offset.
- the mold is designed such that the refractory offset can be introduced by gravity into the mold or into the cavity of the mold.
- the shape is therefore preferably designed such that the refractory offset by no other forces or aids, ie
- the mold is preferably formed such that the refractory s Offset can be introduced from above into the mold or into the cavity of the mold.
- the shape or the cavity of the mold is formed such that the refractory offset is self-acting
- the cavity of the mold for example, no undercuts or portions which can not be filled by the offset when entering the refractory offset in the cavity of the mold.
- the mold is at least partially formed of moisture-permeable material.
- the system according to the invention allows moist constituents of the refractory offset received in the mold to diffuse through the moisture-permeable material of the mold and escape into the environment after passing through the material, whereby the refractory offset received in the mold can dry.
- moisture permeable sig in the context of the present invention, such material is called, the moisture through it
- moisture refers in particular to moist constituents of the refractory offset received in the mold, that is to say in particular water or plastic binder, which has the offset, for example, for adjusting its plasticity or for its formability.
- “Moisture-permeable” in the sense of the present invention therefore refers in particular to what is vapor-permeable or vapor-permeable
- moisture-permeable material may be formed such that it has a low water vapor transmission resistance, for example a Water vapor diffusion resistance ⁇ according to DIN EN ISO 12572: 20 15-01 below 100, in particular also below 50, 20 or below 10.
- a Water vapor diffusion resistance ⁇ according to DIN EN ISO 12572: 20 15-01 below 100, in particular also below 50, 20 or below 10.
- the mold preferably consists entirely or predominantly of such moisture-permeable material siges.
- the mold is at least to such an extent of moisture-permeable material that s of the refractory offset received in the mold is completely dryable in the mold, namely
- the mold consists predominantly of moisture-permeable material, it is provided in particular that the mold is so predominantly made
- moisture-permeable material is formed, the s a received in the form refractory offset or in the form
- the offset green body taken up and formed from the offset green body with at least 50% of its surface (based on the entire surface of the offset or the green body) is applied to moisture-permeable material, more preferably at least 60, 70, 80 or 90% of its surface.
- the moisture-permeable material may be one or more
- Composite material may be formed of a plurality of materials.
- the moisture-permeable material around flammable material.
- the moisture-permeable material is flammable material with an ignition temperature below 500 ° Celsius, in particular with an ignition temperature below 480 °, 460 °, 440 °, 420 °, 400 ° or below 380 ° Celsius.
- the material may have an ignition temperature above 100 ° Celsius, so for example, an ignition temperature above 120 °, 140 °, 160 °, 180 ° or above 200 ° Celsius.
- Product can be arranged and then ignites the flammable material of the mold when the temperature of the system and burned. After the material has burned off, the sections of the refractory offset or the green body formed from the refractory offset in the mold are already at the place of use of the refractory ceramic product which can be produced from the offset without removing the refractory offset from the mold before to have to. As a result, a particularly good protection of the green body formed from the refractory offset is guaranteed, since it does not have to be removed from the mold after its formation in the form of the system according to the invention until it is arranged at the site of the refractory ceramic product to be produced from the refractory offset s.
- the moisture-permeable material of the system according to the invention consists of organic material, for example of cellulose-based material, for example of paper, cardboard or cardboard.
- the material consists of cardboard.
- paperboard it is understood to mean, in general, paper of a large thickness. “In this respect, paperboard can be made, for example, from several layers of paper consist, for example, from several layers of paper
- the several layers of paper can be glued together or pressed together (glued) without leaving any glue.
- One or more of the layers of paper may also be spatially shaped, for example folded, corrugated or profiled in some other way, so that cardboard from which the material of the mold is made can also be present, for example, as a cardboard.
- the material of the system according to the invention consists of cardboard, this may for example have a basis weight in the range of 1 .000 to 3,000 g / m 2 , ie in particular, for example, a basis weight of at least 1, 000, 1, 500, 1, 800 or 2,000 g / m and for example a
- the dimensional stability of a mold can not be sufficient if the thickness of the cardboard is less than 1 mm.
- the material of the mold, insofar as this is present as a cardboard preferably has a thickness of at least 1 mm.
- the material of the form, insofar as this is present as a cardboard preferably has a thickness of at most 6 mm.
