EP2850169B1 - Détergent liquide à faible teneur en eau, contenant des tensioactifs obtenus à partir de matières premières renouvelables - Google Patents

Détergent liquide à faible teneur en eau, contenant des tensioactifs obtenus à partir de matières premières renouvelables Download PDF

Info

Publication number
EP2850169B1
EP2850169B1 EP13720952.4A EP13720952A EP2850169B1 EP 2850169 B1 EP2850169 B1 EP 2850169B1 EP 13720952 A EP13720952 A EP 13720952A EP 2850169 B1 EP2850169 B1 EP 2850169B1
Authority
EP
European Patent Office
Prior art keywords
water
cleaning agent
soluble
washing
fatty
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP13720952.4A
Other languages
German (de)
English (en)
Other versions
EP2850169A1 (fr
Inventor
Frank Meier
Leyla KÖLLING
Luca Bellomi
Sabine SCHÜMANN
Matthias Sunder
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=48325722&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EP2850169(B1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Publication of EP2850169A1 publication Critical patent/EP2850169A1/fr
Application granted granted Critical
Publication of EP2850169B1 publication Critical patent/EP2850169B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
    • C11D17/042—Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
    • C11D17/043—Liquid or thixotropic (gel) compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/722—Ethers of polyoxyalkylene glycols having mixed oxyalkylene groups; Polyalkoxylated fatty alcohols or polyalkoxylated alkylaryl alcohols with mixed oxyalkylele groups
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D10/00—Compositions of detergents, not provided for by one single preceding group
    • C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2006—Monohydric alcohols
    • C11D3/201—Monohydric alcohols linear
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2041—Dihydric alcohols
    • C11D3/2044—Dihydric alcohols linear
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/43—Solvents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146—Sulfuric acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/662—Carbohydrates or derivatives
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/74—Carboxylates or sulfonates esters of polyoxyalkylene glycols

