EP3378044A1 - Dispositif de vitre d'alarme - Google Patents

Dispositif de vitre d'alarme

Info

Publication number
EP3378044A1
EP3378044A1 EP16809656.8A EP16809656A EP3378044A1 EP 3378044 A1 EP3378044 A1 EP 3378044A1 EP 16809656 A EP16809656 A EP 16809656A EP 3378044 A1 EP3378044 A1 EP 3378044A1
Authority
EP
European Patent Office
Prior art keywords
disc
alarm
transparent
electrically conductive
conductive coating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP16809656.8A
Other languages
German (de)
English (en)
Inventor
Stefan Droste
Guillaume Francois
Christian EFFERTZ
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Saint Gobain Glass France SAS
Original Assignee
Saint Gobain Glass France SAS
Compagnie de Saint Gobain SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Saint Gobain Glass France SAS, Compagnie de Saint Gobain SA filed Critical Saint Gobain Glass France SAS
Publication of EP3378044A1 publication Critical patent/EP3378044A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
    • C03C17/3618—Coatings of type glass/inorganic compound/other inorganic layers, at least one layer being metallic
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
    • C03C17/3626—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer one layer at least containing a nitride, oxynitride, boronitride or carbonitride
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
    • G01N27/02—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance
    • G01N27/22—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance by investigating capacitance
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01R—MEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES
    • G01R27/00—Arrangements for measuring resistance, reactance, impedance, or electric characteristics derived therefrom
    • G01R27/02—Measuring real or complex resistance, reactance, impedance, or other two-pole characteristics derived therefrom, e.g. time constant
    • G01R27/26—Measuring inductance or capacitance; Measuring quality factor, e.g. by using the resonance method; Measuring loss factor; Measuring dielectric constants ; Measuring impedance or related variables
    • G01R27/2611—Measuring inductance
    • G—PHYSICS
    • G08—SIGNALLING
    • G08B—SIGNALLING OR CALLING SYSTEMS; ORDER TELEGRAPHS; ALARM SYSTEMS
    • G08B13/00—Burglar, theft or intruder alarms
    • G08B13/02—Mechanical actuation
    • G08B13/04—Mechanical actuation by breaking of glass
    • G—PHYSICS
    • G08—SIGNALLING
    • G08B—SIGNALLING OR CALLING SYSTEMS; ORDER TELEGRAPHS; ALARM SYSTEMS
    • G08B21/00—Alarms responsive to a single specified undesired or abnormal condition and not otherwise provided for
    • G08B21/18—Status alarms
    • G08B21/182—Level alarms, e.g. alarms responsive to variables exceeding a threshold
    • G—PHYSICS
    • G08—SIGNALLING
    • G08C—TRANSMISSION SYSTEMS FOR MEASURED VALUES, CONTROL OR SIMILAR SIGNALS
    • G08C17/00—Arrangements for transmitting signals characterised by the use of a wireless electrical link
    • G08C17/02—Arrangements for transmitting signals characterised by the use of a wireless electrical link using a radio link
    • G—PHYSICS
    • G08—SIGNALLING
    • G08C—TRANSMISSION SYSTEMS FOR MEASURED VALUES, CONTROL OR SIMILAR SIGNALS
    • G08C23/00—Non-electrical signal transmission systems, e.g. optical systems
    • G08C23/04—Non-electrical signal transmission systems, e.g. optical systems using light waves, e.g. infrared
    • H—ELECTRICITY
    • H02—GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
    • H02S—GENERATION OF ELECTRIC POWER BY CONVERSION OF INFRARED RADIATION, VISIBLE LIGHT OR ULTRAVIOLET LIGHT, e.g. USING PHOTOVOLTAIC [PV] MODULES
    • H02S40/00—Components or accessories in combination with PV modules, not provided for in groups H02S10/00 - H02S30/00
    • H02S40/30—Electrical components
    • H02S40/38—Energy storage means, e.g. batteries, structurally associated with PV modules
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N10/00—Thermoelectric devices comprising a junction of dissimilar materials, i.e. devices exhibiting Seebeck or Peltier effects
    • H10N10/80—Constructional details
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00—Energy generation through renewable energy sources
    • Y02E10/50—Photovoltaic [PV] energy
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E70/00—Other energy conversion or management systems reducing GHG emissions
    • Y02E70/30—Systems combining energy storage with energy generation of non-fossil origin

Definitions

  • the invention relates to an alarm disk arrangement, in particular for a
  • Insulating glazing with transparent, electrically conductive coating and a capacitive sensor. Furthermore, the invention relates to a method for operating the alarm disk arrangement.