- the material of the mold, insofar as this is present as a cardboard preferably has a thickness in the range of 1 to 6 mm, more preferably a thickness of at least 1, 0 or 1, 5 or 2.0 or 2.5 mm and preferably at most a thickness of 6.0 or 5, 5 or 5, 0 or 4.5 or 4.0 or 3.5 mm.
- the thickness of the carton can be 3 mm.
- moisture permeable material is also under environmental technology
- the shape of the system according to the invention is dimensionally stable
- the mold preferably consists of an inherently stable material and insofar, for example, not of an elastic material, such as an elastomer or for example a rubber or rubber. In particular, this is also preferred
- moisture-permeable material of the form formed intrinsically stable.
- Moisture-permeable material from cardboard at least partially has a coating of plastic. Such a coating
- Plastic can in particular serve the dimensional stability
- the moisture-permeable material made of cardboard has a coating of a thermoplastic material. This coating, the cardboard inside (ie on its inside surface), on the outside (ie on its outside surface) or as a location within the carton or for example as a
- the cardboard has such a coating of a thermoplastic material as the outside coating, ie on its surface exposed to the environment.
- the cardboard has the coating only in sections.
- thermoplastic for the coating may be provided, for example, of polyethylene (PE), polypropylene (PP) or polystyrene (PS). Particularly preferred is a thermoplastic material in the form of polyethylene.
- the moisture-permeable material of the system according to the invention consists of perforated material or the moisture-permeable material has a perforation.
- the moisture-permeable material accordingly has a perforation, for example in the form of holes and / or slits.
- Perforation can diffuse or vaporize damp components of the offset received in the mold.
- the perforation is dimensioned such that only such moist constituents of the offset received in the mold pass through the perforation
- the shape of the system according to the invention is designed such that the moisture-permeable material comprises an area exposed to the environment from which moisture can evaporate into the environment.
- the moisture-permeable material of the mold is outwardly, ie on its surface exposed to the environment, therefore, for example, not so covered, the s hinders evaporation from the surface or even prevented. This ensures that the s through the
- Moisture-permeable material can diffuse through, damp components of the offset can evaporate into the environment, so that the refractory offset can effectively dry in the mold.
- the system according to the invention has at least one section which, when viewed over the cross-sectional area of the system, exclusively consists of
- the system has at least one section in which a cross-section can be laid through the system, the system along this cross-section only solid material in the form of
- moisture permeable material and refractory offset stas may of course be present in this section.
- Gaseous or liquid components for example air, other gas or binder, for example in cavities or pores, may of course be present in this section.
- refractory offset can be adversely affected, as far as the system next to the refractory offset and the moisture-permeable material has other solid material. Because such other solid
- Offset act as impurities that can lead to the formation of Ris sen in the offset and burnt therefrom refractory ceramic product, which can not only worsen the properties, especially the strength of the refractory offset to burning, refractory ceramic product ses, but the product can also be damaged or even destroyed.
- this section which consists of finally refractory offset and moisture-permeable sigem material, the edge is completely enclosed by the moisture-permeable material of the mold.
- the refractory offset in the area of this section can be formed by the moisture-permeable material of the mold and at the same time dry well, with the refractory offset in the region of this section also being adversely affected by no impurities during drying and firing.
- the system predominantly or also completely, over the cross-sectional area of the system considered to consist exclusively of moisture-permeable material and refractory offset.
- the system according to the invention proves to be particularly advantageous for the production of refractory shaped functional products, in particular for the production of refractory shaped functional products for the Stahlstranggus s, which are largely or completely made of refractory offset, so for example
- Shadow tubes ladle manifolds
- immersion outlets To be particularly advantageous, however, the system according to the invention has proved to be suitable for the production of monobloc stoppers.
- the recorded in the form offset of the system according to the invention has proved to be suitable for the production of monobloc stoppers.
- the aforementioned refractory ceramic products extend in the form of shadow tubes, immersion faucets or
- the offset taken up in the form of the system according to the invention for producing this product extends along a longitudinal axis which corresponds to the longitudinal axis of the respective product to be produced therefrom.
- the system has at least one section which, via its
- Viewed cross-sectional area consists solely of moisture-permeable material and refractory offset, wherein the cross-sectional area intersects this longitudinal axis of the offset or green body.
- the cross-sectional area intersects the longitudinal axis at right angles.
- the system predominantly or else s completely along this longitudinal axis, viewed over the cross-sectional area of the system, consists of finally moisture-permeable material and refractory offset.
