EP3390690A1 - Procédé de passivation d'une surface d'un élément métallique - Google Patents
Procédé de passivation d'une surface d'un élément métalliqueInfo
- Publication number
- EP3390690A1 EP3390690A1 EP17710122.7A EP17710122A EP3390690A1 EP 3390690 A1 EP3390690 A1 EP 3390690A1 EP 17710122 A EP17710122 A EP 17710122A EP 3390690 A1 EP3390690 A1 EP 3390690A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- layer
- concentration
- conversion layer
- component
- passivation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 54
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 44
- 239000002184 metal Substances 0.000 title claims abstract description 44
- 238000002161 passivation Methods 0.000 claims abstract description 44
- 239000000126 substance Substances 0.000 claims abstract description 26
- 239000002738 chelating agent Substances 0.000 claims abstract description 20
- 239000000463 material Substances 0.000 claims abstract description 9
- 239000001506 calcium phosphate Substances 0.000 claims abstract description 8
- 235000011010 calcium phosphates Nutrition 0.000 claims abstract description 8
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 claims abstract description 8
- 229910000389 calcium phosphate Inorganic materials 0.000 claims abstract description 7
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims abstract description 3
- 150000004679 hydroxides Chemical class 0.000 claims abstract description 3
- 239000010410 layer Substances 0.000 claims description 93
- 238000006243 chemical reaction Methods 0.000 claims description 52
- 238000000576 coating method Methods 0.000 claims description 48
- 239000011248 coating agent Substances 0.000 claims description 32
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 18
- 235000002906 tartaric acid Nutrition 0.000 claims description 18
- 239000011975 tartaric acid Substances 0.000 claims description 18
- 239000013522 chelant Substances 0.000 claims description 17
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 14
- 239000008139 complexing agent Substances 0.000 claims description 13
- 230000015572 biosynthetic process Effects 0.000 claims description 11
- 239000011575 calcium Substances 0.000 claims description 11
- 239000003973 paint Substances 0.000 claims description 11
- 235000001014 amino acid Nutrition 0.000 claims description 9
- 150000001413 amino acids Chemical class 0.000 claims description 9
- 239000000470 constituent Substances 0.000 claims description 9
- 239000011777 magnesium Substances 0.000 claims description 9
- 239000000843 powder Substances 0.000 claims description 9
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 7
- 229910052749 magnesium Inorganic materials 0.000 claims description 7
- 239000011780 sodium chloride Substances 0.000 claims description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 6
- 229910052782 aluminium Inorganic materials 0.000 claims description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 6
- 238000007598 dipping method Methods 0.000 claims description 6
- 125000000524 functional group Chemical group 0.000 claims description 6
- 238000007654 immersion Methods 0.000 claims description 6
- 239000011782 vitamin Substances 0.000 claims description 6
- 235000013343 vitamin Nutrition 0.000 claims description 6
- 229940088594 vitamin Drugs 0.000 claims description 6
- 229930003231 vitamin Natural products 0.000 claims description 6
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 5
- 150000007524 organic acids Chemical class 0.000 claims description 5
- ODKSFYDXXFIFQN-BYPYZUCNSA-N L-arginine Chemical compound OC(=O)[C@@H](N)CCCN=C(N)N ODKSFYDXXFIFQN-BYPYZUCNSA-N 0.000 claims description 4
- 229930064664 L-arginine Natural products 0.000 claims description 4
- 235000014852 L-arginine Nutrition 0.000 claims description 4
- 229910045601 alloy Inorganic materials 0.000 claims description 4
- 239000000956 alloy Substances 0.000 claims description 4
- 125000000896 monocarboxylic acid group Chemical group 0.000 claims description 4
- 239000002245 particle Substances 0.000 claims description 4
- 150000003722 vitamin derivatives Chemical class 0.000 claims description 4
- 230000002378 acidificating effect Effects 0.000 claims description 3
- 239000011241 protective layer Substances 0.000 claims description 3
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims description 2
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 claims description 2
- 230000003213 activating effect Effects 0.000 claims description 2
- 239000012190 activator Substances 0.000 claims description 2
- 150000001298 alcohols Chemical class 0.000 claims description 2
- 150000002085 enols Chemical class 0.000 claims description 2
- 239000012530 fluid Substances 0.000 claims description 2
- 239000012634 fragment Substances 0.000 claims description 2
- 150000004780 naphthols Chemical class 0.000 claims description 2
- 150000002989 phenols Chemical class 0.000 claims description 2
