EP3269838B1 - Alliage tial thermostable, procédé de production d'un composant constitué d'un alliage tial correspondant, composant constitué d'un alliage tial correspondant - Google Patents
Alliage tial thermostable, procédé de production d'un composant constitué d'un alliage tial correspondant, composant constitué d'un alliage tial correspondant Download PDFInfo
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- EP3269838B1 EP3269838B1 EP16178936.7A EP16178936A EP3269838B1 EP 3269838 B1 EP3269838 B1 EP 3269838B1 EP 16178936 A EP16178936 A EP 16178936A EP 3269838 B1 EP3269838 B1 EP 3269838B1
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- tial alloy
- tial
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- 229910045601 alloy Inorganic materials 0.000 title claims description 80
- 239000000956 alloy Substances 0.000 title claims description 80
- 238000004519 manufacturing process Methods 0.000 title claims description 15
- 229910010038 TiAl Inorganic materials 0.000 claims description 66
- 229910021332 silicide Inorganic materials 0.000 claims description 49
- 239000010936 titanium Substances 0.000 claims description 39
- FVBUAEGBCNSCDD-UHFFFAOYSA-N silicide(4-) Chemical compound [Si-4] FVBUAEGBCNSCDD-UHFFFAOYSA-N 0.000 claims description 26
- 239000011265 semifinished product Substances 0.000 claims description 20
- 239000000047 product Substances 0.000 claims description 19
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 18
- 229910052719 titanium Inorganic materials 0.000 claims description 18
- 229910052710 silicon Inorganic materials 0.000 claims description 14
- 239000010703 silicon Substances 0.000 claims description 14
- 229910021325 alpha 2-Ti3Al Inorganic materials 0.000 claims description 13
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 13
- 229910052782 aluminium Inorganic materials 0.000 claims description 13
- 239000000843 powder Substances 0.000 claims description 13
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 12
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 12
- 229910052796 boron Inorganic materials 0.000 claims description 12
- 229910052799 carbon Inorganic materials 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 12
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 11
- 229910052750 molybdenum Inorganic materials 0.000 claims description 11
- 239000011733 molybdenum Substances 0.000 claims description 11
- 229910052758 niobium Inorganic materials 0.000 claims description 11
- 239000010955 niobium Substances 0.000 claims description 11
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims description 11
- 229910006281 γ-TiAl Inorganic materials 0.000 claims description 9
- 229910052729 chemical element Inorganic materials 0.000 claims description 8
- 238000001816 cooling Methods 0.000 claims description 8
- 238000004090 dissolution Methods 0.000 claims description 8
- 239000012535 impurity Substances 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 8
- 238000001556 precipitation Methods 0.000 claims description 8
- 238000010438 heat treatment Methods 0.000 claims description 7
- 150000001247 metal acetylides Chemical class 0.000 claims description 7
- 239000000126 substance Substances 0.000 claims description 7
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 7
- 229910052721 tungsten Inorganic materials 0.000 claims description 7
- 239000010937 tungsten Substances 0.000 claims description 7
- 238000005266 casting Methods 0.000 claims description 6
- 229910052735 hafnium Inorganic materials 0.000 claims description 5
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims description 5
- 230000015572 biosynthetic process Effects 0.000 claims description 4
- 230000006641 stabilisation Effects 0.000 claims description 4
- 238000011105 stabilization Methods 0.000 claims description 4
- 239000000155 melt Substances 0.000 claims description 3
- 238000004088 simulation Methods 0.000 claims description 3
- 238000004364 calculation method Methods 0.000 claims description 2
- 238000007711 solidification Methods 0.000 claims 3
- 230000008023 solidification Effects 0.000 claims 3
- 229910052845 zircon Inorganic materials 0.000 claims 3
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 claims 3
- 239000002244 precipitate Substances 0.000 claims 2
- 238000005056 compaction Methods 0.000 claims 1
- 238000002844 melting Methods 0.000 claims 1
- 230000008018 melting Effects 0.000 claims 1
- 238000007493 shaping process Methods 0.000 claims 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 11
- 239000000463 material Substances 0.000 description 8
- 241000446313 Lamella Species 0.000 description 6
- 239000013067 intermediate product Substances 0.000 description 6
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 4
- 238000001513 hot isostatic pressing Methods 0.000 description 4
- 229910052726 zirconium Inorganic materials 0.000 description 4
- 238000005242 forging Methods 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 230000002730 additional effect Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical group [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 230000006735 deficit Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000005538 encapsulation Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- -1 for example Inorganic materials 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 238000010310 metallurgical process Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000004663 powder metallurgy Methods 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/16—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of other metals or alloys based thereon
- C22F1/18—High-melting or refractory metals or alloys based thereon
- C22F1/183—High-melting or refractory metals or alloys based thereon of titanium or alloys based thereon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C14/00—Alloys based on titanium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C30/00—Alloys containing less than 50% by weight of each constituent
Definitions
- the present invention relates to a highly heat-resistant TiAl alloy and a method for producing a component from such a TiAl alloy as well as a corresponding component.