- the system may consist of at least 50, ie, for example, along at least 60, 70, 80, or 90% of the length of the longitudinal axis, across the cross-sectional area of the system, ultimately of moisture permeable material and refractory offset.
- the shape of the system according to the invention moisture-permeable material not only for shaping the outer contour of the offset recorded therein, but also for shaping any inner contours of the offset, for example, as far as the green body formed from the offset inner cavities or other inner
- the system according to the invention is fundamentally suitable for the treatment of any refractory offset known from the prior art, from which a refractory ceramic product can be produced.
- any known from the prior art refractory offset for the production of a refractory ceramic product may be included in the mold.
- the refractory offset is so far in general a refractory offset, so an offset for the production of a refractory ceramic product ses.
- the system according to the invention is particularly suitable for the formation of refractory sets for the production of refractory ceramic products in the form of functional products, in particular of functional products for the casting of steel.
- the refractory offset received in the mold may more preferably be a refractory offset for producing a refractory molded functional product in the form of a shadow tube
- the refractory offset is one for making a sintered refractory ceramic product.
- the refractory offset can be one from which a carbon-bonded refractory ceramic product can be produced. In that regard, it may be at the
- refractory offset for example, to one of at least one oxide selected from the following group:
- the refractory offset is one from which a carbon-bonded refractory ceramic product can be produced, the refractory offset further comprises carbon.
- the specific composition and choice of raw materials it is possible to form such a refractory offset on the refractory offsets known from the prior art on the basis of these substances
- the proportion of the total mass of the oxides aluminum oxide, magnesium oxide and zirconium oxide can be, for example, in the range of 60 to 100% by mass, in the range of 70 to 95% by mass or in the range of 80 to 95% by mass, based on the total mass of refractory offset.
- the offset may, for example, be in the form of a refractory offset for making molded or unshaped refractory ceramic products.
- refractory offsets sen for isostatic Pres sen of refractory ceramic functional products in the form of Monoblockstopfen, shadow tubes or Eintauchausgüs sen known.
- the refractory offset is for producing a refractory shaped
- the system includes retention means. These holding means may in particular be designed such that the system can be held over the holding means.
- Retaining means simplify the holder, the transport and the
- such holding means are arranged on the shape of the system.
- such holding means are arranged on the shape of the system.
- Holding means may be arranged on the outside of the mold, for example in the form of metallic handling means. Not to the shape
- Such handling means are provided, for example, in the form of the form umfas send send cuffs.
- Holding means which are formed in the refractory offset.
- the holding means may simultaneously constitute the means which serves to hold the refractory ceramic refractory ceramic product to be used in its use.
- a holding means is formed in the form of a metallic internal thread, for example in the form of a nut. In this thread are means for holding the refractory offset produced
- the shape may consist of sections of moisture-permeable material.
- Such non-moisture permeable material may in particular be provided to impart properties to the mold as a result of this moisture-impermeable material which is wetted by moisture-permeable material Material can not be lent.
- the shape of the sections may consist of such non-moisture-permeable material in order to increase the intrinsic stability or strength of the mold. Further, for example, the shape of the shape may not be such
- non-moisture-permeable material may be made of metal
- steel or plastic may be formed.
- Moisture-permeable material having a tube may be provided that the two ends of the tube are strigosen by closures or attachments, at least one, preferably both ends by closures of such a not
- moisture permeable material can be striglos sen.
- a cavity is defined by the inner wall of the tube and by surface portions of the closures, in which the offset is receivable.
- the refractory offset is formed by concerns against the inner wall of the tube and the said surface portions to form a green body.
- at least one of the Verschlüs se may have an opening.
- Embodiment of such a system is explained in more detail below as an exemplary embodiment.
- the mold does not comprise moisture-permeable material, it may be provided that this material is removed from the mold before the mold is exposed to temperature, in particular also, as far as the moisture-permeable material is not flammable.
- the invention also provides the use of the inventive system for the treatment of a refractory offset for the production of a refractory ceramic functional product in the form of a
- Monoblock stopper a shade tube, a submerged nozzle or a change spout.
- the invention also provides a process for the treatment of a refractory offset, which comprises the following steps:
- the shape and refractory offset may, as stated herein,
- the introduction of the refractory offset into the mold can in particular be effected by means of gravity, and in particular without pumps or other input means.
