EP3165864B1 - Élément d'échange de chaleur en aluminium poreux - Google Patents

Élément d'échange de chaleur en aluminium poreux Download PDF

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Publication number
EP3165864B1
EP3165864B1 EP15814479.0A EP15814479A EP3165864B1 EP 3165864 B1 EP3165864 B1 EP 3165864B1 EP 15814479 A EP15814479 A EP 15814479A EP 3165864 B1 EP3165864 B1 EP 3165864B1
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EP
European Patent Office
Prior art keywords
aluminum
porous aluminum
porous
heat exchanger
pipe
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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EP15814479.0A
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German (de)
English (en)
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EP3165864A4 (fr
EP3165864A1 (fr
Inventor
Toshihiko SAIWAI
Koichi Kita
Ji-Bin Yang
Koji Hoshino
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Mitsubishi Materials Corp
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Mitsubishi Materials Corp
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Publication of EP3165864A1 publication Critical patent/EP3165864A1/fr
Publication of EP3165864A4 publication Critical patent/EP3165864A4/fr
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Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28—HEAT EXCHANGE IN GENERAL
    • F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F21/00—Constructions of heat-exchange apparatus characterised by the selection of particular materials
    • F28F21/08—Constructions of heat-exchange apparatus characterised by the selection of particular materials of metal
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28—HEAT EXCHANGE IN GENERAL
    • F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D15/00—Heat-exchange apparatus with the intermediate heat-transfer medium in closed tubes passing into or through the conduit walls ; Heat-exchange apparatus employing intermediate heat-transfer medium or bodies
    • F28D15/02—Heat-exchange apparatus with the intermediate heat-transfer medium in closed tubes passing into or through the conduit walls ; Heat-exchange apparatus employing intermediate heat-transfer medium or bodies in which the medium condenses and evaporates, e.g. heat pipes
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28—HEAT EXCHANGE IN GENERAL
    • F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D15/00—Heat-exchange apparatus with the intermediate heat-transfer medium in closed tubes passing into or through the conduit walls ; Heat-exchange apparatus employing intermediate heat-transfer medium or bodies
    • F28D15/02—Heat-exchange apparatus with the intermediate heat-transfer medium in closed tubes passing into or through the conduit walls ; Heat-exchange apparatus employing intermediate heat-transfer medium or bodies in which the medium condenses and evaporates, e.g. heat pipes
    • F28D15/0266—Heat-exchange apparatus with the intermediate heat-transfer medium in closed tubes passing into or through the conduit walls ; Heat-exchange apparatus employing intermediate heat-transfer medium or bodies in which the medium condenses and evaporates, e.g. heat pipes with separate evaporating and condensing chambers connected by at least one conduit; Loop-type heat pipes; with multiple or common evaporating or condensing chambers
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28—HEAT EXCHANGE IN GENERAL
    • F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D15/00—Heat-exchange apparatus with the intermediate heat-transfer medium in closed tubes passing into or through the conduit walls ; Heat-exchange apparatus employing intermediate heat-transfer medium or bodies
    • F28D15/02—Heat-exchange apparatus with the intermediate heat-transfer medium in closed tubes passing into or through the conduit walls ; Heat-exchange apparatus employing intermediate heat-transfer medium or bodies in which the medium condenses and evaporates, e.g. heat pipes
    • F28D15/04—Heat-exchange apparatus with the intermediate heat-transfer medium in closed tubes passing into or through the conduit walls ; Heat-exchange apparatus employing intermediate heat-transfer medium or bodies in which the medium condenses and evaporates, e.g. heat pipes with tubes having a capillary structure
    • F28D15/046—Heat-exchange apparatus with the intermediate heat-transfer medium in closed tubes passing into or through the conduit walls ; Heat-exchange apparatus employing intermediate heat-transfer medium or bodies in which the medium condenses and evaporates, e.g. heat pipes with tubes having a capillary structure characterised by the material or the construction of the capillary structure
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28—HEAT EXCHANGE IN GENERAL
    • F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F21/00—Constructions of heat-exchange apparatus characterised by the selection of particular materials
    • F28F21/08—Constructions of heat-exchange apparatus characterised by the selection of particular materials of metal
    • F28F21/081—Heat exchange elements made from metals or metal alloys
    • F28F21/084—Heat exchange elements made from metals or metal alloys from aluminium or aluminium alloys
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28—HEAT EXCHANGE IN GENERAL
    • F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F13/00—Arrangements for modifying heat-transfer, e.g. increasing, decreasing
    • F28F13/003—Arrangements for modifying heat-transfer, e.g. increasing, decreasing by using permeable mass, perforated or porous materials
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28—HEAT EXCHANGE IN GENERAL
    • F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F13/00—Arrangements for modifying heat-transfer, e.g. increasing, decreasing
    • F28F13/18—Arrangements for modifying heat-transfer, e.g. increasing, decreasing by applying coatings, e.g. radiation-absorbing, radiation-reflecting; by surface treatment, e.g. polishing
    • F28F13/185—Heat-exchange surfaces provided with microstructures or with porous coatings

Definitions

  • the present invention relates to a porous aluminum heat exchanger for performing heat exchange with a heat medium by using porous aluminum.
  • the heat exchanger is used for exchanging heat energy between two fluids having different heat energy such as between the refrigerant gas and air. More specifically, it is used broadly for heating, cooling, evaporating, and condensing of the fluids by transferring heat efficiently from an object having high temperature to an object having low temperature.
  • such an heat exchanger is installed in the steam generator and the condenser of the boiler; in the indoor unit and the discharger of the air conditioner; in the radiator of the automotive part; and the like.
  • the heat pipe which is an example of such a heat exchanger, is capable of heating or cooling the other fluid around the pipe such as air by tubing one fluid such as liquefied refrigerant gas in the pipe as a heat medium; and generating a heat cycle of evaporation (absorption of the latent heat) and condensation (release of the latent heat) of the refrigerant gas.
  • the other fluid performs heat transport.
  • the heat medium can be transferred by utilizing the capillary force of these fine grooves even in the absence of height difference between the one end (evaporating side) and the other end (condensing side) of the pipe, for example (refer Patent Literature 1 (PTL 1), for example).
  • Patent Literature 2 (PTL 2), for example).
  • Patent Literature 3 (PTL 3), for example).
  • the heat pipe disclosed in PTL 1 has a problem that the amount of the heat medium retained is limited since there is a strong limitation for the length of the grooves formed in the pipe.
  • the heat pipe disclosed in PTL 2 has a problem that heat transfer cannot be performed efficiently between the pipe and the heat medium retained by the fibers since the inner wall of the pipe and the fibers only form contacting parts in a linear shape.
  • the aluminum fibers are used for retaining the heat medium.
  • the heat pipe disclosed in PTL 3 has a problem that the holding force of the heat medium is reduced since the porosity of the aluminum fibers is reduced adversely by increasing the compression ratio.
  • the heat medium includes water
  • hydrophilicity impartation processing is needed on the surface of the aluminum fibers since the surface of the aluminum fibers has inferior wettability. Such an extra processing increases the production cost.
  • the present invention is made under the circumstances explained above.
  • the purpose of the present invention is to provide a porous aluminum heat exchanger having high holding ability of the heat medium and excellent thermal conductivity, which is capable of being produced at low cost.