  • alarm discs In order to detect the breakage of a disc, for example in the event of burglary or other damage, so-called alarm discs are used. These alarm discs are usually part of an insulated or multiple glazing. In this case, there is usually at least one disc made of toughened tempered safety glass (ESG). If damaged, the tempered glass breaks over its entire surface into small fragments.
  • ESG toughened tempered safety glass
  • DE 197 54 295 A1 shows an arrangement in which two measuring electrodes spaced apart from one another are galvanically connected to an electrically conductive layer.
  • the object of the present invention is now to provide an improved alarm disk assembly which is simple and inexpensive to manufacture and which is less visually visible.
  • the alarm disc assembly according to the invention is suitable in a retrofit method already
  • the object of the present invention is achieved by a
  • the alarm disk arrangement comprises at least: at least one first pane, which consists of toughened glass, with an outside surface (I) and an inside surface (II), at least one transparent, electrically conductive coating, which is arranged on the inside surface (II) of the first pane and
  • a sensor unit with a capacitive sensor which is capacitively coupled to the transparent, electrically conductive coating
  • the sensor unit outputs an alarm signal in the case of deviations of a measurement signal of the capacitive sensor from a comparison value.
  • the invention is based on the recognition that many disks and in particular insulating glass panes have transparent coatings with a good electrical conductivity. These transparent, electrically conductive coatings have a variety of tasks: for example, to reflect infrared radiation or low-E properties.
  • the alarm disc assembly according to the invention comprises a sensor unit which monitors the integrity of the disc with a sensor without contact and outputs an alarm signal when the disc breaks.
  • the non-contact monitoring eliminates a complex contacting of the transparent, electrically conductive coating.
  • Such contacts are usually soldered and highly susceptible to aging, since the contact resistance at the soldering changes by aging processes. In the capacitive monitoring, this is not a problem, since the direct electrical contacting of the transparent, electrically conductive coating is eliminated. Since an existing transparent, electrically conductive coating is used, there is no need for a separate production step.
  • the transparent, electrically conductive coating is hardly visible visually and therefore very aesthetic. It may, for example, also have antireflective properties and improve the transparency through the glass. All this was unexpected and surprising to the inventors.
  • An alarm disk arrangement comprises at least one first disk with an outside surface (I) and an inside surface (II).
  • the first pane usually serves to separate an exterior space from an interior, for example a building, a showcase or a vehicle.
  • the alarm disc assembly to protect a
  • the inside surface (II) may also be exposed to potential attacks, such as destruction with an emergency hammer in case of danger. In this case, no deliberate manipulation of the sensor unit is assumed.
  • outside surface (I) of the first pane can also have a further coating, for example a further transparent, electrically conductive coating.
  • the sensitivity of the sensor can be chosen so that only the integrity of the transparent, electrically conductive coating on the inside surface (II) of the first pane is monitored, or additionally the integrity of the further transparent, electrically conductive coating on the outside surface ( I) of the first disc is monitored.
  • the transparent, electrically conductive coating is connected to the first pane in such a way that if the first pane breaks, the transparent, electrically conductive coating is damaged.
  • the transparent, electrically conductive coating is preferably directly on the inside
  • Thin film stack Particularly suitable methods for this purpose are cathode sputtering (sputtering, in particular magnetron sputtering), chemical vapor deposition (CVD) and / or thermal evaporation. This is particularly advantageous in order to enable reliable detection of a fracture of the first disk.
  • cathode sputtering sputtering, in particular magnetron sputtering
  • CVD chemical vapor deposition
  • thermal evaporation This is particularly advantageous in order to enable reliable detection of a fracture of the first disk.
  • the capacitive sensor contains at least one electrode, preferably i) exactly one measuring electrode or
  • a measuring electrode and a reference ground electrode in particular exactly one measuring electrode and exactly one reference ground electrode, or
  • a measuring electrode a reference ground electrode and at least one compensation electrode, which is arranged between the measuring electrode and the reference ground electrode, in particular exactly one measuring electrode, exactly one reference ground electrode and at least one compensation electrode, which is arranged between the measuring electrode and the reference ground electrode.
  • the measuring electrode is galvanically separated from the transparent, electrically conductive coating.