Definitions

  • the invention relates to a water-soluble packaging comprising a water-soluble coating and a liquid washing or cleaning agent with anionic and nonionic surfactants.
  • detergents or cleaners usually contain combinations of several surfactants in order to meet the requirements for the agent with regard to washing and cleaning performance.
  • the surfactants are usually both those which are obtained from renewable raw materials, such as, for example, ethoxylated fatty alcohols, fatty alcohol sulfates, fatty alcohol ether sulfates or alkylpolyglycosides, and also petrochemically obtained surfactants, in particular alkylbenzenesulfonates.
  • a detergent or cleaning agent that is as climate neutral as possible, which can be accomplished through the use of surfactants derived from renewable resources.
  • Detergents or cleaners are now available to the consumer in a variety of forms.
  • this offer includes, for example, liquids, gels or sachets (tablets or filled pouches).
  • portion packs containing liquid detergents or cleaning agents are becoming increasingly popular, fulfilling, on the one hand, the consumer's desire for simplified dosing and, on the other hand, more and more consumers prefering liquid detergents or cleaners.
  • WO2013 / 135512 A1 discloses a dusted water-soluble package containing an agent and a water-soluble wrapper.
  • WO 2002/057398 A1 is, for example, a water-soluble container containing a liquid detergent composition comprising: a) an alkylbenzenesulfonic acid neutralized with an alkanolamine, b) an organic solvent and c) less than 3% by weight of water.
  • Alkylbenzenesulfonates are preferably used not only because of their good washing and cleaning performance in low-water liquid detergents or cleaners, but also because they can be highly concentrated, that is in low-water form, can be used. This means that the use of alkylbenzenesulfonates as anionic surfactant little water enters the liquid detergents or cleaning agents.
  • Other anionic surfactants such as fatty alcohol ether sulfates obtained from renewable raw materials, already contain large amounts (> 25%) of water in the raw material.
  • the ionic strength I c of the washing or cleaning agent is preferably less than 250 mmol / l. It has been found that such an ionic strength prevents ingredients, in particular surfactants, of the liquid detergent or cleaning agent from being salted out and depositing on the inner surface of the water-soluble coating.
  • the washing or cleaning agent has a particularly high cleaning performance and good foaming behavior, when the anionic surfactant is a mixture of fatty alcohol ether sulfate and fatty acid soap.
  • the amount of fatty alcohol ether sulfate in the liquid detergent or cleaning agent is at least 5% by weight.
  • the washing or cleaning agent has a water activity a w ⁇ 0.38.
  • the amount of aerobically non-biodegradable organic ingredients (aNBO) in the detergent or cleaner is less than 0.55 g per kg wash load.
  • the amount of anaerobically non-biodegradable organic ingredients (anNBO) in the detergent or cleaner is less than 0.70 g per kg wash load.
  • the water-soluble coating contains polyvinyl alcohol or a polyvinyl alcohol copolymer.
  • Water-soluble coatings containing polyvinyl alcohol or a polyvinyl alcohol copolymer have a good stability with a sufficiently high water solubility, in particular cold water solubility on.
  • the application relates to a water-soluble packaging which contains a liquid washing or cleaning agent and a water-soluble coating.
  • the water-soluble package contains a water-soluble envelope which forms a closed structure having in its interior one or more chambers for receiving one or more detergents or cleaning agents.
  • the water-soluble packaging may be dimensionally stable or deformable.
  • the water-soluble packaging may be formed as a dimensionally stable container, for example in the form of a capsule, box, box or container.
  • the water-soluble packaging in principle it is also possible and preferred to mold the water-soluble packaging as a non-dimensionally stable container, for example as a bag.
  • the shape of such a water-soluble packaging can be largely adapted to the conditions of use.
  • various forms such as hoses, pillows, cylinders, bottles or discs in question.
  • the water-soluble packaging contains a liquid washing or cleaning agent.
  • the liquid washing or cleaning agent contains only surfactants, which are obtained from renewable raw materials.
  • the liquid washing or cleaning agent contains nonionic surfactant selected from the group consisting of alkoxylated fatty alcohols, alkyl polyglycosides, ethoxylated methyl esters of natural fatty acids and mixtures thereof.
  • the alkoxylated fatty alcohols used are preferably ethoxylated, in particular primary, alcohols having preferably 8 to 18 carbon atoms and on average 4 to 12 moles of ethylene oxide (EO) per mole of alcohol, in which the alcohol radical is linear.
  • EO ethylene oxide
  • alcohol ethoxylates having 12 to 18 C atoms for example coconut, palm, tallow or oleyl alcohol, and on average 5 to 8 EO per mole of alcohol are preferred.
  • the preferred ethoxylated alcohols include, for example, C 12-14 alcohols with 4 EO or 7 EO, C 9-11 alcohols with 7 EO, C 12-18 alcohols with 5 EO or 7 EO and mixtures of these.
  • the degrees of ethoxylation given represent statistical means which, for a particular product, may be an integer or a fractional number.
  • Preferred alcohol ethoxylates have a narrow homolog distribution (narrow range ethoxylates, NRE).
  • fatty alcohols containing more than 12 EO can also be used. Examples include tallow fatty alcohol with 14 EO, 25 EO, 30 EO or 40 EO.
  • Alkoxylated fatty alcohols which contain EO and PO groups together in the molecule can also be used according to the invention.
  • alkyl glycosides of the general formula RO (G) x can be used in which R is a primary straight-chain or methyl-branched, especially methyl-branched in the 2-position aliphatic radical having 8 to 22, preferably 12 to 18 carbon atoms and G is the Is a symbol which represents a glycose unit having 5 or 6 C atoms, preferably glucose.
  • the degree of oligomerization x which indicates the distribution of monoglycosides and oligoglycosides, is any number between 1 and 10; preferably x is 1.2 to 1.4.
  • nonionic surfactants are ethoxylated methyl esters of natural fatty acids, such as coconut, palm kernel or olive oil fatty acids, preferably having 8 to 18 EO units.
  • the liquid washing or cleaning agent preferably contains exclusively alkoxylated fatty alcohols as nonionic surfactants.
  • the total amount of nonionic surfactant in the liquid washing or cleaning agent is up to 45 wt .-%, preferably 15 to 40 wt .-% and particularly preferably 20 to 30 wt .-%, based on the total liquid detergent or cleaning agent.