  • An aspect of the present invention is a porous aluminum heat exchanger as defined in claim 1 (hereinafter, referred as "the porous aluminum heat exchanger of the present invention") including: a porous aluminum body in which aluminum substrates are sintered to each other; and a bulk body made of metal or metal alloy, wherein pillar-shaped protrusions projecting toward the outside are formed on outer surfaces of the aluminum substrates, and pores of the porous aluminum body are configured to form flow channels of a heat medium.
  • porous aluminum heat exchanger of the present invention microscopic spaces are formed without increasing the compression ratio by using the sintered compact of the aluminum substrates, on surfaces of which pillar-shaped protrusions are formed, as the porous aluminum body constituting the porous aluminum heat exchanger.
  • the capillary force can be increased. Because of this, heat exchange can be performed efficiently by the porous aluminum body.
  • the holding ability of the heat medium is increased in the porous aluminum body since the capillary force is increased without increasing the compression ratio in the porous aluminum body.
  • heat exchange in a large volume can be performed.
  • the pillar-shaped protrusions are formed on the surfaces of the porous aluminum body; and a high capillary force is obtained by the microscopic spaces formed with the pillar-shaped protrusions.
  • the heat medium is absorbed efficiently and retained without hydrophilic treatment imparting hydrophilicity to the surface of the porous aluminum body.
  • no cost is needed for the hydrophilic treatment, and the porous aluminum heat exchanger can be produced at low cost.
  • the bulk body may be an aluminum bulk body made of aluminum or aluminum alloy.
  • the porous aluminum heat exchanger which is formed in one-piece by sintering the porous aluminum body and the aluminum bulk body, can be produced.
  • a substrate junction in which the aluminum substrates are bonded each other, may include a Ti-Al compound, and the substrate junction may be formed on the pillar-shaped protrusions.
  • the capillary force is further increased since a number of microscopic spaces are secured in the porous aluminum body.
  • the holding ability of the heat medium is increased in the porous aluminum body, making it possible to perform heat exchange efficiently.
  • the bonding strength between each of porous aluminum substrates can be improved significantly since the substrate junction includes the Ti-Al compound.
  • invasion of melted aluminum into the porous part can be suppressed since the melt flow of aluminum is suppressed by the Ti-Al compound.
  • a high porosity can be secured in the porous aluminum body.
  • a specific surface area of the porous aluminum body may be 0.020m 2 /g or more, and a porosity of the porous aluminum body may be in a range of 30% or more and 90% or less.
  • the specific surface area of the porous aluminum body is set to 0.020m 2 /g or more. Accordingly, it has a large surface area per the unit mass, making it possible to perform heat exchange efficiently by increasing the holding ability of the heat medium.
  • the porosity of the porous aluminum body is set in a range of 30% or more and 90% or less. Thus, the porous aluminum heat exchanger having the optimum porosity depending on the application can be provided.
  • the aluminum bulk body may be an aluminum pipe.
  • the fluid holding heat energy for evaporating or condensing the heat medium can be circulated efficiently.
  • heat exchange between the fluid and the heat medium can be performed efficiently by the high thermal conductivity of aluminum.
  • the aluminum substrates may be one of or both of aluminum fibers and an aluminum powder.
  • the porous aluminum body By using one of or both of aluminum fibers and an aluminum powder as the aluminum substrates, a number of microscopic spaces are secured in the porous aluminum body and the capillary force is increased. Thus, the holding ability of the heat medium in the porous aluminum body is increased, making it possible for heat exchange to be performed efficiently.
  • the porous aluminum body in any shape can be obtained easily during formation of the porous aluminum body from the aluminum substrates.
  • the porous aluminum body and the aluminum bulk body may form one-piece part in which the porous aluminum body and the aluminum bulk body are bonded each other by sintering.
  • the porous aluminum heat exchanger can be used as an entirely integrated single block part. Accordingly, ease of handling of the porous aluminum heat exchanger during installation into a larger machine can be improved. At the same time, thermal resistance at the bonding interface is low, since the porous aluminum body and the aluminum bulk body are bonded metallically. Thus, heat exchange can be performed efficiently.
  • a junction in which the aluminum substrates and the aluminum bulk body are bonded, may include a Ti-Al compound, and the junction is formed on the pillar-shaped protrusions.
  • the porous aluminum substrates and the aluminum bulk body can be used as an integrated single block part by high bonding strength.
  • the bonding strength between the aluminum substrates and the aluminum bulk body can be improved significantly since the junction, in which the aluminum substrates and the aluminum bulk body are bonded, includes the Ti-Al compound,
  • porous aluminum heat exchanger of the present invention a porous aluminum heat exchanger having high holding ability of the heat medium and excellent thermal conductivity, which is capable of being produced at low cost, can be provided.
  • heat medium in the following explanations means fluent material (fluid) flowing holding heat, and includes liquid, gaseous body (gas) formed by the liquid being evaporated, mist in which liquid and gas are mixed, and the like when there is no specific explanation.
  • the loop heat pipe is explained as an example of the porous aluminum heat exchanger of the present invention.
  • FIG. 1 is a cross-sectional view showing the heat pipe, which is an example of the porous aluminum heat exchanger of the present invention.
  • the loop heat pipe (the porous aluminum heat exchanger) 10 includes: the evaporator 11; the condenser 12; the stem pipe 13 in which the heat medium M is transferred between the evaporator 11 and the condenser 12; and the liquid pipe 14.
  • the evaporator 11 vaporizes (evaporates) the liquefied heat medium M. In this process, heat is absorbed in the vicinity of the evaporator 11 by the vaporization heat of the heat medium M.
  • the condenser 12 liquefies (condenses) the vaporized heat medium M.
  • the heat medium M vaporized by the evaporator 11 is sent to the condenser 12 through the steam pipe 13.
  • the heat medium M liquefied by the condenser 12 is sent to the evaporator 11 through the liquid pipe 14.
  • the heat medium M may be chosen from various heat medium, such as: water; chlorofluorocarbon; alternative chlorofluorocarbon; carbon dioxide; ammonia; and the like, according to the purpose.
  • the circulation cycle in which heat is absorbed in the evaporator 12 and heat is released in the condenser 12, is formed by circulating the heat medium M between the evaporator 11 and the condenser 12 and repeating evaporation and liquefaction of the heat medium M.
  • the gas liquid-balance regulator which is called a reservoir, may be provided on the front side of the evaporator 11.
  • the evaporator 11 of the loop heat pipe 10 can be used as the heat exchanger that absorbs waste heat of a heat source and cools surrounding environment by vaporization heat, for example.
  • the evaporator 11 is made of the hollow aluminum pipe (the aluminum bulk body) 21, which is the balk body, and the porous aluminum body 22, which is provided long the inner circumference surface 21a of the aluminum pipe (the aluminum bulk body) 21.
  • the aluminum pipe (the aluminum bulk body) 21 is made of aluminum or aluminum alloy, and constituted from the Al-Mn alloy such as A1070, A3003, and the like; Al-Mg alloy such as A5052 and the like; or the like in the present embodiment.
  • the aluminum pipe 21 is formed by extrusion work, for example, and one having the dimension of; about 5 mm to 150 mm of the outer diameter; about 0.8 mm to 10 mm of the wall thickness, is used, for example.
  • the aluminum substrates 31 are sintered to be integrated into one-piece.
