EP3354591A1 - Emballage coloré, hydrosoluble - Google Patents
Emballage coloré, hydrosoluble Download PDFInfo
- Publication number
- EP3354591A1 EP3354591A1 EP18161613.7A EP18161613A EP3354591A1 EP 3354591 A1 EP3354591 A1 EP 3354591A1 EP 18161613 A EP18161613 A EP 18161613A EP 3354591 A1 EP3354591 A1 EP 3354591A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- water
- soluble
- printing
- cavity
- film web
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D65/00—Wrappers or flexible covers; Packaging materials of special type or form
- B65D65/38—Packaging materials of special type or form
- B65D65/46—Applications of disintegrable, dissolvable or edible materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65B—MACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
- B65B9/00—Enclosing successive articles, or quantities of material, e.g. liquids or semiliquids, in flat, folded, or tubular webs of flexible sheet material; Subdividing filled flexible tubes to form packages
- B65B9/02—Enclosing successive articles, or quantities of material between opposed webs
- B65B9/04—Enclosing successive articles, or quantities of material between opposed webs one or both webs being formed with pockets for the reception of the articles, or of the quantities of material
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
- C11D17/042—Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
Definitions
- the invention relates to a water-soluble packaging comprising an agent and a water-soluble coating.
- the invention also relates to a process for producing a water-soluble packaging.
- Detergents or cleaners are now available to the consumer in a variety of forms.
- this offer includes, for example, liquids, gels or sachets (tablets or filled pouches).
- portion packs in the form of water-soluble packaging with liquid detergents or cleaners are becoming increasingly popular, they fulfill the one hand, the consumer's desire for simplified dosage and on the other hand more and more consumers prefer liquid detergents or cleaners.
- Such a water-soluble bag contains an agent and a transparent, water-soluble wrapper.
- detergents or cleaners To increase the washing or cleaning performance of detergents or cleaners they often contain one or more additives.
- detergents in order to prevent re-release of previously released soil in finer distribution (redeposition), detergents contain so-called graying inhibitors, such as carboxymethylcellulose. Due to the low solubility of carboxymethylcellulose in liquid detergents or cleaners, turbidity occurs when incorporating carboxymethylcellulose into liquid detergents or cleaners. This leads to an aesthetically less appealing product.
- washing or cleaning agents In order to increase or prolong the scent impression on the washing or cleaning agents treated therewith surfaces, such as textiles, for example, washing or cleaning agents contain perfume capsules. In order to achieve a homogeneous and stable distribution of the perfume capsules and thus to arrive at an aesthetically pleasing product, the detergents or cleaners contain thickeners and / or dispersants. These funds are often very expensive and show no washing or cleaning performance itself.
- the object of the invention is therefore to further improve the attractiveness and / or functionality of such water-soluble bags.
- a water-soluble packaging which contains an agent and a water-soluble casing, in which the water-soluble casing is at least partially colored with a coloring substance
- the water-soluble packaging after a hereinafter described method in which the printing operation either a curing process with UV light or a drying process in which by up or over blowing tempered gas, passing through a drying oven or irradiation with infrared light in the ink or in the medium, the / which contains the coloring substance, evaporated solvent / is removed, followed, dissolved.
- the printing either a curing process with UV light or a drying process, in which by up or over blowing tempered gas, passing through a drying oven or irradiation with infrared light in the ink or followed by solvent contained in the medium containing the coloring substance.
- a drying process in which by up or over blowing tempered gas, passing through a drying oven or irradiation with infrared light in the ink or followed by solvent contained in the medium containing the coloring substance.
- the use of a horizontal form-fill-seal method is particularly suitable.
- the printing of the first water-soluble film with the coloring substance takes place before the formation of the cavity.
- the printing of the second water-soluble film with the coloring substance takes place before closing the cavity filled with the agent.
- a water-soluble package contains a water-soluble envelope which forms a closed structure having in its interior one or more chambers for receiving one or more agents.
- the water-soluble coating is preferably formed by a water-soluble film material.
- the water-soluble packaging may be dimensionally stable or deformable.
- the water soluble package may include one or more chambers for storing one or more agents.