  • the distance d between the measuring electrode and the transparent, electrically conductive coating is from 0.1 mm to 20 mm, preferably from 0.2 mm to 10 mm and in particular from 0.5 mm to 5 mm.
  • the first disc is made of toughened glass.
  • Embodiment of the first disc is biased so that when breaking the first disc, the fragments are smaller than a detection range of the capacitive sensor.
  • the fragments are smaller, for example, because they have a smaller area than the detection area or a smaller maximum diameter than the
  • the sensor unit is arranged on the inside of the first disk, ie on the side which is defined by the inside surface (II) of the first disk. This is particularly advantageous in order to protect the sensor unit from damage and tampering attempts from the attack side, ie from the side of the first disc, which is defined by the outside surface (I).
  • the capacitive sensor works in principle like an open capacitor, between its measuring electrode and its reference ground electrode an electrical (Alterna-) field is built.
  • the electric field interacts with the
  • the sensor unit preferably contains sensor electronics with at least the following components: an oscillator which applies an alternating electrical voltage to the measuring electrode and optionally to the reference ground electrode; a demodulator, from the measured AC signal to a
  • Capacitance measuring signal with a comparison or threshold value compares and a power amplifier, which optionally outputs a signal voltage level adapted to the usual output signal.
  • the sensor unit has a transmitting unit, preferably a radio transmitting unit with a radio signal whose frequency is in the range from 100 kHz to 100 GHz.
  • the radio transmitter unit is particularly preferably a Bluetooth transmitter or a WLAN transmitter.
  • the transmitting unit may also be an infrared transmitter.
  • Transmitter unit is used for communication with a receiver and in particular for emitting an alarm signal when the sensor unit detects a breakage of the disc.
  • the integration of a transmitting unit has the particular advantage that the sensor unit requires no external leads for passing the alarm signal and thereby a very simple, inexpensive and location-independent installation is possible. Furthermore, eliminates a possibility of manipulation of the sensor unit, whereby the security is increased. This is particularly advantageous for the use or retrofitting of the sensor unit in an insulating glass unit, which is usually completed to the outside. It will be understood that other data may also be sent via the transmitting unit, such as a functional status of the sensor unit, a battery or battery charge state, or other characteristics provided by other sensors, such as temperature or pressure.
  • the receiver communicating with the transmission unit is arranged on the same side of the first disk as the transmission unit and the sensor, namely on the inside of the first disk.
  • the alarm Disk arrangement for the protection of an interior against theft or damage particularly advantageous since the sensor unit, transmitter unit and receiver are protected from damage and tampering and accessible only after breaking the first disc.
  • the receiver can be arranged on any side of the first disk, provided the first disk with the transparent, electrically conductive coating or its surroundings for the signal of the transmitter is sufficiently permeable.
  • the sensor unit contains a power supply, preferably a battery, an accumulator, a supercapacitor, a thermoelectric generator and / or a solar cell.
  • the sensor unit advantageously contains no supply lines to an external power supply, but is energy self-sufficient.
  • the power supply can be done or supplemented by continuous or discontinuous charging via, for example, an inductive charging device. This has the particular advantage that the sensor unit requires no external leads and thus a very simple, inexpensive and location-independent installation is possible. Furthermore, eliminates a possibility of manipulation of the sensor unit, whereby the security is increased. This is particularly advantageous for the use or retrofitting of the sensor unit in an insulating glass unit, which is usually completed to the outside.
  • the alarm disk assembly according to the invention can be used as a single pane or be part of a multi-pane glazing, for example, part of a double glazing, double glazing, triple glazing,
  • the first disk is connected to at least one other spacer via at least one spacer, preferably a spacer which completely surrounds the edge of the disk.
  • the spacer is located between the first disc and the other disc and is preferably fixed by a bond between spacers and discs.
  • the spacer preferably comprises at least one hollow basic body with at least two parallel disc lenses. contact walls, an outer wall with a gas-tight insulation layer and a glazing interior wall.
  • Polymer base bodies preferably contain polyethylene (PE), polycarbonates (PC), polypropylene (PP), polystyrene, polybutadiene, polynitriles, polyesters, polyurethanes, polymethylmethacrylates, polyacrylates, polyamides, polyethylene terephthalate (PET), polybutylene terephthalate (PBT), particularly preferably acrylonitrile.
