EP3067435A1 - Procede de production d'un composant tres resistant en alliage d'aluminure de titane alpha+gamma pour machines a piston et turbines a gaz, en particulier groupes motopropulseurs - Google Patents

Procede de production d'un composant tres resistant en alliage d'aluminure de titane alpha+gamma pour machines a piston et turbines a gaz, en particulier groupes motopropulseurs Download PDF

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Publication number
EP3067435A1
EP3067435A1 EP16153407.8A EP16153407A EP3067435A1 EP 3067435 A1 EP3067435 A1 EP 3067435A1 EP 16153407 A EP16153407 A EP 16153407A EP 3067435 A1 EP3067435 A1 EP 3067435A1
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EP
European Patent Office
Prior art keywords
alloy
component
temperature
phase
forming
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP16153407.8A
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German (de)
English (en)
Other versions
EP3067435B2 (fr
EP3067435B1 (fr
Inventor
Marianne Baumgärtner
Peter Janschek
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Leistritz Turbinentechnik GmbH
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Leistritz Turbinentechnik GmbH
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Application filed by Leistritz Turbinentechnik GmbH filed Critical Leistritz Turbinentechnik GmbH
Priority to PL16153407T priority Critical patent/PL3067435T5/pl
Publication of EP3067435A1 publication Critical patent/EP3067435A1/fr
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Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/16Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of other metals or alloys based thereon
    • C22F1/18High-melting or refractory metals or alloys based thereon
    • C22F1/183High-melting or refractory metals or alloys based thereon of titanium or alloys based thereon
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/26Methods of annealing
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/26Methods of annealing
    • C21D1/30Stress-relieving
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/0068Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for particular articles not mentioned below
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C14/00Alloys based on titanium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C30/00Alloys containing less than 50% by weight of each constituent
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/002Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working by rapid cooling or quenching; cooling agents used therefor
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/02Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working in inert or controlled atmosphere or vacuum
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/16Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of other metals or alloys based thereon