  • the specific surface area is set to 0.020 m 2 /g or more, and the porosity is set in the range of 30% or more and 90% or less.
  • FIG. 2 is a conceptual diagram showing the porous aluminum body 22.
  • the aluminum fibers 31a and the aluminum powder 31b are sued as the aluminum substrates 31.
  • the porous aluminum body 22 has the structure, in which the pillar-shaped protrusions 32 projecting toward the outside are formed on the outer surfaces of the aluminum substrates 31 (the aluminum fibers 31a and the aluminum powder 31b); and the aluminum substrates 31 (the aluminum fibers 31a and the aluminum powder 31b) are bonded each other through the pillar-shaped protrusions 32.
  • the substrate junctions 35 between the aluminum substrates 31, 31 include: a part in which the pillar-shaped protrusions 32, 32 are bonded each other; a part in which the pillar-shaped protrusion 32 and the side surface of the aluminum substrate 31 are bonded each other; and a part in which the side surfaces of the aluminum substrates 31, 31 are bonded each other.
  • pillar-shaped protrusions 32 projecting toward the outside are formed on the outer surfaces of one or both of the aluminum pipe (the aluminum bulk body) 21 and the porous aluminum body 22; and the inner wall surface of the aluminum pipe 21 and the porous aluminum body 22 are bonded through these pillar-shaped protrusions 32, as shown in FIG. 3 .
  • the junctions 39 between the inner wall of the aluminum pipe 21 and the porous aluminum body 22 are formed by the pillar-shaped protrusions 32.
  • the junction 39 between the inner wall of the aluminum pipe 21 and the porous aluminum body 22 bonded through the pillar-shaped protrusions 32 includes the Ti-Al compound 36 and the eutectic element compound 37 including a eutectic element capable of eutectic reaction with Al as shown FIG. 4 .
  • the Ti-Al compound 36 is a compound of Ti and Al in the present embodiment as shown in FIG. 4 . More specifically, it is Al 3 Ti intermetallic compound.
  • the aluminum substrates 31, 31 are bonded each other in the part where the Ti-Al compound 36 exists in the present embodiment.
  • the aluminum pipe 21 and the porous aluminum body 22 are bonded in the part including the Ti-Al compound 36 in the present embodiment.
  • the eutectic element capable of eutectic reaction with Al Ag, Au, Ba, Be, Bi, Ca, Cd, Ce, Co, Cu, Fe, Ga, Gd, Ge, In, La, Li, Mg, Mn, Nd, Ni, Pd, Pt, Ru, Sb, Si, Sm, Sn, Sr, Te, Y, Zn, and the like are named, for example.
  • the eutectic element compound 37 includes Ni, Mg and Si as the eutectic element as shown in FIG. 4 .
  • the substrate junctions 35 between the aluminum substrates 31, 31 each other, which are bonded through the pillar-shaped protrusions 32, include the Ti-Al compound and the eutectic element compound including a eutectic element capable of eutectic reaction with Al.
  • the Ti-Al compound is a compound of Ti and Al. More specifically, it is Al 3 Ti intermetallic compound.
  • the eutectic element compound includes Ni, Mg and Si, is shown. In other words, the aluminum substrates 31, 31 are bonded each other in the part including the Ti-Al compound in the present embodiment.
  • the aluminum raw material for sintering 40 which is the raw material of the porous aluminum body 22, is explained.
  • the aluminum raw material for sintering 40 includes: the aluminum substrate 31; and the titanium powder grains 42 and the eutectic element powder grains 43 (for example, the nickel powder grains, the magnesium powder grains, the silicon powder grains, or the like), both of which are adhered on the outer surface of the aluminum substrate 31, as shown in FIGS. 6A and 6B .
  • the titanium powder grains 42 any one or both of the metal titanium powder grains and the titanium hydride powder grains can be used.
  • the eutectic element powder grains 43 for example, the nickel powder grains, the magnesium powder grains, the silicon powder grains, or the like
  • the metal nickel powder grains; the metal magnesium powder grains; the metal copper powder grains; the metal silicon powder grains; and the like for example.
  • the content amount of the titanium powder grains 42 is set in the range of 0.1 mass% or more and 20 mass% or less. In the present embodiment, it is set to 0.5-10 mass%.
  • the grain size of the titanium powder grains 42 is set in the range of 1 ⁇ m or more and 50 ⁇ m or less. Preferably, it is set to 2 ⁇ m or more and 30 ⁇ m or less.
  • the titanium hydride powder grains can be set to a value finer than that of the metal titanium powder grains. Thus, in the case where the grain size of the titanium powder grains 42 adhered on the outer surface of the aluminum substrate 31 is set to a fine value, it is preferable that the titanium hydride powder grains are used.
  • the distance between the titanium powder grains 42, 22 adhered on the outer surface of the aluminum substrate 31 is set in the range of 5 ⁇ m or more and 100 ⁇ m or less.
  • the content amount of the eutectic element powder grains 43 (for example, the nickel powder grains, the magnesium powder grains, the silicon powder grains, or the like) is in the range of 0.1 mass% or more and 5 mass% or less. In the present embodiment, it is set to 1.0-2.0 mass%.
  • the grain size of the eutectic element powder grains 43 (for example, the nickel powder grains, the magnesium powder grains, the silicon powder grains, or the like) is set in the range of 0.5 ⁇ m or more and 20 ⁇ m or less. Preferably, it is set in the range of 1 ⁇ m or more and 10 ⁇ m or less.
  • the aluminum substrate 31 As the aluminum substrate 31, the aluminum fibers 31a and the aluminum powder 31b are used as described above.
  • As the aluminum powder 31b an atomized powder can be used.
  • the fiber diameter of the aluminum fiber 31a is set in the range of 40 ⁇ m or more and 300 ⁇ m or less. Preferably, it is set in the range of 50 ⁇ m or more and 200 ⁇ m or less.
  • the fiber length of the aluminum fiber 31a is set in the range of 0.2 mm or more and 20 mm or less. Preferably, it is set in the range of 1 mm or more and 10 mm or less.
  • the grain size of the aluminum powder 31b is set in the range of 10 ⁇ m or more and 300 ⁇ m or less. Preferably, it is set in the range of 20 ⁇ m or more and 100 ⁇ m or less.
  • the porosity can be controlled by adjusting the mixing rate of the aluminum fibers 31a and the aluminum powder 31b. More specifically, the porosity of the porous aluminum body 22 can be improved by increasing the ratio of the aluminum fiber 31a.
  • P D ⁇ C / D ⁇ 100 %
  • the porosity of the porous aluminum body 22 is set in the range of 30% or more and 90% or less.
  • the specific surface area of the porous aluminum body 22 is set to 0.020 m 2 /g or more.
  • the specific surface area S is defined by the following formula 2 when: V (cm 3 ) is the volume of the porous aluminum body 22; ⁇ (g/cm 3 ) is the density of the porous aluminum body 22; and A (m 2 ) is the surface area of the porous aluminum body 22.
  • V (cm 3 ) is the volume of the porous aluminum body 22
  • ⁇ (g/cm 3 ) is the density of the porous aluminum body 22
  • a (m 2 ) is the surface area of the porous aluminum body 22.
  • the aluminum fibers 31a are used as the aluminum substrates 31.