- TiAl alloys which have titanium and aluminum as the main components - i.e. as chemical elements with the highest proportions in the composition - are used as materials for moving parts in engines and gas turbines, e.g. as Blades, used.
- This alloy is adjusted during production so that the material has a ⁇ -Ti phase and / or B2-Ti phase at room temperature, both of which will be referred to below as the ⁇ phase for short.
- the ⁇ - phase serves to avoid coarsening of the ⁇ - Ti grains at high temperatures at which in TiAl alloys with a correspondingly high aluminum part a substantial part of the material can be present as an ⁇ - Ti phase with high aluminum solubility, in order to achieve a homogeneous structure that is favorable for the ductility and creep resistance of the material with uniform, not too coarse microstructures.
- the ⁇ - phase stabilizes the grain boundaries of the ⁇ - Ti grains and thus counteracts any coarsening.
- TiAl alloys are from the EP2851445A1 as well as from the article " Silicon distribution and silicide precipitation during annealing in an advanced multiphase ⁇ -TiAl based alloy ", Klein, Thomas et al, ACTA MATERIALIA, ELSEVIER, OXFORD, GB, Vol. 110, March 23, 2016 (2016-03-23), pp 236-245 " known.
- the invention proposes to essentially dispense with the ⁇ phase to hinder the grain growth of ⁇ -Ti grains at high temperatures and that To hinder the growth of the ⁇ -Ti grains at high temperatures through the precipitation of silicides.
- the term “essentially without the ⁇ phase” or “essentially no ⁇ phase” means in this context that the ⁇ phase in the finished alloy is less than 5% by volume, preferably less than 2% by volume. -% and more preferably 0% by volume.
- the invention proposes to select a TiAl alloy which, in addition to the main alloy components titanium and aluminum, has at least niobium, molybdenum, carbon, boron and silicon and also has zirconium and / or tungsten, with silicon being provided for the formation of the silicides which the The aim is to hinder grain growth of the ⁇ -Ti grains at correspondingly high temperatures in order to counteract coarsening of the microstructure.
- the TiAl alloy should be selected in such a way that, given the chosen chemical composition of the TiAl alloy, there is an ⁇ -phase temperature range in whose temperature range there is essentially an ⁇ -Ti phase with silicides.
- a corresponding TiAl alloy which is essentially in the form of ⁇ -Ti in a specific temperature interval for the given chemical composition, can be produced by means of simulation calculations with appropriate simulation programs that take into account a large number of thermodynamic data, and / or by producing appropriate Test melts or test alloys and metallographic examination of the test alloys are determined.
- a corresponding TiAl alloy with a certain chemical composition which has an ⁇ -phase temperature range in which the corresponding TiAl alloy is essentially single-phase as an ⁇ -Ti phase, with only silicides additionally being present in the temperature range
- such a TiAl alloy with the selected chemical composition is melted and then cast in a further step into a semifinished product or atomized into TiAl powder, the semifinished product already being a near-net-shape intermediate product or a starting product for further forming into a Can be a preliminary product.