- 150000003014 phosphoric acid esters Chemical class 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims description 2
- 150000003573 thiols Chemical class 0.000 claims description 2
- 230000007935 neutral effect Effects 0.000 claims 1
- 238000007739 conversion coating Methods 0.000 abstract 2
- 230000008569 process Effects 0.000 description 22
- 150000002500 ions Chemical class 0.000 description 12
- 230000007246 mechanism Effects 0.000 description 9
- 238000005260 corrosion Methods 0.000 description 8
- 150000004697 chelate complex Chemical class 0.000 description 7
- 230000007797 corrosion Effects 0.000 description 7
- 239000003446 ligand Substances 0.000 description 5
- 229910000831 Steel Inorganic materials 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 238000007591 painting process Methods 0.000 description 4
- 230000001681 protective effect Effects 0.000 description 4
- 239000010959 steel Substances 0.000 description 4
- 229910000861 Mg alloy Inorganic materials 0.000 description 3
- 238000010276 construction Methods 0.000 description 3
- 238000010422 painting Methods 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 239000002800 charge carrier Substances 0.000 description 2
- 238000003795 desorption Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- 238000005304 joining Methods 0.000 description 2
- 239000004922 lacquer Substances 0.000 description 2
- 230000020477 pH reduction Effects 0.000 description 2
- 230000035515 penetration Effects 0.000 description 2
- 235000021317 phosphate Nutrition 0.000 description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
- 238000005554 pickling Methods 0.000 description 2
- 230000010287 polarization Effects 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 239000002356 single layer Substances 0.000 description 2
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 239000004918 carbon fiber reinforced polymer Substances 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000005686 electrostatic field Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003574 free electron Substances 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical class [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical class O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 230000037452 priming Effects 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 238000013517 stratification Methods 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 239000013585 weight reducing agent Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
- C23C22/08—Orthophosphates
- C23C22/22—Orthophosphates containing alkaline earth metal cations
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/68—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous solutions with pH between 6 and 8
Definitions
- the invention relates to a method for passivating a surface of a metal component according to the preamble of patent claim 1 and to a passivation solution for forming a conversion layer for the surface of the metal component according to patent claim 16.
- metal components in particular of light metal components, is common practice across industries.
- vehicle construction for example, vehicle bodies in mixed construction, for example
- Alloy and sheet steel parts are manufactured to a
- aluminum or magnesium materials or alloys thereof can be used as light metal.
- vehicle bodies manufactured in mixed construction there is a risk of contact corrosion between the light metal components (off
- Method is generated in a passivation step using an aqueous Passivitationslosung on the surface of the metal component, a calcium phosphate-containing conversion layer.
- the conversion layer has oxides and hydroxides as well as carbonates of the component material and the passivation solution.
- the passivation can be one
- Process chain for painting vehicle bodies process technology are upstream, as known from DE 196 30 289 C2.
- Magnesium alloy is.
- the process can produce a nickel coating of uniform thickness.
- From DE 37 15 663 A1 is a Andosier solution for anodic oxidation of magnesium or
- Magnesium alloys known. From JP 2009-228087 a method for coating a light metal component made of a magnesium alloy is known.
- the object of the invention is to provide a method for passivating the surface of a metal component, in which compared to the prior art, a simple and improved passivation is possible.
- the passivation solution for the formation of the conversion layer has at least one substance acting as chelate complexing agent (ie chelate ligand). This results in a later-described film forming mechanism in which the conversion layer formed is less cracked compared to the prior art.
- Chelating agents ie chelating ligands work. These plurality of different chelating agents can compete with each other in the conversion layer formation, so that the film forming mechanism is impaired, which may lead to the crack structure in the conversion layer.