  • the ratio of the aluminum powder 31b in the aluminum substrates 31 is set to 10-15 mass% or less.
  • the aluminum raw material for sintering 40 is produced as shown in FIG. 5 .
  • the above-described aluminum substrates 31, the titanium powder, and the eutectic element powder (for example, the nickel powder grains, the magnesium powder grains, the silicon powder grains, or the like) are mixed at room temperature (the step of mixing S01). At this time, the binder solution is sprayed on.
  • the binder what is burned and decomposed during heating at 500°C in the air is preferable. More specifically, using an acrylic resin or a cellulose-based polymer material is preferable.
  • various solvents such as the water-based, alcohol-based, and organic-based solvents can be used as the solvent of the binder.
  • the aluminum substrates 31, the titanium powder, and the eutectic element powder are mixed by various mixing machine, such as an automatic mortar, a pan type rolling granulator, a shaker mixer, a pot mill, a high-speed mixer, a V-shaped mixer, and the like, while they are fluidized.
  • various mixing machine such as an automatic mortar, a pan type rolling granulator, a shaker mixer, a pot mill, a high-speed mixer, a V-shaped mixer, and the like, while they are fluidized.
  • the titanium powder grains 42 and the eutectic element powder grain 43 are dispersedly adhered on the surfaces of the aluminum substrates 31 as shown in FIGS. 6A and 6B ; and the aluminum raw material for sintering 40 in the present embodiment is produced.
  • the aluminum pipe (aluminum bulk body) 21 is arranged as shown in FIG. 8 (a) , and the jig G in the cylindrical shape is set in such a way that the jig G penetrates through from the one open surface to the other open surface of the aluminum pipe 21 (the step of arranging aluminum bulk body S03).
  • the material capable of being withdrawn after the step of sintering, which is described later is chosen. In other words, the material not adhering to the porous aluminum body 22 is chosen.
  • carbon, and tungsten alloy (Anviloy R ) can be used, for example.
  • the aluminum raw material for sintering 40 is sprayed between the inner wall surface of the aluminum pipe 21 and the jig G to bulk fill the space as shown in FIG. 8 (b) (the step of spraying raw material S04).
  • the binder is removed by heating it under air atmosphere (the step of removing binder S05).
  • the step of sintering S06 is inserted into the sintering furnace and kept at the temperature range of 600-660°C for 0.5-60 minutes under an inert gas atmosphere (the step of sintering S06). It is preferable to set the retention time to 1 to 20 minutes.
  • the dew point can be reduced sufficiently by setting the sintering atmosphere in the step of sintering S06 to the inert gas atmosphere such as Ar gas or the like.
  • the hydrogen atmosphere or the mixed atmosphere of hydrogen and oxygen is not preferable since a reduced dew point is hard to obtain.
  • nitrogen is not preferable since it reacts with Ti to form TiN for the sintering stimulating effect of Ti to be lost.
  • the aluminum substrates 31 in the aluminum raw material for sintering 40 are melted. Since the oxide films are formed on the surfaces of the aluminum substrates 31, the melted aluminum is held by the oxide film; and the shapes of the aluminum substrates 31 are maintained.
  • the oxide files are destroyed by the reaction with titanium; and the melted aluminum inside spouts out.
  • the spouted out melted aluminum forms a high-melting point compound by reacting with titanium to be solidified.
  • the pillar-shaped protrusions 32 projecting toward the outside are formed on the outer surfaces of the aluminum substrates 31 as shown in FIGS. 7A and 7B .
  • the Ti-Al compound 36 exists on the tip of the pillar-shaped protrusion 32. Growth of the pillar-shaped protrusion 32 is suppressed by the Ti-Al compound 36.
  • titanium hydride is used as the titanium powder grains 42, titanium hydride is decomposed near the temperature of 300°C to 400°C; and the produced titanium reacts with the oxide films on the surfaces of the aluminum substrates 31.
  • locations having a lowered melting point are formed locally to the aluminum substrates 31 by the eutectic element powder grains 43 (for example, the nickel powder grains, the magnesium powder grains, the silicon powder grains, or the like) adhered on the outer surfaces of the aluminum substrates 31. Therefore, the pillar-shaped protrusions 32 are formed reliably even in the relatively low temperature condition such as 640°C to 650°C.
  • the adjacent the aluminum substrates 31, 31 are bonded each other by being combined integrally in a molten state or being sintered in a solid state through the pillar-shaped protrusions 32 of each. Accordingly, the porous aluminum body 22, in which the aluminum substrates 31, 31 are bonded each other through the pillar-shaped protrusions 32 as shown in FIG. 2 , is produced.
  • the substrate junction 35 in which the aluminum substrates 31, 31 are bonded each other through the pillar-shaped protrusion 32, includes the Ti-Al compound (Al 3 Ti intermetallic compound in the present embodiment) and the eutectic element compound.
  • the aluminum pipe 21 and the porous aluminum body 22 are bonded through the pillar-shaped protrusions 32 by the pillar-shaped protrusions 32 of the aluminum substrates 31 constituting the porous aluminum body 22 being bonded to the inner wall surface of the aluminum pipe (aluminum bulk body) 21 as shown in FIGS. 3 and 4 .
  • the eutectic element powder grains 43 for example, the nickel powder grains, the magnesium powder grains, the silicon powder grains, or the like
  • the pillar-shaped protrusions 32 are formed from the surface of the aluminum pipe 21; and the aluminum pipe 21 and the porous aluminum body 22 are bonded.
  • the junction 39 in which the aluminum pipe 21 and the porous aluminum body 22 are bonded through the pillar-shaped protrusions 32, includes the Ti-Al compound 36 (Al 3 Ti intermetallic compound in the present embodiment) and the eutectic element
  • the jig G is withdrawn from the porous aluminum body 22 bonded to the aluminum pipe 21 as shown in FIG. 8 (c) . Because of this, the hollow space in the cylindrical shape in the central part the porous aluminum body 22 is formed.
  • the hollow space functions as the space which the liquefied heat medium M flows in from the liquid pipe 14 when it is used as the evaporator 11 of the loop heat pipe 10.
  • the outer shape of the jig G may include concavity and convexity in a simple concavo-convex shape or spiral shape, as long as it can be withdrawn after sintering.
  • the aluminum substrates 31, 31, in which a number of pillar-shaped protrusions 32 are formed on their surfaces and are bonded through each of the pillar-shaped protrusions 32, are used as the porous aluminum body 22 of the evaporator 11.
  • the microscopic spaces are formed without increasing the compression ratio to increase the capillary force. Because of this, the liquid absorbency of the porous aluminum body 22 for the heat medium M is increased. Thus, heat exchange can be performed efficiently.
  • the capillary force is the force absorbing liquid.
  • H is the liquid absorption height
  • Y is the surface area per unit volume of the porous aluminum body 22
  • Z is the surface tension
  • ⁇ is the wetting angle of the liquid against aluminum
  • E is the density of the liquid
  • P is the porosity of the porous aluminum body 22
  • J is the gravitational acceleration.