- the cast semi-finished product can be formed into a preliminary product by forging.
- the TiAl powder can be used for further processing in powder metallurgical manufacturing processes, such as generative manufacturing processes, or compressed, joined and / or shaped by hot isostatic pressing (HIP) or the like in order to also create a preliminary product.
- powder metallurgical manufacturing processes such as generative manufacturing processes, or compressed, joined and / or shaped by hot isostatic pressing (HIP
- the cast semifinished product or a preliminary product produced from the semifinished product or from the TiAl powder is then cooled from a silicide start temperature in such a way that silicides can separate out in order to carry out precipitation stabilization.
- the cooling from the silicide start temperature can take place, for example, directly after the casting of the semifinished product when the casting is being cooled, or, if the semifinished product is unshaped after casting by hot forming into a preliminary product, by cooling from the forming temperature.
- the preliminary product can be heated to a silicide start temperature after its production and the intermediate product is cooled from the silicide start temperature in such a way that the desired silicides are eliminated.
- the pre-product produced by the powder can also be transferred to a Bred silicide start temperature and cooled by this in such a way that silicides can be excreted.
- the intermediate product can be cooled from a temperature already present during production, such as the HIP temperature, in such a way that silicide is precipitated.
- the HIP temperature is the silicide start temperature. In order to enable the silicides to precipitate, the cooling from the silicide start temperature must take place slowly enough to allow the silicides to precipitate.
- a heat treatment of the precipitation-stabilized semi-finished product or pre-product is carried out in the ⁇ -phase temperature range in which the semi-finished product or pre-product is essentially present as an ⁇ -Ti phase with precipitated silicides, the silicides having a coarsening of the Counteracting ⁇ - Ti grains.
- the existing ⁇ phase largely or completely dissolves.
- the heat treatment in the ⁇ -phase temperature range can be carried out for a period of 0.5 to 2 hours, in particular from 0.5 to 1 hour, the cooling being carried out in such a way that globular colonies of lamellae form from the ⁇ -Ti grains from ⁇ 2 - Ti 3 Al and ⁇ - TiAl, the silicide precipitations previously generated during the precipitation stabilization of the material also being present. This results in a microstructure that has an excellent, balanced profile of properties with improved creep resistance.
- the silicide start temperature to which a semi-finished product after casting or a pre-product formed after casting or a pre-product manufactured by a powder metallurgical process is heated during precipitation stabilization of the TiAl alloy can be at a temperature above a silicide dissolution temperature of the material, so that the Silicide start temperature the silicon is largely in solution in order to then enable a homogeneous precipitation of the silicides when the semi-finished product or intermediate product cools. That This coarser structure can be refined by forging, whereby fine silicides can be excreted by targeted cooling from the forging temperature.
- the silicide start temperature can also be below a silicide dissolution temperature if the silicide start temperature is the temperature during a deformation or compacting of a semi-finished product or a preliminary product.
- a temperature can be set well below the silicide dissolution temperature, so that silicides can form.
- the ⁇ -phase temperature range in which the subsequent heat treatment of the precipitation-stabilized semi-finished product or intermediate product is carried out can be below a silicide dissolution temperature of the TiAl alloy and above a ⁇ -solvus temperature at which the entire ⁇ -TiAl phase in ⁇ - Ti phase goes into solution, so that it is ensured that in the ⁇ phase temperature range, apart from the silicides present, essentially exclusively ⁇ Ti phase is present.
- the proportion of the ⁇ -Ti phase in the ⁇ -phase temperature range can be in the range of 95% by volume or more, in particular 98% by volume or more.