- Chelate complexing agent substance is initiated. Of the
- the layering mechanism is not affected by other competing substances which may also act as chelating agents.
- the conversion layer is thereby formed with a closed, low-crack layer morphology, whereby its protective effect is improved. Substantially the same effect is achieved when the plurality of chelating agents are limited to a few Chelating agent is limited to about two or three Chelatkomplexsentner substances.
- the chelate complexing agent used may preferably be an organic substance having optionally deprotonated functional groups with one or more lone pairs of electrons, that is to say
- an organic substance for example, an organic acid or its salts, an amino acid or a suitable vitamin comes into question.
- the organic acid contained in the passivation solution may be a tartaric acid, an acetic acid or L-arginine.
- the substance acting as chelate complexing agent may preferably be contained in the passivating solution at a concentration in the range of 1-20 mmol / l.
- Possible further groups of chelating agents in addition to carboxylic acids (organic acids) are also: alcohols, phenols, naphthols, enols, thiols, sulfonic acid, phosphoric acid esters, phosphonic acid.
- the chelating agent-substance (hereinafter exemplified by tartaric acid) contained in the passivating solution makes it possible to form a layer-forming mechanism that is perfect in comparison with the prior art for forming the conversion layer.
- Tartaric acid as a chelating agent in which the Ca 2+ ions coordinating in the passivation solution are complexed in the respective tartaric acid molecule to form a chelate complex.
- the chelate complex is briefly physically reversibly adsorbed on optionally deprotonated functional groups, that is, for example via OH end groups, to the metallic component surface.
- the bound in the chelate Ca 2+ ions are therefore transported to the metallic component surface. There it reacts with the phosphates dissolved in the passivation solution and forms the calcium phosphate-containing conversion layer. Subsequently, a desorption of the chelate complexing agent (that is the des
- Penetration resistance therefore behaves inversely proportional to the corrosion currents.
- the passive behavior of the conversion layer is increased due to the substantially closed, low-crack layer structure of the conversion layer.
- the formed with the passivated surface metal component can be used across industries.
- the metal component can be used in the medical field. Alternatively, that is
- Metal component optionally used in the automotive sector, and that is visible within the vehicle or as an externally visible outer part.
- the metal component can be realized as a vehicle-inner-side display frame, an aggregate part, a chassis part or a component of a seat frame structure.
- a component material made of aluminum results with the
- Passivation Solution A compact calcium phosphate and aluminum hydroxide / oxide coating with amino acids.
- the layer morphology is substantially closed, that is, at least low-crack, formed.
- Magnesium hydroxide / oxide-containing coating whose layer morphology is also substantially closed and formed low-crack.
- the passivation solution may preferably comprise at least the following constituents as activators for activating the surface of the component: NaCl having a concentration between 5500 and 7500, in particular 6400 mg / l; and or
- KCl with a concentration between 300 and 500, in particular
- the passivation MgS0 4 -7H 2 0 may be at a concentration between 100 and 400, comprise, in particular 200 mg / l.
- the passivation layer may preferably contain calcium phosphates.
- the conversion layer may contain carbonaceous constituents.
- the passivation solution may contain NaHCO 3 .
- the formation of carbonate also depends on possibly supplied CO 2 .
- the passivation solution may be in a particularly preferred
- Chelate complexing agent with in particular 1 to 20 mmol / l can be carried out at a pH of about 7. In this case, the coating reaction is slow. Alternatively, the coating reaction can also take place in the acidic range. The coating reaction can be achieved by increasing the
- the coating process can preferably by means of a pH reduction (pH of 1 to 5) and by means of a temperature increase of normal
- Room temperature can be accelerated by 15 ° to 80 ° C.
- the metal component may be a vehicle part, which is first pretreated with the passivation solution according to the invention to form the conversion layer.
- the conversion layer of the component can be covered with at least one further layer in a subsequent coating process.
- the coating process can be a first
- Coating step in which a KTL layer, that is, an organic protective layer is formed. This is done in one
- Coating step is then applied a powder coating. This is done in a powder coating process under applied
- the metal component for example as a
- the metal body mounted on the green body is already precoated with a layer structure, namely with the conversion layer, the cathodic electrostatic layer and the powder coating.