  • the specific surface area and the porosity of the porous aluminum body 22 can be kept in the range of: 0.020m 2 /g or more; and 30% or more and 90% or less, respectively, since the capillary force is increased without reducing the porosity by increasing the compression ratio of the porous aluminum body 22. Because of this, the holding ability (liquid volume to be retained) of the heat medium M in the porous aluminum body 22 is increased; and heat exchange of a large volume can be performed. If the porosity were less than 30%, the holding ability of the heat medium M would be too low; and it would be possible that sufficient heat transportation (propagation) cannot be performed. If the porosity exceeded 90%, the mechanical strength would become too low; and it would be possible that the porous aluminum body 22 is damaged by impact or the like.
  • the aluminum substrates 31, 31, in which a number of pillar-shaped protrusions 32 are formed on their surfaces and are bonded through each of the pillar-shaped protrusions 32, are used as the porous aluminum body 22 of the evaporator 11.
  • the liquid absorbency is increased due to the high capillary force; and high movability of the liquid in the porous aluminum body 22 is obtained.
  • the heat medium M can be absorbed and retained efficiently; and heat exchange can be performed efficiently, without performing the hydrophilic treatment for imparting hydrophilicity to the surface of the porous aluminum body 22.
  • the cost for performing the hydrophilic treatment is not needed and the loop heat pipe 10 can be produced at low cost, since the porous aluminum body 22 can absorb and retain the heat medium M efficiently without performing the hydrophilic treatment.
  • the inner wall surface 21a of the aluminum pipe 21 and the porous aluminum body 22 are bonded through the junctions 39. Because of this, heat conduction between the aluminum pipe 21 and the porous aluminum body 22 can be performed efficiently. Thus, the heat absorbing property of the evaporator 11 can be improved; and the loop heat pipe 10 capable of efficient heat exchanging can be obtained.
  • the aluminum pipe 21 and the porous aluminum body 22 constituting the loop heat pipe 10 are bonded each other through the junctions 39.
  • the porous aluminum body 22 is placed at the inside of the aluminum pipe 21 free of a specific bonding between the aluminum pipe 21 and the porous aluminum body 22.
  • FIG. 9 is an explanatory drawing showing the method of producing the evaporator constituting the loop heat pipe of the second embodiment of the present invention. Configurations other than the evaporator are the same as the loop heat pipe of the first embodiment.
  • the mold Q1 which has the hollow molding space in the cylindrical shape, is arranged as shown in FIG. 9 (a) . Then, the molding space is filled with the aluminum sintering material for sintering 40. Then, press molding is performed by pressing the pressing part Q2 in the shape of molding space to the aluminum raw material for sintering 40 filling the molding space.
  • the green compact of the press-molded aluminum raw material for sintering 40 is taken out from the mold Q1 (refer FIG. 9 (a) ) as shown in FIG 9 (b) , and inserted in the degreasing furnace to remove the binder by heating under the air atmosphere.
  • the sintering furnace by inserting in the sintering furnace, it is retained in the temperature range of 640-660°C for 0.5-60 minutes under the inert gas atmosphere. It is preferable that the retention time is 1-20 minutes.
  • the pillar-shaped protrusions 32 projecting toward the outside are formed on the outer surfaces of the aluminum substrates 31 as shown in FIGS. 7A and 7B .
  • the Ti-Al compound 36 exists on the tip of the pillar-shaped protrusion 32. Growth of the pillar-shaped protrusion 32 is suppressed by the Ti-Al compound 36.
  • titanium hydride is used as the titanium powder grains 42, titanium hydride is decomposed near the temperature of 300°C to 400°C; and the produced titanium reacts with the oxide films on the surfaces of the aluminum substrates 31.
  • the adjacent the aluminum substrates 31, 31 are bonded each other by being combined integrally in a molten state or being sintered in a solid state through the pillar-shaped protrusions 32 of each. Accordingly, the porous aluminum body 52, in which the aluminum substrates 31, 31 are bonded each other through the pillar-shaped protrusions 32, is produced.
  • correction processing may be performed by inserting the sintered porous aluminum body 52 into a mold.
  • the porous aluminum body 52 obtained by sintering is inserted to the inside of the aluminum pipe 21, which is the bulk body, to be fixed as shown in FIG. 9 (c) .
  • the evaporator 51 constituting the loop heat pipe of the second embodiment can be obtained.
  • porous aluminum heat exchanger which uses the multi-port tube of the third embodiment of the present invention, is explained.
  • FIG. 10 is an enlarged perspective view of the main part showing the porous aluminum heat exchanger of the present invention.
  • the porous aluminum heat exchanger 60 has the structure in which the porous aluminum body 22, which is made of aluminum or aluminum alloy, and the aluminum multi-port tube (aluminum bulk body) 62, which is a bulk body and made of aluminum or aluminum alloy, are bonded.
  • the porous aluminum heat exchanger 60 of the present embodiment is used as an evaporator or a condenser, for example, and includes: the aluminum multi-port tube (aluminum bulk body) 62 with the passages, in which the fluid Ma that becomes the first heat medium circulates; and the porous aluminum body 22, which is bonded to at least a part of the outer peripheral surface of the aluminum multi-port tube 62, as shown in FIG. 10 .
  • the aluminum multi-port tube 62 is made of aluminum or aluminum alloy, and constituted from the Al-Mn alloy such as A1070, A3003, and the like; Al-Mg alloy such as A5052 and the like; or the like in the present embodiment.
  • the aluminum multi-port tube 62 is formed by extrusion work, for example; has a flat shape; and includes the multiple through holes 63, 63..., which are passages the fluid Ma circulates therein, as shown in FIG. 10 .
  • the aluminum substrates 31 are sintered to be integrated into one-piece as shown in FIG. 2 .
  • the specific surface area is set to 0.020 m 2 /g or more, and the porosity is set in the range of 30% or more and 90% or less.
  • the porous aluminum body 22 one equivalent to the porous aluminum body 22 in the first embodiment is used.
  • the porous aluminum body 22 is configured: to include evaporable liquid; the dried fluid Mb1 to circulate around the aluminum multi-port tube 62; and the through holes 63, 63 to be passages of the high temperature fluid Ma.
  • the dried fluid Mb1 is converted to the fluid Mb2, which contains evaporated liquid, by the heat of the fluid Ma heating and evaporating the liquid contained in the porous aluminum body 22 through the porous aluminum body 22 while the fluid Ma flows the region on which the porous aluminum body 22 is formed on the aluminum multi-port tube 62.
  • the liquid contained in the porous aluminum body 22 is chlorofluorocarbon
  • the fluid Ma is warm water
  • the fluid Mb1 is a dried argon atmosphere
  • it can be used as the evaporator capable of including the steam of chlorofluorocarbon in the fluid Mb1 by evaporating chlorofluorocarbon (vaporizing).
  • the pillar-shaped protrusions 32 shown in FIGS. 7A and 7B behave as boiling nuclei for boiling; and steam can be supplied more efficiently.
  • the porous aluminum body 22 is configured: to be passages for the high temperature fluid Mb1 including steam; and the through holes 63, 63 of the aluminum multi-port tube 62 to be passages for the low temperature fluid Ma.
  • the porous aluminum body 22 is cooled by the fluid Ma; and the steam contained in the fluid Mb is condensed on the surface of the porous aluminum body 22, while the fluid Ma circulates in the region, on which the porous aluminum body 22 is formed, on the aluminum multi-port tube 62.
  • the fluid Ma is cooling water; and the steam contained in the fluid Mb is steam of chlorofluorocarbon, it can be used as the condenser in which chlorofluorocarbon is liquefied by the cooling water.