- a corresponding TiAl alloy which has a suitable ⁇ -phase temperature range with a sufficiently high silicide dissolution temperature and a ⁇ -solvus temperature at least 15 K, in particular at least 20 K lower, at which ⁇ -TiAl components are no longer present, but exclusively
- the ⁇ -Ti phase has a chemical composition with 42 to 48 at.% aluminum, preferably 43 to 45 at.% aluminum, 3 to 5 at.% niobium, preferably 3.5 to 4.5 at.% niobium, 0, 05 to 1 at.% Molybdenum, preferably 0.85 to 0.95 at.% Molybdenum, 0.2 to 2.2 at.% Silicon, preferably 0.25 to 0.35 at.% Silicon, 0.2 to 0.4 at.% Carbon, preferably 0.25 to 0.35 at.% Carbon, 0.05 to 0.2 at.% Boron, preferably 0.05 to 0.15 at.% Boron as well as titanium and unavoidable impurities on, wherein titanium is provided in an amount that the sum of the chemical
- Alternatives according to the invention of the TiAl alloy which are produced in particular by the production method described above or components made from this TiAl alloy, comprise at least one of the elements from a group comprising tungsten, zirconium and hafnium. With such alloys, the structures described can be achieved at room temperature or in the ⁇ -phase temperature range. In addition, the alloy components mentioned can give the alloys or the components produced with them additional properties.
- the TiAl alloy contains, in addition to titanium and unavoidable impurities, 43.5 to 45 at.% Aluminum, 3.5 to 4.5 at.% Niobium, 0.1 to 0.5 at.% Molybdenum, 0, 4 to 1 at.% Tungsten, 0.25 to 0.35 at.% Silicon, 0.25 to 0.35 at.% Carbon and 0.05 to 0.15 at.% Boron, the alloy having precisely this composition may have or may include additional alloy elements. In any case, the proportion of titanium is chosen so that the sum of the chemical elements of the alloy is 100 at.%.
- the TiAl alloy contains, in addition to titanium and unavoidable impurities, 43.5 to 45 at.% Aluminum, 3.5 to 4.5 at.% Niobium, 0.85 to 0.95 at.% Molybdenum, 0 , 1 to 3 at.% Zirconium, 0.25 to 2.2 at.% Silicon, 0.25 to 0.35 at.% Carbon and 0.05 to 0.15 at.% Boron, the alloy being exactly these May have composition or may comprise additional further alloying elements.
- the proportion of titanium is chosen so that the sum of the chemical elements of the alloy is 100 at.%.
- the TiAl alloy contains, in addition to titanium and unavoidable impurities, 46 to 48 at.% Aluminum, 3.5 to 5 at.% Niobium, 0.1 to 0.5 at.% Molybdenum, 0.4 to 1 , 8 at% tungsten, 0.1 to 3 at.% Zirconium, 0.35 to 2.2 at.% Silicon, 0.25 to 0.35 at.% Carbon and 0.05 to 0.15 at.% Boron, wherein the alloy can have precisely this composition or can comprise an additional further alloy element, namely hafnium.
- the proportion of titanium is chosen so that the sum of the chemical elements of the alloy is 100 at.%.
- boron and carbon can both contribute to solid solution strengthening of the alloy and also produce borides and / or carbides, which positively affect the microstructure with regard to a homogeneous microstructure with suitable colony sizes and lamellar thicknesses or spacings of the ⁇ 2 - Ti 3 Al - and ⁇ - TiAl - lamellae can influence.
- the semi-finished product or intermediate product heat-treated in the ⁇ -phase temperature range can be subjected to a second heat treatment at a temperature below a ⁇ -solvus temperature of Material are subjected to influence the formation of the lamellae from ⁇ 2 - Ti 3 Al and ⁇ - TiAl from the ⁇ - Ti grains and to set the desired lamella thicknesses or spacings.
- a corresponding TiAl alloy or a component made therefrom can thus have less than 5% by volume ⁇ phase and preferably no ⁇ phase at all in the TiAl alloy at operating temperatures of up to 1000 ° C., so that the creep resistance is improved.
- the globular colonies with lamellae made of ⁇ 2 - Ti 3 Al and ⁇ - TiAl can form 95% by volume or more, in particular 98% by volume or more, of the TiAl alloy at room temperature.
- the remainder can be formed by silicides, carbides and / or borides, the TiAl alloy being able to contain up to 5% by weight, preferably up to 2% by weight, of silicides, carbides and / or borides, their mean or maximum grain size can be less than or equal to 5 ⁇ m.