  • the liquid detergent or cleaning agent further contains anionic surfactant selected from the group consisting of fatty alcohol sulfates, fatty alcohol ether sulfates, fatty acid soaps, sulfonated estolides and mixtures thereof.
  • the liquid washing or cleaning agent particularly preferably contains fatty alcohol ether sulfates and / or fatty acid soaps as anionic surfactant.
  • the anionic surfactant most preferably contains a mixture of fatty alcohol ether sulfates and fatty acid soaps and is free of further anionic surfactants.
  • fatty alcohol sulfates the salts of the sulfuric acid half esters of C 12 -C 18 fatty alcohols, for example from coconut oil fatty alcohol, tallow fatty alcohol, lauryl, myristyl, cetyl or stearyl alcohol are preferred.
  • the C 12 -C 16 alkyl sulfates and C 12 -C 15 alkyl sulfates and C 14 -C 15 alkyl sulfates are preferred.
  • fatty alcohol ether sulfates are, for example, the sulfuric acid monoesters of ethoxylated with 1 to 6 moles of ethylene oxide straight or branched C 7-21 alcohols such as 2-methyl-branched C 9-11 alcohols having an average of 3.5 moles of ethylene oxide (EO) or C 12th -18 fatty alcohols with 1 to 4 EO used.
  • EO ethylene oxide
  • Suitable anionic surfactants are fatty acid soaps.
  • Suitable are saturated and unsaturated fatty acid soaps, such as the salts of lauric acid, myristic acid, palmitic acid, stearic acid, (hydrogenated) erucic acid and behenic acid and, in particular, soap mixtures derived from natural fatty acids, for example coconut, palm kernel, olive oil or tallow fatty acids.
  • the anionic surfactants may be in the form of their sodium, potassium or ammonium salts.
  • the anionic surfactants are in the form of their sodium salts or ammonium salts.
  • the ammonium salts may be the salts of organic bases.
  • the amine used for the neutralization is preferably choline, triethylamine, monoethanolamine, diethanolamine, triethanolamine, methylethylamine or a mixture thereof, with monoethanolamine being preferred.
  • Suitable sulfonated estolides include compounds of the following formula wherein n is an integer from 1 to 30, one of X or Y is SO 3 -Z and the other is hydrogen, wherein X and Y are present in each repeating unit, A 1 and A 2 are linear or branched, saturated or unsaturated, substituted or unsubstituted C 8 -C 22 alkylene units, a is independently 0, 1, or 2 in each repeat unit, R is a linear or branched, saturated or unsaturated, substituted or unsubstituted C 1 -C 24 alkyl moiety, W is a monovalent or divalent Metal cation, an ammonium cation, a substituted ammonium cation, hydrogen, an alkyl group or a substituted alkyl group and Z is hydrogen, a monovalent or divalent metal cation, an ammonium cation or a substituted ammonium cation.
  • the liquid washing or cleaning agent contains the sodium salt of a fatty alcohol ether sulfate and a fatty acid neutralized with monoethanolamine. It is also preferred that the amount of fatty alcohol ether sulfate in the total liquid detergent or cleaning agent is at least 5% by weight.
  • the total amount of anionic surfactant in the liquid washing or cleaning agent is up to 35% by weight and preferably 15 to 30% by weight, based on the total liquid detergent or cleaning agent.
  • the total amount of nonionic and anionic surfactant in the liquid washing or cleaning agent is up to 75% by weight and preferably 50 to 60% by weight, based on the total liquid detergent or cleaning agent.
  • the liquid detergent or cleaning agent further contains organic solvent comprising a mixture of 1,2-propanediol and ethanol.
  • the amount of ethanol is up to 5 wt .-%, and preferably between 1 and 3 wt .-%, each based on the total washing or cleaning agent.
  • the amount of 1,2-propanediol is up to 50 wt .-%, preferably between 10 and 40 wt .-%, and most preferably between 20 and 35 wt .-%, each based on the total washing or cleaning agent.
  • liquid washing or cleaning agents which have other organic solvent systems, for example a mixture of 1,2-propanediol and isopropanol, are unstable.
  • liquid washing or cleaning agent is free of isopropanol and in a most preferred embodiment free of further organic solvents. Accordingly, a particularly preferred liquid washing or cleaning agent contains an organic solvent which is a mixture of 1,2-propanediol and ethanol.
  • the liquid washing or cleaning agent contains water, wherein the content of water is less than 15 wt .-%, and more preferably less than 13 wt .-%, each based on the total liquid detergent or cleaning agent. Particularly preferably, the entire liquid washing or cleaning agent contains 7 to 12 wt .-% water.
  • the liquid washing or cleaning agent has a water activity a w of more than 0.38, and more preferably more than 0.42.
  • the determination of the water activity is carried out at 25 ° C with an "AquaLab Lite" device from IUL Instruments GmbH.
  • the water activity a w is a measure of freely available water in a material and indicates the availability of the water for chemical, biochemical and microbial reactions.
  • the washing or cleaning agent may contain other ingredients containing the improve the performance and / or aesthetic properties of the detergent or cleaning agent, but not destroy the structural integrity of the water-soluble envelope.
  • the washing or cleaning agent preferably additionally contains one or more substances from the group of builders, bleaches, enzymes, pH adjusters, perfumes, perfume carriers, fluorescers, dyes, hydrotopes, foam inhibitors, silicone oils, antiredeposition agents, grayness inhibitors, anti-shrinkage agents Anti-crease agents, color transfer inhibitors, antimicrobial agents, non-aqueous solvents, germicides, fungicides, antioxidants, preservatives, corrosion inhibitors, antistatic agents, bittering agents, ironing aids, repellents and impregnating agents, skin-care agents, swelling and anti-slip agents, plasticizing components and UV absorbers ,
  • liquid washing or cleaning agent is free from added inorganic salts.
  • the amount of aerobic non-biodegradable organic ingredients (aNBO) in the detergent or cleaning agent is less than 0.55 g per kg wash load.
  • anaerobically nonbiodegradable organic ingredients (anNBO) in the detergent or cleaner be less than 0.70 g per kg wash load.
  • a wash load corresponds to a dosage of 35 g washing or cleaning agent to 4.5 kg of laundry.
  • the liquid washing or cleaning agent is in a water-soluble coating.
  • a water-soluble packaging contains, in addition to the liquid washing or cleaning agent, a water-soluble coating.
  • the water-soluble coating is preferably formed by a water-soluble film material.
  • Such water-soluble packages can be made by either vertical fill-seal (VFFS) or thermoforming techniques.