- Thenas sen of the refractory offset in the mold can
- the method may further comprise the following steps:
- the site of use may be a continuous casting plant and there in particular a tundish.
- the mold with the dried refractory offset received therein is disposed completely at the place of use. This embodiment offers itself
- the shape of the dried refractory offset received therein is partially disposed of at the place of use.
- This embodiment is particularly suitable when the mold consists partly of flammable and partly of non-flammable material.
- the mold consists partly of flammable and partly of non-flammable material.
- at least the parts of the mold which are formed of non-flammable material are removed with temperature.
- the application of the mold with temperature preferably takes place via the aggregate to which the place of use of the refractory ceramic products which can be produced from the refractory offset is located, that is to say in particular, for example, a tundish.
- a tundish As far as the moisture-permeable material of the mold, as stated above, is flammable, this material burns Achieve their ignition temperature so that it must not be removed by a further process step from the molded refractory offset must s.
- the subsequently exposed, shaped offset is finally burned to a refractory ceramic product by further application of temperature, thus in particular by further heating of the tundish.
- the system of the invention and the inventive method proves in particular for the production of a carbon-bonded refractory ceramic product ses from the refractory offset, since the moisture-permeable material sige form until it reaches its ignition temperature as oxidation protection for the
- the invention also provides the use of a disclosed herein form for receiving a refractory offset.
- the shape and refractory offset may be as set forth herein and used in accordance with the features disclosed herein, particularly, the method features disclosed herein.
- the embodiments each relate to a system for treating an offset for producing a
- Figure 1 shows a first embodiment of a system for treating an offset for producing a monoblock plug in a side sectional view
- Figure 2 shows a second embodiment of a system for treating an offset for producing a Monoblockstopfens in a lateral sectional view.
- the system 1 comprises a mold 2 and a refractory offset 3 received in the mold 2.
- the mold 2 comprises a circular cylindrical tube 4 made of cardboard and a first closure 5 and a second closure 6, which are each formed from steel.
- the tube 4 is in Figure 1 in an upright position, ie with a vertical longitudinal axis L of the tube 4.
- first closure 5 By the first closure 5, the tube 4 at its lower end 4u and by the second Ver slos 6 at its upper end 4o locked.
- the tube 4 of the mold 2 is formed from a circular cylindrical shaped cardboard with a clear diameter of 13 1 mm.
- the wall thickness of the box is 3 mm.
- the length of the tube 4 is 1 .590 mm, wherein the length of the tube 4 in the illustration of Figure 1 - indicated by the
- the tube 4 encloses an internal space 4h in the interior of the tube 4.
- the cardboard from which the tube 4 is formed is
- the tube 4 is sealed tightly by the first closure 5.
- the first closure 5 has a section 5. 1, which is inserted into the lower end 4u of the tube 4.
- the section 5. 1 a circular cylindrical outer periphery with a diam water, which corresponds to the clear diam water of the tube 4, so the s the tube 4 at its lower end 4u with its inner wall surface against the circumference of
- Section 5. 1 of the first shutter 5 is present. At the From section 5. 1 of the first shutter 5, a second section connects 5.2, which projects beyond the first section 5. 1 circumference and thereby forms a joint edge 5.3, against which the tube 4 abuts with its lower end face.
- a metallic base plate 8 against the first closure s 5 screwed.
- the base plate 8 is designed disc-shaped and has a diameter of 300 mm diam. About the base plate 8, the mold 2 is safe on one
- the first attachment 5 On its side facing the cavity 4h of the tube 4, the first attachment 5 has a cup-shaped recess 5.5, which extends concavely into the portion 5. 1.
- the second closure s 6 is composed of several parts of individual steel elements.
- the second closure 6 has a first section 6. 1, which is inserted into the upper, end-side section 4 o of the tube 4. Like the section 5. 1 of the first shutter 5, the first section 6. 1 of the second shutter 6 also has a circular cylindrical section
- Closure 6 is present. At the first section 6. 1, a second section 6.2 of the second Verschlus ses 6 connects, which projects beyond the first section 6. 1 on its outer circumference.
- the second closure 6 has a bore 9 which is concentric with the longitudinal axis L of the tube 4 and which comprises three sections 9. 1, 9. 2 and 9. 3 having different diameters.