- the globular colonies of ⁇ 2 - Ti 3 Al and ⁇ - TiAl lamellae can have an average or maximum size of 50 to 300 ⁇ m, in particular 100 to 200 ⁇ m, the average lamellae spacing being in the range from 10 nm to 1 ⁇ m can.
- the lamella spacing is understood here as the distance between lamellae in the same phase, i.e. the distance from one ⁇ -TiAl lamella to the next ⁇ -TiAl lamella or the distance from one ⁇ 2 -Ti 3 Al lamella to the next ⁇ 2 -Ti 3 Al lamella.
- the attached drawing shows in a purely schematic manner the structure of a TiAl alloy according to the invention or a component made from a TiAl alloy.
- a structure can be formed through the corresponding heat treatments in the ⁇ -phase temperature range and a subsequent second heat treatment at a temperature below the ⁇ -solvus temperature of the TiAl alloy, as shown in is shown in the accompanying drawing.
- the globular colonies 1 made up of ⁇ 2 - Ti 3 Al lamellae 2 and ⁇ - TiAl lamellae 3 are equiaxed with similar sizes and spherical shapes, with silicides 4 and borides 5 and carbides 6 having separated at the borders of the colonies 1.
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Claims (12)
- Alliage TiAI présentant, à température ambiante, une microstructure comprenant des colonies globulaires (1) constituées de lamelles de α2-Ti3Al (2) et de γ-TiAl (3) ainsi que des précipités de siliciure (4), la phase β dans l'alliage représentant moins de 5 % en volume et l'alliage contenant l'une des compositions suivantes :(i) 43,5 à 45 % en atome d'aluminium,3,5 à 4,5 % en atome de niobium,0,1 à 0,5 % en atome de molybdène,0,4 à 1 % en atome de tungstène0,25 à 0,35 % en atome de silicium,0,25 à 0,35 % en atome de carbone,0,05 à 0,15 % en atome de bore,0 à 3,5 % en atome de zircon,0 à 0,3 % en atome de hafnium,des impuretés inévitables et
du titane, le titane étant prévu en une quantité telle que la somme des proportions des éléments chimiques contenus donne 100 % en atome ;(ii) 43,5 à 45 % en atome d'aluminium,3,5 à 4,5 % en atome de niobium,0,85 à 0,95 % en atome de molybdène,0,1 à 3 % en atome de zircon0,25 à 2,2 % en atome de silicium,0,25 à 0,35 % en atome de carbone,0,05 à 0,15 % en atome de bore,0 à 2,0 % en atome de tungstène,0 à 0,3 % en atome de hafnium,des impuretés inévitables et
du titane, le titane étant prévu en une quantité telle que la somme des proportions des éléments chimiques contenus donne 100 % en atome ;(iii) 46 à 48 % en atome d'aluminium,3,5 à 5 % en atome de niobium,0,1 à 0,5 % en atome de molybdène,0,4 à 1,8 % en atome de tungstène0,1 à 3 % en atome de zircon0,35 à 2,2 % en atome de silicium,0,25 à 0,35 % en atome de carbone,0,05 à 0,15 % en atome de bore,0 à 0,3 % en atome de hafnium,des impuretés inévitables et
du titane, le titane étant prévu en une quantité telle que la somme des proportions des éléments chimiques contenus donne 100 % en atome. - Procédé permettant la fabrication d'un composant à partir d'un alliage TiAl selon la revendication 1, comprenant les étapes suivantes :- sélectionner un alliage TiAl qui comprend une composition chimique de l'alliage TiAl selon la revendication 1, et qui est présent dans la composition chimique de l'alliage TiAl à sélectionner dans une plage de température de phase α dans la phase α-Ti avec des siliciures,- faire fondre l'alliage TiAl,- mouler l'alliage TiAl en un demi-produit ou atomiser l'alliage TiAl en poudre,- stabiliser par précipitation le demi-produit ou un pré-produit fabriqué à partirdu demi-produit ou de la poudre par refroidissement du demi-produit ou du pré-produit à une température de départ de siliciure de telle sorte que les siliciures sont précipités,- traiter thermiquement le demi-produitou le pré-produit stabilisé par précipitation dans la plage de température de phase α, dans laquelle des précipités de siliciure (4) sont présents, pendant 0,5 à 2 heures et refroidir afin que des colonies globulaires (1) soient constituées de lamelles de α2-Ti3Al (2) et de γ-TiAl (3).