  • PE polyethylene
  • PC polycarbonates
  • PP polypropylene
  • polystyrene polybutadiene
  • polynitriles polyesters
  • polyurethanes polymethylmethacrylates
  • polyacrylates polyamides
  • PET polyethylene terephthalate
  • PBT polybutylene terephthalate
  • ABS butadiene-styrene
  • ASA acrylic ester-styrene-acrylonitrile
  • ABS / PC acrylonitrile-butadiene-styrene - polycarbonate
  • SAN styrene-acrylonitrile
  • PET / PC PBT / PC and / or copolymers or blends thereof
  • Polymeric base bodies may optionally also contain other constituents, such as glass fibers.
  • the polymeric materials used are usually gas-permeable, so that if this permeability is not desired further measures must be taken.
  • Metallic bodies are preferably made of aluminum or stainless steel and preferably have no gas permeability.
  • the walls of the body are gas-permeable in an advantageous embodiment. Areas of the body in which such a permeability is not desired, for example, be sealed with a gas-tight insulating layer. Particularly polymeric base bodies are used in combination with such a gas-tight insulation layer.
  • the main body preferably has a hollow chamber which contains a desiccant, preferably silica gel, CaCl 2 , Na 2 SO 4 , activated carbon, silicates, bentonites, zeolites and / or mixtures thereof, particularly preferably molecular sieves.
  • a desiccant preferably silica gel, CaCl 2 , Na 2 SO 4 , activated carbon, silicates, bentonites, zeolites and / or mixtures thereof, particularly preferably molecular sieves.
  • the outer space between the first disc, further disc and spacer is preferably sealed by at least one sealant to the disc outer space.
  • the sealant preferably contains organic polysulfides, Silicones, RTV (room temperature curing) silicone rubber, HTV (high temperature curing) silicone rubber, peroxide-crosslinking silicone rubber and / or addition-crosslinked silicone rubber, polyurethanes, butyl rubber and / or polyacrylates.
  • additives for increasing the aging resistance for example UV stabilizers, may also be present.
  • the first disk is connected via a spacer to a second disk and forms an insulating glass pane with double glazing.
  • the first disc is connected via its inner surface (II) via the spacer with the second disc.
  • the sensor unit is arranged in a gap between the first disc and the second disc.
  • the measuring electrode is advantageously not arranged exactly in the middle between the disks, but closer to the first disk to be monitored, which has the transparent electrically conductive coating. It is understood that in this arrangement, both discs a transparent, electrically conductive
  • the first disk or the second disk can be connected via a further spacer to another third disk and thus form an insulating glass pane with triple glazing.
  • the first pane consists of flat glass, float glass, soda-lime glass, quartz glass, or borosilicate glass.
  • the first pane is prestressed, preferably in accordance with DIN 12150-1: Glass in construction - thermally toughened soda lime silicate safety glass - Part 1: Definition and description, particularly preferably with a surface compressive stress of more than 100 N / mm 2 and in particular of 100 N / mm 2 to 150 N / mm 2 . Due to the bias, the first disc shatters in case of damage preferably in
  • blunt-edged fragments with sizes of less than 1 cm 2 .
  • the second, third or further pane preferably contains glass, particularly preferably flat glass, float glass, quartz glass, borosilicate glass, soda-lime glass, or clear plastics, preferably rigid clear plastics, in particular polyethylene, polypropylene, polycarbonate, polymethyl methacrylate, polystyrene, polyamide, polyester , Polyvinyl chloride and / or mixtures thereof.
  • Suitable glasses are known, for example, from EP 0 847 965 B1.
  • the second, third or further disc may consist of the aforementioned materials.
  • the thickness of the first, second, third or further disc can vary widely and so perfectly adapted to the requirements of the case. It is preferred to use disks with the standard thicknesses of 1.0 mm to 50 mm and preferably of 3 mm to 16 mm. The size of the disc can vary widely and depends on the size of the use according to the invention.
  • the first disk has dielectric properties and a relative permittivity of 6 to 8 and in particular of about 7.
  • the discs may have any three-dimensional shape.
  • the three-dimensional shape has no shadow zones, so that it can be coated, for example, by sputtering.
  • the disks are planar or slightly or strongly bent in one direction or in several directions of the space.
  • the discs can be colorless or colored.
  • the first pane is connected over its outside surface (I) and at least one intermediate layer, preferably a thermoplastic intermediate layer, to a composite pane with a second pane.
  • the second disc can turn over another intermediate layer surface with another third disc be connected.
  • the second and / or the third disc preferably contains one
  • the second and / or the third disc may consist of a plastic.