  • the pillar-shaped protrusions 32 shown in FIGS. 7A and 7B behave as condensing nuclei for condensing; and steam can be liquefied more efficiently.
  • porous aluminum heat exchanger which uses the multi-port tube of the third embodiment of the present invention, is explained.
  • FIG. 11 is an enlarged perspective view of the main part showing the porous aluminum heat exchanger of the present invention.
  • the porous aluminum heat exchanger 70 has the structure in which the porous aluminum body 22, which is made of aluminum or aluminum alloy, and the multiple aluminum pipes (aluminum bulk body) 72, 72..., which are made of aluminum or aluminum alloy, are bonded.
  • the porous aluminum heat exchanger 70 of the present embodiment is used as an evaporator or a condenser, for example, and includes: the multiple aluminum pipes (aluminum bulk body) 72, which are configured to be passages for the fluid Ma and are bulk bodies (two stacks of 6-pipes are arranged in two in FIG. 11 ); and the porous aluminum body 22, which is bonded to at least a part of the outer peripheral surface of the aluminum pipes 72, as shown in FIG. 11 .
  • 12 aluminum pipes (aluminum bulk body) 72 are formed to penetrate the porous aluminum body in the rectangular parallelepiped shape in FIG. 11 .
  • the aluminum pipes 72, 72... are made of aluminum or aluminum alloy, and constituted from the Al-Mn alloy such as A1070, A3003, and the like; Al-Mg alloy such as A5052 and the like; or the like in the present embodiment.
  • the aluminum substrates 31 are sintered to be integrated into one-piece as shown in FIG. 2 .
  • the specific surface area is set to 0.020 m 2 /g or more, and the porosity is set in the range of 30% or more and 90% or less.
  • the porous aluminum body 22 one equivalent to the porous aluminum body 22 in the first embodiment is used.
  • the porous aluminum body 22 is configured: to include evaporable liquid; the dried fluid Mb1 to circulate around the aluminum pipes 72; and the aluminum pipes 72 to be passages of the high temperature fluid Ma.
  • the dried fluid Mb1 is converted to the fluid Mb2, which contains evaporated liquid, by the heat of the fluid Ma heating and evaporating the liquid contained in the porous aluminum body 22 through the porous aluminum body 22 while the fluid Ma flows the region on which the porous aluminum body 22 is formed on the aluminum pipes 72.
  • the liquid contained in the porous aluminum body 22 is chlorofluorocarbon
  • the fluid Ma is warm water
  • the fluid Mb1 is a dried argon atmosphere
  • it can be used as the evaporator capable of including the steam of chlorofluorocarbon in the fluid Mb1 by evaporating chlorofluorocarbon (vaporizing).
  • the pillar-shaped protrusions 32 shown in FIGS. 7A and 7B behave as boiling nuclei for boiling; and steam can be supplied more efficiently.
  • the porous aluminum heat exchanger 70 configured as described above is used as the condenser, the porous aluminum body 22 is configured: to be passages for the high temperature fluid Mb1 including steam; and the aluminum pipes 72 to be passages for the low temperature fluid Ma.
  • the porous aluminum body 22 is cooled by the fluid Ma; and the steam contained in the fluid Mb is condensed on the surface of the porous aluminum body 22.
  • the fluid Ma is cooling water; and the steam contained in the fluid Mb is steam of chlorofluorocarbon, it can be used as the condenser in which chlorofluorocarbon is liquefied by the cooling water.
  • the pillar-shaped protrusions 32 shown in FIGS. 7A and 7B behave as condensing nuclei for condensing; and steam can be liquefied more efficiently.
  • porous aluminum heat exchanger which uses the bent aluminum pipe of the fifth embodiment of the present invention, is explained.
  • FIG. 12 is an enlarged perspective view of the main part showing the porous aluminum heat exchanger of the present invention.
  • the porous aluminum heat exchanger 80 has the structure in which the porous aluminum body 22, which is made of aluminum or aluminum alloy, and the bent aluminum pipe (aluminum bulk body) 82, which is a bulk body and made of aluminum or aluminum alloy, are bonded.
  • the porous aluminum heat exchanger 80 of the present embodiment is used as an evaporator or a condenser, for example, and includes: the aluminum pipe bent in a U-shape (aluminum bulk body) 82, which is configured to be a passage that the fluid Ma circulates and a bulk body; and the porous aluminum body 22, which is bonded to at least a part of the outer peripheral surface of the bent aluminum pipe 72 including the bent part, as shown in FIG. 12 .
  • U-shape aluminum bulk body
  • the bent aluminum pipe 82 is made of aluminum or aluminum alloy, and constituted from the Al-Mn alloy such as A1070, A3003, and the like; Al-Mg alloy such as A5052 and the like; or the like in the present embodiment.
  • the aluminum substrates 31 are sintered to be integrated into one-piece as shown in FIG. 2 .
  • the specific surface area is set to 0.020 m 2 /g or more, and the porosity is set in the range of 30% or more and 90% or less.
  • the porous aluminum body 22 one equivalent to the porous aluminum body 22 in the first embodiment is used.
  • the porous aluminum body 22 is configured: to include evaporable liquid; the dried fluid Mb1 to circulate around the bent aluminum pipe 82 to be the passage of the high temperature fluid Ma.
  • the dried fluid Mb1 is converted to the fluid Mb2, which contains evaporated liquid, by the heat of the fluid Ma heating and evaporating the liquid contained in the porous aluminum body 22 through the porous aluminum body 22 while the fluid Ma flows the region on which the porous aluminum body 22 is formed on the bent aluminum pipe 82.
  • the liquid contained in the porous aluminum body 22 is chlorofluorocarbon
  • the fluid Ma is warm water
  • the fluid Mb1 is a dried argon atmosphere
  • it can be used as the evaporator capable of including the steam of chlorofluorocarbon in the fluid Mb1 by evaporating chlorofluorocarbon (vaporizing).
  • the pillar-shaped protrusions 32 shown in FIGS. 7A and 7B behave as boiling nuclei for boiling; and steam can be supplied more efficiently.
  • the porous aluminum heat exchanger 80 configured as described above is used as the condenser, the porous aluminum body 22 is configured: to be passages for the high temperature fluid Mb1 including steam; and the bent aluminum pipe 82 to be the passage for the low temperature fluid Ma.
  • the porous aluminum body 22 is cooled by the fluid Ma; and the steam contained in the fluid Mb is condensed on the surface of the porous aluminum body 22, while the fluid Ma circulates in the region, on which the porous aluminum body 22 is formed, on the bent aluminum pipe 82.
  • the fluid Ma is cooling water; and the steam contained in the fluid Mb is steam of chlorofluorocarbon, it can be used as the condenser in which chlorofluorocarbon is liquefied by the cooling water.
  • the pillar-shaped protrusions 32 shown in FIGS. 7A and 7B behave as condensing nuclei for condensing; and steam can be liquefied more efficiently.
  • porous aluminum heat exchanger which uses the multi-port tube of the sixth embodiment of the present invention, is explained.
  • FIGS. 13A and 13B are a perspective view ( FIG. 13A ) and a cross-sectional view ( FIG. 13B ) showing the porous aluminum heat exchanger of the present invention.