- Procédé selon la revendication 2,
dans lequel
la stabilisation par précipitation a lieu directement lors de la solidification de la masse fondue ou lors du refroidissement après compactage ou transformation et/ou la température de départ de siliciure est supérieure ou inférieure à une température de dissolution de siliciure. - Procédé selon l'une des revendications 2 à 3,
dans lequel
la plage de température de phase α est inférieure à une température de dissolution de siliciure et supérieure à une température de gamma solvus et comprend de préférence une plage d'au moins 15 K, en particulier d'au moins 20 K. - Procédé selon l'une des revendications 2 à 4,
dans lequel
la plage de température de phase α, une température de dissolution de siliciure et/ou une température de gamma solvus de l'alliage TiAl est déterminée pardes calculs de simulation et/ou par des fusions d'essai et des examens métallographiques. - Procédé selon l'une des revendications 2 à 5,
dans lequel
l'alliage TiAl est choisi de telle sorte que l'alliage TiAl présente une solidification péritectique avec la formation de phase α-Ti ou une solidification avec une formation de phase β. - Procédé selon l'une des revendications 2 à 6,
dans lequel
le demi-produit ou le pré-produit traité thermiquement est soumis à un second traitement thermique à une température inférieure à une température de gamma solvus pendant une période de 2 heures à 24 heures. - Composant constitué d'un alliage TiAl selon la revendication 1, de préférence pour une machine à écoulement de fluide, dans lequel l'alliage TiAl présente moins de 5 % en volume de phase β à des températures de fonctionnement allant jusqu'à 900 °C et les colonies globulaires présentent une taille moyenne ou maximale de 50 à 300 µm.
- Composant selon la revendication 8,
dans lequel
l'alliage TiAl ne présente pas de phase β à des températures de fonctionnement allant jusqu'à 900 °C. - Composant selon l'une des revendications 8 à 9,
dans lequel
les colonies globulaires constituées de lamelles de α2-Ti3Al et de γ-TiAl forment 95 % en volume ou plus, de préférence 98 % en volume ou plus, de l'alliage TiAl. - Composant selon l'une des revendications 8 à 10,
dans lequel
l'alliage TiAl contient jusqu'à 5 % en poids, de préférence jusqu'à 2 % en poids, de siliciures, carbures et/ou borures, la granulométrie moyenne ou maximale des siliciures, carbures et/ou borures étant inférieure ou égale à 5 µm, en particulier le diamètre étant inférieur ou égal à 5 µm selon un équivalent de surface circulaire. - Composant selon l'une des revendications 8 à 11,
dans lequel
les colonies globulaires constituées de lamelles de α2-Ti3Al et de γ-TiAl présentent une taille moyenne ou maximale de 100 à 200 µm et/ou l'espacement moyen des lamelles est dans la plage de 10 nm à 1 µm.