- the water-soluble packaging preferably has between two and five chambers.
- the water-soluble coating contains polyvinyl alcohol or a polyvinyl alcohol copolymer.
- Water-soluble coatings containing polyvinyl alcohol or a polyvinyl alcohol copolymer have a good stability with a sufficiently high water solubility, in particular cold water solubility on.
- Suitable water-soluble films for producing the water-soluble coating are preferably based on a polyvinyl alcohol or a polyvinyl alcohol copolymer whose molecular weight is in the range of 10,000 to 1,000,000 gmol -1 , preferably 20,000 to 500,000 gmol -1 , more preferably 30,000 to 100,000 gmol -1 and especially from 40,000 to 80,000 gmol -1 .
- polyvinyl alcohol is usually carried out by hydrolysis of polyvinyl acetate, since the direct synthesis route is not possible.
- polyvinyl alcohol copolymers which are prepared from correspondingly polyvinyl acetate copolymers. It is preferred if at least one layer of the water-soluble coating comprises a polyvinyl alcohol whose degree of hydrolysis makes up 70 to 100 mol%, preferably 80 to 90 mol%, particularly preferably 81 to 89 mol% and in particular 82 to 88 mol%.
- a polymer selected from the group consisting of (meth) acrylic acid-containing (co) polymers, polyacrylamides, oxazoline polymers, polystyrenesulfonates, polyurethanes, polyesters, polyethers, polylactic acid, or mixtures of the above may be additionally used in a polyvinyl alcohol-containing film material suitable for producing the water-soluble coating Be added polymers.
- a preferred additional polymer is polylactic acids.
- polyvinyl alcohol copolymers include, in addition to vinyl alcohol, an ethylenically unsaturated carboxylic acid, its salt or its esters.
- Such polyvinyl alcohol copolymers particularly preferably contain, in addition to vinyl alcohol, acrylic acid, methacrylic acid, acrylates, methacrylates or mixtures thereof.
- the film material contains further additives.
- the film material may contain, for example, plasticizers such as dipropylene glycol, ethylene glycol, diethylene glycol, propylene glycol, glycerol, sorbitol, mannitol or mixtures thereof.
- Further additives include, for example, release aids, fillers, crosslinking agents, surfactants, antioxidants, UV absorbers, antiblocking agents, anti-sticking agents or mixtures thereof.
- the water-soluble coating is colored with a coloring substance which is, for example, a dye, a pigment, a bluing agent and / or a pearlescing agent.
- the application of the coloring substance by means of printing has the advantage that the coloring of the water-soluble coating can be individualized, that is to say in accordance with the requirements of the respective water-soluble packaging.
- the printing of the water-soluble coating can be done before the preparation or after the preparation of the water-soluble packaging.
- any form of printing can be used to print the water-soluble wrapper, such as gravure, offset, screen, flexo, airbrush, inkjet or pad printing, or any combination of these printing technologies.
- Printing by means of ink-jet printing preferably takes place since no mechanical contact with and thus no mechanical loading of the water-soluble coating occurs with this printing technology. The same applies to direct printing with piezo technology, as it also takes place without contact.
- the printing by inkjet printing or by direct printing with piezo technology is particularly suitable for printing the water-soluble packaging.
- Water-soluble inks are known, for example, under the trade name SunChemical Aquadestruct from SunChemical, Aqua Poly Super Opaque White QW000046 from Environmental Inks or Opta Film OPQ White WO1009656 from Water Ink Technologies Inc.
- the printing can take place in the form of surfaces, so that the water-soluble coating is at least partially inked nationwide with a coloring substance.
- the printing in the form of letters, numbers, symbols, ornaments or the like respectively.
- the water-soluble envelope may be transparent, translucent or opaque in the area that is colored.
- the water-soluble sheath can be colored by introducing the coloring substance into the film material of the water-soluble sheath.
- Suitable dyes which may be included in the film material for producing the water-soluble envelope or in the medium for printing the inner and / or outer surface of the water-soluble envelope include dyes described in the Color Index (CI) classification as Acid Dye, Direct Dye or Basic Dye.