  • VFFS vertical fill-seal
  • the thermoforming process generally includes forming a first layer of water-soluble sheet material to form protrusions for receiving a composition therein, filling the composition into the protrusions, covering the composition-filled protrusions with a second layer of water-soluble sheet material, and sealing the first and second layers at least around the bulges.
  • the water-soluble coating is preferably formed from a water-soluble film material selected from the group comprising polymers and polymer blends.
  • the wrapper may be formed of one or two or more layers of the water-soluble film material.
  • the water-soluble film material of the first layer and the further layers, if present, may be the same or different.
  • the water-soluble coating contains polyvinyl alcohol or a polyvinyl alcohol copolymer.
  • Suitable water-soluble films for producing the water-soluble coating are preferably based on a polyvinyl alcohol or a polyvinyl alcohol copolymer whose molecular weight is in the range of 10,000 to 1,000,000 gmol -1 , preferably 20,000 to 500,000 gmol -1 , more preferably 30,000 to 100,000 gmol -1 and especially from 40,000 to 80,000 gmol -1 .
  • polyvinyl alcohol is usually carried out by hydrolysis of polyvinyl acetate, since the direct synthesis route is not possible.
  • polyvinyl alcohol copolymers which are prepared from correspondingly polyvinyl acetate copolymers. It is preferred if at least one layer of the water-soluble coating comprises a polyvinyl alcohol whose degree of hydrolysis makes up 70 to 100 mol%, preferably 80 to 90 mol%, particularly preferably 81 to 89 mol% and in particular 82 to 88 mol%.
  • a polymer selected from the group consisting of (meth) acrylic acid-containing (co) polymers, polyacrylamides, oxazoline polymers, polystyrenesulfonates, polyurethanes, polyesters, polyethers, polylactic acids or mixtures of the above may additionally be selected from a polyvinyl alcohol-containing film material suitable for producing the water-soluble coating Be added polymers.
  • a preferred additional polymer is polylactic acids.
  • Preferred polyvinyl alcohol copolymers include, in addition to vinyl alcohol, dicarboxylic acids as further monomers.
  • Suitable dicarboxylic acids are itaconic acid, malonic acid, succinic acid and mixtures thereof, with itaconic acid being preferred.
  • polyvinyl alcohol copolymers include, in addition to vinyl alcohol, an ethylenically unsaturated carboxylic acid, its salt or its esters.
  • Such polyvinyl alcohol copolymers particularly preferably contain, in addition to vinyl alcohol, acrylic acid, methacrylic acid, acrylates, methacrylates or mixtures thereof.
  • the film material contains further additives.
  • the film material may contain, for example, plasticizers such as dipropylene glycol, ethylene glycol, diethylene glycol, propylene glycol, glycerol, sorbitol, mannitol or mixtures thereof.
  • Further additives include, for example, release aids, fillers, crosslinking agents, surfactants, antioxidants, UV absorbers, antiblocking agents, anti-sticking agents or mixtures thereof.
  • Suitable water-soluble films for use in the water-soluble casings of the water-soluble packaging according to the invention are films sold by MonoSol LLC, for example under the designation M8630, M8310, C8400 or M8900.
  • Other suitable films include films named Solublon® PT, Solublon® GA, Solublon® KC or Solublon® KL from Aicello Chemical Europe GmbH or the films VF-HP from Kuraray.
  • the water-soluble packaging has a chamber for receiving the liquid detergent or cleaning agent.
  • the water-soluble packaging has two chambers.
  • the first chamber contains the above-described liquid detergent or cleaning agent and the second chamber may contain a solid or a liquid detergent or cleaning agent.
  • the water-soluble packaging has three chambers, these chambers can each contain a liquid washing or cleaning agent. But it is also possible that a chamber containing a solid detergent or detergent and two chambers containing a liquid detergent or cleaning agent. It is also possible that a solid detergent or cleaning agent is contained in two chambers and a liquid detergent or cleaning agent in a chamber.
  • At least one chamber contains the above-described liquid detergent or cleaning agent according to the invention with exclusively surfactants which are obtained from renewable raw materials.
  • the liquid detergents or cleaning agents contained in the other chambers of a water-soluble packaging may have the same composition.
  • the liquid detergents or cleaners in a water-soluble packaging with at least two chambers preferably have compositions which differ at least in the content of an ingredient.
  • the amount of detergent or cleaning agent, which is in total in the water-soluble packaging, preferably corresponds to the full or half dose required for a wash.
  • Liquid detergents or cleaners were prepared by conventional and known methods and procedures. Table 1 below shows the compositions of two detergents or cleaners E1 and E2 according to the invention and four detergents or cleaners V1 to V4 not according to the invention. Table 1: Liquid washing or cleaning agents E1 and E2 and also V1 to V4 [all amounts are given in% by weight of active ingredient based on the composition] ingredients E1 E2 V1 V2 V3 V4 Na lauryl ether sulfate (2 EO) 12 12 12 12 12 12 12 C 12-18 fatty alcohol with 7 EO 25 25 25 25 25 25 25 C 12-18 fatty acid 15 15 15 15 15 15 15 15 15 15 15 15 15 15 ethanol 1.4 1.4 - - - - isopropanol - - 1.4 1.4 1.4 1.4 phosphonate 1 1 1 1 1 1 Monoethanolamine 3.86 3.86 3.94 3.67 3.71 3.91 Citric acid, sodium salt - - - 1.4 2.25 - MgCl 2 ⁇ 6
  • the ionic strength I c of the liquid washing or cleaning agents E1 and E2 was in each case less than 150 mmol / l.
  • the amount of aerobic non-biodegradable organic ingredients (aNBO) in detergents E1 and E2 was 0.13 g per kg wash load, respectively.
  • the amount of aerobic non-biodegradable organic ingredients (ANNBO) in detergents E1 and E2 was 0.14 g per kg wash load, respectively.
  • the water activity a w of the liquid washing or cleaning agents E1 and E2 was 0.45 in each case.
  • a film of the type M 8630 Ex Monosol
  • a thickness of 76 ⁇ m was pulled into a depression by means of a vacuum to form a bulge.
  • the bulge was mixed with 30 ml of one of the liquid detergents or cleaners E1, E2 or V1 to V4 filled.
  • the first and second layers were sealed together.
  • the sealing temperature was 150 ° C and the sealing time 1.1 seconds.
  • a liquid detergent or cleaning agent which acts as a surfactant system C 12-18 fatty acid soap, C 12-18 fatty alcohol containing 7 EO and a C 9-13 alkylbenzenesulfonate, an equally good cleaning performance.