- the closure 6 is used in particular for positioning a deformable in the refractory offset 3 nut in which a rod is screwed (indicated by the dashed line 10), via which a manufacturable from the refractory offset 3 Monoblockstopfen durable in its later use on Tundish and is movable.
- the cavity H is completely filled with the offset 3.
- the refractory offset 3 is a refractory casting compound for producing a carbon-bonded refractory ceramic
- Offset 3 is composed of 82.5% by mass fused magnesia, 12% by mass graphite, 3% by mass binder, 2.0% by mass antioxidant and 0.5% by mass silica powder, in each case based on the total mass of offset 3.
- the fused magnesia is present in a purity of 97% by weight of MgO.
- the graphite as the carbon carrier of the refractory offset 3, has a carbon content of 94% by mass.
- the binders are a blend of novolac and pitch. As an antioxidant, aluminum powder is present.
- the refractory offset 3 was filled through the hole 9 in the second closure 6 in the cavity H until he filled the cavity H completely. Subsequently, the mold 2 was vibrated so that the refractory offset 3 continued to settle and compact.
- Offset 3 through the moisture-permeable tube 4 to the outside and evaporated on the surface of the tube 4 exposed to the environment U. Further moist portions of the refractory offset 3 evaporated through the bore 9. This diffusion and evaporation continued until the refractory offset 3 dried completely was. Subsequently, a formed by the mold 2, formed from the refractory offset 3 green body for producing a carbon-bonded monoblock plug.
- first closure 5 and the second closure 6 are non-flammable parts of the mold 2, after the refractory offset 3 has dried, the first closure 5 and the second closure 6 have been replaced by the mold 2 and the refractory offset 3 away.
- the removal of the second Verschlus ses 6 from the offset was, despite the undercut of the refractory offset 3 in its formed by the bore 9 section, due to the multiple-part of the Verschlus ses 6 possible.
- the offset 3 of the system 1 constitutes a green body for producing a monobloc stopper, which is combustible without further shaping into a monobloc stopper. This, from the offset 3
- Flammable monoblock plug extends along a longitudinal axis, which corresponds to the longitudinal axis L of the tube 4 and at the same time also the longitudinal axis L of the offset 3 or of the green body formed after drying of the offset 3.
- the system l viewed over a cross-sectional area which intersects this longitudinal axis L at right angles, consists exclusively of moisture-permeable
- the system 1 consists of well over 50% of the length of the longitudinal axis L, viewed over the cross-sectional area of the system 1, finally out
- the system according to FIG. 2 is largely identical to the system according to FIG. 1, so that the matching components of both systems are provided with the same reference numerals.
- Green body is arranged in the mold 2.
- the tube 1 1 is formed from the same box from which the tube 4 is formed.
- the tube 1 1 has a clear diameter of about 10 mm.
- the mold 2 or the one after removal of the first and the second was removed
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Ceramic Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Structural Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Compositions Of Oxide Ceramics (AREA)
- Building Environments (AREA)
- Furnace Housings, Linings, Walls, And Ceilings (AREA)
Abstract
Description
Claims
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/EP2016/059636 WO2017186304A1 (de) | 2016-04-29 | 2016-04-29 | System zur behandlung eines feuerfesten versatzes, die verwendung eines solchen systems, ein verfahren zur behandlung eines feuerfesten versatzes sowie eine verwendung einer form |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP3448828A1 true EP3448828A1 (de) | 2019-03-06 |
Family
ID=55910949
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP16720400.7A Withdrawn EP3448828A1 (de) | 2016-04-29 | 2016-04-29 | System zur behandlung eines feuerfesten versatzes, die verwendung eines solchen systems, ein verfahren zur behandlung eines feuerfesten versatzes sowie eine verwendung einer form |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US20190184599A1 (de) |