- Suitable pigments which may be included in the film material for producing the water-soluble envelope or in the medium for printing on the inner and / or outer surface of the water-soluble envelope are, for example, ultramarine or titanium dioxide.
- Suitable bluing agents which may be included in the film material for producing the water-soluble envelope or in the medium for printing on the inner and / or outer surface of the water-soluble envelope are, for example, dyes which are listed in the Color Index (CI) classification as Direct Blue, Direct Red, Direct Violet, Acid Blue, Acid Red, Acid Violet, Basic Blue, Basic Violet or Basic Red.
- CI Color Index
- polymeric dyes such as those available from Milliken under the name "Liquitint®" may also be used. Even pigments such as ultramarine are suitable as bluing agents.
- the amount of colorant depends on the desired color intensity. Optimum results in printing on the outer surface of the water-soluble wrapper are achieved when the amount of colorant substance is between 1 and 5 g per m 2 dyed surface of the water-soluble wrapper.
- the amount of colorant in the water-soluble package preferably equals the amount necessary to achieve the desired effect.
- the amount of ultramarine is between 10 and 300 mg, preferably between 20 and 200 mg, per water-soluble packaging.
- the amount of photobleach is preferably between 1 and 100 mg, preferably between 3 and 40 mg per water-soluble package.
- the term “inner surface of the water-soluble sheath” refers to the surface that is in contact with the agent enclosed by the water-soluble sheath. Accordingly, the term “outer surface of the water-soluble wrapper” designates the surface facing away from the means enclosed by the water-soluble wrapper.
- the water-soluble packaging has a means.
- this agent may be a solid agent and may comprise a powder, granules or tablet.
- the agent may be a liquid agent and may comprise a gel or a liquid.
- the agent is preferably a liquid or solid detergent or cleaning agent, with liquid detergents or cleaning agents being particularly preferred.
- the water soluble package has a chamber for containing the agent.
- the agent in this embodiment may preferably comprise a powder, a granule, a gel or a liquid.
- the water-soluble packaging has two chambers.
- the first chamber preferably contains a liquid agent and the second chamber contains a solid or a liquid agent.
- both chambers may contain a fixed average.
- the water-soluble packaging may each contain a liquid or a solid agent. But it is also possible that one chamber contains a solid medium and two chambers a liquid medium. In addition, it is possible for a solid agent to be contained in two chambers and a liquid agent in a chamber.
- the agents contained in the different chambers of a water-soluble package may have the same composition.
- the compositions in a water-soluble package having at least two compartments, have compositions which differ in at least one ingredient or at least in content of one ingredient.
- the agent contains ingredients that do not destroy the structural integrity of the water-soluble wrapper.
- the agent used is a liquid or solid detergent, it may contain one or more of surfactants, builders, bleaches, bleach activators, bleach catalysts, enzymes, enzyme stabilizers, electrolytes, pH modifiers, perfumes, fragrance carriers, fluorescers, dyes, Hydrotopes, foam inhibitors, silicone oils, Antiredeposition agents, graying inhibitors, anti-shrinkage agents, crease inhibitors, dye transfer inhibitors, antimicrobial agents, nonaqueous solvents, germicides, fungicides, antioxidants, preservatives, corrosion inhibitors, antistatic agents, bittering agents, ironing aids, repellents and impregnating agents, opacifiers, skin care agents, swelling and anti-slip agents , softening components, fillers and UV absorbers.
- the liquid detergents or cleaners may contain water, the content of water being less than 10% by weight and more preferably less than 8% by weight, based in each case on the total liquid washing or cleaning agent.
- a liquid detergent or cleaning agent was first prepared by conventional methods and methods.
- Table 1 shows the composition of a liquid washing or cleaning agent E1.