  • the porous aluminum heat exchanger 90 is constituted from multiple fins 91, 91..., which are provided in parallel with a predetermined interspace; and the aluminum pipe (aluminum bulk body) 92, which are bulk bodies and formed in such a way to penetrate though the fins 91, 91....
  • the fins 91, 91... are constituted from the substrate plate (aluminum bulk body) 93 and the porous aluminum body 22 bonded on the surfaces of the substrate plates.
  • the porous aluminum heat exchanger 90 of the present embodiment is used as an evaporator or a condenser, for example;
  • the aluminum pipe (aluminum bulk body) 92 which is configured to be the passage of the fluid Ma to be circulated, is provided in such a way that the aluminum pipe 92 penetrates though in the middle of the substrate plates (aluminum bulk body) 93, 93..., which are aligned equally spaced each other and made of aluminum or aluminum alloy; and these substrate plates 93, 93... and the aluminum pipe (aluminum bulk body) 92 are bonded each other.
  • porous aluminum body 22 is bonded in such a way to cover the surfaces of each of the substrate plates 93.
  • the interspaces between the porous aluminum body 22 and each of adjacent porous aluminum bodies 22 become the passages of the fluid Mb circulated in.
  • the aluminum substrates 31 are sintered to be integrated into one-piece as shown in FIG. 2 .
  • the specific surface area is set to 0.020 m 2 /g or more, and the porosity is set in the range of 30% or more and 90% or less.
  • the porous aluminum body 22 one equivalent to the porous aluminum body 22 in the first embodiment is used.
  • the porous aluminum body 22 is configured: to include evaporable liquid; the dried fluid Mb1 to circulate around the aluminum pipe 92 to be the passage of the high temperature fluid Ma.
  • the dried fluid Mb1 is converted to the fluid Mb2, which contains evaporated liquid, by the heat of the fluid Ma heating and evaporating the liquid contained in the porous aluminum body 22 through the porous aluminum body 22 while the fluid Ma flows the region on which the porous aluminum body 22 is formed on the aluminum pipe 92.
  • the liquid contained in the porous aluminum body 22 is chlorofluorocarbon
  • the fluid Ma is warm water
  • the fluid Mb1 is a dried argon atmosphere
  • it can be used as the evaporator capable of including the steam of chlorofluorocarbon in the fluid Mb1 by evaporating chlorofluorocarbon (vaporizing).
  • the pillar-shaped protrusions 32 shown in FIGS. 7A and 7B behave as boiling nuclei for boiling; and steam can be supplied more efficiently.
  • the porous aluminum heat exchanger 90 configured as described above is used as the condenser, the porous aluminum body 22 is configured: to be the passage for the high temperature fluid Mb1 including steam; and the aluminum pipe 92 to be the passage for the low temperature fluid Ma.
  • the porous aluminum body 22 is cooled through the fluid Ma; and the steam contained in the fluid Mb is condensed on the surface of the porous aluminum body 22, while the fluid Ma circulates in the region of fins 91 of the porous aluminum heat exchanger 90 on the aluminum pipe 92.
  • the fluid Ma is cooling water; and the steam contained in the fluid Mb is steam of chlorofluorocarbon, it can be used as the condenser in which chlorofluorocarbon is liquefied by the cooling water.
  • the pillar-shaped protrusions 32 shown in FIGS. 7A and 7B behave as condensing nuclei for condensing; and steam can be liquefied more efficiently.
  • porous aluminum body and the aluminum bulk body examples, in which they are bonded through the pillar-shaped protrusions, are shown in the embodiments.
  • the porous aluminum body and the aluminum bulk body can be bonded by utilizing various bonding methods, such as brazing using brazing material, diffusion bonding, soldering using soldering material, and the like, alternatively, for example.
  • porous aluminum body and the aluminum bulk body are bonded
  • the present invention is not limited by the description, and the material of the bulk body is not limited to aluminum as long as it is a material capable of being bonded in the varieties of methods such as brazing and the like.
  • a bulk body made of any metal or metal alloy can be chosen regardless of its ability to be bonded.
  • hydrophilic treatment on the porous aluminum body is not performed particularly in the embodiments. However, by performing the hydrophilic treatment on the porous aluminum body further, the holding ability of the heat medium in the porous aluminum body can be increased further.
  • Example of the present invention As aluminum bulk bodies for Example of the present invention and a reference example, aluminum pipes made of A1070, A3003 and A5052 having the dimension of: 12 mm of the outer diameter; and 1 mm of the wall thickness, were prepared. Then, porous aluminum bodies having the pillar-shaped protrusions as shown in FIG. 2 on the inside of the aluminum pipes were formed by sintering.
  • the compositions of the porous aluminum bodies are the compositions shown in Table 1. The porosity; the specific surface area; the height of water pulling; and the water retention capability per unit volume were measured on these Examples 1-8 of the present invention and the reference example. Examples 1-3 of the present invention were the examples in which materials of the pipes were varied.
  • Example 4 of the present invention was an example in which the eutectic element in the aluminum sintered material was Mg.
  • Example 5 of the present invention was an example in which the specific surface area was set to a small value.
  • Example 6 was an example in which the hydrophilic treatment was performed.
  • Example 7 of the present invention was an example in which the specific surface area was set to a large value.
  • Example 8 was an example in which the porosity was set to a small value.
  • the reference example was an example in which the specific surface area was set to a value less than 0.020 m 2 /g.
  • the measurement of the specific surface area was performed based on the BET (Brunauer-Emmett-Teller) method relying on the low-temperature-low-humidity physical absorption of an inert gas.
  • BET Brunauer-Emmett-Teller
  • a sample was inserted in a glass tube having a constant volume.
  • vacuum degassing was performed at 200°C for 60 minutes.
  • nitrogen gas was introduced in the glass tube gradually.
  • the specific surface area of each of samples was calculated from the pressure change during the nitrogen gas introduction and the BET method (three point method)
  • the measurement of the height of water pulling measured by: preparing the porous aluminum body having the dimension of 30mm ⁇ 200mm ⁇ 5mm; immersing the porous aluminum body from the water surface in the depth direction of 5mm, having the direction of 200mm be the height direction; and measuring the height of water reached after 10 minutes.
  • the water tank used was large enough compared to the size of the porous aluminum body; and the change of the location of the water surface due to the water pulling by the porous aluminum body was negligible.
  • the porous aluminum body was immersed in water sufficiently; and the water retention capacity was obtained by dividing the difference of the weights before and after the immersion by the volume of the sintered material.
  • Comparative Example 1 was an example in which the aluminum fibers were subjected to diffusion sintering.
  • Comparative Example 2 was an example in which the aluminum fibers, which were subjected to diffusion sintering, were subjected to hydrophilic treatment.
  • Comparative Example 3 was an example in which the aluminum fibers were compressed and subjected to diffusion sintering.
  • Comparative Example 4 was an example in which the aluminum fibers were only compressed. The porosity; the specific surface area; the height of water pulling; and the water retention capability per unit volume were measured on these Comparative Examples 1-4. The measurement conditions in each measurement were the same as in Example of the present invention.
  • Example of the present invention The verification results in Example of the present invention and Comparative Example are shown in Table 1.