  • Such composite discs are particularly breakthrough stable against external intrusion, so that it is possible to achieve high security classes.
  • the discs of the composite disc are connected to each other by at least one intermediate layer.
  • the intermediate layer preferably contains a thermoplastic such as polyvinyl butyral (PVB), ethylene vinyl acetate (EVA),
  • Polyurethane PU
  • PET polyethylene terephthalate
  • PU Polyurethane
  • PET polyethylene terephthalate
  • the transparent, electrically conductive coating is arranged at least 70%, preferably 80% to 100% and particularly preferably 98% to 100% of the viewing surface of the first pane.
  • the see-through area is the area of the first pane, where the view is not prevented by the frame, spacers or other attachments.
  • the transparent, electrically conductive coating is arranged at least 50%, preferably at least 70%, particularly preferably 80% to 100% and in particular 95% to 100% of the area of the inside surface of the first pane.
  • the transparent, electrically conductive coating according to the invention is permeable to electromagnetic radiation, preferably electromagnetic radiation of a wavelength of 300 to 1,300 nm, in particular for visible light of 390 nm to 780 nm.
  • Period means that the total transmission of the disk is in particular for visible light is preferably> 70% and in particular> 75% permeable For certain applications, a lower transmission may be desired, for which "transmissive” may also mean 10% to 70% light transmission.
  • Such applications are, for example, glazing for the protection of objects that should not be exposed to large amounts of light, for example paintings or textiles.
  • the transparent, electrically conductive coating is preferably a functional coating, particularly preferably a functional coating with sunscreen Effect.
  • a coating with a sunscreen effect has reflective properties in the infrared range and thus in the range of solar radiation.
  • the transparent, electrically conductive coating may comprise a sequence of a plurality of individual layers, in particular at least one metallic layer and dielectric layers containing, for example, at least one metal oxide.
  • the metal oxide preferably contains zinc oxide, tin oxide, indium oxide, titanium oxide, silicon oxide, aluminum oxide or the like and combinations of one or more thereof.
  • the dielectric material may also include silicon nitride, silicon carbide or aluminum nitride.
  • This layer construction is generally obtained by a series of deposition processes performed by a vacuum process such as magnetic field assisted sputtering.
  • a vacuum process such as magnetic field assisted sputtering.
  • metal layers which in particular contain titanium or niobium.
  • the lower metal layer serves as an adhesion and crystallization layer.
  • the upper metal layer serves as a protective and getter layer to prevent a change of the silver during the further process steps.
  • Particularly suitable transparent, electrically conductive coatings comprise at least one metal, preferably silver, nickel, chromium, niobium, tin, titanium, copper, palladium, zinc, gold, cadmium, aluminum, silicon, tungsten or alloys thereof, and / or at least one metal oxide layer , preferably tin-doped
  • ITO Indium oxide
  • AZO aluminum-doped zinc oxide
  • FTO fluorine-doped tin oxide
  • ATO antimony-doped tin oxide
  • Sn0 2 Sb
  • electrically conductive polymers preferably poly (3,4-ethylenedioxythiophene), polystyrene sulfonate, poly (4,4-dioctylcylopentadithiophene), 2,3-dichloro-5,6-dicyano-1, 4-benzoquinone, mixtures and / or
  • the thickness of the transparent, electrically conductive coating can vary widely and be adapted to the requirements of the individual case. It is essential that the thickness of the transparent, electrically conductive coating may not be so high that it is suitable for electromagnetic radiation, preferably electromagnetic Radiation of a wavelength of 300 nm to 1 .300 nm and in particular visible light of 390 nm to 780 nm, impermeable.
  • the transparent, electrically conductive coating preferably has a layer thickness of 10 nm to 5 ⁇ m and more preferably of 30 nm to 1 ⁇ m.
  • the sheet resistance of the transparent, electrically conductive coating is preferably from 0.35 ohms / square to 200 ohms / square, preferably 0.5 ohms / square to 200 ohms / square, most preferably from 0.6 ohms / square to
  • the transparent, electrically conductive coating may in principle have even lower surface resistances than 0.35 ohms / square, especially if only a small amount of light transmission is required during their use. Such surface resistances are particularly suitable for detecting damage to the electrically conductive coating in the event of breakage of the first pane.
  • the transparent, electrically conductive coating preferably has good infrared-reflecting properties and / or particularly low emissivities (Low-E).
  • the capacitive sensor as a single component, i. formed in the form of a structural unit.