Claims (6)

  1. Emballage hydrosoluble contenant un agent de lavage ou de nettoyage liquide et une enveloppe hydrosoluble, caractérisé en ce que l'agent détergent ou de nettoyage liquide contient
    a. un tensioactif non ionique choisi dans le groupe comprenant les alcools gras alcoxylés, les alkylpolyglycosides, les esters méthyliques éthoxylés d'acides gras naturels et leurs mélanges,
    b. un tensioactif anionique choisi dans le groupe comprenant les sulfates d'alcools gras, les éther-sulfates d'alcool gras, les savons d'acides gras, les estolides sulfonés et leurs mélanges,
    c. un solvant organique comprenant un mélange de 1,2-propanediol et d'éthanol,
    d. jusqu'à 15 % en poids d'eau, sur la base de tout l'agent de lavage ou de nettoyage,
    e. jusqu'à 50 % en poids de 1,2-propanediol, sur la base de tout l'agent de lavage ou de nettoyage,
    f. jusqu'à 5 % en poids d'éthanol, sur la base de tout l'agent de lavage ou de nettoyage total, et
    g. est exempt d'isopropanol, de préférence exempt d'autres solvants organiques, la quantité totale de tensioactif anionique pouvant aller jusqu'à 35 % en poids, sur la base de tout l'agent de lavage ou de nettoyage.
  2. Emballage hydrosoluble dans selon la revendication 1, caractérisé en ce que la force ionique ic de l'agent de lavage ou de nettoyage est inférieure à 250 mmol/l.
  3. Emballage hydrosoluble selon les revendications 1 et 2, caractérisé en ce que le tensioactif anionique est un mélange d'éther-sulfates d'alcool gras et de savons d'acides gras.
  4. Emballage hydrosoluble selon les revendications 1 à 3, caractérisé en ce que l'agent de lavage ou de nettoyage liquide contient au moins 5 % en poids d'éther-sulfate d'alcool gras.
  5. Emballage hydrosoluble selon l'une des revendications 1 à 4, caractérisé en ce que l'agent de lavage ou de nettoyage présente une activité hydrique aw ≥ 0,38.
  6. Emballage hydrosoluble soluble selon les revendications 1 à 5, caractérisé en ce que l'enveloppe hydrosoluble contient de l'alcool polyvinylique ou un copolymère d'alcool polyvinylique.
EP13720952.4A 2012-05-16 2013-05-07 Détergent liquide à faible teneur en eau, contenant des tensioactifs obtenus à partir de matières premières renouvelables Active EP2850169B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102012208286A DE102012208286A1 (de) 2012-05-16 2012-05-16 Wasserarmes, flüssiges Waschmittel mit aus nachwachsenden Rohstoffen gewonnenen Tensiden
PCT/EP2013/059469 WO2013171095A1 (fr) 2012-05-16 2013-05-07 Détergent liquide à faible teneur en eau, contenant des tensioactifs obtenus à partir de matières premières renouvelables