- Table 1 Liquid washing or cleaning agent E1 [all amounts are given in% by weight of active ingredient, based on the composition] ingredients E1 C 10 -C 13 -alkylbenzenesulfonic acid 21 C 13 -C 15 oxo-alcohol with 8 EO 22.5 C 12-18 fatty acid 17.5 glycerin 13 1,2-propanediol 13.5 ethanol 3.26 phosphonate 0.3 Monoethanolamine 6.4 Dyes, enzymes (cellulase, amylase & protease), optical brightener, perfume 0.8 water 1.74
- a film of the type M 8630 (ex Monosol) having a thickness of 76 ⁇ m was pulled into a depression by means of a vacuum to form a bulge. Subsequently, the bulge was filled with 30 ml of the liquid detergent or cleaning agent E1. After covering the agent-filled bulges with a second layer of a film containing polyvinyl alcohol, polylactic acid, ultramarine, 1,2-propanediol, and glycerin and having a thickness of 76 ⁇ m, the first and second layers were sealed together. The sealing temperature was 150 ° C and the sealing time 1.1 seconds.
- the amount of ultramarine per water-soluble package was 80 mg.
- a water-soluble package 1 which has two chambers 2 and 3 of different sizes, each filled with a liquid washing or cleaning agent, was a film of type M 8630 (ex Monosol) with a thickness of 76 microns to form two Lugs drawn by means of vacuum in a correspondingly shaped trough. Subsequently, the bulges were filled with 10 ml or 20 ml of the liquid detergent or cleaning agent E1. After covering the center filled bulge with a second layer of M 8630 film, the first and second layers were sealed together. The sealing temperature was 150 ° C and the sealing time 1.1 seconds.
- the outer surface of the small chamber 2 of the water-soluble package 1 on both sides was ink-jet-printed with an ultramarine-containing ink.
- the ink was absorbed within 5 seconds by the water-soluble wrapper.
- the amount of ultramarine per water-soluble package was 50 mg.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102012212849.2A DE102012212849A1 (de) | 2012-07-23 | 2012-07-23 | Gefärbte, wasserlösliche Verpackung |
EP13739641.2A EP2874898B1 (fr) | 2012-07-23 | 2013-07-12 | Procédé de fabrication d'un emballage hydrosoluble coloré |
PCT/EP2013/064856 WO2014016144A1 (fr) | 2012-07-23 | 2013-07-12 | Emballage hydrosoluble coloré |
Related Parent Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP13739641.2A Division EP2874898B1 (fr) | 2012-07-23 | 2013-07-12 | Procédé de fabrication d'un emballage hydrosoluble coloré |
EP13739641.2A Division-Into EP2874898B1 (fr) | 2012-07-23 | 2013-07-12 | Procédé de fabrication d'un emballage hydrosoluble coloré |
Publications (1)
Publication Number | Publication Date |
---|---|
EP3354591A1 true EP3354591A1 (fr) | 2018-08-01 |
Family
ID=48832886
Family Applications (4)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP13739641.2A Active EP2874898B1 (fr) | 2012-07-23 | 2013-07-12 | Procédé de fabrication d'un emballage hydrosoluble coloré |
EP18161615.2A Ceased EP3354593A1 (fr) | 2012-07-23 | 2013-07-12 | Emballage coloré, hydrosoluble |
EP18161614.5A Ceased EP3354592A1 (fr) | 2012-07-23 | 2013-07-12 | Emballage coloré, hydrosoluble |
EP18161613.7A Ceased EP3354591A1 (fr) | 2012-07-23 | 2013-07-12 | Emballage coloré, hydrosoluble |
Family Applications Before (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP13739641.2A Active EP2874898B1 (fr) | 2012-07-23 | 2013-07-12 | Procédé de fabrication d'un emballage hydrosoluble coloré |
EP18161615.2A Ceased EP3354593A1 (fr) | 2012-07-23 | 2013-07-12 | Emballage coloré, hydrosoluble |
EP18161614.5A Ceased EP3354592A1 (fr) | 2012-07-23 | 2013-07-12 | Emballage coloré, hydrosoluble |
Country Status (3)
Country | Link |
---|---|