  • the capacitive sensor has exactly one measuring electrode, or (in particular exactly) a measuring electrode and (in particular exactly) a reference ground electrode, or (especially exactly) a measuring electrode, (in particular exactly) a reference ground electrode and at least one compensation electrode, all are Electrodes each a component of the single component.
  • the capacitive sensor may be surrounded by a same (e.g., opaque) housing, wherein the electrode (s) may be disposed within the housing.
  • the shape of a detection area of the capacitive sensor corresponds to the shape of the measuring electrode.
  • Another aspect of the invention includes a method of operating a
  • the measurement of the measuring signal is continuous or periodic, preferably with a period of 0.2 s to 100 s and output as an output signal from the sensor unit.
  • the edition The output signal can be continuous or periodic, preferably with a period of 0.2 s to 100 s.
  • a further aspect of the invention comprises the use of an alarm pane arrangement according to the invention as glazing of a showcase, a showcase, preferably for the protection of valuable goods such as paintings, textiles, jewelery, for example in a museum or at a jeweler, or as architectural glazing, insulating glazing, double glazing Insulating glazing, triple-glazing, fire-resistant glazing, safety glazing or as glazing in a vehicle on land, water or in the air, such as a motor vehicle, a bus, a train or an airplane.
  • valuable goods such as paintings, textiles, jewelery, for example in a museum or at a jeweler, or as architectural glazing, insulating glazing, double glazing Insulating glazing, triple-glazing, fire-resistant glazing, safety glazing or as glazing in a vehicle on land, water or in the air, such as a motor vehicle, a bus, a train or an airplane.
  • a further aspect of the invention comprises a use of a sensor unit according to the invention with a capacitive sensor for retrofitting a glazing with a first pane of toughened glass and transparent, electrically conductive coating on the inside surface (II) to an alarm disk arrangement.
  • Figure 1 A is a schematic representation of an inventive
  • Figure 1 B is a cross-sectional view along section line A-A 'of Figure 1A
  • Figure 2A is a schematic representation of a sensor unit according to the invention
  • Figure 2B is a schematic representation of an alternative invention
  • FIG. 3A shows an enlarged view of the section Z of the transparent, electrically conductive coating according to the invention in the case of an undamaged first pane
  • 3B is an enlarged view of the detail Z of the inventive transparent, electrically conductive coating in a broken first disc
  • Figure 4A is a schematic representation of an alternative invention
  • FIG. 4B shows a cross-sectional view along the section line AA 'of FIG. 4A
  • Figure 1 A shows a schematic representation of an inventive
  • Alarm disk assembly 10 in a plan view of the outside surface I.
  • Figure 1 B shows a cross-sectional view along the section line A-A 'of Figure 1 A.
  • the alarm disk assembly 10 separates an interior space from an exterior one
  • the alarm disk assembly 10 is suitable for example to protect valuables in the interior, for example in a showcase, in a museum or at a jeweler from external access.
  • the alarm disk arrangement 10 comprises a first pane 1 on whose inside surface II a transparent electrically conductive coating 3 is arranged.
  • the transparent, electrically conductive coating 3 is arranged in this example on the entire inside surface II of the first disc 1, minus a marginal stripping with a width of, for example, 10 mm from the disc edge of the first disc 1.
  • the edge deletion serves to protect against corrosion by penetrating moisture over the edge of the pane.
  • the transparent, electrically conductive coating 3 serves, for example, as an infrared-reflecting layer. This means that the amount of heat radiation from incoming sunlight is reflected to a large extent. When using the first pane 1 in an architectural glazing, this provides for a reduced
  • the transparent, electrically conductive coating 3 is known, for example, from EP 0 847 965 B1 and contains two silver layers, each of which is embedded between a plurality of metal and metal oxide layers.
  • the transparent electrically conductive coating 3 has a sheet resistance of about 4 ohms / square.
  • the first pane 1 is, for example, a prestressed soda-lime glass pane with a width of 1 m, a length of 1.5 m and a thickness of 4 mm.
  • the first pane 1 is prestressed according to DIN 12150-1 with a surface compressive stress of, for example, 120 N / mm 2 . Due to the bias, the first disc shatters when damaged in blunt-edged fragments with sizes of less than 1 cm 2 .
  • a sensor unit 20 is arranged on the inside of the first pane 1. Inside here means the area of the inside surface II facing, on which the transparent, electrically conductive coating 3 is arranged.