- the metal component is thus electrically insulated, so that the body in the Rohkarosserie-
- Figs. 1 b and 1 c are views each illustrating the film formation mechanism for forming a conversion layer
- Body part 3 shown.
- the body part 3 made of light metal, such as aluminum, magnesium or an alloy thereof.
- the layer structure 1 directly on the workpiece surface 25 of the light metal component 3, a conversion layer 5, which serves for passivation and corrosion protection.
- Conversion layer 5 is covered by a KTL layer 6. On this a powder coating 7 is formed, on which a conventional automotive, multi-layer paint system 9 (in Fig. 1a for reasons of
- the conversion layer 5 has a substantially closed, low-crack layer morphology.
- the conversion layer 5 is also designed so that in a later described KTL coating process for a sufficient residual conductivity between a KTL immersion bath and the light metal material of the component 3 is provided.
- Conversion layer 5 actually has a layer thickness which is in the ⁇ range.
- a series paint process carried out in a painting installation will be described, in which a passivation solution according to the invention is used: Accordingly, in FIG. 2, as pretreatment steps, an (optional) mechanical treatment, for example, takes place Grind. Subsequently, a wet chemical pretreatment, that is, a degreasing and a pickling, performed. This is followed by a passivation step, in which the metal component 3 is immersed, for example, in a dipping bath of the passivation solution.
- the passivation solution contains at least the following main components: NaCl at 6400 mg / l
- NaCl and KCl in the passivation solution serve to activate the metal surface 25.
- the components NaH 2 PO 4 and CaCb support the coating process by incorporating the Ca 2+ and PO 4 3 " ions into the conversion layer 5.
- the tartaric acid effects the following with reference to FIGS. 1 b and 1 c
- the Ca 2+ ions are bound by electrostatic attraction (indicated by dashed lines in FIGS. 1 b and 1 c).
- amino acids / vitamins can thus bind ions.
- an amino acid for example, the amino acid L-arginine
- a suitable vitamin as a chelating agent in the
- End groups COOH end groups, PO 4 3 " end groups, SH end groups or OH end groups.
- the chelate complex 8 is attached via functional groups, that is to say via OH end groups, to the Surface 25 of the metal component 3 briefly adsorbed physically reversible (in Fig. 1 c indicated by dashed arrow).
- Chelate complex 8 bound Ca 2+ ions are therefore included in the
- Chelate complexing agent that is, the chelating ligand
- the tartaric acid (or other suitable substance) is preferred as the sole chelating agent in the
- Chelating agent-substance acts. That of the tartaric acid
- Chelate complexing agents can act. In this way, the
- the conversion layer 5 therefore has an improved protective effect compared to conversion layers with crack structures.
- the passivation solution may also contain several different chelating agent substances.
- the conversion layer 5 according to the invention also has carbonate-containing layer constituents. These are provided in the passivation solution by the component NaHCO 3 and CO 2 (from the atmosphere). Overall, it is therefore in the inventive
- Passivitations preferably to an aqueous treatment liquid whose pH is in the range of about 7 or in the acidic range.
- the passivation is preferably carried out in the immersion bath at room temperature.
- Treatment time depends on the set pH, the
- Coating process can be accelerated by means of a pH reduction to a pH of 1 to 5 and / or by increasing the temperature by 15 to 80 ° C.
- the coated with the conversion layer 5 component 3 is in
- the KTL is done in common practice in the dipping process, in which between the body 15 and the
- the component 3 passes through a continuous furnace at a predetermined conveying speed, in which the KTL layer 6 at process temperatures in the range of for example 180 ° C. is burned. Subsequently, in process step II in a
- Coating station 20 carried out a powder coating, in which the layer 7 (Fig. 1) is applied to the component 3.
- the layer 7 (Fig. 1) is applied to the component 3.
- Powder coating 20 the paint particles are transported by an electrostatic field of live pointed heads to the grounded component 3. Subsequently, in a further station 19, a baking process takes place in a continuous furnace.
- the light metal component 3 is added in an exemplary possible application as a visible vehicle outer part in a joining process (for example, gluing and / or screws) to a shell body not yet painted.