| EP (1) | EP3448828A1 (de) |
| CN (1) | CN108883993A (de) |
| BR (1) | BR112018069565A2 (de) |
| RU (1) | RU2018132954A (de) |
| WO (1) | WO2017186304A1 (de) |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2115341B (en) * | 1982-01-07 | 1985-04-17 | Foseco Trading Ag | Refractory tube |
-
2016
- 2016-04-29 RU RU2018132954A patent/RU2018132954A/ru not_active Application Discontinuation
- 2016-04-29 CN CN201680084126.9A patent/CN108883993A/zh active Pending
- 2016-04-29 EP EP16720400.7A patent/EP3448828A1/de not_active Withdrawn
- 2016-04-29 US US16/091,453 patent/US20190184599A1/en not_active Abandoned
- 2016-04-29 BR BR112018069565A patent/BR112018069565A2/pt not_active Application Discontinuation
- 2016-04-29 WO PCT/EP2016/059636 patent/WO2017186304A1/de not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| BR112018069565A2 (pt) | 2019-01-29 |
| US20190184599A1 (en) | 2019-06-20 |
| RU2018132954A (ru) | 2020-05-29 |
| CN108883993A (zh) | 2018-11-23 |
| WO2017186304A1 (de) | 2017-11-02 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE69838183T2 (de) | Verfahren zum brennen von keramischen wabenstrukturen und dafür verwendeter tunnelofen | |
| DE1567489B2 (de) | Vorrichtung zum abtrennen von wasserstoff aus gasgemischen | |
| DE1471413A1 (de) | Verfahren zur Herstellung von keramischen Gegenstaenden und ein damit hergestelltes Erzeugnis | |
| DE2421311B2 (de) | Feuerfestes keramisches Erzeugnis sowie Verfahren und Vorrichtung zu dessen Herstellung | |
| EP2960221B1 (de) | Feuerfestes keramisches Erzeugnis | |
| DE2511979C3 (de) | Verfahren zum Herstellen von Feuerfestkörpern | |
| EP4665174A1 (de) | Wickel für die herstellung einer gestopften rauchware, verwendung des wickels zur herstellung einer gestopften zigarre oder eines gestopften zigarillos und verfahren zur herstellung des wickels | |
| DE604691C (de) | Verfahren zur Herstellung von Formlingen, insbesondere aus keramischem Stoff | |
| CH632225A5 (en) | Process for making a fired moulding from particulate material | |
| EP3448828A1 (de) | System zur behandlung eines feuerfesten versatzes, die verwendung eines solchen systems, ein verfahren zur behandlung eines feuerfesten versatzes sowie eine verwendung einer form | |
| DE3907500C1 (en) | Gas bubble brick with directed porosity and method for its manufacture | |
| EP3009209A1 (de) | Verfahren zur herstellung eines speisereinsatzes mit in dessen wandung eingebrachten hohlräumen | |
| DE19543430C2 (de) | Zweischichtstein und Verfahren zu seiner Herstellung | |
| EP3403821B1 (de) | Verfahren zur herstellung eines formteils mit einem mehrschichtigen aufbau und formteil | |
| DE2536556A1 (de) | Geraeuscharmer brennerstein | |
| EP3756787A1 (de) | Speisereinsatz mit hülle | |
| DE60007490T2 (de) | Gasspülstein und dessen Herstellungsverfahren | |
| DE102005032345B4 (de) | Adsorptiver Formkörper mit anorganischer amorpher Stützstruktur, Verfahren zur Herstellung desselben sowie dessen Verwendung | |
| CH495300A (de) | Verfahren zur Herstellung von keramischen Materialien und nach diesem Verfahren hergestellter keramischer Formkörper | |
| DE10329229B3 (de) | Flachmembranstapel und Verfahren zur Herstellung einer solchen | |
| DE1953223C3 (de) | Vorrichtung zur Abtrennung von Waaserstoff aus einem Gasgemisch | |
| DE102012024799A1 (de) | Gepresstes Treibladungselement, Verfahren zu dessen Herstellung und Gasgenerator mit Treibladungselement | |
| DE102016223746B4 (de) | Gaseinlass für ein Ionentriebwerk | |
| DE3034775C2 (de) | Verfahren zur Herstellung einer Vorrichtung zur Wärmedämmung einer Wärmequelle | |
| DE19546959C2 (de) | Verfahren zum Herstellen eines gefüllten Hohlkörpers |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE INTERNATIONAL PUBLICATION HAS BEEN MADE |
|
| PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: REQUEST FOR EXAMINATION WAS MADE |
|
| 17P | Request for examination filed |
Effective date: 20180828 |
|
| AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
| AX | Request for extension of the european patent |
Extension state: BA ME |
|
| DAV | Request for validation of the european patent (deleted) | ||
| DAX | Request for extension of the european patent (deleted) | ||
| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN |
|
| 18D | Application deemed to be withdrawn |
Effective date: 20191101 |