  • the sensor unit 20 has a capacitive sensor 21, which is capacitively coupled to the electrically conductive coating 3. It is understood that the capacitive sensor 21 does not necessarily have to be installed in the same housing as the remaining sensor unit 20.
  • the distance d of the capacitive sensor 21 from the transparent, electrically conductive coating 3 is for example 0.5 mm.
  • the capacitive sensor 21 and the transparent, electrically conductive coating 3 are in particular galvanically separated from one another.
  • the sensor unit measures the capacitance of this arrangement via the capacitive sensor 21 and compares the measured value with a comparison value.
  • the comparison value is determined in the undamaged first disc 1 with undamaged transparent, electrically conductive coating 3.
  • the sensor unit 20 determines the deviation, ie the difference, of the measurement signal of the capacitive sensor 21 with the comparison value and outputs an alarm signal for deviations which are greater than a defined tolerance.
  • the alarm signal is, for example, a voltage or voltage pulse having a certain level and / or pulse duration different from another neutral output signal, whereby an alarm condition can be identified.
  • a deviation typically results in the fracture of the first disk 1 and a concomitant damage to the transparent, electrically conductive coating 3.
  • the alarm signal is forwarded, for example via a transmitting unit to a receiver to be converted there into an acoustic signal or to make an emergency call.
  • FIG. 2A shows a schematic representation of a sensor unit 20 according to the invention.
  • the sensor unit 20 has a capacitive sensor 21.
  • the capacitive sensor 21 includes a measuring electrode 21 .1, which is connected via a supply line to an electronic system. Furthermore, the capacitive sensor 21 includes, for example, a shielding electrode 21 .3 for concentrating the capacitive field.
  • the capacitive sensor 21 is embodied here, for example, without an explicit reference ground electrode, that is to say the reference ground electrode is not integrated into the capacitive sensor 21 21, but instead is represented by the object to be detected, that is to say by the transparent, electrically conductive coating 3.
  • the sensor unit 20 has, for example, several stages of construction: the measuring electrode 21 .1 of the capacitive sensor 21 is connected to an oscillator 20.1.
  • the oscillator 20.1 is connected via a demodulator 20.2 to a comparator 20.3.
  • the comparator 20.3 compares the measurement signal with a comparison value and, if appropriate, outputs an alarm signal via the output stage 20.4 at the output 22.
  • the measuring electrode 21 .1 has, for example, the shape of a circular disk, so that a circular disk-shaped detection area 25 results.
  • FIG. 2B shows a schematic representation of an alternative sensor unit 20 according to the invention, as used, for example, in the abovementioned exemplary embodiment according to FIGS. 1A and 1B.
  • the sensor unit 20 has a capacitive sensor 21.
  • the capacitive sensor 21 includes a measuring electrode 21 .1, which is connected via a supply line to an electronic system. Furthermore, the capacitive sensor 21 contains a reference ground electrode 21 .2, which is arranged annularly around the measuring electrode 21. Between measuring electrode 21 .1 and reference ground electrode 21 .2, for example, a compensation electrode 21 .4 is arranged.
  • the compensation electrode 21 .4 reduces measurement errors caused, for example, by moisture deposits on the
  • Measuring surface of the measuring electrode 21 .1 and reference ground electrode 21 .2 can result.
  • Such capacitive sensors 21 are particularly suitable for measurement in transparent, electrically conductive coatings 3 with high sheet resistance.
  • the sensor unit 20 has, for example, several stages of construction: the measuring electrode 21 .1 and the reference ground electrode 21 .2 of the capacitive sensor 21 are connected to an oscillator 20.1.
  • the oscillator 20.1 is connected via a demodulator 20.2 to a comparator 20.3.
  • the comparator 20.3 compares the measurement signal with a comparison value and, if appropriate, outputs an alarm signal via the output stage 20.4 at the output 22.
  • the measuring electrode 21 .1 has, for example, the shape of a circular disk, so that a circular disk-shaped detection area 25 results.
  • FIG. 3A shows an enlarged illustration of the detail Z of the transparent, electrically conductive coating 3 according to the invention in the case of an undamaged first pane 1.
  • the transparent, electrically conductive coating 3 is undamaged, in particular in the detection region 25 of the capacitive sensor 21.
  • FIG. 3B shows an enlarged illustration of the detail Z of the transparent, electrically conductive coating 3 according to the invention in the case of a broken first pane 1.
  • Penetrating the first disc 1 this is cracked because of their bias in small fragments. This leads to an interruption of the transparent, electrically conductive coating 3 by breaking lines 30.