Definitions

  • the invention relates to a method for producing a heavy-duty component of an ⁇ + ⁇ -titanium aluminide alloy for reciprocating engines and gas turbines, in particular aircraft engines.
  • TiAl-based alloys belong to the group of intermetallic materials which have been developed for applications in the field of application temperatures of superalloys. Due to its low density of about 4 g / cm 3 , this material offers considerable potential for saving weight and reducing the loads on moving components, eg blades and disks of gas turbines or components of piston engines, at temperatures up to approx. 700 ° C. State of the art is the investment casting of z. B. turbine blades for aircraft engines. For applications with higher load such. As in high-speed turbines for novel geared turbofan aircraft engines, the properties of the cast structure are no longer sufficient.
  • thermomechanical treatment by means of plastic forming with a defined degree of deformation and subsequent heat treatment, the static and dynamic properties of TiAl alloys can be increased to the required values.
  • TiAl alloys are not conventionally forgeable because of their high resistance to deformation. Therefore, the forming processes at high temperatures in the region of the ⁇ + ⁇ or ⁇ -phase region must be carried out in a protective atmosphere at low forming speeds. In order to achieve the desired final geometry of the forging part id usually several consecutive forging steps are required.
  • the invention is thus the task of specifying a method for producing a highly loaded component of an ⁇ + ⁇ -Titanaluminid-alloy, which is easier to implement compared to previously known methods.
  • the inventive method is characterized by a single-stage, isothermal forming process of the component in the ⁇ -phase region at slow forming speed, wherein a specific TiAl alloy is used, which makes it possible to stabilize the component in the ⁇ -phase region, so that there is the forming can.
  • the alloy contains a corresponding proportion of at least one ⁇ -phase stabilizing element selected from Mo, V, Ta, Cr, Mn, Ni, Cu, Fe or Si, although mixtures thereof can also be used.
  • ⁇ -phase stabilizing elements Mo, V or Ta are used, which can be used individually or as a mixture.
  • the content of the ⁇ -phase stabilizing element is preferably 0.1-2%, in particular 0.8-1.2%. This in particular when Mo, V and / or Ta are used, since they have a particularly high stabilizing property and therefore their content can be kept relatively low.
  • the forming temperature in the ⁇ -phase range is preferably 1070-1250 ° C., wherein as described, the deformation takes place isothermally, that is, that the forming tools are kept at the forming temperature so as not to leave the required narrow temperature window.
  • the logarithmic deformation rate is 10 -3 s -1 to 10 -1 s -1 .
  • the preform used has a volume distribution which varies over the longitudinal axis, ie that a given three-dimensional basic shape is already given, from which the finished component is forged by the single-stage forming according to the invention.
  • This preform is preferably produced by casting, metal injection molding (MIM) or additive processes (3D printing, laser deposition welding, etc.) or a combination of the abovementioned possibilities.
  • forming tools are preferably used from a highly heat-resistant material, preferably from a Mo alloy.
  • the tools are protected during the forming process by an inert atmosphere against oxidation.
  • they are preferably actively heated, for example inductively or by resistance heating.
  • the preform is heated before the forming process, for example in an oven, inductively or by resistance heating.
  • the deformation is followed by a heat treatment of the formed component in order to set the required performance properties and to convert the ⁇ -phase, which is favorable for the transformation, into a fine-lamellar ⁇ + ⁇ -structure by means of a suitable heat treatment.
  • the heat treatment may comprise a recrystallization annealing at a temperature of 1230-1270 ° C.
  • the holding time during the recrystallization annealing is preferably 50-100 min.
  • the recrystallization annealing takes place in the region of the ⁇ / ⁇ transformation temperature. If, as is further provided according to the invention, after the recrystallization annealing, the component is cooled to a temperature of 900-950 ° C. in 120 s or faster, small ⁇ finite pitches of the ⁇ + ⁇ phase occur.
  • a second heat treatment step follows, in which the component is first cooled to room temperature and then heated to a stabilizing or relaxation temperature of 850-950 ° C.
  • the stabilization and relaxation temperature of 850 ° -950 ° C. can also be gone directly from the temperature of 900-950 ° C. which has been reached rapidly after the recrystallization annealing as described above.
  • the preferred holding time at the stabilizing and relaxing temperature, regardless of how it is achieved, is preferably 300-360 min.
  • the component temperature is preferably reduced to a temperature below 300 ° C. with a defined cooling rate.
  • the cooling rate is preferably 0.5-2 K / min, that is, the cooling is relatively slow, which serves to stabilize and relax the structure.
  • the cooling rate is preferably 1.5 K / min.
  • the respective cooling may take place in a liquid, e.g. in oil, or in air or in an inert gas.
  • the invention further relates to a component of an ⁇ + ⁇ -titanium aluminide alloy, in particular for a piston engine, an aircraft engine or a gas turbine, which is produced in a method of the type described.
  • a component may for example be a blade or a disk of a gas turbine or the like.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Health & Medical Sciences (AREA)
  • Child & Adolescent Psychology (AREA)
  • Turbine Rotor Nozzle Sealing (AREA)
  • Powder Metallurgy (AREA)
  • Forging (AREA)
EP16153407.8A 2015-03-09 2016-01-29 Procede de production d'un composant tres resistant en alliage d'aluminure de titane alpha+gamma pour machines a piston et turbines a gaz, en particulier groupes motopropulseurs Active EP3067435B2 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL16153407T PL3067435T5 (pl) 2015-03-09 2016-01-29 Sposób wytwarzania elementu konstrukcyjnego o wysokiej wytrzymałości ze stopu alfa+gamma-glinku tytanu do maszyn tłokowych i turbin gazowych, w szczególności do silników lotniczych

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE102015103422.0A DE102015103422B3 (de) 2015-03-09 2015-03-09 Verfahren zur Herstellung eines hochbelastbaren Bauteils aus einer Alpha+Gamma-Titanaluminid-Legierung für Kolbenmaschinen und Gasturbinen, insbesondere Flugtriebwerke

Publications (3)

Publication Number Publication Date
EP3067435A1 true EP3067435A1 (fr) 2016-09-14
EP3067435B1 EP3067435B1 (fr) 2017-07-26
EP3067435B2 EP3067435B2 (fr) 2021-11-24

Family

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EP16153407.8A Active EP3067435B2 (fr) 2015-03-09 2016-01-29 Procede de production d'un composant tres resistant en alliage d'aluminure de titane alpha+gamma pour machines a piston et turbines a gaz, en particulier groupes motopropulseurs

Country Status (5)