EP (4) | EP2874898B1 (fr) |
DE (1) | DE102012212849A1 (fr) |
WO (1) | WO2014016144A1 (fr) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2927307A1 (fr) * | 2014-03-31 | 2015-10-07 | The Procter & Gamble Company | Article de dose unitaire de lessive |
ES2617075T3 (es) * | 2014-11-26 | 2017-06-15 | Henkel Ag & Co. Kgaa | Bolsa soluble al agua |
DE102015206040A1 (de) | 2015-04-02 | 2016-10-06 | Henkel Ag & Co. Kgaa | Verfahren zur Herstellung einer wasserlöslichen bedruckten Verpackung |
US10633617B2 (en) | 2015-04-23 | 2020-04-28 | The Procter & Gamble Company | Detergent compositions |
EP3334818B1 (fr) | 2015-08-11 | 2020-11-11 | Unilever PLC | Emballage hydrosoluble |
PL3334817T5 (pl) * | 2015-08-11 | 2023-12-04 | Unilever Ip Holdings B.V. | Rozpuszczalne w wodzie opakowanie |
WO2019072645A1 (fr) | 2017-10-13 | 2019-04-18 | Unilever Plc | Composition aqueuse en aérosol |
US11725163B2 (en) | 2017-10-13 | 2023-08-15 | Conopco, Inc. | Aqueous spray composition |
CN111201308A (zh) | 2017-10-13 | 2020-05-26 | 荷兰联合利华有限公司 | 水性喷雾组合物 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20070259170A1 (en) * | 2006-05-05 | 2007-11-08 | The Procter & Gamble Company | Films with microcapsules |
WO2008073299A1 (fr) * | 2006-12-11 | 2008-06-19 | The Procter & Gamble Company | Perceptibilité visuelle améliorée d'images sur un film imprimé |
US20100294153A1 (en) * | 2009-05-19 | 2010-11-25 | Stephane Content | Method for printing water-soluble film |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3336156A (en) * | 1963-05-20 | 1967-08-15 | Gen Aniline & Film Corp | Copolymer vinylpyrrolidone vinylacetate film former for coating or printing on water soluble films |
GB0021113D0 (en) * | 2000-08-25 | 2000-10-11 | Reckitt & Colmann Prod Ltd | Improvements in or relating to containers |
DE10253214A1 (de) * | 2002-11-15 | 2004-06-03 | Henkel Kgaa | Portionierte Mittel mit unterschiedlichen Bestandteilen |
DE10327878A1 (de) * | 2003-06-18 | 2005-01-20 | Henkel Kgaa | Beschichtete plastische Silikate |
EP2077824A4 (fr) * | 2006-09-29 | 2012-07-18 | Monosol Rx Llc | Conditionnement dans lequel un film est incorporé et son procédé de fabrication |
EP2214911A1 (fr) * | 2007-11-13 | 2010-08-11 | The Procter & Gamble Company | Procédé pour créer un produit en dose unitaire au moyen d'un matériau imprimé soluble dans l'eau |
GB2475538B (en) * | 2009-11-23 | 2011-11-23 | Rideau Machinery Inc | Improvements to continuous motion rotary thermoforming of soluble pouches |
-
2012
- 2012-07-23 DE DE102012212849.2A patent/DE102012212849A1/de not_active Withdrawn
-
2013
- 2013-07-12 EP EP13739641.2A patent/EP2874898B1/fr active Active
- 2013-07-12 EP EP18161615.2A patent/EP3354593A1/fr not_active Ceased
- 2013-07-12 EP EP18161614.5A patent/EP3354592A1/fr not_active Ceased
- 2013-07-12 EP EP18161613.7A patent/EP3354591A1/fr not_active Ceased
- 2013-07-12 WO PCT/EP2013/064856 patent/WO2014016144A1/fr active Application Filing
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20070259170A1 (en) * | 2006-05-05 | 2007-11-08 | The Procter & Gamble Company | Films with microcapsules |
WO2008073299A1 (fr) * | 2006-12-11 | 2008-06-19 | The Procter & Gamble Company | Perceptibilité visuelle améliorée d'images sur un film imprimé |
US20100294153A1 (en) * | 2009-05-19 | 2010-11-25 | Stephane Content | Method for printing water-soluble film |
Also Published As
Publication number | Publication date |
---|---|
EP3354592A1 (fr) | 2018-08-01 |
WO2014016144A1 (fr) | 2014-01-30 |
DE102012212849A1 (de) | 2014-05-22 |
EP2874898B1 (fr) | 2021-09-15 |
EP3354593A1 (fr) | 2018-08-01 |
EP2874898A1 (fr) | 2015-05-27 |
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