- the green body 15 is conveyed in a continuous process in a body painting plant (see Fig. 4).
- the body provided with the primer body 15 is led to another coating station 29, in which a KTL process takes place.
- the KTL process 29 is likewise a continuous furnace 31
- Coating station 33 applied a conventional automotive four-layer paint system 9, which is subsequently subjected to a baking process 35.
- the body painting process shown in FIG. 4 is carried out with already pre-coated light metal component 3. That means that
- Light metal component 3 is electrically insulated, so that the applied in Rohkosheie- Lackier Anlagen KTL layer no longer adhere, whereas the conventional automotive paint system 9 (that is, a Four-layer structure) readily on the powder coating 7 of
- Figs. 5 to 7 is in views corresponding to FIG. 1 the
- Light metal component 3 shown in different process steps. Thus, in FIG. 5, the light metal component 3 with cleaned and exposed metallic surface 25 is shown. In Fig. 6, the light metal component 3 is shown after passivation and rinsing or drying.
- the conversion layer 5 is on the surface 25 of the
- the conversion layer 5 as a sole layer that is, in the single-layer structure without additional intermediate and outer layers
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemical Treatment Of Metals (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102016002852.1A DE102016002852A1 (de) | 2016-03-10 | 2016-03-10 | Verfahren zur Passivierung einer Oberfläche eines Metallbauteils |
PCT/EP2017/000240 WO2017153036A1 (fr) | 2016-03-10 | 2017-02-20 | Procédé de passivation d'une surface d'un élément métallique |
Publications (3)
Publication Number | Publication Date |
---|---|
EP3390690A1 true EP3390690A1 (fr) | 2018-10-24 |
EP3390690B1 EP3390690B1 (fr) | 2022-04-27 |
EP3390690B8 EP3390690B8 (fr) | 2022-06-29 |
Family
ID=58266545
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP17710122.7A Active EP3390690B8 (fr) | 2016-03-10 | 2017-02-20 | Solution de passivation pour la passivation d'une surface d'un élément métallique |
Country Status (3)
Country | Link |
---|---|
EP (1) | EP3390690B8 (fr) |
DE (1) | DE102016002852A1 (fr) |
WO (1) | WO2017153036A1 (fr) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102017107529A1 (de) * | 2017-04-07 | 2018-10-11 | Lisa Dräxlmaier GmbH | Verfahren zur Korrosionsinhibierung von Metallen und Temperierungssystem für ein metallisches Werkzeug |
DE102017011379A1 (de) | 2017-12-11 | 2019-06-13 | Audi Ag | Anti-Korrosionsbeschichtung für metallische Substrate |
DE102019200848A1 (de) * | 2019-01-24 | 2020-07-30 | Audi Ag | Beschichtungsanordnung für Mg-Bauteile |
DE102019131441B3 (de) * | 2019-11-21 | 2020-12-31 | Audi Ag | Elektronikgehäuse zur Aufnahme einer elektrischen Komponente |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1072055B (fr) * | 1952-08-28 | |||
US4744872A (en) | 1986-05-30 | 1988-05-17 | Ube Industries, Ltd. | Anodizing solution for anodic oxidation of magnesium or its alloys |
DE19630289C2 (de) | 1996-07-26 | 2002-03-14 | Audi Ag | Verfahren zum Lackieren von Fahrzeugkarosserien |
JP5520439B2 (ja) * | 2007-11-01 | 2014-06-11 | 日本パーカライジング株式会社 | 表面調整アルミニウム鋳造物の製造方法 |
JP2009228087A (ja) | 2008-03-25 | 2009-10-08 | Hiroshima Univ | マグネシウム合金被膜及びその製造方法 |
JP5517024B2 (ja) * | 2009-02-02 | 2014-06-11 | 独立行政法人物質・材料研究機構 | Mg基構造部材 |
ITMI20131265A1 (it) | 2013-07-29 | 2013-10-28 | Ivan Fischetto | Sistema perfezionato di pretrattamento ai fini della nichelatura chimica e dell'eventale ulteriore trattamento superficiale del magnesio ( e di tutte le sue leghe conosciute) |
DE102014005444A1 (de) | 2014-04-11 | 2015-10-15 | Audi Ag | Verfahren zur Passivierung einer metallischen Oberfläche |
-
2016
- 2016-03-10 DE DE102016002852.1A patent/DE102016002852A1/de not_active Ceased
-
2017
- 2017-02-20 EP EP17710122.7A patent/EP3390690B8/fr active Active
- 2017-02-20 WO PCT/EP2017/000240 patent/WO2017153036A1/fr active Application Filing
Also Published As
Publication number | Publication date |
---|---|
DE102016002852A1 (de) | 2017-09-14 |
WO2017153036A1 (fr) | 2017-09-14 |
EP3390690B8 (fr) | 2022-06-29 |
EP3390690B1 (fr) | 2022-04-27 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP3390690A1 (fr) | Procédé de passivation d'une surface d'un élément métallique | |
DE102012202787B4 (de) | Verfahren zum Lackieren eines Werkstücks | |
EP0187917B1 (fr) | Procédé pour la protection anticorrosive de couches de résine déposées autophorétiquement sur surfaces métalliques | |