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP16178936.7A EP3269838B1 (fr) | 2016-07-12 | 2016-07-12 | Alliage tial thermostable, procédé de production d'un composant constitué d'un alliage tial correspondant, composant constitué d'un alliage tial correspondant |
ES16178936T ES2891724T3 (es) | 2016-07-12 | 2016-07-12 | Aleación de TiAl resistente a altas temperaturas, método para fabricar un componente de una aleación de TiAl correspondiente y componente de una aleación de TiAl correspondiente |
US15/644,927 US10590520B2 (en) | 2016-07-12 | 2017-07-10 | High temperature resistant TiAl alloy, production method therefor and component made therefrom |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP16178936.7A EP3269838B1 (fr) | 2016-07-12 | 2016-07-12 | Alliage tial thermostable, procédé de production d'un composant constitué d'un alliage tial correspondant, composant constitué d'un alliage tial correspondant |
Publications (2)
Publication Number | Publication Date |
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EP3269838A1 EP3269838A1 (fr) | 2018-01-17 |
EP3269838B1 true EP3269838B1 (fr) | 2021-09-01 |
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EP16178936.7A Active EP3269838B1 (fr) | 2016-07-12 | 2016-07-12 | Alliage tial thermostable, procédé de production d'un composant constitué d'un alliage tial correspondant, composant constitué d'un alliage tial correspondant |
Country Status (3)
Country | Link |
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US (1) | US10590520B2 (fr) |
EP (1) | EP3269838B1 (fr) |
ES (1) | ES2891724T3 (fr) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3326746A1 (fr) * | 2016-11-25 | 2018-05-30 | Helmholtz-Zentrum Geesthacht Zentrum für Material- und Küstenforschung GmbH | Procédé pour assembler et/ou réparer des substrats d'alliages d'aluminure de titane |
DE112019007062T5 (de) * | 2019-05-23 | 2021-12-16 | Mitsubishi Heavy Industries Engine & Turbocharger, Ltd. | Verfahren zur herstellung eines tial-legierungsteils und system zur herstellung eines tial-legierungsteils |
WO2020235200A1 (fr) * | 2019-05-23 | 2020-11-26 | 株式会社Ihi | Alliage tial et son procédé de production |
CN113481444B (zh) * | 2021-07-05 | 2022-04-08 | 四川大学 | 一种包晶凝固铸态TiAl合金细晶组织调控方法 |
US11807911B2 (en) * | 2021-12-15 | 2023-11-07 | Metal Industries Research & Development Centre | Heat treatment method for titanium-aluminum intermetallic and heat treatment device therefor |
CN116024457A (zh) * | 2023-01-04 | 2023-04-28 | 中国航空制造技术研究院 | 一种抗拉强度大于750MPa的高强TiAl合金及其增材制造方法 |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
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US4229216A (en) | 1979-02-22 | 1980-10-21 | Rockwell International Corporation | Titanium base alloy |
DE102006052650A1 (de) | 2006-01-17 | 2007-07-19 | Daimlerchrysler Ag | Ventil aus einer α/α2-Titanlegierung und Verfahren zu seiner Herstellung |
DE102007051499A1 (de) | 2007-10-27 | 2009-04-30 | Mtu Aero Engines Gmbh | Werkstoff für ein Gasturbinenbauteil, Verfahren zur Herstellung eines Gasturbinenbauteils sowie Gasturbinenbauteil |
GB2467312B (en) | 2009-01-28 | 2013-06-26 | Mark Labudek Design Ltd | Titanium alloy, a method of producing the alloy and an article made of the alloy |
US20120041276A1 (en) | 2010-08-13 | 2012-02-16 | Delcina Doreus | All in one medical monitor |
WO2012041276A2 (fr) * | 2010-09-22 | 2012-04-05 | Mtu Aero Engines Gmbh | Alliage tial résistant à la chaleur |
US10119178B2 (en) | 2012-01-12 | 2018-11-06 | Titanium Metals Corporation | Titanium alloy with improved properties |
ES2747155T3 (es) * | 2013-09-20 | 2020-03-10 | MTU Aero Engines AG | Aleación de TiAl resistente a la fluencia |
EP3553193A1 (fr) * | 2014-07-14 | 2019-10-16 | MTU Aero Engines GmbH | Alliage tial à haute température riche en al |
-
2016
- 2016-07-12 EP EP16178936.7A patent/EP3269838B1/fr active Active
- 2016-07-12 ES ES16178936T patent/ES2891724T3/es active Active
-
2017
- 2017-07-10 US US15/644,927 patent/US10590520B2/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
ES2891724T3 (es) | 2022-01-31 |
US20180016668A1 (en) | 2018-01-18 |
EP3269838A1 (fr) | 2018-01-17 |
US10590520B2 (en) | 2020-03-17 |
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