  • the fragments are each smaller than the detection region 25, so that at least one breaking line 30 is arranged in the detection region 25.
  • breaking lines 30 By interrupting the transparent, electrically conductive coating 3 by breaking lines 30, the measuring signal of the capacitive sensor 21 changes and an alarm signal can be output.
  • FIG. 4A shows a schematic representation of an alternative alarm disk arrangement 10 'according to the invention in a plan view and FIG. 4B shows a cross-sectional view along the section line AA' from FIG. 4A.
  • the alarm disk assembly 10 ' is, for example, an insulating glass panel containing the alarm disk assembly 10 of Figures 1 A and 1 B.
  • the first disc 1 is connected to a second disc 6 via a circumferential spacer 2.
  • the sensor unit 20 with capacitive sensor 21 is here in the intermediate space, which is formed by the first disc 1, the second disc 6 and the spacer 2, respectively.
  • the sensor unit 20 is glued to the lower portion of the spacer 2 on this example, and thus securely fixed against slipping.
  • the sensor unit 20 includes, for example, an accumulator and a solar cell that charges the accumulator. Furthermore, the sensor unit 20 contains, for example, a transmitting unit which sends an alarm signal via a Bluetooth connection to a receiver arranged outside the alarm disk arrangement 10 '(not shown here).
  • the sensor unit 20 is energy self-sufficient and requires no leads to the outside - neither for Power supply, nor to forward an alarm signal.
  • the sensor unit 20 can be easily retrofitted, for example, in an existing insulating glass unit.

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Electrochemistry (AREA)
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  • Immunology (AREA)
  • Pathology (AREA)
  • Computer Networks & Wireless Communication (AREA)
  • Business, Economics & Management (AREA)
  • Emergency Management (AREA)
  • Burglar Alarm Systems (AREA)
  • Joining Of Glass To Other Materials (AREA)
  • Surface Treatment Of Glass (AREA)

Abstract

L'invention concerne un dispositif de vitre d'alarme (10,10'), comportant : au moins une première vitre (1) qui est composée de verre prétendu, ayant une surface externe (I) et une surface interne (II) ; au moins un revêtement électroconducteur transparent (3) qui est disposée sur la surface interne (II) de la première vitre (1) ; une unité de détection (20) avec un capteur capacitif (21) qui est couplé de manière capacitive au revêtement électroconducteur transparent (3). En cas de différences d'un signal de mesure du capteur capacitif (21) d'une valeur de comparaison, l'unité de détection (20) émet un signal d'alarme. Le capteur capacitif (21) contient : i) précisément une électrode de mesure (21.1) ; ou ii) une électrode de mesure (21.1) et une électrode de masse de référence (21.2) ; ou iii) une électrode de mesure (21.1), une électrode de masse de référence (21.2) et au moins une électrode de compensation (21.3), l'électrode de mesure (21.1) étant séparée galvaniquement du revêtement électroconducteur transparent (3).
EP16809656.8A 2015-11-19 2016-11-19 Dispositif de vitre d'alarme Withdrawn EP3378044A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP15195333 2015-11-19
PCT/EP2016/078214 WO2017085302A1 (fr) 2015-11-19 2016-11-19 Dispositif de vitre d'alarme

Publications (1)

Publication Number Publication Date
EP3378044A1 true EP3378044A1 (fr) 2018-09-26

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US (1) US10242542B2 (fr)
EP (1) EP3378044A1 (fr)
JP (1) JP2018535465A (fr)
KR (1) KR101972720B1 (fr)
CN (1) CN108352101A (fr)
BR (1) BR112018000357A2 (fr)
CA (1) CA2994235A1 (fr)
MX (1) MX2018006125A (fr)
RU (1) RU2703171C1 (fr)
WO (1) WO2017085302A1 (fr)

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Publication number Publication date
US10242542B2 (en) 2019-03-26
WO2017085302A1 (fr) 2017-05-26
MX2018006125A (es) 2018-08-01
JP2018535465A (ja) 2018-11-29
BR112018000357A2 (pt) 2018-09-11
RU2703171C1 (ru) 2019-10-15
CN108352101A (zh) 2018-07-31
US20180197388A1 (en) 2018-07-12
CA2994235A1 (fr) 2017-05-26
KR20180030874A (ko) 2018-03-26
KR101972720B1 (ko) 2019-08-16

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