DE102005059314A1 (de) | Verfahren und Produkt zur Korrosionsschutzbehandlung von Metalloberflächen, insbesondere von Stahloberflächen | |
DE4317217A1 (de) | Chromfreie Konversionsbehandlung von Aluminium | |
WO2011067094A1 (fr) | Procédé de prétraitement à étapes multiples pour des composants métalliques présentant des surfaces en zinc et en fer | |
EP1692325A1 (fr) | Traitement de conversion en deux etapes | |
DE112009001005T5 (de) | Selbst abgeschiedene Beschichtungen auf Magnesiumlegierungen | |
EP0149720B1 (fr) | Procédé de post passivation de surfaces métalliques phosphatées, utilisant des solutions contenant des cations de titane et/ou manganèse et/ou cobalt et/ou nickel et/ou cuivre | |
EP3129527B1 (fr) | Procédé de passivation d'une surface métallique | |
WO2021116318A1 (fr) | Procédé de production d'un produit plat en acier ayant une couche de protection métallique à base de zinc et une couche de phosphatation produite sur une surface de la couche de protection métallique, et produit plat en acier de ce type | |
DE2017327B2 (de) | Verfahren zur beschichtung von metalloberflaechen | |
EP0359296B1 (fr) | Procédé de phosphatation | |
WO1994005826A1 (fr) | Procede de phosphatation d'acier zingue d'un seul cote | |
EP0219779B1 (fr) | Procédé de phosphatation de pièces métalliques zinguées électrolytiquement | |
EP0366941B1 (fr) | Procédé de revêtement par électrodéposition de surfaces métalliques aptes au chromatage | |
EP1029111A1 (fr) | Protection anti-corrosion de feuillards acier galvanises et galvanises par alliage | |
EP2255028B1 (fr) | Peinture électrophorétique par immersion optimisée d'éléments assemblés et partiellement préphosphatés | |
EP2093308B1 (fr) | Procédé de traitement d'un composant de magnésium | |
DE2046449B2 (de) | Verfahren und Vorrichtung zum Aufbringen von Schutzüberzügen auf Metallgegenständen sowie Anwendung des Verfahrens | |
EP1531012B1 (fr) | Protection supplémentaire contre la corrosion pour des piéces de tôle métallique disposant déjà d'un revêtement organique | |
DE2734826A1 (de) | Mittel zur chemischen oberflaechenbehandlung von metallen und duroplasten sowie von metallen, die mit einem anorganischen, nichtmetallischen umwandlungsueberzug versehen sind | |
DE102017011379A1 (de) | Anti-Korrosionsbeschichtung für metallische Substrate | |
DE10261014A1 (de) | Verfahren zur Beschichtung von Metalloberflächen mit einer Alkaliphosphatierungslösung, wässriges Konzentrat und Verwendung der derart beschichteten Metalloberflächen | |
EP0096753A1 (fr) | Procédé pour la production sans courant de couches anticorrosives sur des éléments de construction d'aluminium |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: UNKNOWN |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE INTERNATIONAL PUBLICATION HAS BEEN MADE |
|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: REQUEST FOR EXAMINATION WAS MADE |
|
17P | Request for examination filed |
Effective date: 20180704 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
AX | Request for extension of the european patent |
Extension state: BA ME |
|
DAV | Request for validation of the european patent (deleted) | ||
DAX | Request for extension of the european patent (deleted) | ||
GRAP | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOSNIGR1 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: GRANT OF PATENT IS INTENDED |
|
INTG | Intention to grant announced |
Effective date: 20220105 |
|
RIN1 | Information on inventor provided before grant (corrected) |
Inventor name: VIRTANEN, SANNAKAISA Inventor name: DE CASTRO LODOSA, GUILLERMO Inventor name: KORTE, MICHAEL Inventor name: WETZEL, TOMMY Inventor name: GRABOWSKI, MICHAEL |
|
GRAS | Grant fee paid |
Free format text: ORIGINAL CODE: EPIDOSNIGR3 |
|
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE PATENT HAS BEEN GRANTED |
|
AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
REG | Reference to a national code |
Ref country code: GB Ref legal event code: FG4D Free format text: NOT ENGLISH |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: EP |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R096 Ref document number: 502017013066 Country of ref document: DE |
|
REG | Reference to a national code |