  • Table 1 Pipe material Aluminum fiber sintered material composition Porosity (%) Specific surface area (m 2 /g) Water pulling distance (cm) Water retention capacity per unit volume (g/cm 3 ) Presence or absence of hydrophilic treatment
  • Example of the present invention 1 A1070 Al-5TiH2-1Ni 71 0.051 7.2 7.0 Absent 2 A3003 Al-5TiH2-1Ni 71 0.052 7.3 6.9 Absent 3 A5052 Al-5TiH2-2Ni 72 0.052 7.0 7.1 Absent 4 A1070 Al-5TiH2-1Mg 73 0.061 7.8 7.2 Absent 5 A1070 Al-0.5TiH2-1Ni 71 0.025 3.5 7.0 Absent 6 A1070 Al-5TiH2-1Ni 71 0.051 20 (measurement limit) 7.0 Present 7 A1070 Al-10TiH2-1Ni 67 0.091 15.4 6.8 Absent 8 A10
  • any one of the porous aluminum heat exchanger of Examples of the present invention had an excellent specific surface area compared to the aluminum heat exchanger of Comparative Examples.
  • Example of the present invention had water pulling height higher than Comparative Example, except for Example 5 of the present invention.
  • Example 5 of the present invention had a higher water retention capacity per unit volume than Comparative Examples.
  • Example of the present invention had the water retention capacity per unit volume superior to Comparative Example, except for Example 8 of the present invention.
  • Example 8 of the present invention had the water pulling height higher than Comparative Examples.
  • Example 6 of the present invention was superior to Comparative Example 6 in all categories of: the specific surface are; the water pulling height; and the water retention capacity per unit volume. Based on these result, it was confirmed that the heat exchanger effectiveness to the heat medium was increased in the porous aluminum heat exchanger of the present invention compared to the conventional heat exchanger.
  • the aluminum substrates made of pure aluminum were used in the present embodiment.
  • the present invention is not particularly limited by description; and aluminum substrates made of general aluminum alloy.
  • aluminum substrates made of the A3003 alloy Al-0.6mass%Si-0.7mass%Fe-0.1mass%Cu-1.5mass%Mn-0.1mass%Zn alloy
  • the A5052 alloy Al-0.25mass%Si-0.40mass%Fe-0.10mass%Cu-0.10mass%Mn-2.5mass%Mg alloy-0.2mass%Cr-0.1mass%Zn alloy
  • the like specified in JIS standards can be suitably used.
  • composition of the aluminum substrates is not limited to one specific kind. It can be appropriately adjusted according to the purpose, such as having the aluminum substrate be a mixture made of: pure aluminum fibers; and a powder made of the JIS A3003 alloy, for example.
  • the aluminum bulk body made of aluminum or aluminum alloy was: Al-Mn alloy such as A1070, A3003 and the like; or Al-Mg alloy such as A5052 and the like, in the present embodiment.
  • Al-Mn alloy such as A1070, A3003 and the like
  • Al-Mg alloy such as A5052 and the like
  • the present invention is not limited particularly by the description; and other general aluminum alloy can be used freely.
  • aluminum alloy made of the A2017 alloy Al-0.8mass%Si-0.7mass%Fe-4.5mass%Cu-1.0mass%Mn-0.8mass%Mg-0.1mass%Cr-0. 25mass%Zn-0.15mass%Ti alloy
  • the A7075 alloy Al-0.4mass%Si-0.5mass%Fe-2.0mass%Cu-0.3mass%Mn-2.9mass%Mg-0.28mass%Cr-6.1mass%Zn-0.2mass%Ti alloy
  • the like specified in JIS standards can be suitably used.
  • a high performance heat exchanger can be provided at low cost.

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Claims (7)

  1. Échangeur de chaleur en aluminium poreux (10, 60, 70, 80, 90) comprenant :
    un corps massif (21, 62, 72, 82, 92, 93) réalisé en aluminium ou en alliage métallique ;
    un corps en aluminium poreux (22) prévu le long de la surface de circonférence interne (21a) du corps massif (21) ou de la surface périphérique externe du corps massif (62, 72, 82, 92, 93) où une pluralité de substrats d'aluminium (31, 31a, 31b) sont frittés ensemble ; où
    les pores du corps en aluminium poreux (22) sont configurés pour former des canaux d'écoulement d'un milieu chauffant,
    caractérisé en ce que
    une pluralité de protubérances en forme de pilier (32) projetées vers l'extérieur sont formées sur les surfaces externes des substrats d'aluminium (31, 31a, 31b).
  2. Échangeur de chaleur en aluminium poreux (10, 60, 70, 80, 90) selon la revendication 1, dans lequel une jonction de substrats, dans laquelle la pluralité de substrats d'aluminium (31, 31a, 31b) sont liés entre eux, comporte un composé à base de Ti-Al, et la jonction de substrats est formée sur les protubérances en forme de pilier (32).
  3. Échangeur de chaleur en aluminium poreux (10, 60, 70, 80, 90) selon l'une quelconque des revendications 1 et 2, dans lequel la surface spécifique du corps en aluminium poreux (22) est supérieure ou égale à 0,020 m2/g, et la porosité du corps en aluminium poreux (22) se trouve dans une plage de 30% ou plus et de 90% ou moins.
  4. Échangeur de chaleur en aluminium poreux (10, 60, 70, 80, 90) selon l'une quelconque des revendications 2 et 3, dans lequel, le corps massif en aluminium (21) est un tuyau en aluminium (21, 72, 82, 92, 93).
  5. Échangeur de chaleur en aluminium poreux (10, 60, 70, 80, 90) selon l'une quelconque des revendications 1 à 4, dans lequel les substrats d'aluminium (31, 31a, 31b) sont des fibres d'aluminium et/ou une poudre d'aluminium.
  6. Échangeur de chaleur en aluminium poreux (10, 60, 70, 80, 90) selon l'une quelconque des revendications 2 à 5, dans lequel le corps en aluminium poreux (22) et le corps massif en aluminium (21, 62, 72, 82, 92, 93) sont liés entre eux par frittage.
  7. Échangeur de chaleur en aluminium poreux (10, 60, 70, 80, 90) selon la revendication 6, dans lequel une jonction, dans laquelle les substrats d'aluminium (31, 31a, 31b) et le corps massif en aluminium (21, 62, 72, 82, 92, 93) sont liés, comporte un composé à base de Ti-Al, et la jonction est formée sur les protubérances en forme de pilier (32).
EP15814479.0A 2014-07-02 2015-07-02 Élément d'échange de chaleur en aluminium poreux Active EP3165864B1 (fr)

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PCT/JP2015/069095 WO2016002870A1 (fr) 2014-07-02 2015-07-02 Élément d'échange de chaleur en aluminium poreux

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JP6488876B2 (ja) * 2014-05-16 2019-03-27 三菱マテリアル株式会社 多孔質アルミニウム焼結体及び多孔質アルミニウム焼結体の製造方法
JP6477254B2 (ja) * 2014-05-30 2019-03-06 三菱マテリアル株式会社 多孔質アルミニウム複合体及び多孔質アルミニウム複合体の製造方法
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EP3165864A1 (fr) 2017-05-10
CN106662409B (zh) 2020-10-20
US20170153072A1 (en) 2017-06-01
JP6237500B2 (ja) 2017-11-29
WO2016002870A1 (fr) 2016-01-07
JP2016014508A (ja) 2016-01-28
US10598446B2 (en) 2020-03-24
CN106662409A (zh) 2017-05-10

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