Country Link
US (1) US10196725B2 (fr)
EP (1) EP3067435B2 (fr)
JP (1) JP6200985B2 (fr)
DE (1) DE102015103422B3 (fr)
PL (1) PL3067435T5 (fr)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102015103422B3 (de) 2015-03-09 2016-07-14 LEISTRITZ Turbinentechnik GmbH Verfahren zur Herstellung eines hochbelastbaren Bauteils aus einer Alpha+Gamma-Titanaluminid-Legierung für Kolbenmaschinen und Gasturbinen, insbesondere Flugtriebwerke
CN109312427B (zh) 2016-09-02 2020-12-15 株式会社Ihi TiAl合金及其制造方法
KR101890642B1 (ko) * 2016-12-14 2018-08-22 안동대학교 산학협력단 파괴 인성 및 크리프 저항성이 향상된 Ti-Al-Nb-V계 합금의 제조방법
KR101888049B1 (ko) * 2016-12-14 2018-08-13 안동대학교 산학협력단 파괴 인성 및 크리프 저항성이 향상된 Ti-Al-Nb-Fe계 합금의 제조방법
EP3372700B1 (fr) 2017-03-10 2019-10-09 MTU Aero Engines GmbH Procédé de fabrication d'éléments structuraux en tial forgés
DE102017212082A1 (de) 2017-07-14 2019-01-17 MTU Aero Engines AG Schmieden bei hohen temperaturen, insbesondere von titanaluminiden
DE102018101194A1 (de) 2018-01-19 2019-07-25 Otto Fuchs - Kommanditgesellschaft - Verfahren zum Herstellen eines hoch belastbaren Bauteils aus einem zumindest zweiphasigen metallischen oder intermetallischen Werkstoff
DE102018202723A1 (de) * 2018-02-22 2019-08-22 MTU Aero Engines AG Verfahren zur herstellung eines bauteils aus einer gradierten tial - legierung und entsprechend hergestelltes bauteil
WO2019191450A1 (fr) * 2018-03-29 2019-10-03 Arconic Inc. Alliages d'aluminure de titane, produits en alliage d'aluminure de titane et leurs procédés de fabrication
DE102018209315A1 (de) 2018-06-12 2019-12-12 MTU Aero Engines AG Verfahren zur Herstellung eines Bauteils aus Gamma - TiAl und entsprechend hergestelltes Bauteil
JP7233659B2 (ja) * 2019-03-18 2023-03-07 株式会社Ihi 熱間鍛造用のチタンアルミナイド合金材及びチタンアルミナイド合金材の鍛造方法並びに鍛造体
DE102020214700A1 (de) 2020-11-23 2022-05-25 MTU Aero Engines AG Verfahren zur herstellung eines bauteils aus einer tial – legierung und entsprechend hergestelltes bauteil
DE102021000614A1 (de) 2021-02-08 2022-08-11 Access E.V. Kokille zur rissfreien Herstellung eines Metallgegenstandes mit mindestens einem Hinterschnitt, insbesondere aus intermetallischen Legierungen wie TiAl, FeAl und anderen spröden oder rissanfälligen Werkstoffen, sowie ein entsprechendes Verfahren.
EP4299776A1 (fr) * 2021-04-16 2024-01-03 Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd.) Alliage tial pour forgeage, matériau à base d'alliage tial et procédé de production d'un matériau d'alliage tial
CN113355619B (zh) * 2021-06-04 2022-08-09 西安交通大学 一种阻止锆合金热机械加工开裂的热处理方法
US11807911B2 (en) * 2021-12-15 2023-11-07 Metal Industries Research & Development Centre Heat treatment method for titanium-aluminum intermetallic and heat treatment device therefor
CN115679231B (zh) * 2022-09-16 2024-03-19 中南大学 一种提高钛铝基合金高温强塑性的工艺

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EP2386663A1 (fr) * 2010-05-12 2011-11-16 Böhler Schmiedetechnik GmbH & Co KG Procédé de fabrication d'un composant et composants constitués d'un alliage à base d'aluminium-titane

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US5328530A (en) * 1993-06-07 1994-07-12 The United States Of America As Represented By The Secretary Of The Air Force Hot forging of coarse grain alloys
DE10150674A1 (de) 2000-12-15 2002-07-04 Thyssen Krupp Automotive Ag Verfahren zur Herstellung von hochbelastbaren Bauteilen aus TiAl-Legierungen
DE10150674B4 (de) 2000-12-15 2008-02-07 Leistritz Ag Verfahren zur Herstellung von hochbelastbaren Bauteilen aus TiAl-Legierungen
DE102007051499A1 (de) * 2007-10-27 2009-04-30 Mtu Aero Engines Gmbh Werkstoff für ein Gasturbinenbauteil, Verfahren zur Herstellung eines Gasturbinenbauteils sowie Gasturbinenbauteil
EP2386663A1 (fr) * 2010-05-12 2011-11-16 Böhler Schmiedetechnik GmbH & Co KG Procédé de fabrication d'un composant et composants constitués d'un alliage à base d'aluminium-titane

Also Published As

Publication number Publication date
DE102015103422B3 (de) 2016-07-14
US20160265096A1 (en) 2016-09-15
PL3067435T5 (pl) 2022-03-14
PL3067435T3 (pl) 2018-01-31
EP3067435B2 (fr) 2021-11-24
US10196725B2 (en) 2019-02-05
JP2016166418A (ja) 2016-09-15
EP3067435B1 (fr) 2017-07-26
JP6200985B2 (ja) 2017-09-20

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