Ref country code: AT Ref legal event code: REF Ref document number: 1486984 Country of ref document: AT Kind code of ref document: T Effective date: 20220515 |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: FG4D Free format text: LANGUAGE OF EP DOCUMENT: GERMAN |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R081 Ref document number: 502017013066 Country of ref document: DE Owner name: AUDI AKTIENGESELLSCHAFT, DE Free format text: FORMER OWNERS: AUDI AKTIENGESELLSCHAFT, 85057 INGOLSTADT, DE; FRIEDRICH-ALEXANDER UNIVERSITAET ERLANGEN-NUERNBERG, KOERPERSCHAFT DES OEFFENTLICHEN RECHTS, 91054 ERLANGEN, DE |
|
RAP2 | Party data changed (patent owner data changed or rights of a patent transferred) |
Owner name: AUDI AG |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: PK Free format text: BERICHTIGUNG B8 |
|
REG | Reference to a national code |
Ref country code: LT Ref legal event code: MG9D |
|
REG | Reference to a national code |
Ref country code: NL Ref legal event code: MP Effective date: 20220427 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: NL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20220427 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20220427 Ref country code: PT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20220829 Ref country code: NO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20220727 Ref country code: LT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20220427 Ref country code: HR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20220427 Ref country code: GR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20220728 Ref country code: FI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20220427 Ref country code: ES Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20220427 Ref country code: BG Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20220727 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: RS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20220427 Ref country code: PL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20220427 Ref country code: LV Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20220427 Ref country code: IS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20220827 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R097 Ref document number: 502017013066 Country of ref document: DE |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SM Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20220427 Ref country code: SK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20220427 Ref country code: RO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20220427 Ref country code: EE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20220427 Ref country code: DK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20220427 Ref country code: CZ Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20220427 |
|
PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: AL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20220427 |
|
26N | No opposition filed |
Effective date: 20230130 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: FR Payment date: 20230222 Year of fee payment: 7 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20220427 |
|
P01 | Opt-out of the competence of the unified patent court (upc) registered |
Effective date: 20230530 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MC Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20220427 |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: PL |
|
REG | Reference to a national code |
Ref country code: BE Ref legal event code: MM Effective date: 20230228 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LU Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20230220 Ref country code: LI Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20230228 Ref country code: CH Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20230228 |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: MM4A |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20220427 Ref country code: IE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20230220 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: BE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20230228 |
|
REG | Reference to a national code |
Ref country code: AT Ref legal event code: MM01 Ref document number: 1486984 Country of ref document: AT Kind code of ref document: T Effective date: 20230220 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: AT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20230220 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: AT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20230220 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: DE Payment date: 20240229 Year of fee payment: 8 Ref country code: GB Payment date: 20240221 Year of fee payment: 8 |