Publications (2)

Publication Number Publication Date
EP2850169A1 EP2850169A1 (fr) 2015-03-25
EP2850169B1 true EP2850169B1 (fr) 2018-11-14

Family

ID=48325722

Family Applications (1)

Application Number Title Priority Date Filing Date
EP13720952.4A Active EP2850169B1 (fr) 2012-05-16 2013-05-07 Détergent liquide à faible teneur en eau, contenant des tensioactifs obtenus à partir de matières premières renouvelables

Country Status (4)

Country Link
US (1) US10160939B2 (fr)
EP (1) EP2850169B1 (fr)
DE (1) DE102012208286A1 (fr)
WO (1) WO2013171095A1 (fr)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102014202221A1 (de) * 2014-02-06 2015-08-06 Henkel Ag & Co. Kgaa Mehrphasiges vorportioniertes Reinigungsmittel
DE102014225478A1 (de) * 2014-12-10 2016-06-16 Henkel Ag & Co. Kgaa Wasch- oder Reinigungsmittel mit spezieller a-Amylase und definierter Wasseraktivität aw
US9796948B2 (en) 2016-01-13 2017-10-24 The Procter & Gamble Company Laundry detergent compositions comprising renewable components
US9896648B2 (en) 2016-03-02 2018-02-20 The Procter & Gamble Company Ethoxylated diols and compositions containing ethoxylated diols
EP3372664A3 (fr) * 2017-02-21 2018-11-28 The Procter & Gamble Company Utilisation d'une composition de détergent à lessive liquide afin de réduire au minimum les effets indésirables lors d'une exposition accidentelle à des contenus d'articles de dose unitaire solubles dans l'eau
EP3363889A1 (fr) * 2017-02-21 2018-08-22 The Procter & Gamble Company Utilisation d'une composition détergente liquide pour le lavage afin de réduire au minimum les effets défavorables lors d'une exposition accidentelle à des contenus d'articles de dose unitaire solubles dans l'eau
US20190048296A1 (en) * 2017-08-10 2019-02-14 Henkel IP & Holding GmbH Unit dose detergent products with improved pac rigidity
CN114231362B (zh) * 2021-12-29 2023-10-31 赞宇科技集团股份有限公司 一种抑菌洗衣凝珠及其制备方法

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998000491A1 (fr) 1996-06-28 1998-01-08 The Procter & Gamble Company Composition detergente
US7012053B1 (en) 1999-10-22 2006-03-14 The Procter & Gamble Company Fabric care composition and method comprising a fabric care polysaccharide and wrinkle control agent
US20100093595A1 (en) 2008-10-15 2010-04-15 Holzhauer Frederick W Liquid cleaning compositions
US20110065625A1 (en) 2009-09-14 2011-03-17 Jean-Pol Boutique External structuring system for liquid laundry detergent composition
WO2011075551A1 (fr) 2009-12-18 2011-06-23 The Procter & Gamble Company Parfums et encapsulats de parfums
US8097579B2 (en) 2007-11-09 2012-01-17 The Procter & Gamble Company Cleaning compositions with amphiphilic water-soluble polyalkylenimines having an inner polyethylene oxide block and an outer polypropylene oxide block
WO2012166768A1 (fr) 2011-06-03 2012-12-06 The Procter & Gamble Company Compositions d'entretien du linge contenant des colorants
WO2013135512A1 (fr) * 2012-03-14 2013-09-19 Henkel Ag & Co. Kgaa Emballage soluble dans l'eau avec saupoudrage

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4341050A1 (de) * 1993-12-02 1995-06-08 Huels Chemische Werke Ag Tensidkonzentrate als Basistenside für konzentrierte Flüssigformulierungen
US6995126B2 (en) * 2000-04-28 2006-02-07 The Procter & Gamble Company Pouched compositions
PL199452B1 (pl) 2001-01-19 2008-09-30 Reckitt Benckiser Nv Ciekła kompozycja detergentowa zawarta w rozpuszczalnym w wodzie pojemniku oraz jej zastosowanie
EP1354939A1 (fr) * 2002-04-19 2003-10-22 The Procter & Gamble Company Compositions detergentes en sachet
US7879790B2 (en) * 2008-01-22 2011-02-01 Stepan Company Mixed salts of sulfonated estolides and other derivatives of fatty acids, and methods of making them
US7666828B2 (en) * 2008-01-22 2010-02-23 Stepan Company Sulfonated estolides and other derivatives of fatty acids, methods of making them, and compositions and processes employing them
EP2133410B1 (fr) * 2008-06-13 2011-12-28 The Procter & Gamble Company Sachet à compartiments multiples
US7939487B2 (en) * 2008-08-26 2011-05-10 The Clorox Company Natural cleaners
US8119588B2 (en) * 2009-01-21 2012-02-21 Stepan Company Hard surface cleaner compositions of sulfonated estolides and other derivatives of fatty acids and uses thereof
HUE048039T2 (hu) * 2009-06-02 2020-05-28 Procter & Gamble Vízoldható tasak
RU2546651C2 (ru) * 2010-01-29 2015-04-10 МОНОСОЛ, ЭлЭлСи Водорастворимая пленка с улучшенной растворимостью и улучшенными механическими свойствами, а также пакеты, изготовленные из нее
MX345026B (es) * 2010-07-02 2017-01-12 Procter & Gamble Material de trama y método para su elaboración.
EP2441824A1 (fr) * 2010-10-15 2012-04-18 Cognis IP Management GmbH Liquide pour le lavage du linge adapté pour un conditionnement dans des sachets à l'alcool polyvinylique

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998000491A1 (fr) 1996-06-28 1998-01-08 The Procter & Gamble Company Composition detergente
US7012053B1 (en) 1999-10-22 2006-03-14 The Procter & Gamble Company Fabric care composition and method comprising a fabric care polysaccharide and wrinkle control agent
US8097579B2 (en) 2007-11-09 2012-01-17 The Procter & Gamble Company Cleaning compositions with amphiphilic water-soluble polyalkylenimines having an inner polyethylene oxide block and an outer polypropylene oxide block
US20100093595A1 (en) 2008-10-15 2010-04-15 Holzhauer Frederick W Liquid cleaning compositions
WO2010044835A1 (fr) 2008-10-15 2010-04-22 Method Products, Inc. Compositions nettoyantes liquides
US20110065625A1 (en) 2009-09-14 2011-03-17 Jean-Pol Boutique External structuring system for liquid laundry detergent composition
WO2011075551A1 (fr) 2009-12-18 2011-06-23 The Procter & Gamble Company Parfums et encapsulats de parfums
WO2012166768A1 (fr) 2011-06-03 2012-12-06 The Procter & Gamble Company Compositions d'entretien du linge contenant des colorants
WO2013135512A1 (fr) * 2012-03-14 2013-09-19 Henkel Ag & Co. Kgaa Emballage soluble dans l'eau avec saupoudrage

Also Published As

Publication number Publication date
WO2013171095A1 (fr) 2013-11-21
US10160939B2 (en) 2018-12-25
EP2850169A1 (fr) 2015-03-25
US20150065410A1 (en) 2015-03-05
DE102012208286A1 (de) 2013-11-21

Similar Documents

Publication Publication Date Title
EP2850169B1 (fr) Détergent liquide à faible teneur en eau, contenant des tensioactifs obtenus à partir de matières premières renouvelables
EP2867352B1 (fr) Produit détergent ou nettoyant liquide hautement concentré
EP2773735B1 (fr) Composition detergente structurée à limite d'écoulement
DE60106631T2 (de) Wasserlösliche, warmgeformte, wässrige zusammensetzungen enthaltende behälter
EP2802643B1 (fr) Emballage parfumé soluble dans l'eau
DE60216256T2 (de) Wasserlöslicher behälter mit mindestens zwei öffnungen
EP3204309A1 (fr) Monodose de produit emballée sous film
EP2828368B1 (fr) Composition détergente liquide ayant une puissance de nettoyage augmentée
DE602004007791T2 (de) Wasserlöslicher behälter
EP3354592A1 (fr) Emballage coloré, hydrosoluble
WO2015150231A1 (fr) Dose préemballée soluble dans l'eau dotée d'un couvercle de forme stable
EP2809759B1 (fr) Détergent liquide pauvre en eau à pouvoir dégraissant renforcé
EP2875107B1 (fr) Détergent liquide stable à capacité antiredéposition
WO2014040865A1 (fr) Détergent liquide structuré à faible teneur en eau contenant des particules
DE102013226426A1 (de) Konservierungsmittelsystem für Waschmittel
DE102011085639A1 (de) Strukturiertes Wasch- oder Reinigungsmittel mit Fließgrenze
DE102014014767A1 (de) Folienverpackte Mittelportion
EP2875106B1 (fr) Composition détergente liquide stable à capacité antiredéposition
EP4077623B1 (fr) Composition de traitement textile
DE102016206647A1 (de) Flüssigwaschmittel
DE102019219881A1 (de) Klarspülmittel für automatische Geschirrspülmaschinen
WO2015091109A1 (fr) Lessive liquide contenant de la hpmc

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 20140306

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

AX Request for extension of the european patent

Extension state: BA ME

RIN1 Information on inventor provided before grant (corrected)

Inventor name: KOELLING, LEYLA

Inventor name: SCHUEMANN, SABINE

Inventor name: MEIER, FRANK

Inventor name: BELLOMI, LUCA

Inventor name: SUNDER, MATTHIAS

DAX Request for extension of the european patent (deleted)
STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: EXAMINATION IS IN PROGRESS

17Q First examination report despatched

Effective date: 20170104

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: GRANT OF PATENT IS INTENDED

INTG Intention to grant announced

Effective date: 20180627

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE PATENT HAS BEEN GRANTED

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

REG Reference to a national code

Ref country code: CH

Ref legal event code: EP

Ref country code: AT

Ref legal event code: REF

Ref document number: 1064828

Country of ref document: AT

Kind code of ref document: T

Effective date: 20181115

REG Reference to a national code

Ref country code: DE

Ref legal event code: R096

Ref document number: 502013011608

Country of ref document: DE

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

Free format text: LANGUAGE OF EP DOCUMENT: GERMAN

REG Reference to a national code

Ref country code: NL

Ref legal event code: MP

Effective date: 20181114

REG Reference to a national code

Ref country code: LT

Ref legal event code: MG4D

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: ES

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20181114

Ref country code: IS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190314

Ref country code: BG

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190214

Ref country code: LT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20181114

Ref country code: NO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190214

Ref country code: LV

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20181114

Ref country code: HR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20181114

Ref country code: FI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20181114

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: AL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20181114

Ref country code: RS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20181114

Ref country code: SE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20181114

Ref country code: GR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190215

Ref country code: NL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20181114

Ref country code: PT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190314

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20181114

Ref country code: PL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20181114

Ref country code: DK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20181114

Ref country code: CZ

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20181114

REG Reference to a national code

Ref country code: DE

Ref legal event code: R026

Ref document number: 502013011608

Country of ref document: DE

PLBI Opposition filed

Free format text: ORIGINAL CODE: 0009260

PLAX Notice of opposition and request to file observation + time limit sent

Free format text: ORIGINAL CODE: EPIDOSNOBS2

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: EE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20181114

Ref country code: SM

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20181114

Ref country code: RO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20181114

Ref country code: SK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20181114

26 Opposition filed

Opponent name: THE PROCTER & GAMBLE COMPANY

Effective date: 20190814

Opponent name: DALLI-WERKE GMBH & CO. KG

Effective date: 20190809

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20181114

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

PLBB Reply of patent proprietor to notice(s) of opposition received

Free format text: ORIGINAL CODE: EPIDOSNOBS3

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20190531

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20190531

Ref country code: MC

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20181114

REG Reference to a national code

Ref country code: BE

Ref legal event code: MM

Effective date: 20190531

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20190507

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: TR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20181114

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20190507

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20190531

REG Reference to a national code

Ref country code: AT

Ref legal event code: MM01

Ref document number: 1064828

Country of ref document: AT

Kind code of ref document: T

Effective date: 20190507

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: AT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20190507

PLAB Opposition data, opponent's data or that of the opponent's representative modified

Free format text: ORIGINAL CODE: 0009299OPPO

PLCK Communication despatched that opposition was rejected

Free format text: ORIGINAL CODE: EPIDOSNREJ1

R26 Opposition filed (corrected)

Opponent name: DALLI-WERKE GMBH & CO. KG

Effective date: 20190809

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CY

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20181114

APAH Appeal reference modified

Free format text: ORIGINAL CODE: EPIDOSCREFNO

APBM Appeal reference recorded

Free format text: ORIGINAL CODE: EPIDOSNREFNO

APBP Date of receipt of notice of appeal recorded

Free format text: ORIGINAL CODE: EPIDOSNNOA2O

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20181114

Ref country code: HU

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT; INVALID AB INITIO

Effective date: 20130507

APBQ Date of receipt of statement of grounds of appeal recorded

Free format text: ORIGINAL CODE: EPIDOSNNOA3O

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20181114

P01 Opt-out of the competence of the unified patent court (upc) registered

Effective date: 20230530

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 20230526

Year of fee payment: 11

Ref country code: DE

Payment date: 20230519

Year of fee payment: 11

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 20230524

Year of fee payment: 11

APBU Appeal procedure closed

Free format text: ORIGINAL CODE: EPIDOSNNOA9O

PLAY Examination report in opposition despatched + time limit

Free format text: ORIGINAL CODE: EPIDOSNORE2